Synthesis of Y2O3 Films by Spray Coating with Milled EDTA·Y·H Complexes

Year: 2014 Volume: 8 Issue: 12 1419 - 1423 Pages

• Authors:
• Keiji Komatsu
• Tetsuo Sekiya
• Ayumu Toyama
• Atsushi Nakamura
• Ikumi Toda
• Shigeo Ohshio
• Hiroyuki Muramatsu
• Hidetoshi Saitoh
• Atsushi Nakamura
• Ariyuki Kato

Abstract: Yttrium oxide (Y2O3) films have been successfully deposited with yttrium-ethylenediamine tetraacetic acid (EDTA·Y·H) complexes prepared by various milling techniques. The effects of the properties of the EDTA·Y·H complex on the properties of the deposited Y2O3 films have been analyzed. Seven different types of the raw EDTA·Y·H complexes were prepared by various commercial milling techniques such as ball milling, hammer milling, commercial milling, and mortar milling. The milled EDTA·Y·H complexes exhibited various particle sizes and distributions, depending on the milling method. Furthermore, we analyzed the crystal structure, morphology and elemental distribution profile of the metal oxide films deposited on stainless steel substrate with the milled EDTA·Y·H complexes. Depending on the milling technique, the flow properties of the raw powders differed. The X-ray diffraction pattern of all the samples revealed the formation of Y2O3 crystalline phase, irrespective of the milling technique. Of all the different milling techniques, the hammer milling technique is considered suitable for fabricating dense Y2O3 films.

• Keywords:
• Powder sizes and distributions
• Flame spray coating techniques
• Yttrium oxide.

Low-Temperature Luminescence Spectroscopy of Violet Sr-Al-O:Eu2+ Phosphor Particles

Year: 2014 Volume: 8 Issue: 12 1413 - 1418 Pages

• Authors:
• Keiji Komatsu
• Hayato Maruyama
• Ariyuki Kato
• Atsushi Nakamura
• Shigeo Ohshio
• Hiroki Akasaka
• Hidetoshi Saitoh

Abstract: Violet Sr–Al–O:Eu2+ phosphor particles were synthesized from a metal–ethylenediaminetetraacetic acid (EDTA) solution of Sr, Al, Eu, and particulate alumina via spray drying and sintering in a reducing atmosphere. The crystal structures and emission properties at 85–300 K were investigated. The composition of the violet Sr–Al–O:Eu2+ phosphor particles was determined from various Sr–Al–O:Eu2+ phosphors by their emission properties’ dependence on temperature. The highly crystalline SrAl12O19:Eu2+ emission phases were confirmed by their crystallite sizes and the activation energies for the 4f5d–8S7/2 transition of the Eu2+ ion. These results showed that the material identification for the violet Sr–Al–O:Eu2+ phosphor was accomplished by the low-temperature luminescence measurements.

• Keywords:
• Low temperature luminescence spectroscopy
• Material Identification
• Strontium aluminates phosphor.