Abstract: Polycyclic Aromatic Hydrocarbons (PAHs) are
formed mainly because of incomplete combustion of organic
materials during industrial, domestic activities or natural occurrence.
Their toxicity and contamination of terrestrial and aquatic ecosystem
have been established. However, with limited validity index, previous
research has focused on PAHs isomer pair ratios of variable
physicochemical properties in source identification. The objective of
this investigation was to determine the empirical validity of Pearson
Correlation Coefficient (PCC) and Cluster Analysis (CA) in PAHs
source identification along soil samples of different land uses.
Therefore, 16 PAHs grouped, as Endocrine Disruption Substances
(EDSs) were determined in 10 sample stations in top and sub soils
seasonally. PAHs was determined the use of Varian 300 gas
chromatograph interfaced with flame ionization detector. Instruments
and reagents used are of standard and chromatographic grades
respectively. PCC and CA results showed that the classification of
PAHs along pyrolitic and petrogenic organics used in source
signature is about the predominance PAHs in environmental matrix.
Therefore, the distribution of PAHs in the studied stations revealed
the presence of trace quantities of the vast majority of the sixteen
PAHs, which may ultimately inhabit the actual source signature
authentication. Therefore, factors to be considered when evaluating
possible sources of PAHs could be; type and extent of bacterial
metabolism, transformation products/substrates, and environmental
factors such as salinity, pH, oxygen concentration, nutrients, light
intensity, temperature, co-substrates, and environmental medium are
hereby recommended as factors to be considered when evaluating
possible sources of PAHs.
Abstract: The Portuguese footwear industry had in the last five years a remarkable performance in the exportation values, the trade balance and others economic indicators. After a long period of difficulties and with a strong reduction of companies and employees since 1994 until 2009, the Portuguese footwear industry changed the strategy and is now a success case between the international players of footwear. Only the Italian industry sells footwear with a higher value than the Portuguese and the distance between them is decreasing year by year. This paper analyses how the Portuguese footwear companies innovate and make innovation, according the classification proposed by the Oslo Manual. Also, analyses the strategy follow in the innovation process and shows the linkage between the type of innovation and the strategy of innovation. The research methodology was qualitative and the strategy for data collection was the case study. The qualitative data will be analyzed with the MAXQDA software. The economic results of the footwear companies studied shows differences between all of them and these differences are related with the innovation strategy adopted. The companies focused in product and marketing innovation, oriented to their target market, have higher ratios “turnover per worker” than the companies focused in process innovation. However, all the footwear companies in this “low-tech” industry create value and contribute to a positive foreign trade of 1.310 million euros in 2013. The growth strategies implemented has the participation of the sectorial organizations in several innovative projects. And it’s obvious that cooperation between all of them is a critical element to the performance achieved by the companies and the innovation observed. The Portuguese footwear sector has in the last years an excellent performance (economic results, exportation values, trade balance, brands and international image) and his performance is strongly related with the strategy in innovation followed, the type of innovation and the networks in the cluster. A simplified model, called “Ace of Diamonds”, is proposed by the authors and explains the way how this performance was reached by the seven companies that participate in the study (two of them are the leaders in the setor), and if this model can be used in others traditional and “low-tech” industries.
Abstract: The world crude oil demand is projected to rise to 108.5 million bbl/d by the year 2035. With reserves estimated at 869 billion tonnes worldwide, coal remains an abundant resource. The aim of this work was to produce a high value hydrocarbon liquid product using a Direct Coal Liquefaction (DCL) process at, relatively mild operating conditions. Via hydrogenation, the temperature-staged approach was investigated in a dual reactor lab-scale pilot plant facility. The objectives included maximising thermal dissolution of the coal in the presence of tetralin as the hydrogen donor solvent in the first stage with 2:1 and 3:1 solvent: coal ratios. Subsequently, in the second stage, hydrogen saturation, in particular, hydrodesulphurization (HDS) performance was assessed. Two commercial hydrotreating catalysts were investigated viz. NickelMolybdenum (Ni-Mo) and Cobalt-Molybdenum (Co-Mo). GC-MS results identified 77 compounds and various functional groups present in the first and second stage liquid product. In the first stage 3:1 ratios and liquid product yields catalysed by magnetite were favoured. The second stage product distribution showed an increase in the BTX (Benzene, Toluene, Xylene) quality of the liquid product, branched chain alkanes and a reduction in the sulphur concentration. As an HDS performer and selectivity to the production of long and branched chain alkanes, Ni-Mo had an improved performance over Co-Mo. Co-Mo is selective to a higher concentration of cyclohexane. For 16 days on stream each, Ni-Mo had a higher activity than Co-Mo. The potential to cover the demand for low–sulphur, crude diesel and solvents from the production of high value hydrocarbon liquid in the said process, is thus demonstrated.
Abstract: The properties of hollow sandcrete blocks produced in
Minna, Nigeria are presented. Sandcrete block is made of cement,
water and sand binded together in certain mix proportions. For the
purpose of this work, fifty (50) commercial sandcrete block industries
were visited in Minna, Nigeria to obtain block samples and
aggregates used for the manufacture, and to take inventory of the mix
composition and the production process. Sieve analysis tests were
conduction on the soil sample from various block industries to
ascertain their quality to be used for block making. The mix ratios
were also investigated. Five (5) nine inches (9’’ or 225mm) blocks
were obtained from each block industry and tested for dimensional
compliance and compressive strength. The results of the soil test
shows that the grading fall within the limit for natural aggregate and
can easily are used to obtain workable mix. Physical examinations of
the block sizes show slight deviation from the standard requirement
in NIS 87:2000. Compressive strength of hollow sandcrete blocks in
range of 0.12 N/mm2 to 0.54 N/mm2 was obtained which is below the
recommendable value of 3.45 N/mm2 for load bearing hollow
sandcrete blocks. This indicates that these blocks are below the
standard for load-bearing sandcrete blocks and cannot be used as load
bearing walling units. The mix composition also indicated low
cement content resulting in low compressive strength. Most of the
commercial block industries visited does not take curing very serious.
Water were only sprinkled ones or twice before the blocks were
stacked and made readily available for sale. It is recommended that a
mix ratio of 1:4 to 1:6 should be used for the production of sandcrete
blocks and proper curing practice should be adhered. Blocks should
also be cured for 14 days before making them available for
consumers.
Abstract: In this paper, relationship between different properties
of IC concrete and water cement ratio, obtained from a
comprehensive experiment conducted on IC using local materials
(Burnt clay chips- BC) is presented. In addition, saturated SAP was
used as an IC material in some cases. Relationships have been
developed through regression analysis. The focus of this analysis is
on developing relationship between a dependent variable and an
independent variable. Different percent replacements of BC and
water cement ratios were used. Compressive strength, modulus of
elasticity, water permeability and chloride permeability were tested
and variations of these parameters were analyzed with respect to
water cement ratio.
Abstract: Barley (Hordeum vulgare L.), vetch (Vicia villosa),
and grass pea (Lathyrus sativus L.) monocultures as well as mixtures
of barley with each of the above legumes, in three seeding ratios (i.e.,
barley: legume 75:25, 50:50 and 25:75, based on seed numbers) were
used to investigated forage yield and competition indices. The results
showed that intercropping reduced the dry matter yield of the three
component plants, compared with their respective monocrops. The
greatest value of total dry matter yield was obtained from barley25-
grasspea75 (5.44 t ha-1) mixture, followed by grass pea sole crop (4.99
t ha-1). The total actual yield loss (AYL) values were positive and
greater than 0 in all mixtures, indicating an advantage from
intercropping over sole crops. Intercropped barley had a higher
relative crowding coefficient (K=1.64) than intercropped legumes
(K=1.20), indicating that barley was more competitive than legumes
in mixtures. Furthermore, grass pea was more competitive than vetch
in mixtures with barley. The highest land equivalent ratio (LER),
system productivity index (SPI) and monetary advantage index
(MAI) were obtained when barley was mixed at a rate of 25% with
75% seed rate of grass pea. It is concluded that intercropping of
barley with grass pea has a good potential to improve the
performance of forage with high land-use efficiency.
Abstract: This paper represents an experimental study of LPG
diffusion flame at elevated preheated air temperatures. The flame is
stabilized in a vertical water-cooled combustor by using air swirler. An
experimental test rig was designed to investigate the different
operating conditions. The burner head is designed so that the LPG fuel
issued centrally and surrounded by the swirling air issues from an air
swirler. There are three air swirlers having the same dimensions but
having different blade angles to give different swirl numbers of 0.5,
0.87 and 1.5. The combustion air was heated electrically before
entering the combustor up to a temperature about 500 K. Five air to
fuel mass ratios of 15, 20, 30, 40 and 50 were also studied. The effect
of preheated air temperature, swirl number and air to fuel mass ratios
on the temperature maps, visible flame length, high temperature region
(size) and exhaust species concentrations are studied. Some results
show that as the preheated air temperature increases, the volume of
high temperature region also increased but the flame length decreased.
Increasing the preheated air temperature, EINOx, EICO2 and EIO2
increased, while EICO decreased. Increasing the preheated air
temperature from 300 to 500 K, for all air swirl numbers used, the
highest increase in EINOx, EICO2 and EIO2 are 141, 4 and 65%,
respectively.
Abstract: The synthesis of CuFe2O4 spinel powders by an
optimized combustion-like process followed by calcination is
described herein. The samples were characterized using X-ray
diffraction (XRD), differential thermal analysis (TG/DTA), scanning
electron microscopy (SEM), dilatometry and 4-probe DC methods.
Different glycine to nitrate (G/N) ratios of 1 (fuel-deficient), 1.48
(stoichiometric) and 2 (fuel-rich) were employed. Calcining the asprepared
powders at 800 and 1000°C for 5 hours showed that the G/N
ratio of 2 results in the formation of the desired copper spinel single
phase at both calcination temperatures. For G/N=1, formation of
CuFe2O4 takes place in three steps. First, iron and copper nitrates
decompose to iron oxide and pure copper. Then, copper transforms to
copper oxide and finally, copper and iron oxides react with each other
to form a copper ferrite spinel phase. The electrical conductivity and
the coefficient of thermal expansion of the sintered pelletized
samples were 2 S.cm-1 (800°C) and 11×10-6 °C-1 (25-800°C),
respectively.
Abstract: This paper describes a new approach which can be
used to interpret the experimental creep deformation data obtained
from miniaturized thin plate bending specimen test to the
corresponding uniaxial data based on an inversed application of the
reference stress method. The geometry of the thin plate is fully
defined by the span of the support, l, the width, b, and the thickness,
d. Firstly, analytical solutions for the steady-state, load-line creep
deformation rate of the thin plates for a Norton’s power law under
plane stress (b→0) and plane strain (b→∞) conditions were obtained,
from which it can be seen that the load-line deformation rate of the
thin plate under plane-stress conditions is much higher than that
under the plane-strain conditions. Since analytical solution is not
available for the plates with random b-values, finite element (FE)
analyses are used to obtain the solutions. Based on the FE results
obtained for various b/l ratios and creep exponent, n, as well as the
analytical solutions under plane stress and plane strain conditions, an
approximate, numerical solutions for the deformation rate are
obtained by curve fitting. Using these solutions, a reference stress
method is utilised to establish the conversion relationships between
the applied load and the equivalent uniaxial stress and between the
creep deformations of thin plate and the equivalent uniaxial creep
strains. Finally, the accuracy of the empirical solution was assessed
by using a set of “theoretical” experimental data.
Abstract: Numerical investigations were conducted to study the
influence of flexural reinforcement ratio on the diagonal cracking
strength and ultimate shear strength of reinforced concrete (RC)
beams without stirrups. Three-dimensional nonlinear finite element
analyses (FEAs) of the beams with flexural reinforcement ratios
ranging from 0.58% to 2.20% subjected to a mid-span concentrated
load were carried out. It is observed that the load-deflection and loadstrain
curves obtained from the numerical analyses agree with those
obtained from the experiments. It is concluded that flexural
reinforcement ratio has a significant effect on the shear strength and
deflection capacity of RC beams without stirrups. The predictions of
diagonal cracking strength and ultimate shear strength of beams
obtained by using the equations defined by a number of codes and
researchers are compared with each other and with the experimental
values.
Abstract: This paper presents a computational study of steady
state three dimensional very high turbulent flow and heat transfer
characteristics in a constant temperature-surfaced circular duct fitted
with 900 hemispherical inline baffles. The computations are based on
realizable k-ɛ model with standard wall function considering the
finite volume method, and the SIMPLE algorithm has been
implemented. Computational Study are carried out for Reynolds
number, Re ranging from 80000 to 120000, Prandtl Number, Pr of
0.73, Pitch Ratios, PR of 1,2,3,4,5 based on the hydraulic diameter of
the channel, hydrodynamic entry length, thermal entry length and the
test section. Ansys Fluent 15.0 software has been used to solve the
flow field. Study reveals that circular pipe having baffles has a higher
Nusselt number and friction factor compared to the smooth circular
pipe without baffles. Maximum Nusselt number and friction factor
are obtained for the PR=5 and PR=1 respectively. Nusselt number
increases while pitch ratio increases in the range of study; however,
friction factor also decreases up to PR 3 and after which it becomes
almost constant up to PR 5. Thermal enhancement factor increases
with increasing pitch ratio but with slightly decreasing Reynolds
number in the range of study and becomes almost constant at higher
Reynolds number. The computational results reveal that optimum
thermal enhancement factor of 900 inline hemispherical baffle is
about 1.23 for pitch ratio 5 at Reynolds number 120000.It also shows
that the optimum pitch ratio for which the baffles can be installed in
such very high turbulent flows should be 5. Results show that pitch
ratio and Reynolds number play an important role on both fluid flow
and heat transfer characteristics.
Abstract: This paper deals with the study of reflection and
transmission characteristics of acoustic waves at the interface of a
semiconductor half-space and elastic solid. The amplitude ratios
(reflection and transmission coefficients) of reflected and transmitted
waves to that of incident wave varying with the incident angles have
been examined for the case of quasi-longitudinal wave. The special
cases of normal and grazing incidence have also been derived with
the help of Gauss elimination method. The mathematical model
consisting of governing partial differential equations of motion and
charge carriers’ diffusion of n-type semiconductors and elastic solid
has been solved both analytically and numerically in the study. The
numerical computations of reflection and transmission coefficients
has been carried out by using MATLAB programming software for
silicon (Si) semiconductor and copper elastic solid. The computer
simulated results have been plotted graphically for Si
semiconductors. The study may be useful in semiconductors,
geology, and seismology in addition to surface acoustic wave (SAW)
devices.
Abstract: Potassium borates, which are widely used in welding
and metal refining industry, as a lubricating oil additive, cement
additive, fiberglass additive and insulation compound, are one of the
important groups of borate minerals. In this study the production of a
potassium borate mineral via hydrothermal method is aimed. The
potassium source of potassium nitrate (KNO3) was used along with a
sodium source of sodium hydroxide (NaOH) and boron source of
boric acid (H3BO3). The constant parameters of reaction temperature
and reaction time were determined as 80°C and 1 h, respectively. The
molar ratios of 1:1:3 (as KNO3:NaOH:H3BO3), 1:1:4, 1:1:5, 1:1:6
and 1:1:7 were used. Following the synthesis the identifications of
the produced products were conducted by X-Ray Diffraction (XRD),
Fourier Transform Infrared Spectroscopy (FT-IR) and Raman
Spectroscopy. The results of the experiments and analysis showed in
the ratio of 1:1:6, the Santite mineral with powder diffraction file
number (pdf no.) of 01-072-1688, which is known as potassium
pentaborate (KB5O8·4H2O) was synthesized as best.
Abstract: This paper addresses the design of hospital Intensive
Care Unit windows for the achievement of visual comfort and energy
savings. The aim was to identify the window size and shading system
configurations that could fulfill daylighting adequacy, avoid glare
and reduce energy consumption. The study focused on addressing the
effect of utilizing different shading systems in association with a
range of Window-to-Wall Ratios (WWR) in different orientations
under the desert clear-sky of Cairo, Egypt.
The results of this study demonstrated that solar penetration is a
critical concern affecting the design of ICU windows in desert
locations, as in Cairo, Egypt. Use of shading systems was found to be
essential in providing acceptable daylight performance and energy
saving. Careful positioning of the ICU window towards a proper
orientation can dramatically improve performance. It was observed
that ICU windows facing the north direction enjoyed the widest range
of successful window configuration possibilities at different WWRs.
ICU windows facing south enjoyed a reasonable number of
configuration options as well. By contrast, the ICU windows facing
the east orientation had a very limited number of options that provide
acceptable performance. These require additional local shading
measures at certain times due to glare incidence. Moreover, use of
horizontal sun breakers and solar screens to protect the ICU windows
proved to be more successful than the other alternatives in a wide
range of Window to Wall Ratios. By contrast, the use of light shelves
and vertical shading devices seemed questionable.
Abstract: Damage status of RC buildings is greatly influenced
by the characteristics of the imposed ground motion. Peak Ground
Acceleration and frequency contents are considered the main two
factors that affect ground motion characteristics; hence, affecting the
seismic response of RC structures and consequently their damage
state. A detailed investigation on the combined effects of these two
factors on damage assessment of RC buildings is carried out. Twenty
one earthquake records are analyzed and arranged into three groups,
according to their frequency contents. These records are used in an
investigation to define the expected damage state that would be
attained by RC buildings, if subjected to varying ground motion
characteristics. The damage assessment is conducted through
examining drift ratios and damage indices of the overall structure and
the significant structural components of RC building. Base and story
shear of RC building model, are also investigated, for cases when the
model is subjected to the chosen twenty one earthquake records.
Nonlinear dynamic analyses are performed on a 2-dimensional model
of a 12-story RC building.
Abstract: A simple adaptive voice activity detector (VAD) is
implemented using Gabor and gammatone atomic decomposition of
speech for high Gaussian noise environments. Matching pursuit is
used for atomic decomposition, and is shown to achieve optimal
speech detection capability at high data compression rates for low
signal to noise ratios. The most active dictionary elements found by
matching pursuit are used for the signal reconstruction so that the
algorithm adapts to the individual speakers dominant time-frequency
characteristics. Speech has a high peak to average ratio enabling
matching pursuit greedy heuristic of highest inner products to isolate
high energy speech components in high noise environments. Gabor
and gammatone atoms are both investigated with identical
logarithmically spaced center frequencies, and similar bandwidths.
The algorithm performs equally well for both Gabor and gammatone
atoms with no significant statistical differences. The algorithm
achieves 70% accuracy at a 0 dB SNR, 90% accuracy at a 5 dB SNR
and 98% accuracy at a 20dB SNR using 30d B SNR as a reference
for voice activity.
Abstract: The present study was carried out to investigate the
effect of alloying elements and thermo-mechanical treatment (TMT)
i.e. hot rolling and forging with different reduction ratios on the
hardness (HV) and impact toughness (J) of heat-treated low alloy
steels. An understanding of the combined effect of TMT and alloying
elements and by measuring hardness, impact toughness, resulting
from different heat treatment following TMT of the low alloy steels,
it is possible to determine which conditions yielded optimum
mechanical properties and high strength to weight ratio.
Experimental Correlations between hot work reduction ratio,
hardness and impact toughness for thermo-mechanically heat treated
low alloy steels are analyzed quantitatively, and both regression and
mathematical hardness and impact toughness models are developed.
Abstract: A reliability-based methodology which uses structural demand hazard curves to consider the increment of the ductility demands of structures with tilting is proposed. The approach considers the effect of two orthogonal components of the ground motions as well as the influence of soil-structure interaction. The approach involves the calculation of ductility demand hazard curves for symmetric systems and, alternatively, for systems with different degrees of asymmetry. To get this objective, demand hazard curves corresponding to different global ductility demands of the systems are calculated. Next, Uniform Exceedance Rate Spectra (UERS) are developed for a specific mean annual rate of exceedance value. Ratios between UERS corresponding to asymmetric and to symmetric systems located in soft soil of the valley of Mexico are obtained. Results indicate that the ductility demands corresponding to tilted structures may be several times higher than those corresponding to symmetric structures, depending on several factors such as tilting angle and vibration period of structure and soil.
Abstract: This study investigates the suitability of using plastic,
such as polyethylene terephthalate (PET), as a partial replacement of
natural coarse and fine aggregates (for example, brick chips and
natural sand) to produce lightweight concrete for load bearing
structural members. The plastic coarse aggregate (PCA) and plastic
fine aggregate (PFA) were produced from melted polyethylene
terephthalate (PET) bottles. Tests were conducted using three
different water–cement (w/c) ratios, such as 0.42, 0.48, and 0.57,
where PCA and PFA were used as 50% replacement of coarse and
fine aggregate respectively. Fresh and hardened properties of
concrete have been compared for natural aggregate concrete (NAC),
PCA concrete (PCC) and PFA concrete (PFC). The compressive
strength of concrete at 28 days varied with the water–cement ratio for
both the PCC and PFC. Between PCC and PFC, PFA concrete
showed the highest compressive strength (23.7 MPa) at 0.42 w/c ratio
and also the lowest compressive strength (13.7 MPa) at 0.57 w/c
ratio. Significant reduction in concrete density was mostly observed
for PCC samples, ranging between 1977–1924 kg/m³. With the
increase in water–cement ratio PCC achieved higher workability
compare to both NAC and PFC. It was found that both the PCA and
PFA contained concrete achieved the required compressive strength
to be used for structural purpose as partial replacement of the natural
aggregate; but to obtain the desired lower density as lightweight
concrete the PCA is most suited.
Abstract: Increasing prevalence of childhood obesity has
increased the interest in early and late indicators of gaining weight.
Cell blood counts may be indicators of pro-inflammatory states. The
aim was to evaluate associations of hematological parameters,
including hematocrit (HTC), hemoglobin, blood cell counts and their
indices with the degree of obesity in pediatric population. A total of
249; -139 morbidly obese (MO), 82 healthy normal weight (NW) and
28 overweight (OW) children were included into the scope of the
study. WHO BMI-for age percentiles were used to form age- and sexmatched
groups. Informed consent forms and the Ethics Committee
approval were obtained. Anthropometric measurements were
performed. Hematological parameters were determined. Statistical
analyses were performed using SPSS. The degree for statistical
significance was p≤0.05. Significant differences (p=0.000) between
waist-to-hip ratios and head-to- neck ratios (hnrs) of MO and NW
children were detected. A significant difference between hnrs of OW
and MO children (p=0.000) was observed. Red cell distribution width
(RDW) was higher in OW children than NW group (p=0.030). Such
finding couldn’t be detected between MO and NW groups. Increased
RDW was prominent in OW children. The decrease in mean
corpuscular hemoglobin concentration (MCHC) values in MO
children was sharper than the values in OW children (p=0.006 vs
p=0.042) compared to those in NW group. Statistically higher HTC
levels were observed between MO-NW (p=0.014), but none between
OW-NW. Though the cause-effect relationship between obesity and
erythrocyte indices still needs further investigation, alterations in
RDW, HTC, MCHC during obesity may be of significance in the
early life.