Remediation of Petroleum Hydrocarbon-contaminated Soil Slurry by Fenton Oxidation
Theobjective of this study was to evaluate the optimal
treatment condition of Fenton oxidation process to removal
contaminant in soil slurry contaminated by petroleum hydrocarbons.
This research studied somefactors that affect the removal efficiency
of petroleum hydrocarbons in soil slurry including molar ratio of
hydrogen peroxide (H2O2) to ferrous ion(Fe2+), pH condition and
reaction time.The resultsdemonstrated that the optimum condition
was that the molar ratio of H2O2:Fe3+ was 200:1,the pHwas 4.0and
the rate of reaction was increasing rapidly from starting point to 7th
hour and destruction kinetic rate (k) was 0.24 h-1. Approximately
96% of petroleum hydrocarbon was observed(initialtotal petroleum
hydrocarbon (TPH) concentration = 70±7gkg-1)
[1] S. Peng, Q. Zhou, Z. Caia, and Z. Zhanga, "Phytoremediation of
petroleum contaminated soil byMirabilis Jalapa L. in a greenhouse plot
experiment," Journal of Hazardous Materials, vol. 168, pp. 1490-1496,
Mar. 2009.
[2] W. Duan, G. Chen, Q. Ye, and Q. Chen, "The situation of hazardous
chemical accidents in China between 2000 and 2006" Journal of
Hazardous Materials, vol. 186, pp. 1489-1494, Dec. 2010.
[3] E. Okstad, E. Jersin, and R.K. Tinmannsvik, "Accident investigation in
the Norwegian petroleum industry - Common features and future
challenges" Safety Science, vol. 50, pp. 1408 - 1414, Jan. 2011.
[4] N. Merkl, R. Schultze-Kraft, and C. Infante, "Phytoremediation in the
tropics - influence of heavy crude oil on root morphological
characteristics of graminoids" Environmental Pollution 138, vol. 138,
pp. 86-91, Feb. 2005.
[5] K. Das, and A.K. Mukherjee, "Crude petroleum-oil biodegradation
efficiency of Bacillus subtilisand Pseudomonas aeruginosa strains
isolated from a petroleum-oilcontaminated soil from North-East
India"Bioresource Technology, vol. 98, pp. 1339-1345, May. 2006.
[6] E.J. Jonera, D, Hirmannb, O. H.J. Szolarb, D.Todorovicb, C.Leyvala,
and A.P. Loibnerb, "Priming effects on PAH degradation and
ecotoxicity during a phytoremediation experiment"Environmental
Pollution, vol. 128, pp. 429-435, Sep. 2003.
[7] M. Lu, Z. Zhang, W.Qiao, Y.Guanb, M. Xiao, and C.Peng, "Removal of
residual contaminants in petroleum-contaminated soil by Fenton-like
oxidation" Journal of Hazardous Materials, vol. 179, pp. 604-611, Mar.
2010.
[8] M. Lu, Z. Zhang, W. Qiao, X. Wei, Y. Guan, Q. Ma, and Y. Guan,
"Remediation of petroleum-contaminated soil after composting by
sequential treatment with Fenton-like oxidation and
biodegradation"Bioresource Technology, vol. 101, pp. 2016-2113, Nov.
2009.
[9] R. Baciocchi, M.R. Boni, and L.D. April, "Hydrogen peroxide lifetime
as an indicator of the efficiency of 3-chlorophenol Fenton-s and Fentonlike
oxidation in soils" Journal of Hazardous Materials, B96, pp. 305-
329, 2003.
[10] L. Di Palma, In situ chemical oxidation of environments combined
withhazardous materials. In: Lens, P., Grotenhuis, T., Malina, G., Tabak,
H. (Eds.), Soil and Sediment Remediation: Mechanisms, Technologies
and Applications. IWA Publishing, London, pp. 200-222, 2005.
[11] J.H. Langwaldt, Stimulated in situ soil treatment: biodegradation
coupled to Fenton-sreaction. In: Lens, P., Grotenhuis, T., Malina, G.,
Tabak, H. (Eds.), Soil and Sediment Remediation: Mechanisms,
Technologies and Applications. IWA Publishing, London, pp. 223-247,
2005.
[12] Venny, S. Gan and H.K. Ng, "Inorganic chelated modified-Fenton
treatment of polycyclic aromatic hydrocarbon (PAH)-contaminated
soils" Chemical Engineering, vol. 180, pp. 1-8, Oct. 2011.
[1] S. Peng, Q. Zhou, Z. Caia, and Z. Zhanga, "Phytoremediation of
petroleum contaminated soil byMirabilis Jalapa L. in a greenhouse plot
experiment," Journal of Hazardous Materials, vol. 168, pp. 1490-1496,
Mar. 2009.
[2] W. Duan, G. Chen, Q. Ye, and Q. Chen, "The situation of hazardous
chemical accidents in China between 2000 and 2006" Journal of
Hazardous Materials, vol. 186, pp. 1489-1494, Dec. 2010.
[3] E. Okstad, E. Jersin, and R.K. Tinmannsvik, "Accident investigation in
the Norwegian petroleum industry - Common features and future
challenges" Safety Science, vol. 50, pp. 1408 - 1414, Jan. 2011.
[4] N. Merkl, R. Schultze-Kraft, and C. Infante, "Phytoremediation in the
tropics - influence of heavy crude oil on root morphological
characteristics of graminoids" Environmental Pollution 138, vol. 138,
pp. 86-91, Feb. 2005.
[5] K. Das, and A.K. Mukherjee, "Crude petroleum-oil biodegradation
efficiency of Bacillus subtilisand Pseudomonas aeruginosa strains
isolated from a petroleum-oilcontaminated soil from North-East
India"Bioresource Technology, vol. 98, pp. 1339-1345, May. 2006.
[6] E.J. Jonera, D, Hirmannb, O. H.J. Szolarb, D.Todorovicb, C.Leyvala,
and A.P. Loibnerb, "Priming effects on PAH degradation and
ecotoxicity during a phytoremediation experiment"Environmental
Pollution, vol. 128, pp. 429-435, Sep. 2003.
[7] M. Lu, Z. Zhang, W.Qiao, Y.Guanb, M. Xiao, and C.Peng, "Removal of
residual contaminants in petroleum-contaminated soil by Fenton-like
oxidation" Journal of Hazardous Materials, vol. 179, pp. 604-611, Mar.
2010.
[8] M. Lu, Z. Zhang, W. Qiao, X. Wei, Y. Guan, Q. Ma, and Y. Guan,
"Remediation of petroleum-contaminated soil after composting by
sequential treatment with Fenton-like oxidation and
biodegradation"Bioresource Technology, vol. 101, pp. 2016-2113, Nov.
2009.
[9] R. Baciocchi, M.R. Boni, and L.D. April, "Hydrogen peroxide lifetime
as an indicator of the efficiency of 3-chlorophenol Fenton-s and Fentonlike
oxidation in soils" Journal of Hazardous Materials, B96, pp. 305-
329, 2003.
[10] L. Di Palma, In situ chemical oxidation of environments combined
withhazardous materials. In: Lens, P., Grotenhuis, T., Malina, G., Tabak,
H. (Eds.), Soil and Sediment Remediation: Mechanisms, Technologies
and Applications. IWA Publishing, London, pp. 200-222, 2005.
[11] J.H. Langwaldt, Stimulated in situ soil treatment: biodegradation
coupled to Fenton-sreaction. In: Lens, P., Grotenhuis, T., Malina, G.,
Tabak, H. (Eds.), Soil and Sediment Remediation: Mechanisms,
Technologies and Applications. IWA Publishing, London, pp. 223-247,
2005.
[12] Venny, S. Gan and H.K. Ng, "Inorganic chelated modified-Fenton
treatment of polycyclic aromatic hydrocarbon (PAH)-contaminated
soils" Chemical Engineering, vol. 180, pp. 1-8, Oct. 2011.
@article{"International Journal of Earth, Energy and Environmental Sciences:55241", author = "C. Pongcharoen and K. Kaiyavongand T. Satapanajaru", title = "Remediation of Petroleum Hydrocarbon-contaminated Soil Slurry by Fenton Oxidation", abstract = "Theobjective of this study was to evaluate the optimal
treatment condition of Fenton oxidation process to removal
contaminant in soil slurry contaminated by petroleum hydrocarbons.
This research studied somefactors that affect the removal efficiency
of petroleum hydrocarbons in soil slurry including molar ratio of
hydrogen peroxide (H2O2) to ferrous ion(Fe2+), pH condition and
reaction time.The resultsdemonstrated that the optimum condition
was that the molar ratio of H2O2:Fe3+ was 200:1,the pHwas 4.0and
the rate of reaction was increasing rapidly from starting point to 7th
hour and destruction kinetic rate (k) was 0.24 h-1. Approximately
96% of petroleum hydrocarbon was observed(initialtotal petroleum
hydrocarbon (TPH) concentration = 70±7gkg-1)", keywords = "Contaminated soil, Fenton oxidation, Petroleumhydrocarbon, Remediation.", volume = "6", number = "9", pages = "595-3", }