Synthesis of Y2O3 Films by Spray Coating with Milled EDTA·Y·H Complexes
Yttrium oxide (Y2O3) films have been successfully
deposited with yttrium-ethylenediamine tetraacetic acid (EDTA·Y·H)
complexes prepared by various milling techniques. The effects of the
properties of the EDTA·Y·H complex on the properties of the
deposited Y2O3 films have been analyzed. Seven different types of the
raw EDTA·Y·H complexes were prepared by various commercial
milling techniques such as ball milling, hammer milling, commercial
milling, and mortar milling. The milled EDTA·Y·H complexes
exhibited various particle sizes and distributions, depending on the
milling method. Furthermore, we analyzed the crystal structure,
morphology and elemental distribution profile of the metal oxide films
deposited on stainless steel substrate with the milled EDTA·Y·H
complexes. Depending on the milling technique, the flow properties of
the raw powders differed. The X-ray diffraction pattern of all the
samples revealed the formation of Y2O3 crystalline phase, irrespective
of the milling technique. Of all the different milling techniques, the
hammer milling technique is considered suitable for fabricating dense
Y2O3 films.
[1] J. Trpcevska, N. Ganev, W. Zorawski, D. Jakubeczyova, and J. Briancin,
“Effect of Powder Particle Size on the Structure of HVOF WC-Co
Sprayed Coatings, Powder Metall. Prog.”, vol. 9, p. 42-48 (2009).
[2] T.S. Srivatsan, R. Woods, M. Petraroli, and T.S. Sudarshan, “An
Investigation of the Influence of Powder Particle Size on Microstructure
and Hardness of Bulk Samples of Tungsten Carbide”, Powder Tech., vol.
122, p. 54-60 (2002).
[3] Q. Yang, T. Senda, and A. Ohmori, “Effect of Carbide Grain Size on
Microstructure and Sliding Wear Behavior of HVOF-sprayed WC–12%
Co Coatings”, Wear, vol. 254, p. 23-34 (2003).
[4] M. Li and P.D. Christofides, “Modeling and Analysis of HVOF Thermal
Spray Process Accounting for Powder Size Distribution”, Chem. Eng.
Sci., vol. 58, p. 849-857 (2003).
[5] P. Cheng and K.A. Khor, “Thermal Spraying of Hydroxyapatite (HA)
Coatings” Powder Feedstock, J. Mater. Process. Tech., vol. 48, p.
429-436 (1995).
[6] Y. Qiao, T.E. Fischer, and A. Dent, “The Effects of Fuel Chemistry and
Feedstock Powder Structure on the Mechanical and Tribological
Properties of HVOF Thermal-sprayed WC–Co Coatings with Very Fine
Structures”, Surf. Coat. Tech., vol. 172, p. 24-41 (2003).
[7] J.-H. Hani and D.-Y. Kim, “Determination of Three-dimensional Grain
Size Distribution by Linear Intercept Measurement”, Acta Mater., vol.46,
p .2021-2028 (1998).
[8] P. Chivavibul, M. Watanabe, S. Kuroda, J. Kawakita, M. Komatsu, K.
Sato, and J. Kitamura, “Effect of Powder Characteristics on Properties of
Warm-Sprayed WC-Co Coatings”, J. Therm. Spray Tech., vol. 19 p.
81-88 (2010).
[9] H. Akasaka, M. Ohto, Y. Hasebe, A. Nakamura, S. Ohshio, and H. Saitoh,
“Yttria Coating Synthesized by Reactive Flame Spray Process Using
Y-EDTA Complex”, Surf. Coat. Tech., vol. 205, p. 3877-3880 (2011).
[10] H. Saitoh, K. Kawahara, S. Ohshio, A. Nakamura, and N. Nambu,
“Synthesis of Blue Phosphor by Decomposition of Metal Complex
Powder”, J. Ceram. Sci., vol. 110, p. 874-876 (2002).
[11] H. Saitoh, R. Satoh, A. Nakamura, N. Nambu, and S. Ohshio, “Metal
Oxide Powder Synthesized with Amorphous Metal Chelates”, J.
Mater.Sci., vol. 37 p. 4315-4320 (2002).
[12] H. Saitoh, K. Kawahara, S. Ohshio, A. Nakamura, and N. Nambu, “Metal
Composition of Y2O3:Eu Powder Evaluated Using Particle Analyzer”,
Sci. Tech. Adv. Mater., vol. 6, p. 205-209 (2005).
[13] N. Tanaka, S. Ohshio, H. Saitoh, and K. Uematsu, “Crystal Growth of
Highly Oriented Zinc Oxide by Laser Deposition Technique with
Metal-EDTA (Ethylene Diamine Tetra-acetic Acid) Complexes”, Jpn. J.
Appl. Phys., vol. 37, p. L1165-L1168 (1998).
[14] N. Tanaka, H. Wakabayashi, Y. Takata, S. Ohashio, H. Saitoh, and
K.Uematsu, “Complex Beam Epitaxy of Metal Oxide Films”, Mater. Res.
Innovat., vol. 2, p. 39-44 (1998).
[15] A. Nakamura, R. Satoh, S. Ohshio, N. Nambu, and H. Saitoh, “Laser
Deposition of (Sr,Ba)TiO3 Films with Metal-ethylenediaminetetraacetic
Acid Complexes”, Jpn. J. Appl. Phys., vol. 41, p. 3033-3038 (2002).
[16] Y.V. Griko, “Energetics of Ca2+ EDTA Interactions: Calorimetric
Study”, Biophys. Chem., vol. 79, p. 117-127 (1999).
[17] M. Suzuki, “Overview for Suspension Plasma Spray and Solution
Precursor Plasma Spray (SPS/ SPPS)” 2012 Spring National Meeting of
Japan Thermal Spray Society Abstract, p. 25-26 (2012) (in Japanese).
[18] Z.Z. Fang, X. Wang, T. Ryu, K.S. Hwang, and H.Y. Sohn, “Synthesis,
Sintering, and Mechanical Properties of Nanocrystalline Cemented
Tungsten Carbide–A Review”, Int. J. Refra. Metals Hard Mater., vol. 27,
p. 288-299 (2009).
[19] S.-H. Back, G.-H. Lee, and S. Kang, “Effect of Cryomilling on Particle
Size and Microstrain in a WC-Co Alloy”, Mater. Trans., vol. 46, p.
105-110 (2005).
[20] http://www.vector.co.jp/soft/dos/art/se492512.html (free software)
[21] B.V. Melkebeke, C. Vervaet, and J.P. Remon, “Validation of a
Continuous Granulation Process Using a Twin-screw Extruder”, Int. J.
Pharm., vol. 356, p. 224-230 (2008).
[22] V. Landillon, D. Cassan, M.-H. Morel, and B. Cuq, “Flowability,
Cohesive, and Granulation Properties of Wheat Powders”, J. Food Eng.,
vol. 86, p. 178-193 (2008).
[23] S.H. Na, S.H. Kim, Y.-W. Lee, and D.S. Sohn, “Effect of Ball-mill
Treatment on Powder Characteristics, Compaction and Sintering
Behaviors of ex-AUC and ex-ADU UO2 Powder”, J. Korean Nucl. Soc.,
vol. 34, p.60-67 (2002).
[24] Z.P. Xie, Y. Huang, and J.G. Wu, “Effects of Powder Characteristics and
Grinding Processes on Fluidity of Ceramic Injection Moulding
Mixtures”, J. Mater. Sci Lett., vol. 14, p. 1165-1167 (1995).
[25] C. Karatas, A. Kocer, H.I. Unal, and S. Saritas, “Rheological Properties of
Feedstocks Prepared with Steatite Powder and Polyethylene-based
Thermoplastic Binders”, J. Mater. Process. Tech., vol. 152, p 77-83
(2004).
[26] P. Zhang, A. Navrotsky, B. Guo, I. Kennedy, A.N. Clark, C. Lesher, and
Q. Liu, “Energetics of Cubic and Monoclinic Yttrium Oxide Polymorphs:
Phase Transitions, Surface Enthalpies, and Stability at the Nanoscale”, J.
Phys. Chem. C, vol. 112, p. 932-938 (2008).
[27] M. Vardelle, A. Vardelle, A.C. Leger, P. Fauchais, and D. Gobin,
“Influence of Particle Parameters at Impact on Splat Formation and
Solidification in Plasma Spraying Processes”, J. Therm. Spray Tech., vol.
4, p. 50-58 (1994).
[1] J. Trpcevska, N. Ganev, W. Zorawski, D. Jakubeczyova, and J. Briancin,
“Effect of Powder Particle Size on the Structure of HVOF WC-Co
Sprayed Coatings, Powder Metall. Prog.”, vol. 9, p. 42-48 (2009).
[2] T.S. Srivatsan, R. Woods, M. Petraroli, and T.S. Sudarshan, “An
Investigation of the Influence of Powder Particle Size on Microstructure
and Hardness of Bulk Samples of Tungsten Carbide”, Powder Tech., vol.
122, p. 54-60 (2002).
[3] Q. Yang, T. Senda, and A. Ohmori, “Effect of Carbide Grain Size on
Microstructure and Sliding Wear Behavior of HVOF-sprayed WC–12%
Co Coatings”, Wear, vol. 254, p. 23-34 (2003).
[4] M. Li and P.D. Christofides, “Modeling and Analysis of HVOF Thermal
Spray Process Accounting for Powder Size Distribution”, Chem. Eng.
Sci., vol. 58, p. 849-857 (2003).
[5] P. Cheng and K.A. Khor, “Thermal Spraying of Hydroxyapatite (HA)
Coatings” Powder Feedstock, J. Mater. Process. Tech., vol. 48, p.
429-436 (1995).
[6] Y. Qiao, T.E. Fischer, and A. Dent, “The Effects of Fuel Chemistry and
Feedstock Powder Structure on the Mechanical and Tribological
Properties of HVOF Thermal-sprayed WC–Co Coatings with Very Fine
Structures”, Surf. Coat. Tech., vol. 172, p. 24-41 (2003).
[7] J.-H. Hani and D.-Y. Kim, “Determination of Three-dimensional Grain
Size Distribution by Linear Intercept Measurement”, Acta Mater., vol.46,
p .2021-2028 (1998).
[8] P. Chivavibul, M. Watanabe, S. Kuroda, J. Kawakita, M. Komatsu, K.
Sato, and J. Kitamura, “Effect of Powder Characteristics on Properties of
Warm-Sprayed WC-Co Coatings”, J. Therm. Spray Tech., vol. 19 p.
81-88 (2010).
[9] H. Akasaka, M. Ohto, Y. Hasebe, A. Nakamura, S. Ohshio, and H. Saitoh,
“Yttria Coating Synthesized by Reactive Flame Spray Process Using
Y-EDTA Complex”, Surf. Coat. Tech., vol. 205, p. 3877-3880 (2011).
[10] H. Saitoh, K. Kawahara, S. Ohshio, A. Nakamura, and N. Nambu,
“Synthesis of Blue Phosphor by Decomposition of Metal Complex
Powder”, J. Ceram. Sci., vol. 110, p. 874-876 (2002).
[11] H. Saitoh, R. Satoh, A. Nakamura, N. Nambu, and S. Ohshio, “Metal
Oxide Powder Synthesized with Amorphous Metal Chelates”, J.
Mater.Sci., vol. 37 p. 4315-4320 (2002).
[12] H. Saitoh, K. Kawahara, S. Ohshio, A. Nakamura, and N. Nambu, “Metal
Composition of Y2O3:Eu Powder Evaluated Using Particle Analyzer”,
Sci. Tech. Adv. Mater., vol. 6, p. 205-209 (2005).
[13] N. Tanaka, S. Ohshio, H. Saitoh, and K. Uematsu, “Crystal Growth of
Highly Oriented Zinc Oxide by Laser Deposition Technique with
Metal-EDTA (Ethylene Diamine Tetra-acetic Acid) Complexes”, Jpn. J.
Appl. Phys., vol. 37, p. L1165-L1168 (1998).
[14] N. Tanaka, H. Wakabayashi, Y. Takata, S. Ohashio, H. Saitoh, and
K.Uematsu, “Complex Beam Epitaxy of Metal Oxide Films”, Mater. Res.
Innovat., vol. 2, p. 39-44 (1998).
[15] A. Nakamura, R. Satoh, S. Ohshio, N. Nambu, and H. Saitoh, “Laser
Deposition of (Sr,Ba)TiO3 Films with Metal-ethylenediaminetetraacetic
Acid Complexes”, Jpn. J. Appl. Phys., vol. 41, p. 3033-3038 (2002).
[16] Y.V. Griko, “Energetics of Ca2+ EDTA Interactions: Calorimetric
Study”, Biophys. Chem., vol. 79, p. 117-127 (1999).
[17] M. Suzuki, “Overview for Suspension Plasma Spray and Solution
Precursor Plasma Spray (SPS/ SPPS)” 2012 Spring National Meeting of
Japan Thermal Spray Society Abstract, p. 25-26 (2012) (in Japanese).
[18] Z.Z. Fang, X. Wang, T. Ryu, K.S. Hwang, and H.Y. Sohn, “Synthesis,
Sintering, and Mechanical Properties of Nanocrystalline Cemented
Tungsten Carbide–A Review”, Int. J. Refra. Metals Hard Mater., vol. 27,
p. 288-299 (2009).
[19] S.-H. Back, G.-H. Lee, and S. Kang, “Effect of Cryomilling on Particle
Size and Microstrain in a WC-Co Alloy”, Mater. Trans., vol. 46, p.
105-110 (2005).
[20] http://www.vector.co.jp/soft/dos/art/se492512.html (free software)
[21] B.V. Melkebeke, C. Vervaet, and J.P. Remon, “Validation of a
Continuous Granulation Process Using a Twin-screw Extruder”, Int. J.
Pharm., vol. 356, p. 224-230 (2008).
[22] V. Landillon, D. Cassan, M.-H. Morel, and B. Cuq, “Flowability,
Cohesive, and Granulation Properties of Wheat Powders”, J. Food Eng.,
vol. 86, p. 178-193 (2008).
[23] S.H. Na, S.H. Kim, Y.-W. Lee, and D.S. Sohn, “Effect of Ball-mill
Treatment on Powder Characteristics, Compaction and Sintering
Behaviors of ex-AUC and ex-ADU UO2 Powder”, J. Korean Nucl. Soc.,
vol. 34, p.60-67 (2002).
[24] Z.P. Xie, Y. Huang, and J.G. Wu, “Effects of Powder Characteristics and
Grinding Processes on Fluidity of Ceramic Injection Moulding
Mixtures”, J. Mater. Sci Lett., vol. 14, p. 1165-1167 (1995).
[25] C. Karatas, A. Kocer, H.I. Unal, and S. Saritas, “Rheological Properties of
Feedstocks Prepared with Steatite Powder and Polyethylene-based
Thermoplastic Binders”, J. Mater. Process. Tech., vol. 152, p 77-83
(2004).
[26] P. Zhang, A. Navrotsky, B. Guo, I. Kennedy, A.N. Clark, C. Lesher, and
Q. Liu, “Energetics of Cubic and Monoclinic Yttrium Oxide Polymorphs:
Phase Transitions, Surface Enthalpies, and Stability at the Nanoscale”, J.
Phys. Chem. C, vol. 112, p. 932-938 (2008).
[27] M. Vardelle, A. Vardelle, A.C. Leger, P. Fauchais, and D. Gobin,
“Influence of Particle Parameters at Impact on Splat Formation and
Solidification in Plasma Spraying Processes”, J. Therm. Spray Tech., vol.
4, p. 50-58 (1994).
@article{"International Journal of Chemical, Materials and Biomolecular Sciences:68591", author = "Keiji Komatsu and Tetsuo Sekiya and Ayumu Toyama and Atsushi Nakamura and Ikumi Toda and Shigeo Ohshio and Hiroyuki Muramatsu and Hidetoshi Saitoh and Atsushi Nakamura and Ariyuki Kato", title = "Synthesis of Y2O3 Films by Spray Coating with Milled EDTA·Y·H Complexes", abstract = "Yttrium oxide (Y2O3) films have been successfully
deposited with yttrium-ethylenediamine tetraacetic acid (EDTA·Y·H)
complexes prepared by various milling techniques. The effects of the
properties of the EDTA·Y·H complex on the properties of the
deposited Y2O3 films have been analyzed. Seven different types of the
raw EDTA·Y·H complexes were prepared by various commercial
milling techniques such as ball milling, hammer milling, commercial
milling, and mortar milling. The milled EDTA·Y·H complexes
exhibited various particle sizes and distributions, depending on the
milling method. Furthermore, we analyzed the crystal structure,
morphology and elemental distribution profile of the metal oxide films
deposited on stainless steel substrate with the milled EDTA·Y·H
complexes. Depending on the milling technique, the flow properties of
the raw powders differed. The X-ray diffraction pattern of all the
samples revealed the formation of Y2O3 crystalline phase, irrespective
of the milling technique. Of all the different milling techniques, the
hammer milling technique is considered suitable for fabricating dense
Y2O3 films.
", keywords = "Powder sizes and distributions, Flame spray coating
techniques, Yttrium oxide.", volume = "8", number = "12", pages = "1419-5", }
