Abstract: The construction industry has been demonstrating
increased growth and importance in Brazil’s national economic
development. This study aims to evaluate the financial performance
of the leading companies in the construction sector in Brazil in the
period from 2009 to 2012. An analysis is made of the capital
structure, liquidity, and profitability of the six largest companies in
the construction sector in Brazil: Brookfield, Cyrela, Gafisa, MRV,
PDG and Rossi. The results are then compared with standard industry
ratios. It was found that among the companies analyzed, MRV and
Cyrela showed the best relative performance in the period under
consideration.
Abstract: Co-crystal is believed to improve the solubility and
dissolution rates and thus, enhanced the bioavailability of poor water
soluble drugs particularly during the oral route of administration.
With the existing of poorly soluble drugs in pharmaceutical industry,
the screening of co-crystal formation using carbamazepine (CBZ) as
a model drug compound with dicarboxylic acids co-crystal formers
(CCF) namely fumaric (FA) and succinic (SA) acids in ethanol has
been studied. The co-crystal formations were studied by varying the
mol ratio values of CCF to CBZ to access the effect of CCF
concentration on the formation of the co-crystal. Solvent evaporation,
slurry and cooling crystallization which representing the solution
based method co-crystal screening were used. Based on the
differential scanning calorimetry (DSC) analysis, the melting point of
CBZ-SA in different ratio was in the range between 188oC-189oC.
For CBZ-FA form A and CBZ-FA form B the melting point in
different ratio were in the range of 174oC-175oC and 185oC-186oC
respectively. The product crystal from the screening was also
characterized using X-ray powder diffraction (XRPD). The XRPD
pattern profile analysis has shown that the CBZ co-crystals with FA
and SA were successfully formed for all ratios studied. The findings
revealed that CBZ-FA co-crystal were formed in two different
polymorphs. It was found that CBZ-FA form A and form B were
formed from evaporation and slurry crystallization methods
respectively. On the other hand, in cooling crystallization method,
CBZ-FA form A was formed at lower mol ratio of CCF to CBZ and
vice versa. This study disclosed that different methods and mol ratios
during the co-crystal screening can affect the outcome of co-crystal
produced such as polymorphic forms of co-crystal and thereof. Thus,
it was suggested that careful attentions is needed during the screening
since the co-crystal formation is currently one of the promising
approach to be considered in research and development for
pharmaceutical industry to improve the poorly soluble drugs.
Abstract: Ionic liquids consisting of a phosphonium cationic
moiety and a saccharinate anion are synthesized and compared with
their precursors, phosphonium chlorides, in reference to their
extraction efficiency towards L-lactic acid. On the base of
measurements of the acid and the water partitioning in the
equilibrium biphasic systems, the molar ratios between acid, water
and ionic liquid are estimated which allows to deduce the lactic acid
extractive pathway. The effect of a salting-out addition that
strengthens hydrophobicity in both phases is studied in view to reveal
the best biphasic system with respect to IL low toxicity and high
extraction efficiency.
Abstract: Over the past four decades, the fatigue behavior of
nickel-based alloys has been widely studied. However, in recent
years, significant advances in the fabrication process leading to grain
size reduction have been made in order to improve fatigue properties
of aircraft turbine discs. Indeed, a change in particle size affects the
initiation mode of fatigue cracks as well as the fatigue life of the
material. The present study aims to investigate the fatigue behavior of
a newly developed nickel-based superalloy under biaxial-planar
loading. Low Cycle Fatigue (LCF) tests are performed at different
stress ratios so as to study the influence of the multiaxial stress state
on the fatigue life of the material. Full-field displacement and strain
measurements as well as crack initiation detection are obtained using
Digital Image Correlation (DIC) techniques. The aim of this
presentation is first to provide an in-depth description of both the
experimental set-up and protocol: the multiaxial testing machine, the
specific design of the cruciform specimen and performances of the
DIC code are introduced. Second, results for sixteen specimens
related to different load ratios are presented. Crack detection, strain
amplitude and number of cycles to crack initiation vs. triaxial stress
ratio for each loading case are given. Third, from fractographic
investigations by scanning electron microscopy it is found that the
mechanism of fatigue crack initiation does not depend on the triaxial
stress ratio and that most fatigue cracks initiate from subsurface
carbides.
Abstract: Previous studies on financial distress prediction choose
the conventional failing and non-failing dichotomy; however, the
distressed extent differs substantially among different financial
distress events. To solve the problem, “non-distressed”, “slightlydistressed”
and “reorganization and bankruptcy” are used in our article
to approximate the continuum of corporate financial health. This paper
explains different financial distress events using the two-stage method.
First, this investigation adopts firm-specific financial ratios, corporate
governance and market factors to measure the probability of various
financial distress events based on multinomial logit models.
Specifically, the bootstrapping simulation is performed to examine the
difference of estimated misclassifying cost (EMC). Second, this work
further applies macroeconomic factors to establish the credit cycle
index and determines the distressed cut-off indicator of the two-stage
models using such index. Two different models, one-stage and
two-stage prediction models are developed to forecast financial
distress, and the results acquired from different models are compared
with each other, and with the collected data. The findings show that the
one-stage model has the lower misclassification error rate than the
two-stage model. The one-stage model is more accurate than the
two-stage model.
Abstract: Poly vinyl acetate (PVA)-based titania (TiO2)–carbon
nanotube composite nanofibers (PVA-TCCNs) with various
PVA-to-solvent ratios and PVA-based TiO2 composite nanofibers
(PVA-TN) were synthesized using an electrospinning process,
followed by thermal treatment. The photocatalytic activities of these
nanofibers in the degradation of airborne monocyclic aromatics under
visible-light irradiation were examined. This study focuses on the
application of these photocatalysts to the degradation of the target
compounds at sub-part-per-million indoor air concentrations. The
characteristics of the photocatalysts were examined using scanning
electron microscopy, X-ray diffraction, ultraviolet-visible
spectroscopy, and Fourier-transform infrared spectroscopy. For all the
target compounds, the PVA-TCCNs showed photocatalytic
degradation efficiencies superior to those of the reference PVA-TN.
Specifically, the average photocatalytic degradation efficiencies for
benzene, toluene, ethyl benzene, and o-xylene (BTEX) obtained using
the PVA-TCCNs with a PVA-to-solvent ratio of 0.3 (PVA-TCCN-0.3)
were 11%, 59%, 89%, and 92%, respectively, whereas those observed
using PVA-TNs were 5%, 9%, 28%, and 32%, respectively.
PVA-TCCN-0.3 displayed the highest photocatalytic degradation
efficiency for BTEX, suggesting the presence of an optimal
PVA-to-solvent ratio for the synthesis of PVA-TCCNs. The average
photocatalytic efficiencies for BTEX decreased from 11% to 4%, 59%
to 18%, 89% to 37%, and 92% to 53%, respectively, when the flow
rate was increased from 1.0 to 4.0 L min1. In addition, the average
photocatalytic efficiencies for BTEX increased 11% to ~0%, 59% to
3%, 89% to 7%, and 92% to 13%, respectively, when the input
concentration increased from 0.1 to 1.0 ppm. The prepared
PVA-TCCNs were effective for the purification of airborne aromatics
at indoor concentration levels, particularly when the operating
conditions were optimized.
Abstract: Natural hydrocarbon seepage has helped petroleum
exploration as a direct indicator of gas and/or oil subsurface
accumulations. Surface macro-seeps are generally an indication of a
fault in an active Petroleum Seepage System belonging to a Total
Petroleum System. This paper describes a case study in which
multiple analytical techniques were used to identify and characterize
trace petroleum-related hydrocarbons and other volatile organic
compounds in groundwater samples collected from Sousse aquifer
(Central Tunisia). The analytical techniques used for analyses of
water samples included gas chromatography-mass spectrometry (GCMS),
capillary GC with flame-ionization detection, Compound
Specific Isotope Analysis, Rock Eval Pyrolysis. The objective of the
study was to confirm the presence of gasoline and other petroleum
products or other volatile organic pollutants in those samples in order
to assess the respective implication of each of the potentially
responsible parties to the contamination of the aquifer. In addition,
the degree of contamination at different depths in the aquifer was also
of interest. The oil and gas seeps have been investigated using
biomarker and stable carbon isotope analyses to perform oil-oil and
oil-source rock correlations. The seepage gases are characterized by
high CH4 content, very low δ13CCH4 values (-71,9 ‰) and high
C1/C1–5 ratios (0.95–1.0), light deuterium–hydrogen isotope ratios (-
198 ‰) and light δ13CC2 and δ13CCO2 values (-23,8‰ and-23,8‰
respectively) indicating a thermogenic origin with the contribution of
the biogenic gas. An organic geochemistry study was carried out on
the more ten oil seep samples. This study includes light hydrocarbon
and biomarkers analyses (hopanes, steranes, n-alkanes, acyclic
isoprenoids, and aromatic steroids) using GC and GC-MS. The
studied samples show at least two distinct families, suggesting two
different types of crude oil origins: the first oil seeps appears to be
highly mature, showing evidence of chemical and/or biological
degradation and was derived from a clay-rich source rock deposited
in suboxic conditions. It has been sourced mainly by the lower
Fahdene (Albian) source rocks. The second oil seeps was derived
from a carbonate-rich source rock deposited in anoxic conditions,
well correlated with the Bahloul (Cenomanian-Turonian) source rock.
Abstract: Evaluated nuclear decay data for the 217Po nuclide is
presented in the present work. These data include recommended
values for the half-life T1/2, α-, β-- and γ-ray emission energies and
probabilities. Decay data from 221Rn α and 217Bi β—decays are
presented. Q(α) has been updated based on the recent published work
of the Atomic Mass Evaluation AME2012. In addition, the logft
values were calculated using the Logft program from the ENSDF
evaluation package. Moreover, the total internal conversion electrons
and the K-shell to L-shell and L-shell to M-shell and to N-shell
conversion electrons ratios K/L, L/M and L/N have been calculated
using Bricc program. Meanwhile, recommendation values or the
multi-polarities have been assigned based on recently measurement
yield a better intensity balance at the 254 keV and 264 keV gamma
transitions.
Abstract: This paper presents Finite Element Method (FEM) for
analyzing the internal responses generated in thin rectangular plates
with various edge conditions and rigidity conditions. Comparison has
been made between the FEM (ANSYS software) results for
displacement, stresses and moments generated with and without the
consideration of hole in plate and different aspect ratios. In the end
comparison for responses in plain and composite square plates has
been studied.
Abstract: The effects of basil and/or chamomile seed
supplementation on the growth of Hubbard broiler chicks were
evaluated. The antioxidant effects of these supplements were also
assessed. 120 1-day-old broiler chicks were randomly divided into
four equal groups. The control group (group 1) was fed a basal diet
(BD) without supplementation. Groups 2, 3, and 4 were fed the BD
supplemented with 10g basil, 10g chamomile, and 5g basil plus 5g
chamomile per kg of food, respectively. Basil supplementation alone
or in combination with chamomile non-significantly (P≥0.05)
increased final body weight (3.2% and 0.3%, respectively) and
weight gain (3.5% and 3.6%, respectively) over the experimental
period. Chamomile supplementation alone non-significantly (P≥0.05)
reduced final body weight and weight gain over the experimental
period by 1.7% and 1.7%, respectively. In comparison to the control
group, herbal seed supplementation reduced feed intake and
improved the feed conversion and protein efficiency ratios. In
general, basil seed supplementation stimulated chicken growth and
improved the feed efficiency more effectively than chamomile seed
supplementation. The antioxidant activities of basil and/or chamomile
supplementation were examined in the thymus, bursa, and spleen. In
chickens that received supplements, the level of malondialdehyde
was significantly decreased, whereas the activities of glutathione,
superoxide dismutase, and catalase were significantly increased
(P
Abstract: In this paper, the effect of grades 32.4 and 42.5
Portland-limestone cements generally used for concrete production in
Nigeria on concrete compressive strength is investigated.
Investigation revealed that the compressive strength of concrete
produced with Portland-limestone cement grade 42.5 is generally
higher than that produced with cement grade 32.5. The percentage
difference between the compressive strengths of the concrete cubes
produced with Portland-limestone cement grades 42.5 and 32.5 is
inversely proportional to the richness of the concrete with the highest
and the least percentage difference associated with the 1:2:4 and
1:1:2 mix ratios respectively. It is recommended that cement grade
42.5 be preferred for construction in Nigeria as this will lead to the
construction of stronger concrete structures, which will reduce the
incidence of failure of building and other concrete structures at no
additional cost since the cost of both cement grades are the same.
Abstract: The Standard Penetration Test (SPT) is the most
common in situ test for soil investigations. On the other hand, the
Cone Penetration Test (CPT) is considered one of the best
investigation tools. Due to the fast and accurate results that can be
obtained it complaints the SPT in many applications like field
explorations, design parameters, and quality control assessments.
Many soil index and engineering properties have been correlated to
both of SPT and CPT. Various foundation design methods were
developed based on the outcome of these tests. Therefore it is vital to
correlate these tests to each other so that either one of the tests can be
used in the absence of the other, especially for preliminary evaluation
and design purposes.
The primary purpose of this study was to investigate the
relationships between the SPT and CPT for different type of sandy
soils in Florida. Data for this research were collected from number of
projects sponsored by the Florida Department of Transportation
(FDOT), six sites served as the subject of SPT-CPT correlations. The
correlations were established between the cone resistance (qc), sleeve
friction (fs) and the uncorrected SPT blow counts (N) for various
soils.
A positive linear relationship was found between qc, fs and N for
various sandy soils. In general, qc versus N showed higher
correlation coefficients than fs versus N. qc/N ratios were developed
for different soil types and compared to literature values, the results
of this research revealed higher ratios than literature values.
Abstract: In this paper, a nonlinear Finite Element Analysis
(FEA) was carried out using ANSYS software to build a model able
of predicting the behavior of Reinforced Concrete (RC) beams with
unbonded reinforcement. The FEA model was compared to existing
experimental data by other researchers. The existing experimental
data consisted of 16 beams that varied from structurally sound beams
to beams with unbonded reinforcement with different unbonded
lengths and reinforcement ratios. The model was able to predict the
ultimate flexural strength, load-deflection curve, and crack pattern of
concrete beams with unbonded reinforcement. It was concluded that
when the when the unbonded length is less than 45% of the span,
there will be no decrease in the ultimate flexural strength due to the
loss of bond between the steel reinforcement and the surrounding
concrete regardless of the reinforcement ratio. Moreover, when the
reinforcement ratio is relatively low, there will be no decrease in
ultimate flexural strength regardless of the length of unbond.
Abstract: In the present work, the alloy of Bismuth-lead is
prepared on the basis of percentage of molecular weight 9:1, 5:5 and
1:9 ratios and grown by Zone- Refining Technique under a vacuum
atmosphere. The EDAX of these samples are done and the results are
reported. Micro hardness test has been used as an alternative test for
measuring material’s tensile properties. The effect of temperature and
load on the hardness of the grown alloy has been studied. Further the
comparative studies of work hardening coefficients are reported.
Abstract: In this paper, model order reduction method is used
for approximation in linear and nonlinearity aspects in some
experimental data. This method can be used for obtaining offline
reduced model for approximation of experimental data and can
produce and follow the data and order of system and also it can
match to experimental data in some frequency ratios. In this study,
the method is compared in different experimental data and influence
of choosing of order of the model reduction for obtaining the best and
sufficient matching condition for following the data is investigated in
format of imaginary and reality part of the frequency response curve
and finally the effect and important parameter of number of order
reduction in nonlinear experimental data is explained further.
Abstract: Compositions of different molar ratios of
polymethylmethacrylate-co-methacrylic acid (PMMA-co-MAA)
were synthesized via free-radical polymerization. Polymer coated
surfaces have been produced on silicon wafers. Coated samples were
analyzed by atomic force microscopy (AFM). The results have shown
that the roughness of the surfaces have increased by increasing the
molar ratio of monomer methacrylic acid (MAA). This study reveals
that the gradual increase in surface roughness is due to the fact that
carboxylic functional groups have been generated by MAA segments.
Such surfaces can be desirable platforms for fabrication of the
biosensors for detection of the viruses and diseases.
Abstract: The aim of this work was to apply extractive
distillation for acetonitrile removal from water solutions, to validate
thermodynamic criterion based on excess Gibbs energy to entrainer
selection process for acetonitrile – water mixture separation and show
its potential efficiency at isothermal conditions as well as at isobaric
(conditions of real distillation process), to simulate and analyze an
extractive distillation process with chosen entrainers: optimize
amount of trays and feeds, entrainer/original mixture and reflux
ratios. Equimolar composition of the feed stream was chosen for the
process, comparison of the energy consumptions was carried out.
Glycerol was suggested as the most energetically and ecologically
suitable entrainer.
Abstract: In view of a possible application in optical data
storage devices, diffraction grating efficiency of an organic dye, Acid
Fuchsin doped in PMMA matrix was studied under excitation with
CW diode pumped Nd: YAG laser at 532 nm. The open aperture Zscan
of dye doped polymer displayed saturable absorption and the
closed aperture Z-scan of the samples exhibited negative
nonlinearity. The diffraction efficiency of the grating is the ratio of
the intensity of the first order diffracted power to the incident read
beam power. The dye doped polymer films were found to be good
media for recording. It is observed that the formation of gratings
strongly depend on the concentration of dye in the polymer film, the
intensity ratios of the writing beams and the angle between the
writing beams. It has been found that efficient writing can be made at
an angle of 20o and when the intensity ratio of the writing beams is
unity.
Abstract: This paper proposes a backward/forward sweep
method to analyze the power flow in radial distribution systems. The
distribution system has radial structure and high R/X ratios. So the
newton-raphson and fast decoupled methods are failed with
distribution system. The proposed method presents a load flow study
using backward/forward sweep method, which is one of the most
effective methods for the load-flow analysis of the radial distribution
system. By using this method, power losses for each bus branch and
voltage magnitudes for each bus node are determined. This method
has been tested on IEEE 33-bus radial distribution system and
effective results are obtained using MATLAB.
Abstract: The hydrogenated amorphous carbon films (α-C:H)
were deposited on p-type Si (100) substrates at different thicknesses by
radio frequency plasma enhanced chemical vapor deposition
technique (rf-PECVD). Raman spectra display asymmetric
diamond-like carbon (DLC) peaks, representative of the α-C:H films.
The decrease of intensity ID/IG ratios revealed the sp3 content arise at
different thicknesses of the α-C:H films. In terms of mechanical
properties, the high hardness and elastic modulus values showed the
elastic and plastic deformation behaviors related to sp3 content in
amorphous carbon films. Electrochemical properties showed that the
α-C:H films exhibited excellent corrosion resistance in air-saturated
3.5 wt.% NaCl solution for pH 2 at room temperature. Thickness
increasing affected the small sp2 clusters in matrix, restricting the
velocity transfer and exchange of electrons. The deposited α-C:H films
exhibited excellent mechanical properties and corrosion resistance.