On the Oil Repellency of Nanotextured Aluminum Surface

Two different superhydrophobic surfaces were elaborated and their oil repellency behavior was evaluated using several liquid with different surface tension. A silicone rubber/SiO2 nanocomposite coated (A) on aluminum substrate by “spin-coating" and the sample B was an anodized aluminum surface covered by Teflon-like coating. A high static contact angle about ∼162° was measured for two prepared surfaces on which the water droplet rolloff. Scanning electron microscopy (SEM) showed the presence of micro/nanostructures for both sample A and B similar to that of lotus leaf. However the sample A presented significantly different behaviour of wettability against the low surface tension liquid. Sample A has been wetted totally by oil (dodecan) droplet while sample B showed oleophobic behaviour. Oleophobic property of Teflon like coating can be contributed to the presence of CF2 and CF3 functional group which was shown by XPS analysis.




References:
[1] R. Jafari & M. Farzaneh, "Fabrication of superhydrophobic
nanostructured surface on aluminum alloy", Journal of Applied physics
A, vol. 102, issue 1, 2011, pp. 195-199.
[2] A. Tuteja, W. Choi, G.H. McKinley, R. E. Cohen, and M.F. Rubner,
MRS BULLETIN ÔÇó Vol. 33, Auguest 2008 .
[3] G. Momen & M. Farzaneh, Applied Surface Science Vol. 258, Issue 15,
2012, pp. 5723-5728.
[4] R. Jafari, R. Menini & M. Farzaneh," Superhydrophobic and icephobic
surfaces prepared by RF-sputtered polytetrafluoroethylene coatings",
Journal of Applied surface science, no.257, Nov.2010, pp. 1540-1543.
[5] G. Momen & M. Farzaneh, "A simple process to fabricate a
superhydrophobic Silicone rubber coating", Micro & Nano Letters, Vol.
6, issue 6, 2011, pp. 405-407.
[6] L. Foroughi mobarakeh,R Jafari & M. Farzaneh, "Superhydrophobic
surface elaboration using plasma polymerization of
hexamethyldisiloxane (HMDSO)", Advanced Materials Research, Vol.
409, 2012, pp. 783-787.
[7] G. Momen, M. Farzaneh & R. Jafari," Wettability behaviour of RTV
silicone rubber coated on nanostructured aluminium surface " Applied
Surface Science, Vol. 257, issue 15, 2011, pp. 9489-6493.
[8] B.t Bhushan, Y Chae Jung, "Lotus Effect: Surfaces with
RoughnessInduced Superhydrophobicity, Self-Cleaningand Low
Adhesion", Ultramicroscopy, Vol. 107, 2007, pp.1033-1041.
[9] R.-H Yoon, and S. A Ravishankar, "Long-Range Hydrophobic Forces
between Mica Surfaces in Alkaline Dodecylammonium Chloride
Solutions", J. Colloid Interface Science, Vol. 179, 391, 1996, pp. 403-
411.
[10] Yoon, R.-H. and Pazhianur, R., "Direct Force Measurement between
Hydrophobic Glass Sphere and Covellite Electrode in Potassium Ethyl
Xanthate Solutions at pH 9.2," Colloids and Surfaces, vol. A144, 1998.
pp. 59-69.
[11] P. Gonon," Effect of nitrogen addition on the properties of C.F thin films
deposited by RF sputtering" Eur. Phys. J. Appl. Phys. 32, 2005, pp. 15-
21.
[12] V. Stelmashuk, H. Biederman, D. Slavinska, M. Trchova, P. Hlídek, "Rf
magnetron sputtering of polypropylene", Vacuum 75, 2004, pp. 207-215.