Abstract: The aim of this study was to compare the solubility of selected volatile organic compounds in water and silicon oil using the simple static headspace method. The experimental design allowed equilibrium achievement within 30 – 60 minutes. Infinite dilution activity coefficients and Henry-s law constants for various organics representing esters, ketones, alkanes, aromatics, cycloalkanes and amines were measured at 303K. The measurements were reproducible with a relative standard deviation and coefficient of variation of 1.3x10-3 and 1.3 respectively. The static determined activity coefficients using shaker flasks were reasonably comparable to those obtained using the gas liquid - chromatographic technique and those predicted using the group contribution methods mainly the UNIFAC. Silicon oil chemically known as polydimethysiloxane was found to be better absorbent for VOCs than water which quickly becomes saturated. For example the infinite dilution mole fraction based activity coefficients of hexane is 0.503 and 277 000 in silicon oil and water respectively. Thus silicon oil gives a superior factor of 550 696. Henry-s law constants and activity coefficients at infinite dilution play a significant role in the design of scrubbers for abatement of volatile organic compounds from contaminated air streams. This paper presents the phase equilibrium of volatile organic compounds in very dilute aqueous and polymeric solutions indicating the movement and fate of chemical in air and solvent. The successful comparison of the results obtained here and those obtained using other methods by the same authors and in literature, means that the results obtained here are reliable.
Abstract: We have devised a thermal carpet cloak theoretically
and implemented in silicon using layered metamaterial. The layered
metamaterial is composed of single crystalline silicon and its phononic
crystal. The design is based on a coordinate transformation. We
demonstrate the result with numerical simulation. Great cloaking
performance is achieved as a thermal insulator is well hidden under the
thermal carpet cloak. We also show that the thermal carpet cloak can
even the temperature on irregular surface. Using thermal carpet cloak
to manipulate the heat conduction is effective because of its low
complexity.
Abstract: The recycling of concrete, bricks and masonry rubble
as concrete aggregates is an important way to contribute to a
sustainable material flow. However, there are still various
uncertainties limiting the widespread use of Recycled Concrete
Aggregates (RCA). The fluctuations in the composition of grade
recycled aggregates and their influence on the properties of fresh and
hardened concrete are of particular concern regarding the use of
RCA. Most of problems occurring while using recycled concrete
aggregates as aggregates are due to higher porosity and hence higher
water absorption, lower mechanical strengths, residual impurities on
the surface of the RCA forming weaker bond between cement paste
and aggregate. So, the reuse of RCA is still limited. Efficient
polymer based treatment is proposed in order to reuse RCA easier.
The silicon-based polymer treatments of RCA were carried out and
were compared. This kind of treatment can improve the properties of
RCA such as the rate of water absorption on treated RCA is
significantly reduced.
Abstract: In this paper, RSA encryption algorithm and its hardware
implementation in Xilinx-s Virtex Field Programmable Gate
Arrays (FPGA) is analyzed. The issues of scalability, flexible performance,
and silicon efficiency for the hardware acceleration of
public key crypto systems are being explored in the present work.
Using techniques based on the interleaved math for exponentiation,
the proposed RSA calculation architecture is compared to existing
FPGA-based solutions for speed, FPGA utilization, and scalability.
The paper covers the RSA encryption algorithm, interleaved multiplication,
Miller Rabin algorithm for primality test, extended Euclidean
math, basic FPGA technology, and the implementation details of
the proposed RSA calculation architecture. Performance of several
alternative hardware architectures is discussed and compared. Finally,
conclusion is drawn, highlighting the advantages of a fully flexible
& parameterized design.
Abstract: In this paper, we analyze the problem of quasiballistic electron transport in ultra small of mercury -cadmiumtelluride (Hg0.8Cd0.2Te -MCT) n+-n- n+ devices from hydrodynamic point view. From our study, we note that, when the size of the active layer is low than 0.1μm and for low bias application( ( ≥ 9mV), the quasi-ballistic transport has an important effect.
Abstract: This paper presents the experimental results of silicone rubber housing material for 24kV lightning arrester under artificial accelerated ageing test based on IEC 61109 specifications. Specimens having inclined and alternated shed made of HTV silicone rubber with ATH content and having leakage distance 625 mm were tested continuously 1000 hrs in artificial salt fog chamber. After 1000 hrs of salt fog ageing test, obviously surface erosion was observed on trunk between the upper large shed and the lower small shed near the energized end. Decreasing in hydrophobicity and increasing in hardness were measured on tested specimen comparing with new specimen. Chemical analysis by ATR-FTIR confirmed the observation results.
Abstract: Aluminum alloy has an extensive range of industrial application due to its consistent mechanical properties and structural integrity. The heat treatment by precipitation technique affected the Magnesium, Silicon Manganese and copper crystals dissolved in the Aluminum alloy. The crystals dislocated to precipitate on the crystal’s boundaries of the Aluminum alloy when given a thermal energy increased its hardness. In this project various times and temperature were varied to find out the best combination of these variables to increase the precipitation of the metals on the Aluminum crystal’s boundaries which will lead to get the highest hardness. These specimens are then tested for their hardness and tensile strength. It is noticed that when the temperature increases, the precipitation increases and consequently the hardness increases. A threshold temperature value (264C0) of Aluminum alloy should not be reached due to the occurrence of recrystalization which causes the crystal to grow. This recrystalization process affected the ductility of the alloy and decrease hardness. In addition, and while increasing the temperature the alloy’s mechanical properties will decrease. The mechanical properties, namely tensile and hardness properties are investigated according to standard procedures. In this research, different temperature and time have been applied to increase hardening.The highest hardness at 100°c in 6 hours equals to 207.31 HBR, while at the same temperature and time the lowest elongation equals to 146.5.
Abstract: Two different superhydrophobic surfaces were
elaborated and their oil repellency behavior was evaluated using
several liquid with different surface tension. A silicone rubber/SiO2
nanocomposite coated (A) on aluminum substrate by “spin-coating"
and the sample B was an anodized aluminum surface covered by
Teflon-like coating. A high static contact angle about ∼162° was
measured for two prepared surfaces on which the water droplet rolloff.
Scanning electron microscopy (SEM) showed the presence of
micro/nanostructures for both sample A and B similar to that of lotus
leaf.
However the sample A presented significantly different behaviour
of wettability against the low surface tension liquid. Sample A has
been wetted totally by oil (dodecan) droplet while sample B showed
oleophobic behaviour. Oleophobic property of Teflon like coating
can be contributed to the presence of CF2 and CF3 functional group
which was shown by XPS analysis.
Abstract: Multi-level voltage source inverters offer several
advantages such as; derivation of a refined output voltage with
reduced total harmonic distortion (THD), reduction of voltage ratings
of the power semiconductor switching devices and also the reduced
electro-magnetic-interference problems etc. In this paper, new
carrier-overlapped phase-disposition or sub-harmonic sinusoidal
pulse width modulation (CO-PD-SPWM) and also the carrieroverlapped
phase-disposition space vector modulation (CO-PDSVPWM)
schemes for a six-level diode-clamped inverter topology
are proposed. The principle of the proposed PWM schemes is similar
to the conventional PD-PWM with a little deviation from it in the
sense that the triangular carriers are all overlapped. The overlapping
of the triangular carriers on one hand results in an increased number
of switchings, on the other hand this facilitates an improved spectral
performance of the output voltage. It is demonstrated through
simulation studies that the six-level diode-clamped inverter with the
use of CO-PD-SPWM and CO-PD-SVPWM proposed in this paper is
capable of generating multiple levels in its output voltage. The
advantages of the proposed PWM schemes can be derived to benefit,
especially at lower modulation indices of the inverter and hence this
aspect of the proposed PWM schemes can be well exploited in high
power applications requiring low speeds of operation of the drive.
Abstract: Induction motors are being used in greater numbers
throughout a wide variety of industrial and commercial applications
because it provides many benefits and reliable device to convert the
electrical energy into mechanical motion. In some application it-s
desired to control the speed of the induction motor. Because of the
physics of the induction motor the preferred method of controlling its
speed is to vary the frequency of the AC voltage driving the motor. In
recent years, with the microcontroller incorporated into an appliance
it becomes possible to use it to generate the variable frequency AC
voltage to control the speed of the induction motor.
This study investigates the microcontroller based variable
frequency power inverter. the microcontroller is provide the variable
frequency pulse width modulation (PWM) signal that control the
applied voltage on the gate drive, which is provides the required
PWM frequency with less harmonics at the output of the power
inverter.
The fully controlled bridge voltage source inverter has been
implemented with semiconductors power devices isolated gate
bipolar transistor (IGBT), and the PWM technique has been
employed in this inverter to supply the motor with AC voltage.
The proposed drive system for three & single phase power inverter
is simulated using Matlab/Simulink. The Matlab Simulation Results
for the proposed system were achieved with different SPWM. From
the result a stable variable frequency inverter over wide range has
been obtained and a good agreement has been found between the
simulation and hardware of a microcontroller based single phase
inverter.
Abstract: Although silicon photonic devices provide a significantly larger bandwidth and dissipate a substantially less power than the electronic devices, they suffer from a large size due to the fundamental diffraction limit and the weak optical response of Si. A potential solution is to exploit Si plasmonics, which may not only miniaturize the photonic device far beyond the diffraction limit, but also enhance the optical response in Si due to the electromagnetic field confinement. In this paper, we discuss and summarize the recently developed metal-insulator-Si-insulator-metal nanoplasmonic waveguide as well as various passive and active plasmonic components based on this waveguide, including coupler, bend, power splitter, ring resonator, MZI, modulator, detector, etc. All these plasmonic components are CMOS compatible and could be integrated with electronic and conventional dielectric photonic devices on the same SOI chip. More potential plasmonic devices as well as plasmonic nanocircuits with complex functionalities are also addressed.
Abstract: In the present work homogeneous silica film on
silicon was fabricated by colloidal silica sol. The silica sol precursor
with uniformly granular particle was derived by the alkaline
hydrolysis of tetraethoxyorthosilicate (TEOS) in presence of glycerol
template. The film was prepared by dip coating process. The
templated hetero-structured silica film was annealed at elevated
temperatures to generate nano- and meso porosity in the film. The
film was subsequently annealed at different temperatures to make it
defect free and abrasion resistant. The sol and the film were
characterized by the measurement of particle size distribution,
scanning electron microscopy, XRD, FTIR spectroscopy,
transmission electron microscopy, atomic force microscopy,
measurement of the refractive index, thermal conductivity and
abrasion resistance. The porosity of the films decreased whereas
refractive index and dielectric constant of it `increased with the
increase in the annealing temperature. The thermal conductivity of
the films increased with the increase in the film thickness. The
developed porous silica film holds strong potential for use in
different areas.
Abstract: A generalized method for small-signal simulation of
avalanche noise in Mixed Tunneling Avalanche Transit Time
(MITATT) device is presented in this paper where the effect of series
resistance is taken into account. The method is applied to a
millimeter-wave Double Drift Region (DDR) MITATT device based
on Silicon to obtain noise spectral density and noise measure as a
function of frequency for different values of series resistance. It is
found that noise measure of the device at the operating frequency
(122 GHz) with input power density of 1010 Watt/m2 is about 35 dB
for hypothetical parasitic series resistance of zero ohm (estimated
junction temperature = 500 K). Results show that the noise measure
increases as the value of parasitic resistance increases.
Abstract: This paper presents the experimental results of silicone rubber outdoor polymer insulators in salt fog ageing test based on IEC 61109. Specimens made ofHTV silicone rubber with ATH content having three different configurations, straight shedsalternated sheds, and incline and alternate sheds, were tested continuously 1000 hrs.in artificial salt fog chamber. Contamination level, reduction of hydrophobicity and hardness measurement were used as physical damaged inspection techniques to evaluate degree of surface deterioration. In addition, chemical changing of tested specimen surface was evaluated by ATR-FTIRto confirm physical damaged inspection. After 1000 hrs.of salt fog test, differences in degree of surface deterioration were observed on all tested specimens. Physical damaged inspection and chemical analysis results confirmed the experimental results as well.
Abstract: In this article, a high vacuum system for the evaporation of organic semiconductors is introduced and a mathematical model is given. Based on the exact input output linearization a deposition rate controller is designed and tested with different evaporation materials.
Abstract: Shrunken patterning for integrated device
manufacturing requires surface cleanliness and surface smoothness in
wet chemical processing [1]. It is necessary to control all process
parameters perfectly especially for the common cleaning technique
RCA clean (SC-1 and SC-2) [2]. In this paper the characteristic and
effect of surface preparation parameters are discussed. The properties
of RCA wet chemical processing in silicon technology is based on
processing time, temperature, concentration and megasonic power of
SC-1 and QDR. An improvement of wafer surface preparation by
the enhanced variables of the wet cleaning chemical process is
proposed.
Abstract: A device analysis of the photoconductive
semiconductor switch is carried out to investigate distribution of
electric field and carrier concentrations as well as the current density
distribution. The operation of this device was then investigated as a
switch operating in X band. It is shown that despite the presence of
symmetry geometry, switch current density of the on-state steady
state mode is distributed asymmetrically throughout the device.
Abstract: The optical properties of InGaN/GaN laser diode based on quaternary alloys stopper and superlattice layers are numerically studied using ISE TCAD (Integrated System Engineering) simulation program. Improvements in laser optical performance have been achieved using quaternary alloy as superlattice layers in InGaN/GaN laser diodes. Lower threshold current of 18 mA and higher output power and slope efficiency of 22 mW and 1.6 W/A, respectively, at room temperature have been obtained. The laser structure with InAlGaN quaternary alloys as an electron blocking layer was found to provide better laser performance compared with the ternary AlxGa1-xN blocking layer.
Abstract: The steam cracking reactions are always accompanied with the formation of coke which deposits on the walls of the tubular reactors. The investigation has attempted to control catalytic coking by the applying aluminum, zinc and ceramic coating like aluminum-magnesium by thermal spray and pack cementation method. Rate of coke formation during steam cracking of naphtha has been investigated both for uncoated stainless steel (with different alloys) and metal coating constructed with thermal Spray and pack cementation method with metal powders of Aluminum, Aluminum-Magnesium, zinc, silicon, nickel and chromium. The results of the study show that passivating the surface of SS321 with a coating of Aluminum and Aluminum-Magnesium can significantly reduce the rate of coke deposition during naphtha pyrolysis. SEM and EDAX techniques (Philips XL Series) were used to examine the coke deposits formed by the metal-hydrocarbon reactions. Our objective was to separate the different stages by identifying the characteristic morphologies.
Abstract: Text Mining is an important step of Knowledge
Discovery process. It is used to extract hidden information from notstructured
o semi-structured data. This aspect is fundamental because
much of the Web information is semi-structured due to the nested
structure of HTML code, much of the Web information is linked,
much of the Web information is redundant. Web Text Mining helps
whole knowledge mining process to mining, extraction and
integration of useful data, information and knowledge from Web
page contents.
In this paper, we present a Web Text Mining process able to
discover knowledge in a distributed and heterogeneous multiorganization
environment. The Web Text Mining process is based on
flexible architecture and is implemented by four steps able to
examine web content and to extract useful hidden information
through mining techniques. Our Web Text Mining prototype starts
from the recovery of Web job offers in which, through a Text Mining
process, useful information for fast classification of the same are
drawn out, these information are, essentially, job offer place and
skills.