Experimental Investigation of Proton Exchange Membrane Fuel Cells Operated with Nanofiber and Nanofiber/Nanoparticle
Nanofibers are defined as fibers with diameters less
than 100 nanometers. In this study, behaviours of activated carbon
nanofiber (ACNF), carbon nanofiber (CNF), polyacrylonitrile/ carbon
nanotube (PAN/CNT), polyvinyl alcohol/nanosilver (PVA/Ag) in
proton exchange membrane (PEM) fuel cells are investigated
experimentally. This material was used as gas diffusion layer (GDL)
in PEM fuel cells. In this study, the electrical conductivities of
nanofiber and nanofiber/nanoparticles have been studied to
understand their effects on PEM fuel cell performance. According to
the experimental results, the maximum electrical conductivity
performance of the fuel cell with nanofiber was found to be at
PVA/Ag (at UConn condition). The electrical conductivities of CNF,
ACNF, PAN/CNT are lower for PEM. The resistance of cell with
PVA/Ag is lower than the resistance of cell with PAN/CNT, ACNF,
CNF.
[1] Steven J. Hamrock and Michael A. Yandrasits, Proton Exchange
Membranes for Fuel Cell Applications, Journal of Macromolecular
Sciencew, Part C: Polymer Reviews, 46: 219-244, 2006.
[2] R. Bajon, S. Balaji, S. M. Guo, Electrospun Nafion Nanofiber for Proton
Exchange Membrane Fuel Cell Application, Journal of Fuel Cell
Science and Technology, August 2009, Vol. 6 / 031004-1-6.
[3] Li-Cheng Jheng, Steve Lien-Chung Hsu, Tzung-Yu Tsai, Wesley Jen-
Yang Chang, A novel asymmetric polybenzimidazole membrane for
high temperature proton exchange membrane fuel cells, Journal of
Materials Chemistry A, 2014, 2, 4225-4233.
[4] Libo Deng, Robert J. Young, Ian A. Kinloch, Amr M. Abdelkader,
Stuart M. Holmes, David A. De Haro-Del Rio, Stephen J. Eichhorn,
Supercapacitance from Cellulose and Carbon Nanotube Nanocomposite
Fibers, Applied Materials Interfaces, 5, 9983-9990, 2013.
[5] Kyung Jin Lee, Nanako Shiratori, Gang Ho Lee, Jin Miyawaki, Isao
Mochida, Seong-Ho Yoon, Jyongsik Jang, Activated carbon nanofiber
produced from electrospunpolyacrylonitrile nanofiber as a highly
efficient formaldehyde adsorbent, Carbon, 48, 4248-4255, 2010.
[6] Thandavamoorthy Subbiah, G. S. Bhat, R. W. Tock, S. Parameswaran,
S. S. Ramkumar, Electrospinning of Nanofibers, Journal of Applied
Polymer Science, Vol. 96, 557-569, 2005.
[7] Zheng-Ming Huang, Y.Z. Zhang, M. Kotaki, S. Ramakrishna, a review
on polymer nanofibers by electrospinning and their applications in
nanocomposites, Composites Science and Technology (63) 2223-2253,
2003.
[8] Mohd Faiz Muaz Ahmad Zamri, Sharif Hussein Sharif Zein, Ahmad
Zuhari Abdullah and Nor Irwin Basir, Improved Electrical Conductivity
of Polyvinyl Alcohol/ Multiwalled Carbon Nanotube Nanofibre
Composite Films with MnO2 as Filler Synthesised using the
Electrospinning Process, International Journal of Engineering &
Technology IJET-IJENS Vol: 11 No: 06.
[9] https://www.ndeed.org/EducationResources/CommunityCollege/Materia
ls/Physical_ Chemical/Electrical.htm.
[10] Suman Mahendia, A.K. Tomar, Shyam Kumar, Electrical conductivity
and dielectric spectroscopic studies of PVA-Ag nanocomposite films,
Journal of Alloys and Compounds, 508 (2), 2010, 406-411.
[11] The Florida Solar Energy Center_ Document Number WP0012WPQRS.
[1] Steven J. Hamrock and Michael A. Yandrasits, Proton Exchange
Membranes for Fuel Cell Applications, Journal of Macromolecular
Sciencew, Part C: Polymer Reviews, 46: 219-244, 2006.
[2] R. Bajon, S. Balaji, S. M. Guo, Electrospun Nafion Nanofiber for Proton
Exchange Membrane Fuel Cell Application, Journal of Fuel Cell
Science and Technology, August 2009, Vol. 6 / 031004-1-6.
[3] Li-Cheng Jheng, Steve Lien-Chung Hsu, Tzung-Yu Tsai, Wesley Jen-
Yang Chang, A novel asymmetric polybenzimidazole membrane for
high temperature proton exchange membrane fuel cells, Journal of
Materials Chemistry A, 2014, 2, 4225-4233.
[4] Libo Deng, Robert J. Young, Ian A. Kinloch, Amr M. Abdelkader,
Stuart M. Holmes, David A. De Haro-Del Rio, Stephen J. Eichhorn,
Supercapacitance from Cellulose and Carbon Nanotube Nanocomposite
Fibers, Applied Materials Interfaces, 5, 9983-9990, 2013.
[5] Kyung Jin Lee, Nanako Shiratori, Gang Ho Lee, Jin Miyawaki, Isao
Mochida, Seong-Ho Yoon, Jyongsik Jang, Activated carbon nanofiber
produced from electrospunpolyacrylonitrile nanofiber as a highly
efficient formaldehyde adsorbent, Carbon, 48, 4248-4255, 2010.
[6] Thandavamoorthy Subbiah, G. S. Bhat, R. W. Tock, S. Parameswaran,
S. S. Ramkumar, Electrospinning of Nanofibers, Journal of Applied
Polymer Science, Vol. 96, 557-569, 2005.
[7] Zheng-Ming Huang, Y.Z. Zhang, M. Kotaki, S. Ramakrishna, a review
on polymer nanofibers by electrospinning and their applications in
nanocomposites, Composites Science and Technology (63) 2223-2253,
2003.
[8] Mohd Faiz Muaz Ahmad Zamri, Sharif Hussein Sharif Zein, Ahmad
Zuhari Abdullah and Nor Irwin Basir, Improved Electrical Conductivity
of Polyvinyl Alcohol/ Multiwalled Carbon Nanotube Nanofibre
Composite Films with MnO2 as Filler Synthesised using the
Electrospinning Process, International Journal of Engineering &
Technology IJET-IJENS Vol: 11 No: 06.
[9] https://www.ndeed.org/EducationResources/CommunityCollege/Materia
ls/Physical_ Chemical/Electrical.htm.
[10] Suman Mahendia, A.K. Tomar, Shyam Kumar, Electrical conductivity
and dielectric spectroscopic studies of PVA-Ag nanocomposite films,
Journal of Alloys and Compounds, 508 (2), 2010, 406-411.
[11] The Florida Solar Energy Center_ Document Number WP0012WPQRS.
@article{"International Journal of Chemical, Materials and Biomolecular Sciences:71798", author = "Kevser Dincer and Basma Waisi and M. Ozan Ozdemir and Ugur Pasaogullari and Jeffrey McCutcheon", title = "Experimental Investigation of Proton Exchange Membrane Fuel Cells Operated with Nanofiber and Nanofiber/Nanoparticle", abstract = "Nanofibers are defined as fibers with diameters less
than 100 nanometers. In this study, behaviours of activated carbon
nanofiber (ACNF), carbon nanofiber (CNF), polyacrylonitrile/ carbon
nanotube (PAN/CNT), polyvinyl alcohol/nanosilver (PVA/Ag) in
proton exchange membrane (PEM) fuel cells are investigated
experimentally. This material was used as gas diffusion layer (GDL)
in PEM fuel cells. In this study, the electrical conductivities of
nanofiber and nanofiber/nanoparticles have been studied to
understand their effects on PEM fuel cell performance. According to
the experimental results, the maximum electrical conductivity
performance of the fuel cell with nanofiber was found to be at
PVA/Ag (at UConn condition). The electrical conductivities of CNF,
ACNF, PAN/CNT are lower for PEM. The resistance of cell with
PVA/Ag is lower than the resistance of cell with PAN/CNT, ACNF,
CNF.", keywords = "Proton exchange membrane fuel cells,
electrospinning, carbon nanofiber, activate carbon nanofiber, PVA
fiber, pan fiber, carbon nanotube, nanoparticle, nanocomposites.", volume = "9", number = "12", pages = "1484-5", }