Abstract: A Friction stir welding tool is a critical component to
the success of the process. The tool typically consists of a rotating
round shoulder and a threaded cylindrical pin that heats the work
piece, mostly by friction, and moves the softened alloy around it to
form the joint. In this research work, an attempt has been made to
investigate the relationship between FSW variables mainly tool
profile, rotating speed, welding speed and the mechanical properties
(tensile strength, yield strength, percentage elongation, and micro
hardness) of friction stir welded aluminum alloy 5083 joints. From
the experimental details, it can be assessed that the joint produced by
using Triflute profile tool has contribute superior mechanical and
structural properties as compared to Tapered unthreaded & Threaded
tool for 1000rpm.
Abstract: In the present work, forming limit diagrams and strain
distribution profile diagrams for extra deep drawing steel at room and
elevated temperatures have been determined experimentally by
conducting stretch forming experiments by using designed and
fabricated warm stretchforming tooling setup. With the help of
forming Limit Diagrams (FLDs) and strain, distribution profile
diagrams the formability of Extra Deep Drawing steel has been
analyzed and co-related with mechanical properties like strain
hardening COEFFICIENT (n) and normal anisotropy (r−). Mechanical
properties of EDD steel from room temperature to 4500C were
determined and discussed the impact of temperature on the properties
like work hardening exponent (n) anisotropy (r-) and strength
coefficient of the material. In addition, the fractured surfaces after
stretching have undergone the some metallurgical investigations and
attempt has been made to co-relate with the formability of EDD steel
sheets. They are co-related and good agreement with FLDs at various
temperatures.
Abstract: Hard coatings are widely used in cutting and forming
tool industries. Titanium Nitride (TiN) possesses good hardness,
strength, and corrosion resistance. The coating properties are
influenced by many process parameters. The coatings were deposited
on steel substrate by changing the process parameters such as
substrate temperature, nitrogen flow rate and target power in a D.C
planer magnetron sputtering. The structure of coatings were analysed
using XRD. The hardness of coatings was found using Micro
hardness tester. From the experimental data, a regression model was
developed and the optimum response was determined using Response
Surface Methodology (RSM).
Abstract: This experimental study consists of a characterization
of epoxy grout where an amount of 2% of graphene nanoplatelets
particles were added to commercial epoxy resin to evaluate their
behavior regarding neat epoxy resin. Compressive tests, tensile tests
and flexural tests were conducted to study the effect of graphene
nanoplatelets on neat epoxy resin. By comparing graphene-based and
neat epoxy grout, there is no significant increase of strength due to
weak interface in the graphene nanoplatelets/epoxy composites.
From this experiment, the tension and flexural strength of graphenebased
epoxy grouts is slightly lower than ones of neat epoxy grout.
Nevertheless, the addition of graphene has produced more consistent
results according to a smaller standard deviation of strength.
Furthermore, the graphene has also improved the ductility of the
grout, hence reducing its brittle behaviour. This shows that the
performance of graphene-based grout is reliably predictable and able
to minimise sudden rupture. This is important since repair design of
damaged pipeline is of deterministic nature.
Abstract: Polymeric composites are being increasingly used as
repair material for repairing critical infrastructures such as building,
bridge, pressure vessel, piping and pipeline. Technique in repairing
damaged pipes is one of the major concerns of pipeline owners.
Considerable researches have been carried out on the repair of
corroded pipes using composite materials. This article attempts a
short review of the subject matter to provide insight into various
techniques used in repairing corroded pipes, focusing on a wide range
of composite repair systems. These systems including pre-cured
layered, flexible wet lay-up, pre-impregnated, split composite sleeve
and flexible tape systems. Both advantages and limitations of these
repair systems were highlighted. Critical technical aspects have been
discussed through the current standards and practices. Research gaps
and future study scopes in achieving more effective design
philosophy are also presented.
Abstract: Low density polyethylene (LDPE) nanocomposites
with 3, 5 and 7 wt. % cobalt ferrite (CoFe2O4) nanopowder fabricated
with extrusion mixing and followed up by hot press to reach compact
samples. The transmission/reflection measurements were carried out
with a network analyzer in the frequency range of 8-12 GHz. By
increasing the percent of CoFe2O4 nanopowder, reflection loss (S11)
increases, while transferring loss (S21) decreases. Reflectivity (R)
calculations made using S11 and S21. Increase in percent of CoFe2O4
nanopowder up to 7 wt. % in composite leaded to higher reflectivity
amount, and revealed that increasing the percent of CoFe2O4
nanopowder up to 7 wt. % leads to further microwave absorption in
8-12 GHz range.
Abstract: Nanofibers are defined as fibers with diameters less
than 100 nanometers. In this study, behaviours of activated carbon
nanofiber (ACNF), carbon nanofiber (CNF), polyacrylonitrile/ carbon
nanotube (PAN/CNT), polyvinyl alcohol/nanosilver (PVA/Ag) in
proton exchange membrane (PEM) fuel cells are investigated
experimentally. This material was used as gas diffusion layer (GDL)
in PEM fuel cells. In this study, the electrical conductivities of
nanofiber and nanofiber/nanoparticles have been studied to
understand their effects on PEM fuel cell performance. According to
the experimental results, the maximum electrical conductivity
performance of the fuel cell with nanofiber was found to be at
PVA/Ag (at UConn condition). The electrical conductivities of CNF,
ACNF, PAN/CNT are lower for PEM. The resistance of cell with
PVA/Ag is lower than the resistance of cell with PAN/CNT, ACNF,
CNF.
Abstract: Electro-osmosis in clayey soils and sediments, for
purposes of clay consolidation, dewatering, or cleanup, and electro
injection in porous media is widespread recent decades. It is
experimentally found that the chemical properties of porous media
especially PH change the characteristics of media. Electro-osmotic
conductivity is a function of soil and grout material chemistry,
altering with time. Many numerical approaches exist to simulate the
of electro kinetic flow rate considering chemical changes. This paper
presents a simplified analytical solution for constant flow rate based
on varying electro osmotic conductivity and time dependent viscosity
for injection of colloidal silica.
Abstract: In this current contribution, authors are dedicated to
investigate influence of the crystal lamellae orientation on
electromechanical behaviors of relaxor ferroelectric Poly
(vinylidene fluoride –trifluoroethylene -chlorotrifluoroethylene)
(P(VDF-TrFE-CTFE)) films by control of polymer microstructure,
aiming to picture the full map of structure-property relationship. In
order to define their crystal orientation films, terpolymer films were
fabricated by solution-casting, stretching and hot-pressing process.
Differential scanning calorimetry, impedance analyzer, and tensile
strength techniques were employed to characterize crystallographic
parameters, dielectric permittivity, and elastic Young’s modulus
respectively. In addition, large electrical induced out-of-plane
electrostrictive strain was obtained by cantilever beam mode.
Consequently, as-casted pristine films exhibited surprisingly high
electrostrictive strain 0.1774% due to considerably small value of
elastic Young’s modulus although relatively low dielectric
permittivity. Such reasons contributed to large mechanical elastic
energy density. Instead, due to 2 folds increase of elastic Young’s
modulus and less than 50% augmentation of dielectric constant, fullycrystallized
film showed weak electrostrictive behavior and
mechanical energy density as well. And subjected to mechanical
stretching process, Film C exhibited stronger dielectric constant and
out-performed electrostrictive strain over Film B because edge-on
crystal lamellae orientation induced by uniaxially mechanical stretch.
Hot-press films were compared in term of cooling rate. Rather large
electrostrictive strain of 0.2788% for hot-pressed Film D in
quenching process was observed although its dielectric permittivity
equivalent to that of pristine as-casted Film A, showing highest
mechanical elastic energy density value of 359.5 J/m3. In hot-press
cooling process, dielectric permittivity of Film E saw values at 48.8
concomitant with ca.100% increase of Young’s modulus. Films with
intermediate mechanical energy density were obtained.
Abstract: The rheological response of blends obtained from
quaternized polysulfone and polyvinyl alcohol in N-methyl-2-
pyrrolidone as against structural peculiarity of polymers from the
blend, composition of polymer mixtures, as well as the types of
interactions were investigated. Results show that the variation of
polyvinyl alcohol composition in the studied system determines
changes of the rheological properties, suggesting that the PVA acts as
a plasticizer. Consequently, rheological behavior of complex system,
described by the nonlinear flow curve, indicates the impact of
polyvinil alcohol content to polysulfone solution, in order to facilitate
the subsequently preparation of bioactive membranes.
Abstract: We have aimed to produce a self-cleaning transparent
polymer coating with polyurethane (PU) matrix as the latter is highly
solvent, chemical and weather resistant having good mechanical
properties. Nano-silica modified by 1H, 1H, 2H, 2Hperflurooctyltriethoxysilane
was incorporated into the PU matrix for
attaining self-cleaning ability through hydrophobicity. The
modification was confirmed by particle size analysis and scanning
electron microscopy (SEM). Thermo-gravimetric (TGA) studies were
carried to ascertain the grafting of silane onto the silica. Several
coating formulations were prepared by varying the silica loading
content and compared to a commercial equivalent. The effect of
dispersion and the morphology of the coated films were assessed by
SEM analysis. All coating standardized tests like solvent resistance,
adhesion, flexibility, acid, alkali, gloss etc. have been performed as
per ASTM standards. Water contact angle studies were conducted to
analyze the hydrophobic character of the coating. In addition, the
coatings were also subjected to salt spray and accelerated weather
testing to analyze the durability of the coating.
Abstract: Some of the main causes for degradation of polymeric materials are thermal aging, hydrolysis, oxidation or chemical degradation by acids, alkalis or water. The first part of this paper provides a brief summary of advances in technology, methods and specification of composite materials for relining as a rehabilitation technique for sewage systems. The second part summarizes an investigation on frequently used composite materials for relining in Sweden, the rubber filled epoxy composite and reinforced polyester composite when they were immersed in deionized water or in dry conditions, and elevated temperatures up to 80°C in the laboratory. The tests were conducted by visual inspection, microscopy, Dynamic Mechanical Analysis (DMA), Differential Scanning Calorimetry (DSC) as well as mechanical testing, three point bending and tensile testing.
Abstract: Microstructure and mechanical properties of AZ91D
Mg alloys for nonflammable use, containing Ca and Y, were
investigated in this study. Solid solution treatment of AZ91D Mg alloy
with Ca and Y was successfully conducted at 420oC and
supersaturated microstructure with almost all beta phases resolved into
matrix was obtained. After solid solution treatment, the alloy was
annealed at temperatures of 180 and 200oC for time intervals from 1
min to 48 hrs and hardness of each condition was measured by
micro-Vickers method. Peak aging conditions were deduced from the
results as at the temperature of 200oC for 10 hrs. Hot rolling was also
carried out at 400oC by the reduction ratio of 0.6 through 5 passes
followed by recrystallization treatment. Tensile and compressive
properties were measured at room temperature on the specimens of
each process, i.e. as-cast, solution treatment, hot rolling, and
recrystallization.
Abstract: Magnetic Resonance Imaging Contrast Agents
(MRI-CM) are significant in the clinical and biological imaging as
they have the ability to alter the normal tissue contrast, thereby
affecting the signal intensity to enhance the visibility and detectability
of images. Superparamagnetic Iron Oxide (SPIO) nanoparticles,
coated with dextran or carboxydextran are currently available for
clinical MR imaging of the liver. Most SPIO contrast agents are
T2 shortening agents and Resovist (Ferucarbotran) is one of a
clinically tested, organ-specific, SPIO agent which has a low
molecular carboxydextran coating. The enhancement effect of
Resovist depends on its relaxivity which in turn depends on factors
like magnetic field strength, concentrations, nanoparticle properties,
pH and temperature. Therefore, this study was conducted to
investigate the impact of field strength and different contrast
concentrations on enhancement effects of Resovist. The study
explored the MRI signal intensity of Resovist in the physiological
range of plasma from T2-weighted spin echo sequence at three
magnetic field strengths: 0.47 T (r1=15, r2=101), 1.5 T (r1=7.4,
r2=95), and 3 T (r1=3.3, r2=160) and the range of contrast
concentrations by a mathematical simulation. Relaxivities of r1 and r2
(L mmol-1 Sec-1) were obtained from a previous study and the selected
concentrations were 0.05, 0.06, 0.07, 0.08, 0.09, 0.1, 0.2, 0.3, 0.4, 0.5,
0.6, 0.7, 0.8, 0.9, 1.0, 2.0, and 3.0 mmol/L. T2-weighted images were
simulated using TR/TE ratio as 2000 ms /100 ms. According to the
reference literature, with increasing magnetic field strengths, the
r1 relaxivity tends to decrease while the r2 did not show any
systematic relationship with the selected field strengths. In parallel,
this study results revealed that the signal intensity of Resovist at lower
concentrations tends to increase than the higher concentrations. The
highest reported signal intensity was observed in the low field strength
of 0.47 T. The maximum signal intensities for 0.47 T, 1.5 T and 3 T
were found at the concentration levels of 0.05, 0.06 and 0.05 mmol/L,
respectively. Furthermore, it was revealed that, the concentrations
higher than the above, the signal intensity was decreased
exponentially. An inverse relationship can be found between the field
strength and T2 relaxation time, whereas, the field strength was
increased, T2 relaxation time was decreased accordingly. However,
resulted T2 relaxation time was not significantly different between
0.47 T and 1.5 T in this study. Moreover, a linear correlation of
transverse relaxation rates (1/T2, s–1) with the concentrations of
Resovist can be observed. According to these results, it can conclude
that the concentration of SPIO nanoparticle contrast agents and the
field strengths of MRI are two important parameters which can affect the signal intensity of T2-weighted SE sequence. Therefore, when MR
imaging those two parameters should be considered prudently.
Abstract: This paper investigates the application of metallic
coatings on high fiber volume fraction carbon/epoxy polymer matrix
composites. For the grip of the metallic layer, a method of modifying
the surface of the composite by introducing a mixture of copper and
steel powder (filler powders) which can reduce the impact of thermal
spray particles. The powder was introduced to the surface at the time
of the forming. Arc spray was used to project the zinc coating layer.
The substrate was grit blasted to avoid poor adherence. The porosity, microstructure, and morphology of layers are
characterized by optical microscopy, SEM and image analysis. The
samples were studied also in terms of hardness and erosion resistance.
This investigation did not reveal any visible evidence damage to the
substrates. The hardness of zinc layer was about 25.94 MPa and the
porosity was around (∼6.70%). The erosion test showed that the zinc
coating improves the resistance to erosion. Based on the results
obtained, we can conclude that thermal spraying allows the production
of protective coating on PMC. Zinc coating has been identified as a
compatible material with the substrate. The filler powders layer
protects the substrate from the impact of hot particles and allows
avoiding the rupture of brittle carbon fibers.
Abstract: A composite material with carbon fiber and polymer
matrix has been used as adherent for manufacturing adhesive joints.
In order to evaluate different fiber orientations on joint performance,
the adherents with the 0°, ±15°, ±30°, ±45° fiber orientations were
used in the single lap joint configuration. The joints with an overlap
length of 25 mm were prepared according to the ASTM 1002
specifications and subjected to tensile loadings. The structural
adhesive used was a two-part epoxy to be cured at 70°C for an hour.
First, mechanical behaviors of the adherents were measured using
three point bending test. In the test, considerations were given to
stress to failure and elastic modulus. The results were compared with
theoretical ones using rule of mixture. Then, the joints were
manufactured in a specially prepared jig, after a proper surface
preparation. Experimental results showed that the fiber orientations
of the adherents affected the joint performance considerably; the
joints with ±45° adherents experienced the worst shear strength, half
of those with 0° adherents, and in general, there was a great
relationship between the fiber orientations and failure mechanisms.
Delamination problems were observed for many joints, which were
thought to be due to peel effects at the ends of the overlap. It was
proved that the surface preparation applied to the adherent surface
was adequate. For further explanation of the results, a numerical
work should be carried out using a possible non-linear analysis.
Abstract: The irradiation of polymeric materials has received
much attention because it can produce diverse changes in chemical
structure and physical properties. Thus, studying the chemical and
structural changes of polymers is important in practice to achieve
optimal conditions for the modification of polymers. The effect of
gamma irradiation on the crystalline structure of poly(vinylidene
fluoride) (PVDF) has been investigated using differential scanning
calorimetry (DSC) and X-ray diffraction techniques (XRD). Gamma
irradiation was carried out in atmosphere air with doses between 100
kGy at 3,000 kGy with a Co-60 source. In the melting thermogram of
the samples irradiated can be seen a bimodal melting endotherm is
detected with two melting temperature. The lower melting
temperature is attributed to melting of crystals originally present and
the higher melting peak due to melting of crystals reorganized upon
heat treatment. These results are consistent with those obtained by
XRD technique showing increasing crystallinity with increasing
irradiation dose, although the melting latent heat is decreasing.
Abstract: In this study, thermal fatigue properties of 400 series
ferritic stainless steels have been evaluated in the temperature ranges
of 200-800oC and 200-900oC. Systematic methods for control of
temperatures within the predetermined range and measurement of load
applied to specimens as a function of temperature during thermal
cycles have been established. Thermal fatigue tests were conducted
under fully constrained condition, where both ends of specimens were
completely fixed. It has been revealed that load relaxation behavior at
the temperatures of thermal cycle was closely related with the thermal
fatigue property. Thermal fatigue resistance of 430J1L stainless steel
is found to be superior to the other steels.
Abstract: Fe-2%Mn-0.5%Si-0.2C steel was welded and corroded
at 600, 700 and 800oC for 20 h in 1 atm of N2/H2S/H2O-mixed gas in
order to characterize the high-temperature corrosion behavior of the
welded joint. Corrosion proceeded fast and almost linearly. It
increased with an increase in the corrosion temperature. H2S formed
FeS owing to sulfur released from H2S. The scales were fragile and
nonadherent.
Abstract: The combination of the properties of graphene oxide
(OG) and PVDF homopolymer makes their combined composite
materials as multifunctional systems with great potential. Knowledge
of the molecular structure is essential for better use. In this work, the
degradation of PVDF polymer exposed to gamma irradiation in
oxygen atmosphere in high dose rate has been studied and compared
to degradation of PVDF/OG composites. The samples were irradiated
with a Co-60 source at constant dose rate, with doses ranging from
100 kGy to 1,000 kGy. In FTIR data shown that the formation of
oxidation products was at the both samples with formation of
carbonyl and hydroxyl groups amongst the most prevalent products
in the pure PVDF samples. In the other hand, the composites samples
exhibit less presence of degradation products with predominant
formation of carbonyl groups, these results also seen in the UV-Vis
analysis. The results show that the samples of composites may have
greater resistance to the irradiation process, since they have less
degradation products than pure PVDF samples seen by spectroscopic
techniques.