Abstract: Hydrogenated amorphous carbon (a-C:H) films have
been synthesized by a radio frequency plasma enhanced chemical
vapor deposition (rf-PECVD) technique with different bias voltage
from 0.0 to -0.5 kV. The Raman spectra displayed the polymer-like
hydrogenated amorphous carbon (PLCH) film with 0.0 to -0.1 and
a-C:H films with -0.2 to -0.5 kV of bias voltages. The surface chemical
information of all films were studied by X-ray photoelectron
spectroscopy (XPS) technique, presented to C-C (sp2 and sp3) and C-O
bonds, and relative carbon (C) and oxygen (O) atomics contents. The
O contamination had affected on structure and optical properties. The
true density of PLCH and a-C:H films were characterized by X-ray
refractivity (XRR) method, showed the result as in the range of
1.16-1.73 g/cm3 that depending on an increasing of bias voltage. The
hardness was proportional to the true density of films. In addition, the
optical properties i.e. refractive index (n) and extinction coefficient (k)
of these films were determined by a spectroscopic ellipsometry (SE)
method that give formation to in 1.62-2.10 (n) and 0.04-0.15 (k)
respectively. These results indicated that the optical properties
confirmed the Raman results as presenting the structure changed with
applied bias voltage increased.
Abstract: Calcium phosphate cement (CPC) is one of the most
attractive bioceramics due to its moldable and shape ability to fill
complicated bony cavities or small dental defect positions. In this
study, CPC was produced by using mixture of tetracalcium phosphate
(TTCP, Ca4O(PO4)2) and dicalcium phosphate anhydrous (DCPA,
CaHPO4) in equimolar ratio (1/1) with aqueous solutions of acetic
acid (C2H4O2) and disodium hydrogen phosphate dehydrate
(Na2HPO4.2H2O) in combination with sodium alginate in order to
improve theirs moldable characteristic. The concentration of the
aqueous solutions and sodium alginate were varied to investigate the
effect of different aqueous solutions and alginate on properties of the
cements. The cement paste was prepared by mixing cement powder
(P) with aqueous solution (L) in a P/L ratio of 1.0g/0.35ml. X-ray
diffraction (XRD) was used to analyses phase formation of the
cements. Setting time and compressive strength of the set CPCs were
measured using the Gilmore apparatus and Universal testing
machine, respectively.
The results showed that CPCs could be produced by using both
basic (Na2HPO4.2H2O) and acidic (C2H4O2) solutions. XRD results
show the precipitation of hydroxyapatite in all cement samples. No
change in phase formation among cements using difference
concentrations of Na2HPO4.2H2O solutions. With increasing
concentration of acidic solutions, samples obtained less
hydroxyapatite with a high dicalcium phosphate dehydrate leaded to
a shorter setting time. Samples with sodium alginate exhibited higher
crystallization of hydroxyapatite than that of without alginate as a
result of shorten setting time in a basic solution but a longer setting
time in an acidic solution. The stronger cement was attained from
samples using the acidic solution with sodium alginate; however the
strength was lower than that of using the basic solution.
Abstract: Magnetic powder of Sr-ferrite was prepared by
conventional and sol-gel auto-combustion methods. In conventional
method, strontium carbonate and ferric oxide powders were mixed
together and then mixture was calcined. In sol-gel auto-combustion
method, a solution containing strontium nitrate, ferric nitrate and
citric acid was heated until the combustion took place automatically;
then, as-burnt powder was calcined. Thermal behavior, phase
identification, morphology and magnetic properties of powders
obtained by these two methods were compared by DTA, XRD, SEM
and VSM techniques. According to the results of DTA analysis,
formation temperature of Sr-ferrite obtained by conventional and solgel
auto-combustion methods were 1300°C and 1000°C, respectively.
XRD results confirmed the formation of pure Sr-ferrite at the
mentioned temperatures. Plate and hexagonal-shape particles of Srferrite
were observed using SEM. The Sr-ferrite powder obtained by
sol-gel auto-combustion method had saturation magnetization of
66.03 emu/g and coercivity of 5731 Oe in comparison with values of
58.20 emu/g and 4378 Oe obtained by conventional method.
Abstract: This work presents the result of investigations aimed
at determining the hardness of the welded Chromoly (A 4130) steel
plate of 2” thickness. Multi pass welding for the thick sections was
carried out and analyzed for the Chromoly alloy steel plates. The
study of hardness at the weld metal reveals that there is the presence
of different micro structure products which yields diverse properties.
The welding carried out using GMAW with ER70s-2 electrode.
Single V groove design was selected for the butt joint configuration.
The presence of hydrogen has been suppressed by selecting low
hydrogen electrode. Preheating of the plate prior to welding reduces
the cooling rate which also affects the weld metal microstructure. The
shielding gas composition used in this analysis is 80% Ar-20% CO2.
The experimental analysis gives the detailed study of the hardness of
the material.
Abstract: Two micromechanical models for 3D smart composite
with embedded periodic or nearly periodic network of generally
orthotropic reinforcements and actuators are developed and applied to
cubic structures with unidirectional orientation of constituents.
Analytical formulas for the effective piezothermoelastic coefficients
are derived using the Asymptotic Homogenization Method (AHM).
Finite Element Analysis (FEA) is subsequently developed and used
to examine the aforementioned periodic 3D network reinforced smart
structures. The deformation responses from the FE simulations are
used to extract effective coefficients. The results from both
techniques are compared. This work considers piezoelectric materials
that respond linearly to changes in electric field, electric
displacement, mechanical stress and strain and thermal effects. This
combination of electric fields and thermo-mechanical response in
smart composite structures is characterized by piezoelectric and
thermal expansion coefficients. The problem is represented by unitcell
and the models are developed using the AHM and the FEA to
determine the effective piezoelectric and thermal expansion
coefficients. Each unit cell contains a number of orthotropic
inclusions in the form of structural reinforcements and actuators.
Using matrix representation of the coupled response of the unit cell,
the effective piezoelectric and thermal expansion coefficients are
calculated and compared with results of the asymptotic
homogenization method. A very good agreement is shown between
these two approaches.
Abstract: Aluminum hybrid reinforcement technology is a
response to the dynamic ever increasing service requirements of such
industries as transportation, aerospace, automobile, marine, etc. It is
unique in that it offers a platform of almost unending combinations of
materials to produce various hybrid composites. This article reviews
the studies carried out on various combinations of aluminum hybrid
composite and the effects on mechanical, physical and chemical
properties. It is observed that the extent of enhancement of these
properties of hybrid composites is strongly dependent on the nature
of the reinforcement, its hardness, particle size, volume fraction,
uniformity of dispersion within the matrix and the method of hybrid
production.
Abstract: This paper reveals the interaction between hydrogen
and surface stress in austenitic stainless steel by X-ray diffraction
stress measurement and thermal desorption analysis before and after
being charged with hydrogen. The surface residual stress was varied
by surface finishing using several disc polishing agents. The obtained
results show that the residual stress near surface had a significant
effect on hydrogen absorption behavior, that is, tensile residual stress
promoted the hydrogen absorption and compressive one did opposite.
Also, hydrogen induced equi-biaxial stress and this stress has a linear
correlation with hydrogen content.
Abstract: To elucidate the material characteristics of single
crystals of pure aluminum and copper, the respective relations between
crystallographic orientations and microstructures were examined,
along with bending and mechanical properties. The texture
distribution was also analysed. Bending tests were performed in a
SEM apparatus while its behaviors were observed. Some analytical
results related to crystal direction maps, inverse pole figures, and
textures were obtained from electron backscatter diffraction (EBSD)
analyses.
Abstract: The hydrogenated amorphous carbon films (α-C:H)
were deposited on p-type Si (100) substrates at different thicknesses by
radio frequency plasma enhanced chemical vapor deposition
technique (rf-PECVD). Raman spectra display asymmetric
diamond-like carbon (DLC) peaks, representative of the α-C:H films.
The decrease of intensity ID/IG ratios revealed the sp3 content arise at
different thicknesses of the α-C:H films. In terms of mechanical
properties, the high hardness and elastic modulus values showed the
elastic and plastic deformation behaviors related to sp3 content in
amorphous carbon films. Electrochemical properties showed that the
α-C:H films exhibited excellent corrosion resistance in air-saturated
3.5 wt.% NaCl solution for pH 2 at room temperature. Thickness
increasing affected the small sp2 clusters in matrix, restricting the
velocity transfer and exchange of electrons. The deposited α-C:H films
exhibited excellent mechanical properties and corrosion resistance.
Abstract: Violet Sr–Al–O:Eu2+ phosphor particles were
synthesized from a metal–ethylenediaminetetraacetic acid (EDTA)
solution of Sr, Al, Eu, and particulate alumina via spray drying and
sintering in a reducing atmosphere. The crystal structures and emission
properties at 85–300 K were investigated. The composition of the
violet Sr–Al–O:Eu2+ phosphor particles was determined from various
Sr–Al–O:Eu2+ phosphors by their emission properties’ dependence
on temperature. The highly crystalline SrAl12O19:Eu2+ emission phases
were confirmed by their crystallite sizes and the activation energies for
the 4f5d–8S7/2 transition of the Eu2+ ion. These results showed that the
material identification for the violet Sr–Al–O:Eu2+ phosphor was
accomplished by the low-temperature luminescence measurements.
Abstract: Yttrium oxide (Y2O3) films have been successfully
deposited with yttrium-ethylenediamine tetraacetic acid (EDTA·Y·H)
complexes prepared by various milling techniques. The effects of the
properties of the EDTA·Y·H complex on the properties of the
deposited Y2O3 films have been analyzed. Seven different types of the
raw EDTA·Y·H complexes were prepared by various commercial
milling techniques such as ball milling, hammer milling, commercial
milling, and mortar milling. The milled EDTA·Y·H complexes
exhibited various particle sizes and distributions, depending on the
milling method. Furthermore, we analyzed the crystal structure,
morphology and elemental distribution profile of the metal oxide films
deposited on stainless steel substrate with the milled EDTA·Y·H
complexes. Depending on the milling technique, the flow properties of
the raw powders differed. The X-ray diffraction pattern of all the
samples revealed the formation of Y2O3 crystalline phase, irrespective
of the milling technique. Of all the different milling techniques, the
hammer milling technique is considered suitable for fabricating dense
Y2O3 films.
Abstract: In sheet metal forming process, raw material
mechanical properties are important parameters. This paper is to
compare the wall’s incline angle or formability of SS 400 steel and
SUS 304 stainless steel in single point incremental forming. The two
materials are ferrous base alloyed, which have the different unit cell,
mechanical property and chemical composition. They were forming
into cone shape specimens having 100 mm diameter with different
wall’s incline angle: 90o, 75o and 60o. The investigation was
continued until the specimens formed surface facture. The
experimental result showed that the smaller the wall incline angle
higher the formability with the both materials. The formability limit
of the ferrous base alloy was approx. 60o wall’s incline angle. By
nature, SS 400 has higher formability than SUS 304. This result can
be used as the initial data in designing the single point incremental
forming parts.
Abstract: The reliability of the filtered HVBK model is now
investigated via some large eddy simulations (LES) of freely
decaying isotropic superfluid turbulence. For homogeneous
turbulence at very high Reynolds numbers, comparison of the terms
in the spectral kinetic energy budget equation indicates, in the
energy-containing range, that the production and energy transfer
effects become significant except for dissipation. In the inertial range,
where the two fluids are perfectly locked, the mutual friction maybe
neglected with respect to other terms. Also, the LES results for the
other terms of the energy balance are presented.
Abstract: Two Lithium Disilicate (LD) glass ceramics based on
SiO2-Li2O-K2O-Al2O3 system were prepared through a glass melting
method. The glass rods were then fabricated into dental crowns via a
hot pressing at 900˚C and 850˚C in order to study the effect of the
pressing temperatures on the phase formation and microstructure of
the glasses. Different samples of as cast glass and heat treated
samples (600˚C and 700˚C) were used to press for investigating the
effect of an initial microstructure on the hot pressing technique. Xray
diffraction (XRD) and scanning electron microscopy (SEM) were
performed to determine the phase formation and microstructure of the
samples, respectively. XRD results show that the main crystalline
structure was Li2Si2O5 by having Li3PO4, Li0.6Al0.6Si2O6, Li2SiO3,
Ca5 (PO4)3F and SiO2 as minor phases. Glass compositions with
different heat treatment temperatures exhibited a difference phase
formations but have less effect during pressing. SEM micrographs
showed the microstructure of Li2Si2O5 as lath-like shape in all
glasses. With increasing the initial heat treatment temperature, the
longer the lath-like crystals of lithium disilicate were increased
especially when using glass heat treatment at 700˚C followed by
pressing at 900˚C. This could be suggested that LD1 heat treatment at
700˚C which pressing at 900˚C presented the best formation by the
hot pressing and compiled microstructure.
Abstract: Particles are the most common and cheapest
reinforcement producing discontinuous reinforced composites with
isotropic properties. Conventional fabrication methods can be used to
produce a wide range of product forms, making them relatively
inexpensive. Optimising composite development must include
consideration of all the fundamental aspect of particles including
their size, shape, volume fraction, distribution and mechanical
properties. Research has shown that the challenges of low fracture
toughness, poor crack growth resistance and low thermal stability can
be overcome by reinforcement with particles. The unique properties
exhibited by micro particles reinforced ceramic composites have
made them to be highly attractive in a vast array of applications.
Abstract: Corrosion inhibitors are widely used in concrete
industry to reduce the corrosion rate of steel rebar which is present in
contact with aggressive environments. The present work aims to
using Zamzam water from well located within the Masjid al-Haram
in Mecca, Saudi Arabia 20 m (66 ft) east of the Kaaba, the holiest
place in Islam as corrosion inhibitor for steel in rain water and
simulated acid rain. The effect of Zamzam water was investigated by
electrochemical impedance spectroscopy (EIS) and Potentiodynamic
polarization techniques in Department of Civil Engineering - IUT
Saint-Nazaire, Nantes University, France. Zamzam water is
considered to be one of the most important steel corrosion inhibitor
which is frequently used in different industrial applications. Results
showed that zamzam water gave a very good inhibition for steel
corrosion in rain water and simulated acid rain.
Abstract: Components with sensory properties such as gentelligent components developed at the Collaborative Research Centre 653 offer a new angle in terms of the full utilization of the remaining service life as well as preventive maintenance. The developed methodology of component status driven maintenance analyzes the stress data obtained during the component's useful life and on the basis of this knowledge assesses the type of maintenance required in this case. The procedure is derived from the case-based reasoning method and will be explained in detail. The method's functionality is demonstrated with real-life data obtained during test runs of a racing car prototype.
Abstract: The main purpose of this work was verify the
influence of the accelerated carbonation in the physical and
mechanical properties of the hybrid composites, reinforced with
micro and nanofibers and composites with microfibers. The
composites were produced by the slurry vacuum dewatering method,
followed by pressing. It was produced using two formulations: 8% of
eucalyptus pulp + 1% of the nanofibrillated cellulose and 9% of
eucalyptus pulp, both were subjected to accelerated carbonation. The
results showed that the accelerated carbonation contributed to
improve the physical and mechanical properties of the hybrid
composites and of the composites reinforced with microfibers
(eucalyptus pulp).
Abstract: In this study, microcrystalline cellulose (MCC) was
extracted from oil palm empty fruit bunch (EFB) cellulose which was
earlier isolated from oil palm EFB fibre. In order to isolate the
cellulose, the chlorination method was carried out. Then, the MCC
was prepared by simultaneous ultrasonic and alkali treatment from
the isolated α-cellulose. Based on mass balance calculation, the yields
for MCC obtained from EFB was 44%. For fiber characterization, it
is observed that the chemical composition of the hemicellulose and
lignin for all samples decreased while composition for cellulose
increased. The structural property of the MCC was studied by X-ray
diffraction (XRD) method and the result shows that the MCC
produced is a cellulose-I polymorph, with 73% crystallinity.
Abstract: Two types of glass fibers having different lengths
(1/16" and 1/32") were added into rigid PVC foams to enhance the
dimensional stability of extruded rigid Polyvinyl Chloride (PVC)
foam at different concentrations (0-20 phr) using a single screw
profile extruder. PVC foam-glass fiber composites (PVC-GF) were
characterized for their dimensional stability, structural, thermal, and
mechanical properties. Experimental results show that the
dimensional stability, heat resistance, and storage modulus were
enhanced without compromising the tensile and flexural strengths of
the composites. Overall, foam composites which were prepared with
longer glass fibers exhibit better mechanical and thermal properties
than those prepared with shorter glass fibers due to higher
interlocking between the fibers and the foam cells, which result in
better load distribution in the matrix.