Abstract: The rapidly increasing costs of power line extensions
and fossil fuel, combined with the desire to reduce carbon dioxide
emissions pushed the development of hybrid power system suited for
remote locations, the purpose in mind being that of autonomous local
power systems. The paper presents the suggested solution for a “high
penetration" hybrid power system, it being determined by the
location of the settlement and its “zero policy" on carbon dioxide
emissions. The paper focuses on the technical solution and the power
flow management algorithm of the system, taking into consideration
local conditions of development.
Abstract: Renewable energy sources have gained ultimate urgency due to the need of the preservation of the environment for a sustainable development. Pyrolysis is an ultimate promising process in the recycling and acquisition of precious chemicals from wastes. Here, the co-pyrolysis of hazelnut shell with ultra-high molecular weight polyethylene was carried out catalytically and noncatalytically at 500 and 650 ºC. Potassium dichromate was added in certain amounts to act as a catalyst. The liquid, solid and gas products quantities were determined by gravimetry. As a main result, remarkable increases in gasification were observed by using this catalyst for pure components and their blends especially at 650 ºC. The increase in gas product quantity was compensated mainly with the decreases in the solid products and additionally in some cases liquid products quantities. These observations may stem from mainly the activation of carbon-carbon bonds rather than carbon-hydrogen bonds via potassium dichromate. Also, the catalytic effect of potassium dichromate on HS: PEO and HS: UHMWPE co-pyrolysis was compared.
Abstract: There are several means to measure the oxidation of edible oils, such as the acid value, the peroxide value, and the anisidine value. However, these means require large quantities of reagents and are time-consuming tasks. Therefore, a more convenient and time-saving way to measure the oxidation of edible oils is required. In this report, an edible oil condition sensor was fabricated by using single-walled nanotubes (SWNT). In order to test the sensor, oxidized edible oils, each one at a different acid value, were prepared. The SWNT sensors were immersed into these oxidized oils and the resistance changes in the sensors were measured. It was found that the conductivity of the sensors decreased as the oxidation level of oil increased. This result suggests that a change of the oil components induced by the oxidation process in edible oils is related to the conductivity change in the SWNT sensor.
Abstract: This paper presents the development of low cost Nano membrane fabrication system. The system is specially designed for anodic aluminum oxide membrane. This system is capable to perform the processes such as anodization and electro-polishing. The designed machine was successfully tested for 'mild anodization' (MA) for 48 hours and 'hard anodization' (HA) for 3 hours at constant 0oC. The system is digitally controlled and guided for temperature maintenance during anodization and electro-polishing. The total cost of the developed machine is 20 times less than the multi-cooling systems available in the market which are generally used for this purpose.
Abstract: The complexity of lignocellulosic biomass requires
a pretreatment step to improve the yield of fermentable sugars. The
efficient pretreatment of corn cobs using microwave and potassium
hydroxide and enzymatic hydrolysis was investigated. The
objective of this work was to characterize the optimal condition of
pretreatment of corn cobs using microwave and potassium
hydroxide enhance enzymatic hydrolysis. Corn cobs were
submerged in different potassium hydroxide concentration at varies
temperature and resident time. The pretreated corn cobs were
hydrolyzed to produce the reducing sugar for analysis. The
morphology and microstructure of samples were investigated by
Thermal gravimetric analysis (TGA, scanning electron microscope
(SEM), X-ray diffraction (XRD). The results showed that lignin
and hemicellulose were removed by microwave/potassium
hydroxide pretreatment. The crystallinity of the pretreated corn
cobs was higher than the untreated. This method was compared
with autoclave and conventional heating method. The results
indicated that microwave-alkali treatment was an efficient way to
improve the enzymatic hydrolysis rate by increasing its
accessibility hydrolysis enzymes.
Abstract: The research investigates the effects of super plasticizer and molarity of sodium hydroxide alkaline solution on the workability, microstructure and compressive strength of self compacting geopolymer concrete (SCGC). SCGC is an improved way of concreting execution that does not require compaction and is made by complete elimination of ordinary Portland cement content. The parameters studied were superplasticizer (SP) dosage and molarity of NaOH solution. SCGC were synthesized from low calcium fly ash, activated by combinations of sodium hydroxide and sodium silicate solutions, and by incorporation of superplasticizer for self compactability. The workability properties such as filling ability, passing ability and resistance to segregation were assessed using slump flow, T-50, V-funnel, L-Box and J-ring test methods. It was found that the essential workability requirements for self compactability according to EFNARC were satisfied. Results showed that the workability and compressive strength improved with the increase in superplasticizer dosage. An increase in strength and a decrease in workability of these concrete samples were observed with the increase in molarity of NaOH solution from 8M to 14M. Improvement of interfacial transition zone (ITZ) and micro structure with the increase of SP and increase of concentration from 8M to 12M were also identified.
Abstract: Plastics occupy wide place in the applications of
automotive, electronics and house goods. Especially reinforced
plastics become popular because of their high strength besides their
advantages of low weight and easy manufacturability. In this study,
mechanical and morphological properties of polypropylene (PP) and
high density polyethylene (HDPE) matrix composites reinforced with
surface modified nano titan dioxide (TiO2) particles were
investigated. Surface modification was made by coating the nano
powders with maleic anhydride grafted styrene ethylene butylene
styrene (SEBS-g-MA) and silane, respectively. After surface
modification, PP/TiO2 and HDPE/TiO2 composites were obtained by
using twin screw extruder at titan dioxide loading of 1 wt.%, 3 wt.%
and 5 wt.%. Effects of surface modification were determined by
thermal and morphological analysis. SEBS-g-MA provided bridging
effect between TiO2 particles and polymer matrix while silane was
effective as a dispersant. Depending on that, homogenous structures
without agglomeration were obtained. Mechanical tests were
performed on the injection moldings of the composites for obtaining
the impact strength, tensile strength, stress at break, elongation and
elastic modulus. Reinforced HDPE and PP moldings gave higher
tensile strength and elastic modulus due to the rigid structure of TiO2.
Slight increment was seen in stress at break. Elongation and impact
strength decreased due to the stiffness of the nano titan dioxide.
Abstract: The objective of the present study was to examine the
dose-response relationships between antioxidant parameters and liver
contaminant levels of Kazakhstan light crude oil (KLCO) in albino
rats. The animals were repeatedly exposed, by intraperitoneal
injection, to low dosages (0.5–1.5 ml/kg) of KLCO. Rats exposed to
these doses levels did not show any apparent symptoms of
intoxication. Serum aminotransferases increased significantly
(p
Abstract: High pressure adsorption of carbon dioxide on zeolite
13X was investigated in the pressure range (0 to 4) Mpa and
temperatures 298, 308 and 323K. The data fitting is accomplished
with the Toth, UNILAN, Dubinin-Astakhov and virial adsorption
models which are generally used for micro porous adsorbents such as
zeolites. Comparison with experimental data from the literature
indicated that the virial model would best determine results. These
results may be partly attributed to the flexibility of the virial model
which can accommodate as many constants as the data warrants.
Abstract: Theobjective of this study was to evaluate the optimal
treatment condition of Fenton oxidation process to removal
contaminant in soil slurry contaminated by petroleum hydrocarbons.
This research studied somefactors that affect the removal efficiency
of petroleum hydrocarbons in soil slurry including molar ratio of
hydrogen peroxide (H2O2) to ferrous ion(Fe2+), pH condition and
reaction time.The resultsdemonstrated that the optimum condition
was that the molar ratio of H2O2:Fe3+ was 200:1,the pHwas 4.0and
the rate of reaction was increasing rapidly from starting point to 7th
hour and destruction kinetic rate (k) was 0.24 h-1. Approximately
96% of petroleum hydrocarbon was observed(initialtotal petroleum
hydrocarbon (TPH) concentration = 70±7gkg-1)
Abstract: In this paper, Zinc Oxide (ZnO) thin films are deposited on glass substrate by sol-gel method. The ZnO thin films with well defined orientation were acquired by spin coating of zinc acetate dehydrate monoethanolamine (MEA), de-ionized water and isopropanol alcohol. These films were pre-heated at 275°C for 10 min and then annealed at 350°C, 450°C and 550°C for 80 min. The effect of annealing temperature and different thickness on structure and surface morphology of the thin films were verified by Atomic Force Microscopy (AFM). It was found that there was a significant effect of annealing temperature on the structural parameters of the films such as roughness exponent, fractal dimension and interface width. Thin films also were characterizied by X-ray Diffractometery (XRD) method. XRD analysis revealed that the annealed ZnO thin films consist of single phase ZnO with wurtzite structure and show the c-axis grain orientation. Increasing annealing temperature increased the crystallite size and the c-axis orientation of the film after 450°C. Also In this study, ZnO thin films in different thickness have been prepared by sol-gel method on the glass substrate at room temperature. The thicknesses of films are 100, 150 and 250 nm. Using fractal analysis, morphological characteristics of surface films thickness in amorphous state were investigated. The results show that with increasing thickness, surface roughness (RMS) and lateral correlation length (ξ) are decreased. Also, the roughness exponent (α) and growth exponent (β) were determined to be 0.74±0.02 and 0.11±0.02, respectively.
Abstract: Gas hydrates form when a number of factors co-exist:
free water, hydrocarbon gas, cold temperatures and high pressures are typical of the near mud-line conditions in a deepwater drilling
operation. Subsequently, when drilling with water based muds, particularly on exploration wells, the risk of hydrate formation
associated with a gas influx is high. The consequences of gas hydrate
formation while drilling are severe, and as such, every effort should be made to ensure the risk of hydrate formation is either eliminated
or significantly reduced. Thermodynamic inhibitors are used to reduce the free water content of a drilling mud, and thus suppress the
hydrate formation temperature. Very little experimental work has
been performed by oil and gas research companies on the evaluation
of gas hydrate formation in a water-based drilling mud. The main
objective of this paper is to investigate the experimental gas hydrate
formation for a mixture of methane, carbon dioxide & nitrogen in a
water-based drilling mud with or without presence of different
concentrations of thermodynamic inhibitors including pure salt and a
combination of salt with methanol or ethylene glycol at different
concentrations in a static loop apparatus. The experiments were
performed using a static loop apparatus consisting of a 2.4307 cm
inside diameter and 800 cm long pipe. All experiments were conducted at 2200 psia. The temperature in the loop was decreased at
a rate of 3.33 °F/h from initial temperature of 80 °F.
Abstract: The conventional production of biodiesel from crude
palm oil which contains large amounts of free fatty acids in the
presence of a homogeneous base catalyst confronts the problems of
soap formation and very low yield of biodiesel. To overcome these
problems, free fatty acids must be esterified to their esters in the
presence of an acid catalyst prior to alkaline-catalyzed
transesterification. Sulfated metal oxides are a promising group of
catalysts due to their very high acidity. In this research, aluminadoped
sulfated tin oxide (SO4
2-/Al2O3-SnO2) catalysts were prepared
and used for esterification of free fatty acids in crude palm oil in a
batch reactor. The SO4
2-/Al2O3-SnO2 catalysts were prepared from
different Al precursors. The results showed that different Al
precursors gave different activities of the SO4
2-/Al2O3-SnO2 catalysts.
The esterification of free fatty acids in crude palm oil with methanol
in the presence of SO4
2-/Al2O3-SnO2 catalysts followed first-order
kinetics.
Abstract: Magnetic and semiconductor nanomaterials exhibit
novel magnetic and optical properties owing to their unique size and
shape-dependent effects. With shrinking the size down to nanoscale
region, various anomalous properties that normally not present in bulk
start to dominate. Ability in harnessing of these anomalous properties
for the design of various advance electronic devices is strictly
dependent on synthetic strategies. Hence, current research has focused
on developing a rational synthetic control to produce high quality
nanocrystals by using organometallic approach to tune both size and
shape of the nanomaterials. In order to elucidate the growth
mechanism, transmission electron microscopy was employed as a
powerful tool in performing real time-resolved morphologies and
structural characterization of magnetic (Fe3O4) and semiconductor
(ZnO) nanocrystals. The current synthetic approach is found able to
produce nanostructures with well-defined shapes. We have found that
oleic acid is an effective capping ligand in preparing oxide-based
nanostructures without any agglomerations, even at high temperature.
The oleate-based precursors and capping ligands are fatty acid
compounds, which are respectively originated from natural palm oil
with low toxicity. In comparison with other synthetic approaches in
producing nanostructures, current synthetic method offers an effective
route to produce oxide-based nanomaterials with well-defined shapes
and good monodispersity. The nanocystals are well-separated with
each other without any stacking effect. In addition, the as-synthesized
nanopellets are stable in terms of chemically and physically if
compared to those nanomaterials that are previous reported. Further
development and extension of current synthetic strategy are being
pursued to combine both of these materials into nanocomposite form
that will be used as “smart magnetic nanophotocatalyst" for industry
waste water treatment.
Abstract: Novel Coconut oil nanofluids of various concentrations have been prepared through ultrasonically assisted sol-gel method. The structural and morphological properties of the copper oxide nanoparticle have been analyzed with respectively and it revealed the monoclinic end-centered structure of crystallite and shuttle like flake morphology of agglomerates. Ultrasonic studies have been made for the nanofluids at different temperatures. The molecular interactions responsible for the changes in acoustical parameter with respect to concentration and temperature are discussed.
Abstract: The rangelands, as one of the largest dynamic biomes
in the world, have very capabilities. Regulation of greenhouse gases
in the Earth's atmosphere, particularly carbon dioxide as the main
these gases, is one of these cases. The attention to rangeland, as
cheep and reachable resources to sequestrate the carbon dioxide,
increases after the Industrial Revolution. Rangelands comprise the
large parts of Iran as a steppic area. Rudshur (Saveh), as area index of
steppic area, was selected under three sites include long-term
exclosure, medium-term exclosure, and grazable area in order to the
capable of carbon dioxide’s sequestration of dominated species.
Canopy cover’s percentage of two dominated species (Artemisia
sieberi Besser & Stipa barbata Desf) was determined via establishing
of random 1 square meter plot. The sampling of above and below
ground biomass style was obtained by complete random. After
determination of ash percentage in the laboratory; conversion ratio of
plant biomass to organic carbon was calculated by ignition method.
Results of the paired t-test showed that the amount of carbon
sequestration in above ground and underground biomass of Artemisia
sieberi Besser & Stipa barbata Desf is different in three regions. It,
of course, hasn’t any difference between under and surface ground’s
biomass of Artemisia sieberi Besser in long-term exclosure. The
independent t-test results indicate differences between underground
biomass corresponding each other in the studied sites. Carbon
sequestration in the Stipa barbata Desf was totally more than
Artemisia sieberi Besser. Altogether, the average sequestration of the
long-term exclosure was 5.842gr/m², the medium-term exclosure was
4.115gr/m², and grazable area was 5.975gr/m² so that there isn’t
valuable statistical difference in term of total amount of carbon
sequestration to three sites.
Abstract: Acid rain occurs when sulphur dioxide (SO2) and
nitrogen oxides (Nox) gases react in the atmosphere with water,
oxygen, and other chemicals to form various acidic compounds. The
result is a mild solution of sulfuric acid and nitric acid. Soil has a
greater buffering capacity than aquatic systems. However excessive
amount of acids introduced by acid rains may disturb the entire soil
chemistry. Acidity and harmful action of toxic elements damage
vegetation while susceptible microbial species are eliminated. In
present study, the effects of simulated sulphuric acid and nitric acid
rains were investigated on crop Glycine max. The effect of acid rain
on change in soil fertility was detected in which pH of control sample
was 6.5 and pH of 1%H2SO4 and 1%HNO3 were 3.5. Nitrogen nitrate
in soil was high in 1% HNO3 treated soil & Control sample.
Ammonium nitrogen in soil was low in 1% HNO3 & H2SO4 treated
soil. Ammonium nitrogen was medium in control and other samples.
The effect of acid rain on seed germination on 3rd day of germination
control sample growth was 7 cm, 0.1% HNO3 was 8cm, and 0.001%
HNO3 & 0.001% H2SO4 was 6cm each. On 10th day fungal growth
was observed in 1% and 0.1%H2SO4 concentrations, when all plants
were dead. The effect of acid rain on crop productivity was
investigated on 3rd day roots were developed in plants. On12th day
Glycine max showed more growth in 0.1% HNO3, 0.001% HNO3 and
0.001% H2SO4 treated plants growth were same as compare to control
plants. On 20th day development of discoloration of plant pigments
were observed on acid treated plants leaves. On 38th day, 0.1, 0.001%
HNO3 and 0.1, 0.001% H2SO4 treated plants and control plants were
showing flower growth. On 42th day, acid treated Glycine max variety
and control plants were showed seeds on plants. In Glycine max
variety 0.1, 0.001% H2SO4, 0.1, 0.001% HNO3 treated plants were
dead on 46th day and fungal growth was observed. The toxicological
study was carried out on Glycine max plants exposed to 1% HNO3
cells were damaged more than 1% H2SO4. Leaf sections exposed to
0.001% HNO3 & H2SO4 showed less damaged of cells and
pigmentation observed in entire slide when compare with control
plant. The soil analysis was done to find microorganisms in HNO3 &
H2SO4 treated Glycine max and control plants. No microorganism
growth was observed in 1% HNO3 & H2SO4 but control plant showed
microbial growth.
Abstract: Removal of a reactive dye (Reactive blue 4) by
adsorption utilizing waste aluminium hydroxide sludge as an
adsorbent was investigated. The removal of the dye was optimized
using response surface methodology (RSM). In the RSM
experiments; initial dye concentration, adsorbent concentration and
contact time were critical parameters. RSM experiments were
performed at the range of initial dye concentration 31.82-368.18
mg/L, adsorbent concentration 3.18-36.82 g/L, contact time 15.82-
56.18 h. Optimum initial dye concentration, adsorbent concentration
and contact time were obtained as 108.83 mg/L, 29.36 g/L and 33.57
h respectively. At these conditions, maximum removal of the dye was
obtained as 95%. The experiments were performed at the optimum
conditions to verify these results and the same results were obtained.
Abstract: Transesterified vegetable oils (biodiesel) are promising alternative fuel for diesel engines. Used vegetable oils are disposed from restaurants in large quantities. But higher viscosity restricts their direct use in diesel engines. In this study, used cooking oil was dehydrated and then transesterified using an alkaline catalyst. The combustion, performance and emission characteristics of Used Cooking oil Methyl Ester (UCME) and its blends with diesel oil are analysed in a direct injection C.I. engine. The fuel properties and the combustion characteristics of UCME are found to be similar to those of diesel. A minor decrease in thermal efficiency with significant improvement in reduction of particulates, carbon monoxide and unburnt hydrocarbons is observed compared to diesel. The use of transesterified used cooking oil and its blends as fuel for diesel engines will reduce dependence on fossil fuels and also decrease considerably the environmental pollution.
Abstract: The removal efficiency of 4-chlorophenol with
different advanced oxidation processes have been studied. Oxidation
experiments were carried out using two 4-chlorophenol
concentrations: 100 mg L-1 and 250 mg L-1 and UV generated from a
KrCl excilamp with (molar ratio H2O2: 4-chlorophenol = 25:1) and
without H2O2, and, with Fenton process (molar ratio H2O2:4-
chlorophenol of 25:1 and Fe2+ concentration of 5 mg L-1).
The results show that there is no significant difference in the 4-
chlorophenol conversion when using one of the three assayed
methods. However, significant concentrations of the photoproductos
still remained in the media when the chosen treatment involves UV
without hydrogen peroxide. Fenton process removed all the
intermediate photoproducts except for the hydroquinone and the
1,2,4-trihydroxybenzene. In the case of UV and hydrogen peroxide
all the intermediate photoproducts are removed.
Microbial bioassays were carried out utilising the naturally
luminescent bacterium Vibrio fischeri and a genetically modified
Pseudomonas putida isolated from a waste treatment plant receiving
phenolic waste. The results using V. fischeri show that with samples
after degradation, only the UV treatment showed toxicity (IC50 =38)
whereas with H2O2 and Fenton reactions the samples exhibited no
toxicity after treatment in the range of concentrations studied. Using
the Pseudomonas putida biosensor no toxicity could be detected for
all the samples following treatment due to the higher tolerance of the
organism to phenol concentrations encountered.