SWNT Sensors for Monitoring the Oxidation of Edible Oils

There are several means to measure the oxidation of edible oils, such as the acid value, the peroxide value, and the anisidine value. However, these means require large quantities of reagents and are time-consuming tasks. Therefore, a more convenient and time-saving way to measure the oxidation of edible oils is required. In this report, an edible oil condition sensor was fabricated by using single-walled nanotubes (SWNT). In order to test the sensor, oxidized edible oils, each one at a different acid value, were prepared. The SWNT sensors were immersed into these oxidized oils and the resistance changes in the sensors were measured. It was found that the conductivity of the sensors decreased as the oxidation level of oil increased. This result suggests that a change of the oil components induced by the oxidation process in edible oils is related to the conductivity change in the SWNT sensor.





References:
[1] S. Iijima, Helical microtubules of graphitic carbon, Nature 354 (1991)
56-58.
[2] J. Kong, NR Franklin, C. Zhou, MG Chapline, S. Peng, K. Cho, and H.
Dai, Nanotube molecular wires as chemical sensors, Science 287 (2000)
622-625.
[3] J. Li, Y. Lu, Q. Ye, M. Cinke, J. Han and M. Meyyappan, Carbon
Nanotube Sensors for Gas and Organic Vapor Detection, Nano Letters 3
(2003) 929-933.
[4] PW Barone, S. Baik, DA Heller, MS Strano, Near-infrared optical sensors
based on single-walled carbon nanotubes, Nat. Mater. 4 (2005) 86-92.
[5] Q. Zhao, Z. Gan, Q. Zhuang, Electrochemical Sensors Based on Carbon
Nanotubes, Electroanalysis 14 (2002) 1609-1613.
[6] FT Orthoefer, Care of food service frying oils, J. Am. Oil Chem. Soc. 65
(1988) 1417-1419.
[7] T. Yasukawa, K. Yasunaga, Nutritional functions of dietary
diacylglycerols, J. Oleo Sci. 50 (2001) 427-432.
[8] C. W. Fritsch, Measurements of frying fat deterioration: a brief review, J.
Am. Oil Chem. Soc. 58 (1981) 272-274.
[9] K. Robards, A. F. Kerr, E. Patsalides, Rancidity and its measurement in
edible oils and snack foods. A review, Analyst 113 (1988) 213-224.
[10] Seung-Hoon Jhi, Steven G. Louie, and Marvin L. Cohen, Electronic
Properties of Oxidized Carbon Nanotubes, Phys. Rev. Lett. 85 (2000)
1710-1713.
[11] Zsolt E. Horv├íth, Antal A. Ko├│s, Kriszti├ín Kertész, György Moln├ír,
G├íbor Vértesy, M├írton C. Bein, Tam├ís Frigyes, Zolt├ín Mész├íros, J├│zsef
Gyulai, László P. Biró, The role of defects in chemical sensing properties
of carbon nanotube films, Appl. Phys. A-Mater. Sci. Process. 93 (2008)
495-504.
[12] E. N. FRANKEL, Lipid peroxidation, Prog. Lipid Res. 19 (1980) 1-22.
[13] Felix A. Aladedunye, Roman Przybylski, Degradation and Nutritional
Quality Changes of Oil During Frying, J. Am. Oil Chem. Soc. 86 (2009)
149-156.
[14] Jian Chen, Mark A. Hamon, Hui Hu, Yongsheng Chen, Apparao M. Rao,
Peter C. Eklund, Robert C. Haddon, Solution Properties of Single-Walled
Carbon Nanotubes Science 282 (1998) 95-98.