Abstract: An autonomous environmental monitoring system
(Smart Landfill) has been constructed for the quantitative
measurement of the components of landfill gas found at borehole
wells at the perimeter of landfill sites. The main components of
landfill gas are the greenhouse gases, methane and carbon dioxide
and have been monitored in the range 0-5 % volume. This monitoring
system has not only been tested in the laboratory but has been
deployed in multiple field trials and the data collected successfully
compared with on-site monitors. This success shows the potential of
this system for application in environments where reliable gas
monitoring is crucial.
Abstract: Biodiesel is traditionally produced from oleaginous
plants. On the other hand, increasing biodiesel production from these
raw materials could create problems of food supply. Producing
biodiesel from microalgae could help to overcome this difficulty,
because microalgae are rich in lipids and do not compete for arable
lands. However, no studies had compared vegetable and microalgae
oil-based biodiesel in terms of yield, viscosity and heat of
combustion. In the present study, commercial canola and microalgae
oil were therefore transesterified with methanol under a homogenous
alkali catalyst (potassium hydroxide) at 100oC for 1h. The result
showed that microalgae-based oil has a higher yield in biodiesel with
89.7% (g biodiesel/g oil) and a lower kinematic viscosity (22oC) of
4.31 mm/s2 than canola oil.
Abstract: Biodisel is a type of biofuel having similar properties of diesel fuel but lacks substances (undesirable emissions) such as sulfur, nitrogen and aromatic polycyclic. Upon filtration of waste oil, the biodiesel fuel was produced via carrying out transestrification reaction of triglycerides followed by conducting viscosity, density, flash point, cloud point, pour point and copper strip corrosion tests on the samples and comparing with EN14214 and ASTM 6751 standards and all results were found in the permitted limit. The highest yield of biodiesel production reaction was found 46.6435 g when Sodium Hydroxide catalyst in amount of 0.375g was employed, 44.2347 g when Sodium methoxide catalyst in amount of 0.5g was employed and 56.5124 g when acid sulfuric catalyst in amount of 1g was employed and 47.3290 g when two stage reaction was done.
Abstract: In this paper, we propose a novel metal oxide
semiconductor field effect transistor with L-shaped channel structure
(LMOS), and several type of L-shaped structures are also designed,
studied and compared with the conventional MOSFET device for the
same average gate length (Lavg). The proposed device electrical
characteristics are analyzed and evaluated by three dimension (3-D)
ISE-TCAD simulator. It can be confirmed that the LMOS devices
have higher on-state drain current and both lower drain-induced
barrier lowering (DIBL) and subthreshold swing (S.S.) than its
conventional counterpart has. In addition, the transconductance and
voltage gain properties of the LMOS are also improved.
Abstract: The use of magnetic and magnetic/gold core/shell
nanoparticles in biotechnology or medicine has shown good promise
due to their hybrid nature which possesses superior magnetic and
optical properties. Some of these potential applications include
hyperthermia treatment, bio-separations, diagnostics, drug delivery
and toxin removal. Synthesis refinement to control geometric and
magnetic/optical properties, and finding functional surfactants for
biomolecular attachment, are requirements to meet application
specifics.
Various high-temperature preparative methods were used for the
synthesis of iron oxide and gold-coated iron oxide nanoparticles.
Different surface functionalities, such as 11-aminoundecanoic and
11-mercaptoundecanoic acid, were introduced on the surface of the
particles to facilitate further attachment of biomolecular functionality
and drug-like molecules. Nanoparticle thermal stability, composition,
state of aggregation, size and morphology were investigated and the
results from techniques such as Fourier Transform-Infra Red
spectroscopy (FT-IR), Ultraviolet visible spectroscopy (UV-vis),
Transmission Electron Microscopy (TEM) and thermal analysis are
discussed.
Abstract: Nano sized zirconium dioxide in monoclinic phase (m-ZrO2) has been synthesized in pure form through co-precipitation processing at different calcination temperatures and has been characterized by several techniques such as XRD, FT-IR, UV-Vis Spectroscopy and SEM. The dielectric and capacitance values of the pelletized samples have been examined at room temperature as the functions of frequency. The higher dielectric constant value of the sample having larger grain size proves the strong influence of grain size on the dielectric constant.
Abstract: As the Textile Industry is the second largest industry
in Egypt and as small and medium-sized enterprises (SMEs) make up
a great portion of this industry therein it is essential to apply the
concept of Cleaner Production for the purpose of reducing pollution.
In order to achieve this goal, a case study concerned with ecofriendly
stone-washing of jeans-garments was investigated. A raw
material-substitution option was adopted whereby the toxic
potassium permanganate and sodium sulfide were replaced by the
environmentally compatible hydrogen peroxide and glucose
respectively where the concentrations of both replaced chemicals
together with the operating time were optimized. In addition, a
process-rationalization option involving four additional processes
was investigated. By means of criteria such as product quality,
effluent analysis, mass and heat balance; and cost analysis with the
aid of a statistical model, a process optimization treatment revealed
that the superior process optima were 50%, 0.15% and 50min for
H2O2 concentration, glucose concentration and time, respectively.
With these values the superior process ought to reduce the annual
cost by about EGP 105 relative to the currently used conventional
method.
Abstract: The accelerated sonophotocatalytic degradation of
Reactive Red (RR) 120 dye under visible light using dye sensitized
TiO2 activated by ultrasound has been carried out. The effect of
sonolysis, photocatalysis and sonophotocatalysis under visible light
has been examined to study the influence on the degradation rates by
varying the initial substrate concentration, pH and catalyst loading to
ascertain the synergistic effect on the degradation techniques.
Ultrasonic activation contributes degradation through cavitation
leading to the splitting of H2O2 produced by both photocatalysis and
sonolysis. This results in the formation of oxidative species, such as
singlet oxygen (1O2) and superoxide (O2
-●) radicals in the presence of
oxygen. The increase in the amount of reactive radical species which
induce faster oxidation of the substrate and degradation of
intermediates and also the deaggregation of the photocatalyst are
responsible for the synergy observed under sonication. A
comparative study of photocatalysis and sonophotocatalysis using
TiO2, Hombikat UV 100 and ZnO was also carried out.
Abstract: Construction projects generally take place in
uncontrolled and dynamic environments where construction waste is
a serious environmental problem in many large cities. The total
amount of waste and carbon dioxide emissions from transportation
vehicles are still out of control due to increasing construction
projects, massive urban development projects and the lack of
effective tools for minimizing adverse environmental impacts in
construction. This research is about utilization of the integrated
applications of automated advanced tracking and data storage
technologies in the area of environmental management to monitor
and control adverse environmental impacts such as construction
waste and carbon dioxide emissions. Radio Frequency Identification
(RFID) integrated with the Global Position System (GPS) provides
an opportunity to uniquely identify materials, components, and
equipments and to locate and track them using minimal or no worker
input. The transmission of data to the central database will be carried
out with the help of Global System for Mobile Communications
(GSM).
Abstract: This paper presents the findings of an
experimental investigation to study the effect of alkali content
in geopolymer mortar specimens exposed to sulphuric acid.
Geopolymer mortar specimens were manufactured from Class F fly
ash by activation with a mixture of sodium hydroxide and sodium
silicate solution containing 5% to 8% Na2O. Durability of specimens
were assessed by immersing them in 10% sulphuric acid solution and
periodically monitoring surface deterioration and depth of
dealkalization, changes in weight and residual compressive strength
over a period of 24 weeks. Microstructural changes in the specimens
were studied with Scanning electron microscopy (SEM) and EDAX.
Alkali content in the activator solution significantly affects the
durability of fly ash based geopolymer mortars in sulphuric acid.
Specimens manufactured with higher alkali content performed better
than those manufactured with lower alkali content. After 24 weeks in
sulphuric acid, specimen with 8% alkali still recorded a residual
strength as high as 55%.
Abstract: This study investigates the electrical performance of a
planar solid oxide fuel cell unit with cross-flow configuration when the fuel utilization gets higher and the fuel inlet flow are non-uniform.
A software package in this study solves two-dimensional,
simultaneous, partial differential equations of mass, energy, and
electro-chemistry, without considering stack direction variation. The
results show that the fuel utilization increases with a decrease in the molar flow rate, and the average current density decreases when the
molar flow rate drops. In addition, non-uniform Pattern A will induce more severe happening of non-reaction area in the corner of the fuel
exit and the air inlet. This non-reaction area deteriorates the average
current density and then deteriorates the electrical performance to –7%.
Abstract: The greenhouse effect and limitations on carbon
dioxide emissions concern engine maker and the future of the
internal combustion engines should go toward substantially and
improved thermal efficiency engine. Homogeneous charge
compression ignition (HCCI) is an alternative high-efficiency
technology for combustion engines to reduce exhaust emissions and
fuel consumption. However, there are still tough challenges in the
successful operation of HCCI engines, such as controlling the
combustion phasing, extending the operating range, and high
unburned hydrocarbon and CO emissions. HCCI and the exploitation
of ethanol as an alternative fuel is one way to explore new frontiers
of internal combustion engines with an eye towards maintaining its
sustainability. This study was done to extend database knowledge
about HCCI with ethanol a fuel.
Abstract: In a world of climate change and limited fossil fuel resources, renewable energy sources are playing an increasingly important role. Due to industrializations and population growth our economy and technologies today largely depend upon natural resources, which are not replaceable. Approximately 90% of our energy consumption comes from fossil fuels (viz. coal, oil and natural gas). The irony is that these resources are depleting. Also, the huge consumption of fossil fuels has caused visible damage to the environment in various forms viz. global warming, acid rains etc.
Abstract: Antimosy-doped tin oxide (ATO) particles were
prepared via chemical coprecipitation and reverse emulsion. The size
and size distribution of ATO particles were obviously decreased via
reverse microemulsion method. At the relatively high yield the ATO
particles were nearly spherical in shape, meanwhile the crystalline
structure and excellent conductivity were reserved, which could satisfy
the requirement as composite fillers, such as dielectric filler of
polyimide film.
Abstract: Fluids are used for heat transfer in many engineering
equipments. Water, ethylene glycol and propylene glycol are some
of the common heat transfer fluids. Over the years, in an attempt to
reduce the size of the equipment and/or efficiency of the process,
various techniques have been employed to improve the heat transfer
rate of these fluids. Surface modification, use of inserts and
increased fluid velocity are some examples of heat transfer
enhancement techniques. Addition of milli or micro sized particles
to the heat transfer fluid is another way of improving heat transfer
rate. Though this looks simple, this method has practical problems
such as high pressure loss, clogging and erosion of the material of
construction. These problems can be overcome by using nanofluids,
which is a dispersion of nanosized particles in a base fluid.
Nanoparticles increase the thermal conductivity of the base fluid
manifold which in turn increases the heat transfer rate. In this work,
the heat transfer enhancement using aluminium oxide nanofluid has
been studied by computational fluid dynamic modeling of the
nanofluid flow adopting the single phase approach.
Abstract: The mineral having chemical compositional formula MgAl2O4 is called “spinel". The ferrites crystallize in spinel structure are known as spinel-ferrites or ferro-spinels. The spinel structure has a fcc cage of oxygen ions and the metallic cations are distributed among tetrahedral (A) and octahedral (B) interstitial voids (sites). The X-ray diffraction (XRD) intensity of each Bragg plane is sensitive to the distribution of cations in the interstitial voids of the spinel lattice. This leads to the method of determination of distribution of cations in the spinel oxides through XRD intensity analysis. The computer program for XRD intensity analysis has been developed in C language and also tested for the real experimental situation by synthesizing the spinel ferrite materials Mg0.6Zn0.4AlxFe2- xO4 and characterized them by X-ray diffractometry. The compositions of Mg0.6Zn0.4AlxFe2-xO4(x = 0.0 to 0.6) ferrites have been prepared by ceramic method and powder X-ray diffraction patterns were recorded. Thus, the authenticity of the program is checked by comparing the theoretically calculated data using computer simulation with the experimental ones. Further, the deduced cation distributions were used to fit the magnetization data using Localized canting of spins approach to explain the “recovery" of collinear spin structure due to Al3+ - substitution in Mg-Zn ferrites which is the case if A-site magnetic dilution and non-collinear spin structure. Since the distribution of cations in the spinel ferrites plays a very important role with regard to their electrical and magnetic properties, it is essential to determine the cation distribution in spinel lattice.
Abstract: Addition of milli or micro sized particles to the heat
transfer fluid is one of the many techniques employed for improving
heat transfer rate. Though this looks simple, this method has
practical problems such as high pressure loss, clogging and erosion
of the material of construction. These problems can be overcome by
using nanofluids, which is a dispersion of nanosized particles in a
base fluid. Nanoparticles increase the thermal conductivity of the
base fluid manifold which in turn increases the heat transfer rate.
Nanoparticles also increase the viscosity of the basefluid resulting in
higher pressure drop for the nanofluid compared to the base fluid. So
it is imperative that the Reynolds number (Re) and the volume
fraction have to be optimum for better thermal hydraulic
effectiveness. In this work, the heat transfer enhancement using
aluminium oxide nanofluid using low and high volume fraction
nanofluids in turbulent pipe flow with constant wall temperature has
been studied by computational fluid dynamic modeling of the
nanofluid flow adopting the single phase approach. Nanofluid, up till
a volume fraction of 1% is found to be an effective heat transfer
enhancement technique. The Nusselt number (Nu) and friction factor
predictions for the low volume fractions (i.e. 0.02%, 0.1 and 0.5%)
agree very well with the experimental values of Sundar and Sharma
(2010). While, predictions for the high volume fraction nanofluids
(i.e. 1%, 4% and 6%) are found to have reasonable agreement with
both experimental and numerical results available in the literature.
So the computationally inexpensive single phase approach can be
used for heat transfer and pressure drop prediction of new nanofluids.
Abstract: Carbon nanotubes (CNTs) with their high mechanical,
electrical, thermal and chemical properties are regarded as promising
materials for many different potential applications. Having unique
properties they can be used in a wide range of fields such as
electronic devices, electrodes, drug delivery systems, hydrogen
storage, textile etc. Catalytic chemical vapor deposition (CCVD) is a
common method for CNT production especially for mass production.
Catalysts impregnated on a suitable substrate are important for
production with chemical vapor deposition (CVD) method. Iron
catalyst and MgO substrate is one of most common catalyst-substrate
combination used for CNT. In this study, CNTs were produced by
CCVD of acetylene (C2H2) on magnesium oxide (MgO) powder
substrate impregnated by iron nitrate (Fe(NO3)3•9H2O) solution. The
CNT synthesis conditions were as follows: at synthesis temperatures
of 500 and 800°C multiwall and single wall CNTs were produced
respectively. Iron (Fe) catalysts were prepared by with Fe:MgO ratio
of 1:100, 5:100 and 10:100. The duration of syntheses were 30 and
60 minutes for all temperatures and catalyst percentages. The
synthesized materials were characterized by thermal gravimetric
analysis (TGA), transmission electron microscopy (TEM) and Raman
spectroscopy.
Abstract: Magnesium is used implant material potentially for
non-toxicity to the human body. Due to the excellent
bio-compatibility, Mg alloys is applied to implants avoiding removal
second surgery. However, it is found commercial magnesium alloys
including aluminum has low corrosion resistance, resulting
subcutaneous gas bubbles and consequently the approach as
permanent bio-materials. Generally, Aluminum is known to pollution
substance, and it raises toxicity to nervous system. Therefore
especially Mg-35Zn-3Ca alloy is prepared for new biodegradable
materials in this study. And the pulsed power is used in
constant-current mode of DC power kinds of anodization. Based on
the aforementioned study, it examines corrosion resistance and
biocompatibility by effect of current and frequency variation. The
surface properties and thickness were compared using scanning
electronic microscopy. Corrosion resistance was assessed via
potentiodynamic polarization and the effect of oxide layer on the body
was assessed cell viability. Anodized Mg-35Zn-3Ca alloy has good
biocompatibility in vitro by current and frequency variation.
Abstract: In this study, the Taguchi method was used to optimize the effect of HALO structure or halo implant variations on threshold voltage (VTH) and leakage current (ILeak) in 45nm p-type Metal Oxide Semiconductor Field Effect Transistors (MOSFETs) device. Besides halo implant dose, the other process parameters which used were Source/Drain (S/D) implant dose, oxide growth temperature and silicide anneal temperature. This work was done using TCAD simulator, consisting of a process simulator, ATHENA and device simulator, ATLAS. These two simulators were combined with Taguchi method to aid in design and optimize the process parameters. In this research, the most effective process parameters with respect to VTH and ILeak are halo implant dose (40%) and S/D implant dose (52%) respectively. Whereas the second ranking factor affecting VTH and ILeak are oxide growth temperature (32%) and halo implant dose (34%) respectively. The results show that after optimizations approaches is -0.157V at ILeak=0.195mA/μm.