Abstract: A numerical investigation has carried out to understand the melting characteristics of phase change material (PCM) in a fin type latent heat storage with the addition of embedded aluminum spiral fillers. It is known that melting performance of PCM can be significantly improved by increasing the number of embedded metallic fins in the latent heat storage system but to certain values where only lead to small improvement in heat transfer rate. Hence, adding aluminum spiral fillers within the fin gap can be an option to improve heat transfer internally. This paper presents extensive computational visualizations on the PCM melting patterns of the proposed fin-spiral fillers configuration. The aim of this investigation is to understand the PCM-s melting behaviors by observing the natural convection currents movement and melting fronts formation. Fluent 6.3 simulation software was utilized in producing twodimensional visualizations of melting fractions, temperature distributions and flow fields to illustrate the melting process internally. The results show that adding aluminum spiral fillers in Fin type latent heat storage can promoted small but more active natural convection currents and improve melting of PCM.
Abstract: It is well known that enhancing interfacial adhesion
between inorganic filler and matrix resin in a composite lead to
favorable properties such as excellent mechanical properties, high
thermal resistance, prominent electric insulation, low expansion
coefficient, and so on. But it should be avoided that much excess of
coupling agent is reacted due to a negative impact of their final
composite-s properties. There is no report to achieve classification of
the bonding state excepting investigation of coating layer thickness.
Therefore, the analysis of the bonding state of the coupling agent
reacted with the filler surface such as BN particles with less functional
group and silica particles having much functional group was
performed by thermal gravimetric analysis and pyrolysis GC/MS. The
reacted number of functional groups on the silane-coupling agent was
classified as a result of the analysis. Thus, we succeeded in classifying
the reacted number of the functional groups as a result of this study.
Abstract: Nowadays due to globalization of economy and
competition environment, innovation and technology plays key role
at creation of wealth and economic growth of countries. In fact
prompt growth of practical and technologic knowledge may results in
social benefits for countries when changes into effective innovation.
Considering the importance of innovation for the development of
countries, this study addresses the radical technological innovation
introduced by nanopapers at different stages of producing paper
including stock preparation, using authorized additives, fillers and
pigments, using retention, calender, stages of producing conductive
paper, porous nanopaper and Layer by layer self-assembly. Research
results show that in coming years the jungle related products will lose
considerable portion of their market share, unless embracing radical
innovation. Although incremental innovations can make this industry
still competitive in mid-term, but to have economic growth and
competitive advantage in long term, radical innovations are
necessary. Radical innovations can lead to new products and
materials which their applications in packaging industry can produce
value added. However application of nanotechnology in this industry
can be costly, it can be done in cooperation with other industries to
make the maximum use of nanotechnology possible. Therefore this
technology can be used in all the production process resulting in the
mass production of simple and flexible papers with low cost and
special properties such as facility at shape, form, easy transportation,
light weight, recovery and recycle marketing abilities, and sealing.
Improving the resistance of the packaging materials without reducing
the performance of packaging materials enhances the quality and the
value added of packaging. Improving the cellulose at nano scale can
have considerable electron optical and magnetic effects leading to
improvement in packaging and value added. Comparing to the
specifications of thermoplastic products and ordinary papers,
nanopapers show much better performance in terms of effective
mechanical indexes such as the modulus of elasticity, tensile strength,
and strain-stress. In densities lower than 640 kgm -3, due to the
network structure of nanofibers and the balanced and randomized
distribution of NFC in flat space, these specifications will even
improve more. For nanopapers, strains are 1,4Gpa, 84Mpa and 17%,
13,3 Gpa, 214Mpa and 10% respectively. In layer by layer self
assembly method (LbL) the tensile strength of nanopaper with Tio3
particles and Sio2 and halloysite clay nanotube are 30,4 ±7.6Nm/g
and 13,6 ±0.8Nm/g and 14±0.3,3Nm/g respectively that fall within
acceptable range of similar samples with virgin fiber. The usage of
improved brightness and porosity index in nanopapers can create
more competitive advantages at packaging industry.
Abstract: Materials added to the matrix help improving operating properties of a composite. This experimental study has targeted to investigate this aim where Silicon Oxide particles were added to glass fibre and epoxy resin at an amount of 15% to the main material to obtain a sort of new composite material. Erosive wear behavior of epoxy-resin dipped composite materials reinforced with glass fibre and Silicon Oxide under three different impingement angles (30°, 60° and 90°), three different impact velocities (23, 34 and 53 m/s), two different angular Aluminum abrasive particle sizes (approximately 200 and 400 μm) and the fibre orientation of 45° (45/-45) were investigated. In the test results, erosion rates were obtained as functions of impingement angles, impact velocities, particle sizes and fibre orientation. Moreover, materials with addition of Silicon Oxide filler material exhibited lower wear as compared to neat materials with no added filler material. In addition, SEM views showing worn out surfaces of the test specimens were scrutinized.
Abstract: Lightweight ceramic materials in the form of bricks
and blocks are widely used in modern construction. They may be
obtained by adding of rice husk, rye straw, etc, as porous forming
materials. Rice husk is a major by-product of the rice milling
industry. Its utilization as a valuable product has always been a
problem. Various technologies for utilization of rice husk through
biological and thermochemical conversion are being developed.
The purpose of this work is to develop lightweight ceramic
materials with clay matrix and filler of rice husk and examine their
main physicomechanical properties. The results obtained allow to
suppose that the materials synthesized on the basis of waste materials
can be used as lightweight materials for construction purpose.
Abstract: In the present study, the incorporation of graphene
into blends of acrylonitrile-butadiene-styrene terpolymer with
polypropylene (ABS/PP) was investigated focusing on the
improvement of their thermomechanical characteristics and the effect
on their rheological behavior. The blends were prepared by melt
mixing in a twin-screw extruder and were characterized by measuring
the MFI as well as by performing DSC, TGA and mechanical tests.
The addition of graphene to ABS/PP blends tends to increase their
melt viscosity, due to the confinement of polymer chains motion.
Also, graphene causes an increment of the crystallization temperature
(Tc), especially in blends with higher PP content, because of the
reduction of surface energy of PP nucleation, which is a consequence
of the attachment of PP chains to the surface of graphene through the
intermolecular CH-π interaction. Moreover, the above nanofiller
improves the thermal stability of PP and increases the residue of
thermal degradation at all the investigated compositions of blends,
due to the thermal isolation effect and the mass transport barrier
effect. Regarding the mechanical properties, the addition of graphene
improves the elastic modulus, because of its intrinsic mechanical
characteristics and its rigidity, and this effect is particularly strong in
the case of pure PP.
Abstract: This paper deals with the evaluation of flow properties
of polymeric matrix with natural animal fillers. Technical university
of Liberec cooperates on the long-term development of “green
materials“ that should replace conventionally used materials
(especially in automotive industry). Natural fibres (of animal and
plant origin) from all over the world are collected and adapted
(drying, cutting etc.) for extrusion processing. Inside the extruder
these natural additives are blended with polymeric (synthetic and
biodegradable - PLA) matrix and created compound is subsequently
cut for pellets in the wet way. These green materials with unique
recipes are then studied and their mechanical, physical and
processing properties are determined. The main goal of this research
is to develop new ecological materials very similar to unfilled
polymers. In this article the rheological behaviour of chosen natural
animal fibres is introduced considering their shape and surface that
were observed with use of SEM microscopy.
Abstract: Binder drainage test is widely used to set an upper
limit to the design binder content of porous asphalt. However, the
presence of high amount of fine particles in the drained binder may
affect the accuracy of the test result. This paper presents a study to
characterize the composition and particle size distribution of fine
particles accumulated in the drained binder. Fine aggregates and filler
in the drained binder were extracted using a suitable solvent. Then,
wet and dry sieve analysis was carried out to identify the actual
composition of the extracted fine aggregates and filler. From the
results, almost half of the drained binder consisted of fine aggregates
and this significantly affects the accuracy of the design binder content
of porous asphalt mix. This simple finding highlights the importance
of taking into account the presence of fine aggregates in the
calculation of drained binder.
Abstract: A novel physico-chemical route to produce few layer graphene nanoribbons with atomically smooth edges is reported, via acid treatment (H2SO4:HNO3) followed by characteristic thermal shock processes involving extremely cold substances. Samples were studied by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), Raman spectroscopy and X-ray photoelectron spectroscopy. This method demonstrates the importance of having the nanotubes open ended for an efficient uniform unzipping along the nanotube axis. The average dimensions of these nanoribbons are approximately ca. 210 nm wide and consist of few layers, as observed by transmission electron microscopy. The produced nanoribbons exhibit different chiralities, as observed by high resolution transmission electron microscopy. This method is able to provide graphene nanoribbons with atomically smooth edges which could be used in various applications including sensors, gas adsorption materials, composite fillers, among others.
Abstract: Conventional materials like glass, wood or metals
replacement with polymer materials is still continuing. More simple
thus cheaper production is the main reason. However due to high
energy and petrochemical prices are polymer prices increasing too.
That´s why various kinds of fillers are used to make polymers
cheaper. Of course target is to maintain or improve properties of
these compounds. In this paper are solved rheology issues of
polymers compounded with vegetal origin fibers.
Abstract: Reactive powder concretes (RPC) are characterized by
particle diameter not exceeding 600 μm and having very high
compressive and tensile strengths. This paper describes a new
generation of micro concrete, which has an initial, as well as a final,
high physicomechanical performance. To achieve this, we replaced
the Portland cement (15% by weight) by materials rich in Silica (Slag
and Dune Sand).
The results obtained from tests carried out on RPC show that
compressive and tensile strengths increase when adding the additions,
thus improving the compactness of mixtures via filler and pozzolanic
effect.
With a reduction of the aggregate phase in the RPC and the
abundance of dune sand (south Algeria) and slag (industrial byproduct
of blast furnace), the use of the RPC will allow Algeria to
fulfil economical as well as ecological requirements.
Abstract: The dental composites are preferably used as filling
materials due to their esthetic appearances. Nevertheless one of the
major problems, during the application of the dental composites, is
shape change named as “polymerisation shrinkage" affecting clinical
success of the dental restoration while photo-polymerisation.
Polymerisation shrinkage of composites arises basically from the
formation of a polymer due to the monomer transformation which
composes of an organic matrix phase. It was sought, throughout this
study, to detect and evaluate the structural polymerisation shrinkage
of prepared dental composites in order to optimize the effects of
various fillers included in hydroxyapatite (HA)-reinforced dental
composites and hence to find a means to modify the properties of
these dental composites prepared with defined parameters. As a
result, the shrinkage values of the experimental dental composites
were decreased by increasing the filler content of composites and the
composition of different fillers used had effect on the shrinkage of
the prepared composite systems.
Abstract: This work presents a low-cost and eco-friendly
building material named Agrostone panel. Africa-s urban population
is growing at an annual rate of 2.8% and 62% of its population will
live in urban areas by 2050. As a consequence, many of the least
urbanized and least developed African countries- will face serious
challenges in providing affordable housing to the urban dwellers.
Since the cost of building materials accounts for the largest
proportion of the overall construction cost, innovating low-cost
building material is vital. Agrostone panel is used in housing projects
in Ethiopia. It uses raw materials of agricultural/industrial wastes
and/or natural minerals as a filler, magnesium-based chemicals as a
binder and fiberglass as reinforcement. Agrostone panel reduces the
cost of wall construction by 50% compared with the conventional
building materials. The pros and cons of Agrostone panel as well as
the use of other waste materials as a raw material to make the panel
more sustainable, low-cost and better properties are discussed.
Abstract: Self-compacting concrete (SCC), a new kind of high
performance concrete (HPC) have been first developed in Japan in
1986. The development of SCC has made casting of dense
reinforcement and mass concrete convenient, has minimized noise.
Fresh self-compacting concrete (SCC) flows into formwork and
around obstructions under its own weight to fill it completely and
self-compact (without any need for vibration), without any
segregation and blocking. The elimination of the need for
compaction leads to better quality concrete and substantial
improvement of working conditions. SCC mixes generally have a
much higher content of fine fillers, including cement, and produce
excessively high compressive strength concrete, which restricts its
field of application to special concrete only. To use SCC mixes in
general concrete construction practice, requires low cost materials to
make inexpensive concrete.
Rice husk ash (RHA) has been used as a highly reactive
pozzolanic material to improve the microstructure of the interfacial
transition zone (ITZ) between the cement paste and the aggregate in
self compacting concrete. Mechanical experiments of RHA blended
Portland cement concretes revealed that in addition to the pozzolanic
reactivity of RHA (chemical aspect), the particle grading (physical
aspect) of cement and RHA mixtures also exerted significant
influences on the blending efficiency.
The scope of this research was to determine the usefulness of Rice
husk ash (RHA) in the development of economical self compacting
concrete (SCC). The cost of materials will be decreased by reducing
the cement content by using waste material like rice husk ash instead
of.
This paper presents a study on the development of Mechanical
properties up to 180 days of self compacting and ordinary concretes
with rice-husk ash (RHA), from a rice paddy milling industry in
Rasht (Iran). Two different replacement percentages of cement by
RHA, 10%, and 20%, and two different water/cementicious material
ratios (0.40 and 0.35), were used for both of self compacting and
normal concrete specimens. The results are compared with those of
the self compacting concrete without RHA, with compressive,
flexural strength and modulus of elasticity. It is concluded that RHA
provides a positive effect on the Mechanical properties at age after
60 days.
Base of the result self compacting concrete specimens have higher
value than normal concrete specimens in all test except modulus of
elasticity. Also specimens with 20% replacement of cement by RHA
have the best performance.
Abstract: Antimosy-doped tin oxide (ATO) particles were
prepared via chemical coprecipitation and reverse emulsion. The size
and size distribution of ATO particles were obviously decreased via
reverse microemulsion method. At the relatively high yield the ATO
particles were nearly spherical in shape, meanwhile the crystalline
structure and excellent conductivity were reserved, which could satisfy
the requirement as composite fillers, such as dielectric filler of
polyimide film.
Abstract: In this study the effect of incorporation of recycled
glass-fibre reinforced polymer (GFRP) waste materials, obtained by
means of milling processes, on mechanical behaviour of polyester
polymer mortars was assessed. For this purpose, different contents of
recycled GFRP waste powder and fibres, with distinct size gradings,
were incorporated into polyester based mortars as sand aggregates
and filler replacements. Flexural and compressive loading capacities
were evaluated and found better than unmodified polymer mortars.
GFRP modified polyester based mortars also show a less brittle
behaviour, with retention of some loading capacity after peak load.
Obtained results highlight the high potential of recycled GFRP waste
materials as efficient and sustainable reinforcement and admixture for
polymer concrete and mortars composites, constituting an emergent
waste management solution.
Abstract: In the past many uneconomic solutions for limitation
and interruption of short-circuit currents in low power applications
have been introduced, especially polymer switch based on the
positive temperature coefficient of resistance (PCTR) concept.
However there are many limitations in the active material, which
consists of conductive fillers. This paper presents a significantly
improved and simplified approach that replaces the existing current
limiters with faster switching elements. Its elegance lies in the
remarkable simplicity and low-cost processes of producing the device
using polyaniline (PANI) doped with methane-sulfonic acid (MSA).
Samples characterized as lying in the metallic and critical regimes of
metal insulator transition have been studied by means of electrical
performance in the voltage range from 1V to 5 V under different
environmental conditions. Moisture presence is shown to increase the
resistivity and also improved its current limiting performance.
Additionally, the device has also been studied for electrical resistivity
in the temperature range 77 K-300 K. The temperature dependence of
the electrical conductivity gives evidence for a transport mechanism
based on variable range hopping in three dimensions.
Abstract: Composites based on a biodegradable polycaprolactone (PCL) containing 0.5, 1.0 and 2.0 wt % of titanium dioxide (TiO2) micro and nanoparticles were prepared by melt mixing and the effect of filler type and contents on the thermal properties, dynamic-mechanical behaviour and morphology were investigated. Measurements of storage modulus and loss modulus by dynamic mechanical analysis (DMA) showed better results for microfilled PCL/TiO2 composites than nanofilled composites, with the same filler content. DSC analysis showed that the Tg and Tc of micro and nanocomposites were slightly lower than those of neat PCL. The crystallinity of the PCL increased with the addition of TiO2 micro and nanoparticles; however, the cc for the PCL was unchanged with micro TiO2 content. The thermal stability of PCL/TiO2 composites were characterized using thermogravimetric analysis (TGA). The initial weight loss (5 wt %) occurs at slightly higher temperature with micro and nano TiO2 addition and with increasing TiO2 content.
Abstract: Bionanotechnology deals with nanoscopic interactions between nanostructured materials and biological systems. Polymer nanocomposites with optimized biological activity have attracted great attention. Nanoclay is considered as reinforcing nanofiller in manufacturing of high performance nanocomposites. In current study, organomodified-nanoclay with negatively charged silicate layers was incorporated into biomedical grade silicone rubber. Nanoparticle loading has been tailored to enhance cell behavior. Addition of nanoparticles led to improved mechanical properties of substrate with enhanced strength and stiffness while no toxic effects was observed. Results indicated improved viability and proliferation of cells by addition of nanofillers. The improved mechanical properties of the matrix result in proper cell response through adjustment and arrangement of cytoskeletal fibers. Results can be applied in tissue engineering when enhanced substrates are required for improvement of cell behavior for in vivo applications.
Abstract: The term hybrid composite refers to the composite
containing more than one type of fiber material as reinforcing fillers.
It has become attractive structural material due to the ability of
providing better combination of properties with respect to single fiber
containing composite. The eco-friendly nature as well as processing
advantage, light weight and low cost have enhanced the attraction
and interest of natural fiber reinforced composite. The objective of
present research is to study the mechanical properties of jute-coir
fiber reinforced hybrid polypropylene (PP) composite according to
filler loading variation. In the present work composites were
manufactured by using hot press machine at four levels of fiber
loading (5, 10, 15 and 20 wt %). Jute and coir fibers were utilized at a
ratio of (1:1) during composite manufacturing. Tensile, flexural,
impact and hardness tests were conducted for mechanical
characterization. Tensile test of composite showed a decreasing trend
of tensile strength and increasing trend of the Young-s modulus with
increasing fiber content. During flexural, impact and hardness tests,
the flexural strength, flexural modulus, impact strength and hardness
were found to be increased with increasing fiber loading. Based on
the fiber loading used in this study, 20% fiber reinforced composite
resulted the best set of mechanical properties.