Abstract: Lanthanum oxide is to be recovered from monazite,
which contains about 13.44% lanthanum oxide. The principal
objective of this study is to be able to extract lanthanum oxide from
monazite of Moemeik Myitsone Area. The treatment of monazite in
this study involves three main steps; extraction of lanthanum
hydroxide from monazite by using caustic soda, digestion with nitric
acid and precipitation with ammonium hydroxide and calcination of
lanthanum oxalate to lanthanum oxide.
Abstract: Coal will continue to be the predominant source of
global energy for coming several decades. The huge generation of fly
ash (FA) from combustion of coal in thermal power plants (TPPs) is
apprehended to pose the concerns of its disposal and utilization. FA
application based on its typical characteristics as soil ameliorant for
agriculture and forestry is the potential area, and hence the global
attempt. The inferences drawn suffer from the variations of ash
characteristics, soil types, and agro-climatic conditions; thereby
correlating the effects of ash between various plant species and soil
types is difficult. Indian FAs have low bulk density, high water
holding capacity and porosity, rich silt-sized particles, alkaline
nature, negligible solubility, and reasonable plant nutrients. Findings
of the demonstrations trials for more than two decades from lab/pot
to field scale long-term experiments are developed as FA soil
amendment technology (FASAT) by Central Institute of Mining and
Fuel Research (CIMFR), Dhanbad. Performance of different crops
and plant species in cultivable and problematic soils, are
encouraging, eco-friendly, and being adopted by the farmers. FA
application includes ash alone and in combination with
inorganic/organic amendments; combination treatments including
bio-solids perform better than FA alone. Optimum dose being up to
100 t/ha for cultivable land and up to/ or above 200 t/ha of FA for
waste/degraded land/mine refuse, depending on the characteristics of
ash and soil. The elemental toxicity in Indian FA is usually not of
much concern owing to alkaline ashes, oxide forms of elements, and
elemental concentration within the threshold limits for soil
application. Combating toxicity, if any, is possible through
combination treatments with organic materials and phytoremediation.
Government initiatives through extension programme
involving farmers and ash generating organizations need to be
accelerated
Abstract: Delayed wound healing in diabetes is primarily
associated with hyperglycemia, over-expression of inflammatory
marker, oxidative stress and delayed collagen synthesis. This
unmanaged wound is producing high economic burden on the
society. Thus research is required to develop new and effective
treatment strategies to deal with this emerging issue. Our present
study incorporates the evaluation of wound healing effects of 50%
ethanol extract of Ocimum sanctum (OSE) in streptozotocin
(45mg/kg)-induced diabetic rats with concurrent wound ulcer. The
animals showing diabetes (Blood glucose level >140 and
Abstract: Commercial nanocomposite food packaging type nano-silver containers were characterised using scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDX). The presence of nanoparticles consistent with the incorporation of 1% nano-silver (Ag) and 0.1% titanium dioxide (TiO2) nanoparticle into polymeric materials formed into food containers was confirmed. Both nanomaterials used in this type of packaging appear to be embedded in a layered configuration within the bulk polymer. The dimensions of the incorporated nanoparticles were investigated using X-ray diffraction (XRD) and determined by calculation using the Scherrer Formula; these were consistent with Ag and TiO2 nanoparticles in the size range 20-70nm both were spherical shape nanoparticles. Antimicrobial assessment of the nanocomposite container has also been performed and the results confirm the antimicrobial activity of Ag and TiO2 nanoparticles in food packaging containers. Migration assessments were performed in a wide range of food matrices to determine the migration of nanoparticles from the packages. The analysis was based upon the relevant European safety Directives and involved the application of inductively coupled plasma mass spectrometry (ICP-MS) to identify the range of migration risk. The data pertain to insignificance levels of migration of Ag and TiO2 nanoparticles into the selected food matrices.
Abstract: An innovative approach utilizing highly alkaline oil
shale waste ash and carbon dioxide gas (CO2), associated with power
production, as a resource for production of precipitated calcium
carbonate (PCC) is introduced in this paper. The specifics and
feasibility of the integrated ash valorization and CO2 sequestration
process by indirect aqueous carbonation of lime-consisting ash were
elaborated and the main parameters established. Detailed description
of the formed precipitates was included. Complimentary carbonation
experiments with commercial CaO fine powder were conducted for
comparative characterization of the final products obtained on the
basis of two different raw materials. Finally, the expected CO2
uptake was evaluated.
Abstract: The C3 plants are frequently suffering from exposure
to high temperature stress which limits the growth and yield of these
plants. This study seeks to clarify the physiological mechanisms of
heat tolerance in relation to oxidative stress in C3 species. Fifteen C3
species were exposed to prolonged moderately high temperature
stress 36/30°C for 40 days in a growth chamber. Chlorophyll
fluorescence (Fv/Fm) showed great difference among species at 40
days of the stress. The species showed decreases in Fv/Fm and
increases in malondialdehyde (MDA) content under stress condition
as well as negative correlation between Fv/Fm and MDA (r = -0.61*)
at 40 days of the stress. Hydrogen peroxide (H2O2) content before
and after stress in addition to its response under stress showed great
differences among species. The results suggest that the difference in
heat tolerance among C3 species is closely associated with the ability
to suppress oxidative damage but not with the content of reactive
oxygen species (ROS) which is regulated by complex network.
Abstract: In this study, we investigated the effects of ginger and
L-carnitine on the reproductive performance of male rats with respect
to semen parameters, male sex hormones and the testicular
antioxidant system. A total of sixty mature male albino rats were
divided into four groups of fifteen rats. The control group received
saline, whereas the other three groups received ginger (100 mg kg-1 d-
1.), L-carnitine (150 mg kg-1 d-1.) or a combination of both ginger
(100 mg kg-1 d-1.) and L-carnitine (150 mg kg-1 d-1.) via a stomach
tube daily for one month. At the end of the treatment period, the rats
were sacrificed, and their sperm characteristics (count, motility and
viability), antioxidant enzyme factors levels (reduced glutathione,
catalase, superoxide dismutase and total antioxidant capacity) and sex
hormone levels (testosterone, Follicle stimulating hormone(FSH) and
luteinizing hormone (LH) were analysed. Our results showed that the
three experimental treatments improved sperm parameters,
antioxidant enzyme activity and testosterone hormone levels; the
most pronounced positive effects were observed in the group that
received a combination of both ginger and L-carnitine. Therefore, the
administration of a combination of ginger and L-carnitine may be
beneficial for improving male sexual performance.
Abstract: Titanium oxide hollow microspheres were synthesized from organic precursor titanium tetraisopropoxide (TTIP) using continuous spray pyrolysis reactor. Effects of precursor concentration, applied voltage and annealing have been investigated. It was observed that the annealing of the as-synthesized TiO2 hollow microspheres at 2500C, which had an average external diameter of 200 nm, leads to an increase in the size and also more spherical shape. The precursor concentration was found to have a direct impact on the size of the microspheres, which is also evident in the absorption spectrum. The as-prepared TiO2 hollow microspheres exhibited good photocatalytic activity for the degradation of MO.
Abstract: A 7-step method (with 25 sub-steps) to assess risk of
air pollutants is introduced. These steps are: pre-considerations,
sampling, statistical analysis, exposure matrix and likelihood, doseresponse
matrix and likelihood, total risk evaluation, and discussion
of findings. All mentioned words and expressions are wellunderstood;
however, almost all steps have been modified, improved,
and coupled in such a way that a comprehensive method has been
prepared. Accordingly, the SADRA (Statistical Analysis-Driven Risk
Assessment) emphasizes extensive and ongoing application of
analytical statistics in traditional risk assessment models. A Sulfur
Dioxide case study validates the claim and provides a good
illustration for this method.
Abstract: In this research sodium bicarbonate (NaHCO3) was introduced to generate carbon dioxide gas (CO2) to the existing nitrogen gas (N2) of elastomeric foam, to lower thermal conductivity (K). Various loadings of NaHCO3 (0 to 60 phr) were added into the azodicarbonamide (AZC)-containing compound and its properties were then determined. Two vulcanization methods, i.e., hot air and infrared (IR), were employed and compared in this study. Results revealed that compound viscosity tended to increase slightly with increasing NaHCO3 content but cure time was delayed. The effect of NaHCO3 content on thermal conductivity depended on the vulcanization method. For hot air method, the thermal conductivity was insignificantly changed with increasing NaHCO3 up to 40 phr whereas it tended to decrease gradually for IR method. At higher NaHCO3 content (60 phr), unexpected increase of thermal conductivity was observed. The water absorption was also determined and foam structures were then used to explain the results.
Abstract: Continuous-time delta-sigma analog digital converter (ADC) for radio frequency identification (RFID) complementary metal oxide semiconductor (CMOS) biosensor has been reported. This delta-sigma ADC is suitable for digital conversion of biosensor signal because of small process variation, and variable input range. As the input range of continuous-time switched current delta-sigma ADC (Dynamic range : 50 dB) can be limited by using current reference, amplification of biosensor signal is unnecessary. The input range is switched to wide input range mode or narrow input range mode by command of current reference. When the narrow input range mode, the input range becomes ± 0.8 V. The measured power consumption is 5 mW and chip area is 0.31 mm^2 using 1.2 um standard CMOS process. Additionally, automatic input range detecting system is proposed because of RFID biosensor applications.
Abstract: Magnetic Nanoparticles (MNPs) have great potential
to overcome many of the shortcomings of the present diagnostic and
therapeutic approaches used in cancer diagnosis and treatment. This
Literature review discusses the use of Magnetic Nanoparticles
focusing mainly on Iron oxide based MNPs in cancer imaging using
MRI.
Abstract: A composite made of plasma functionalized multiwall
carbon nanotubes (MWNTs) coated with SnO2 was synthesized by
sonochemical precipitation method. Thick layer of this
nanocomposite material was used as ethanol sensor at low
temperatures. The composite sensitivity for ethanol has increased by
a factor of 2 at room temperature and by a factor of 13 at 250°C in
comparison to that of pure SnO2. SEM image of nanocomposite
material showed MWNTs were embedded in SnO2 matrix and also a
higher surface area was observed in the presence of functionalized
MWNTs. Greatly improved sensitivity of the composite material to
ethanol can be attributed to new gas accessing passes through
MWNTs and higher specific surface area.
Abstract: Green propellants used for satellite-level propulsion
system become attractive in recent years because the non-toxicity and
lower requirements of safety protection. One of the green propellants,
high-concentration hydrogen peroxide H2O2 solution (≥70% w/w,
weight concentration percentage), often known as high-test peroxide
(HTP), is considered because it is ITAR-free, easy to manufacture and
the operating temperature is lower than traditional monopropellant
propulsion. To establish satellite propulsion technology, the National
Space Organization (NSPO) in Taiwan has initialized a long-term
cooperation project with the National Cheng Kung University to
develop compatible tank and thruster. An experimental propulsion
payload has been allocated for the future self-reliant satellite to
perform orbit transfer and maintenance operations. In the present
research, an 1-Newton thruster prototype is designed and the thrusting
force is measured by a pendulum-type platform. The preliminary
hot-firing test at ambient environment showed the generated thrust and
the specific impulse are about 0.7 Newton and 102 seconds,
respectively.
Abstract: In this paper, we have developed an explicit analytical
drain current model comprising surface channel potential and
threshold voltage in order to explain the advantages of the proposed
Gate Stack Double Diffusion (GSDD) MOSFET design over the
conventional MOSFET with the same geometric specifications that
allow us to use the benefits of the incorporation of the high-k layer
between the oxide layer and gate metal aspect on the immunity of the
proposed design against the self-heating effects. In order to show the
efficiency of our proposed structure, we propose the simulation of the
power chopper circuit. The use of the proposed structure to design a
power chopper circuit has showed that the (GSDD) MOSFET can
improve the working of the circuit in terms of power dissipation and
self-heating effect immunity. The results so obtained are in close
proximity with the 2D simulated results thus confirming the validity
of the proposed model.
Abstract: Alkali treated oil palm empty fruit bunch (EFB) fibres
(TEFBF) and untreated EFBF fibers (UEFBF) were incorporated in
polypropylene (PP) with and without malic anhydride grafted PP
(MAPP) and magnesium hydroxide as flame retardant (FR) to
produce TEFBF-PP and UEFBF-PP composites by the melt casting
method. The composites were characterized by mechanical and
burning tests along with a scanning electron microscope and Fourier
transform infrared spectroscopy. The significant improvement in
flexural modulus (133%) and flame retardant property (60%) of
TEFBF-PP composite with MAPP and FR is observed. The improved
mechanical property is discussed by the development of encapsulated
textures.
Abstract: Magnesium wastes and scraps, one of the metal wastes, are produced by many industrial activities, all over the world. Their growing size is becoming a future problem for the world. In this study, the use of magnesium wastes as a raw material in the production of the magnesium borate hydrates are aimed. The method used in the experiments is hydrothermal synthesis. The conditions are set to, waste magnesium to B2O3, 1:3 as a molar ratio. Four different reaction times are studied which are 30, 60, 120 and 240 minutes. For the identification analyses X-Ray Diffraction (XRD), Fourier Transform Infrared Spectroscopy (FT-IR) and Raman spectroscopy techniques are used. As a result at all the reaction times magnesium borate hydrates are synthesized and the most crystalline forms are obtained at a reaction time of 120 minutes. The overall yields of the production are found between the values of 65-80 %.
Abstract: Sulphur dioxide is a harmful gaseous product that
needs to be minimized in the atmosphere. This research work
investigates the use of zeolite as a possible additive that can improve
the sulphur dioxide capture in wet flue gas desulphurisation
dissolution process. This work determines the effect of temperature,
solid to liquid ratio, acid concentration and stirring speed on the
leaching of zeolite using a pH stat apparatus. The atomic absorption
spectrometer was used to measure the calcium ions from the solution.
It was found that the dissolution rate of zeolite decreased with
increase in solid to liquid ratio and increases with increase in
temperature, stirring speed and acid concentration. The activation
energy for the dissolution rate of zeolite in hydrochloric acid was
found to be 9.29kJ/mol. and therefore the product layer diffusion was
the rate limiting step.
Abstract: Engineered nanoparticles’ usage rapidly increased in
various applications in the last decade due to their unusual properties.
However, there is an ever increasing concern to understand their
toxicological effect in human health. Particularly, metal and metal
oxide nanoparticles have been used in various sectors including
biomedical, food and agriculture. But their impact on human health is
yet to be fully understood. In this present investigation, we assessed
the toxic effect of engineered nanoparticles (ENPs) including Ag,
MgO and Co3O4 nanoparticles (NPs) on human mesenchymal stem
cells (hMSC) adopting cell viability and cellular morphological
changes as tools The results suggested that silver NPs are more toxic
than MgO and Co3O4NPs. The ENPs induced cytotoxicity and
nuclear morphological changes in hMSC depending on dose. The cell
viability decreases with increase in concentration of ENPs. The
cellular morphology studies revealed that ENPs damaged the cells.
These preliminary findings have implications for the use of these
nanoparticles in food industry with systematic regulations.
Abstract: This work deals with modeling and simulation of SO2 removal in a ceramic membrane by means of FEM. A mass transfer model was developed to predict the performance of SO2 absorption in a chemical solvent. The model was based on solving conservation equations for gas component in the membrane. Computational fluid dynamics (CFD) of mass and momentum were used to solve the model equations. The simulations aimed to obtain the distribution of gas concentration in the absorption process. The effect of the operating parameters on the efficiency of the ceramic membrane was evaluated. The modeling findings showed that the gas phase velocity has significant effect on the removal of gas whereas the liquid phase does not affect the SO2 removal significantly. It is also indicated that the main mass transfer resistance is placed in the membrane and gas phase because of high tortuosity of the ceramic membrane.