Abstract: Direct methanol fuel cells (DMFCs) are considered to be one of the most promising candidates for portable and stationary applications in the view of their advantages such as high energy density, easy manipulation, high efficiency and they operate with liquid fuel which could be used without requiring any fuel-processing units. Electrolyte membrane of DMFC plays a key role as a proton conductor as well as a separator between electrodes. Increasing concern over environmental protection, biopolymers gain tremendous interest owing to their eco-friendly bio-degradable nature. Pectin is a natural anionic polysaccharide which plays an essential part in regulating mechanical behavior of plant cell wall and it is extracted from outer cells of most of the plants. The aim of this study is to develop and demonstrate pectin based polymer composite membranes as methanol impermeable polymer electrolyte membranes for DMFCs. Pectin based nanocomposites membranes are prepared by solution-casting technique wherein pectin is blended with chitosan followed by the addition of optimal amount of sulphonic acid modified Titanium dioxide nanoparticle (S-TiO2). Nanocomposite membranes are characterized by Fourier Transform-Infra Red spectroscopy, Scanning electron microscopy, and Energy dispersive spectroscopy analyses. Proton conductivity and methanol permeability are determined into order to evaluate their suitability for DMFC application. Pectin-chitosan blends endow with a flexible polymeric network which is appropriate to disperse rigid S-TiO2 nanoparticles. Resulting nanocomposite membranes possess adequate thermo-mechanical stabilities as well as high charge-density per unit volume. Pectin-chitosan natural polymeric nanocomposite comprising optimal S-TiO2 exhibits good electrochemical selectivity and therefore desirable for DMFC application.
Abstract: Lignin is a major constituent of woody biomass, and exists abundantly in nature. It is the major byproducts from the paper industry and bioethanol production processes. The byproducts are mainly used for low-valued applications. Instead, lignin can be converted into higher-valued gaseous fuel, thereby helping to curtail the ever-growing price of oil and to slow down the trend of global warming. Although biochemical treatment is capable of converting cellulose into liquid ethanol fuel, it cannot be applied to the conversion of lignin. Alternatively, it is possible to convert lignin into gaseous fuel thermochemically. In the present work, trans-4-hydroxycinnamic acid, a model compound for lignin, which closely resembles the basic building blocks of lignin, is gasified in an autoclave with ethanol at elevated temperatures and pressures, that are above the critical point of ethanol. Ethanol, instead of water, is chosen, because ethanol dissolves trans-4-hydroxycinnamic acid easily and helps to convert it into lighter gaseous species relatively well. The major operating parameters for the gasification reaction include temperature (673-873 K), reaction pressure (5-25 MPa) and feed concentration (0.05-0.3 M). Generally, more than 80% of the reactant, including trans-4-hydroxycinnamic acid and ethanol, were converted into gaseous products at an operating condition of 873 K and 5 MPa.
Abstract: A proton exchange membrane has been developed for
direct methanol fuel cell (DMFC). The nanofiber network composite
membranes were prepared by interconnected network of Nafion
(perfuorosulfonic acid) nanofibers that have been embedded in an
uncharged and inert polymer matrix, by electro-spinning. The
spinning solution of Nafion with a low concentration (1 wt%
compared to Nafion) of high molecular weight poly(ethylene oxide),
as a carrier polymer. The interconnected network of Nafion
nanofibers with average fiber diameter in the range of 160-700nm,
were used to make the membranes, with the nanofiber occupying up
to 85% of the membrane volume. The matrix polymer was
crosslinked with Norland Optical Adhesive 63 under UV. The
resulting membranes showed proton conductivity of 0.10 S/cm at
25°C and 80% RH; and methanol permeability of 3.6 x 10-6 cm2/s.
Abstract: Liners are made to protect the groundwater table from
the infiltration of leachate which normally carries different kinds of
toxic materials from landfills. Although these liners are engineered to
last for long period of time; unfortunately these liners fail; therefore,
toxic materials pass to groundwater. This paper focuses on the
changes of the hydraulic conductivity of a sand-bentonite liner due to
the infiltration of biofuel and ethanol fuel. Series of laboratory tests
were conducted in 20-cm-high PVC columns. Several compositions
of sand-bentonite liners were tested: 95% sand: 5% bentonite; 90%
sand: 10% bentonite; and 100% sand (passed mesh #40). The
columns were subjected to extreme pressures of 40 kPa, and 100 kPa
to evaluate the transport of alternative fuels (biofuel and ethanol
fuel). For comparative studies, similar tests were carried out using
water. Results showed that hydraulic conductivity increased due to
the infiltration of alternative fuels through the liners. Accordingly,
the increase in the hydraulic conductivity showed significant
dependency on the type of liner mixture and the characteristics of the
liquid. The hydraulic conductivity of a liner (subjected to biofuel
infiltration) consisting of 5% bentonite: 95% sand under pressure of
40 kPa and 100 kPa had increased by one fold. In addition, the
hydraulic conductivity of a liner consisting of 10% bentonite: 90%
sand under pressure of 40 kPa and 100 kPa and infiltrated by biofuel
had increased by three folds. On the other hand, the results obtained
by water infiltration under 40 kPa showed lower hydraulic
conductivities of 1.50×10-5 and 1.37×10-9 cm/s for 5% bentonite:
95% sand, and 10% bentonite: 90% sand, respectively. Similarly,
under 100 kPa, the hydraulic conductivities were 2.30×10-5 and
1.90×10-9 cm/s for 5% bentonite: 95% sand, and 10% bentonite: 90%
sand, respectively.
Abstract: The greenhouse effect and limitations on carbon
dioxide emissions concern engine maker and the future of the
internal combustion engines should go toward substantially and
improved thermal efficiency engine. Homogeneous charge
compression ignition (HCCI) is an alternative high-efficiency
technology for combustion engines to reduce exhaust emissions and
fuel consumption. However, there are still tough challenges in the
successful operation of HCCI engines, such as controlling the
combustion phasing, extending the operating range, and high
unburned hydrocarbon and CO emissions. HCCI and the exploitation
of ethanol as an alternative fuel is one way to explore new frontiers
of internal combustion engines with an eye towards maintaining its
sustainability. This study was done to extend database knowledge
about HCCI with ethanol a fuel.
Abstract: Homogeneous Charge Compression (HCCI) Ignition technology has been around for a long time, but has recently received renewed attention and enthusiasm. This paper deals with experimental investigations of HCCI engine using hydrous methanol as a primary fuel and Dimethyl Ether (DME) as an ignition improver. A regular diesel engine has been modified to work as HCCI engine for this investigation. The hydrous methanol is inducted and DME is injected into a single cylinder engine. Hence, hydrous methanol is used with 15% water content in HCCI engine and its performance and emission behavior is documented. The auto-ignition of Methanol is enabled by DME. The quantity of DME varies with respect to the load. In this study, the experiments are conducted independently and the effect of the hydrous methanol on the engine operating limit, heat release rate and exhaust emissions at different load conditions are investigated. The investigation also proves that the Hydrous Methanol with DME operation reduces the oxides of Nitrogen and smoke to an extreme low level which is not possible by the direct injection CI engine. Therefore, it is beneficial to use hydrous methanol-DME HCCI mode while using hydrous methanol in internal Combustion Engines.
Abstract: An aqueous methanol sensor for use in direct
methanol fuel cells (DMFCs) applications is demonstrated; the
methanol sensor is built using dispersed single-walled carbon
nanotubes (SWCNTs) with Nafion117 solution to detect the methanol
concentration in water. The study is aimed at the potential use of the
carbon nanotubes array as a methanol sensor for direct methanol fuel
cells (DMFCs). The concentration of methanol in the fuel circulation
loop of a DMFC system is an important operating parameter, because
it determines the electrical performance and efficiency of the fuel cell
system. The sensor is also operative even at ambient temperatures
and responds quickly to changes in the concentration levels of the
methanol. Such a sensor can be easily incorporated into the methanol
fuel solution flow loop in the DMFC system.