Abstract: In situ modified cyclohexanone-formaldehyde resins
were prepared by addition of alendronic acid during resin
preparation. Clay nanocomposites in ketonic resins were achieved by
adding clay into the flask at the beginning of the resin preparation.
The prepared resins were used for the synthesis of fire resistant
polyurethanes foam. Both phosphorous containing modifier
compound alendronic acid and nanoclay increases fire resistance of
the cyclohexanone-formaldehyde resin thus polyurethane produced
from these resins. The effect of the concentrations of alendronic acid
and clay on the fire resistance and physical properties of
polyurethanes was studied.
Abstract: In the scope of application of technical textiles, Non-
Crimp Fabrics are increasingly used. In general, NCF exhibit
excellent load bearing properties, but caused by the manufacturing
process, there are some remaining disadvantages which have to be
reduced. Regarding to this, a novel technique of processing NCF was
developed substituting the binding-thread by an adhesive. This stitchfree
method requires new manufacturing concept as well as new basic
methods to prove adhesion of glue at fibres and textiles. To improve
adhesion properties and the wettability of carbon-fibres by the
adhesive, oxy-fluorination was used. The modification of carbonfibres
by oxy-fluorination was investigated via scanning electron
microscope, X-ray photoelectron spectroscopy and single fibre
tensiometry. Special tensile tests were developed to determine the
maximum force required for detachment.
Abstract: Wet scrubbers have found widespread use in cleaning
contaminated gas streams because of their ability to remove
particulates and based on the applications of scrubbing of marine
engine exhaust gases by spraying sea-water. In order to examine the
flow characteristics inside the scrubber, the model is designated with
flow properties of hot air and water sprayer. The flow dynamics of
evaporation of hot air by the injection of water droplets is the key
factor considered in this paper. The flow behavior inside the scrubber
was investigated from the previous works and to sum up the
evaporation rate with respect to the concentration of water droplets are
predicted to bring out the competent modelling. The numerical
analysis using CFD facilitates in understanding the problem better and
empathies the behavior of the model over its entire operating envelope.
Abstract: Alkylated silicon nanocrystals (C11-SiNCs) were
prepared successfully by galvanostatic etching of p-Si(100) wafers
followed by a thermal hydrosilation reaction of 1-undecene in
refluxing toluene in order to extract C11-SiNCs from porous silicon.
Erbium trichloride was added to alkylated SiNCs using a simple
mixing chemical route. To the best of our knowledge, this is the first
investigation on mixing SiNCs with erbium ions (III) by this
chemical method. The chemical characterization of C11-SiNCs and
their mixtures with Er3+(Er/C11-SiNCs) were carried out using X-ray
photoemission spectroscopy (XPS). The optical properties of C11-
SiNCs and their mixtures with Er3+ were investigated using Raman
spectroscopy and photoluminescence (PL). The erbium mixed
alkylated SiNCs shows an orange PL emission peak at around 595
nm that originates from radiative recombination of Si. Er/C11-SiNCs
mixture also exhibits a weak PL emission peak at 1536 nm that
originates from the intra-4f transition in erbium ions (Er3+). The PL
peak of Si in Er/C11-SiNCs mixture is increased in the intensity up to
three times as compared to pure C11-SiNCs. The collected data
suggest that this chemical mixing route leads instead to a transfer of
energy from erbium ions to alkylated SiNCs.
Abstract: Water spray cooling is a technique typically used in
heat treatment and other metallurgical processes where controlled
temperature regimes are required. Water spray cooling is used in
static (without movement) or dynamic (with movement of the steel
plate) regimes. The static regime is notable for the fixed position of
the hot steel plate and fixed spray nozzle. This regime is typical for
quenching systems focused on heat treatment of the steel plate. The
second application of spray cooling is the dynamic regime. The
dynamic regime is notable for its static section cooling system and
moving steel plate. This regime is used in rolling and finishing mills.
The fixed position of cooling sections with nozzles and the
movement of the steel plate produce nonhomogeneous water
distribution on the steel plate. The length of cooling sections and
placement of water nozzles in combination with the nonhomogeneity
of water distribution lead to discontinued or interrupted cooling
conditions. The impact of static and dynamic regimes on cooling
intensity and the heat transfer coefficient during the cooling process
of steel plates is an important issue.
Heat treatment of steel is accompanied by oxide scale growth. The
oxide scale layers can significantly modify the cooling properties and
intensity during the cooling. The combination of static and dynamic
(section) regimes with the variable thickness of the oxide scale layer
on the steel surface impact the final cooling intensity. The study of
the influence of the oxide scale layers with different cooling regimes
was carried out using experimental measurements and numerical
analysis. The experimental measurements compared both types of
cooling regimes and the cooling of scale-free surfaces and oxidized
surfaces. A numerical analysis was prepared to simulate the cooling
process with different conditions of the section and samples with
different oxide scale layers.
Abstract: The thermal conductivity of a fluid can be
significantly enhanced by dispersing nano-sized particles in it, and
the resultant fluid is termed as "nanofluid". A theoretical model for
estimating the thermal conductivity of a nanofluid has been proposed
here. It is based on the mechanism that evenly dispersed
nanoparticles within a nanofluid undergo Brownian motion in course
of which the nanoparticles repeatedly collide with the heat source.
During each collision a rapid heat transfer occurs owing to the solidsolid
contact. Molecular dynamics (MD) simulation of the collision
of nanoparticles with the heat source has shown that there is a pulselike
pick up of heat by the nanoparticles within 20-100 ps, the extent
of which depends not only on thermal conductivity of the
nanoparticles, but also on the elastic and other physical properties of
the nanoparticle. After the collision the nanoparticles undergo
Brownian motion in the base fluid and release the excess heat to the
surrounding base fluid within 2-10 ms. The Brownian motion and
associated temperature variation of the nanoparticles have been
modeled by stochastic analysis. Repeated occurrence of these events
by the suspended nanoparticles significantly contributes to the
characteristic thermal conductivity of the nanofluids, which has been
estimated by the present model for a ethylene glycol based nanofluid
containing Cu-nanoparticles of size ranging from 8 to 20 nm, with
Gaussian size distribution. The prediction of the present model has
shown a reasonable agreement with the experimental data available
in literature.
Abstract: Geopolymer concretes are new class of construction
materials that have emerged as an alternative to Ordinary Portland
cement concrete. Considerable researches have been carried out on
material development of geopolymer concrete; however, a few studies
have been reported on the structural use of them. This paper presents
the bond behaviors of reinforcement embedded in fly ash based
geopolymer concrete. The development lengths of reinforcement for
various compressive strengths of concrete, 20, 30 and 40 MPa, and
reinforcement diameters, 10, 16 and 25 mm, are investigated. Total 27
specimens were manufactured and pull-out test according to EN 10080
was applied to measure bond strength and slips between concrete and
reinforcements. The average bond strengths decreased from 23.06MPa
to 17.26 MPa, as the diameters of reinforcements increased from
10mm to 25mm. The compressive strength levels of geopolymer
concrete showed no significant influence on bond strengths in this
study. Also, the bond-slip relations between geopolymer concrete and
reinforcement are derived using non-linear regression analysis for
various experimental conditions.
Abstract: TiO2 thin films have been prepared by the sol-gel dipcoating
technique in order to elaborate antireflective thin films for
monocrystalline silicon (mono-Si). The titanium isopropoxyde was
chosen as a precursor with hydrochloric acid as a catalyser for
preparing a stable solution. The optical properties have been tailored
with varying the solution concentration, the withdrawn speed, and the
heat-treatment. We showed that using a TiO2 single layer with 64.5
nm in thickness, heat-treated at 450°C or 300°C reduces the mono-Si
reflection at a level lower than 3% over the broadband spectral
domains [669-834] nm and [786-1006] nm respectively. Those latter
performances are similar to the ones obtained with double layers of
low and high refractive index glasses respectively.
Abstract: In recent years, the compression of date (Phoenix
dactylifera L.) fruit powders (DP) to obtain date tablets (DT) has
been suggested as a promising form of valorization of non
commercial valuable date fruit (DF) varieties. To further improve
and characterize DT, the present study aims to investigate the
influence of the DP particle size and compression force on some
physical properties of DT. The results show that independently of
particle size, the hardness (y) of tablets increases with the increase of
the compression force (x) following a logarithmic law (y = a ln (bx)
where a and b are the constants of model). Further, a full factorial
design (FFD) at two levels, applied to investigate the erosion %,
reveals that the effects of time and particle size are the same in
absolute value and they are beyond the effect of the compression.
Regarding the disintegration time, the obtained results also by means
of a FFD show that the effect of the compression force exceeds 4
times that of the DP particle size. As final stage, the color parameters
in the CIELab system of DT immediately after their obtaining are
differently influenced by the size of the initial powder.
Abstract: In this research, waterglass based aerogel powder was
prepared by sol–gel process and ambient pressure drying. Inspired by
limited dust releasing, aerogel powder was introduced to the PET
electrospinning solution in an attempt to create required bulk and
surface structure for the nanofibers to improve their hydrophobic and
insulation properties. The samples evaluation was carried out by
measuring density, porosity, contact angle, heat transfer, FTIR, BET,
and SEM. According to the results, porous silica aerogel powder was
fabricated with mean pore diameter of 24 nm and contact angle of
145.9º. The results indicated the usefulness of the aerogel powder
confined into nanofibers to control surface roughness for
manipulating superhydrophobic nanowebs with water contact angle
of 147º. It can be due to a multi-scale surface roughness which was
created by nanowebs structure itself and nanofibers surface
irregularity in presence of the aerogels while a layer of fluorocarbon
created low surface energy. The wettability of a solid substrate is an
important property that is controlled by both the chemical
composition and geometry of the surface. Also, a decreasing trend in
the heat transfer was observed from 22% for the nanofibers without
any aerogel powder to 8% for the nanofibers with 4% aerogel
powder. The development of thermal insulating materials has become
increasingly more important than ever in view of the fossil energy
depletion and global warming that call for more demanding energysaving
practices.
Abstract: The paper involves a chain of activities from
synthesis, establishment of the methodology for characterization and
testing of novel protective materials through the pilot production and
application on model supports.
It summarizes the results regarding the development of the pilot
production protocol for newly developed self-cleaning materials. The
optimization of the production parameters was completed in order to
improve the most important functional properties (mineralogy
characteristics, particle size, self-cleaning properties and
photocatalytic activity) of the newly designed nanocomposite
material.
Abstract: To develop AZ91D magnesium alloys with improved
properties, we have applied TiN and VN/TiN multilayer coatings
using DC magnetron sputter technique. Coating structure, surface
morphology, chemical bonding and corrosion resistance of coatings
were analyzed by x-ray diffraction (XRD), scanning electron
microscope (SEM), x-ray photoelectron spectroscopy (XPS), and
tafel extrapolation method, respectively. XPS analysis reveal that VN
overlayer reacts with oxygen at the VN/TiN interface and forms more
stable TiN layer. Morphological investigations and the corrosion
results show that VN/TiN multilayer thin film coatings are quite
effective to optimize the corrosion resistance of Mg alloys.
Abstract: Bamboo is extensively used in construction industry.
Low durability of bamboo due to fungus infestation and termites
attack under storage puts certain constrains for it usage as modern
structural material. Looking at many chemical formulations for
bamboo treatment leading to severe harmful environment effects,
research on eco-friendly preservatives for bamboo treatment has been
initiated world-over. In the present studies, eco-friendly preservative
for bamboo treatment has been developed. To validate its application
for structural purposes, investigation of effect of treatment on
compressive strength has been investigated. Neemoil (25%)
integrated with copper naphthenate (0.3%) on dilution with kerosene
oil impregnated into bamboo culm at 2 bar pressure, has shown
weight loss of only 3.15% in soil block analysis method. The results
from compressive strength analysis using HEICO Automatic
Compression Testing Machine reveal that preservative treatment has
not altered the structural properties of bamboo culms. Compressive
strength of control (11.72 N/mm2) and above treated samples (11.71
N/mm2) was found to be comparable.
Abstract: Metal matrix composites (MMCs) attract considerable
attention as a result from its ability in providing a high strength, high
modulus, high toughness, high impact properties, improving wear
resistance and providing good corrosion resistance compared to
unreinforced alloy. Aluminium Silicon (Al/Si) alloy MMC has been
widely used in various industrial sectors such as in transportation,
domestic equipment, aerospace, military, construction, etc.
Aluminium silicon alloy is an MMC that had been reinforced with
aluminium nitrate (AlN) particle and become a new generation
material use in automotive and aerospace sector. The AlN is one of
the advance material that have a bright prospect in future since it has
features such as lightweight, high strength, high hardness and
stiffness quality. However, the high degree of ceramic particle
reinforcement and the irregular nature of the particles along the
matrix material that contribute to its low density is the main problem
which leads to difficulties in machining process. This paper examined
the tool wear when milling AlSi/AlN Metal Matrix Composite using
a TiB2 (Titanium diboride) coated carbide cutting tool. The volume
of the AlN reinforced particle was 10% and milling process was
carried out under dry cutting condition. The TiB2 coated carbide
insert parameters used were at the cutting speed of (230, 300 and
370m/min, feed rate of 0.8, Depth of Cut (DoC) at 0.4m). The
Sometech SV-35 video microscope system used to quantify of the
tool wear. The result shown that tool life span increasing with the
cutting speeds at (370m/min, feed rate of 0.8mm/tooth and DoC at
0.4mm) which constituted an optimum condition for longer tool life
lasted until 123.2 mins. Meanwhile, at medium cutting speed which
at 300m/m, feed rate of 0.8mm/tooth and depth of cut at 0.4mm we
found that tool life span lasted until 119.86 mins while at low cutting
speed it lasted in 119.66 mins. High cutting speed will give the best
parameter in cutting AlSi/AlN MMCs material. The result will help
manufacturers in machining process of AlSi/AlN MMCs materials.
Abstract: Image spam is a kind of email spam where the spam
text is embedded with an image. It is a new spamming technique
being used by spammers to send their messages to bulk of internet
users. Spam email has become a big problem in the lives of internet
users, causing time consumption and economic losses. The main
objective of this paper is to detect the image spam by using histogram
properties of an image. Though there are many techniques to
automatically detect and avoid this problem, spammers employing
new tricks to bypass those techniques, as a result those techniques are
inefficient to detect the spam mails. In this paper we have proposed a
new method to detect the image spam. Here the image features are
extracted by using RGB histogram, HSV histogram and combination
of both RGB and HSV histogram. Based on the optimized image
feature set classification is done by using k- Nearest Neighbor(k-NN)
algorithm. Experimental result shows that our method has achieved
better accuracy. From the result it is known that combination of RGB
and HSV histogram with k-NN algorithm gives the best accuracy in
spam detection.
Abstract: This study presents an attempt to evaluate the
antioxidant potential and antimicrobial activity of methanolic extract,
and essential oils prepared from the leaves of sage (Salvia officinalis
L.). The content of polyphenol in the methanolic extracts from the
leaves of Salvia officinalis was determined spectrophotometrically,
calculated as gallic acid and catechin equivalent. The essential oils
and methanol extract were also subjected to screenings for the
evaluation of their antioxidant activities using 2, 2-diphenyl-1-
picrylhydrazyl (DPPH) test. While the plant essential oils showed
only weak antioxidant activities, its methanol extract was
considerably active in DPPH (IC50 = 37.29 μg/ml) test. Appreciable
total polyphenol content (31.25 mg/g) was also detected for the plant
methanol extract as gallic acid equivalent in the Folin–Ciocalteu test.
The plant was also screened for its antimicrobial activity and good to
moderate inhibitions were recorded for its essential oils, and
methanol extracts against most of the tested microorganisms.
The present investigation revealed that this plant had rich source
of antioxidant properties. It is for this reason that sage has found
increasing application in food formulations.
Abstract: The edge waviness in hot rolled steel is a common
defect. Variables that affect such defect include raw material and
machine. These variables are necessary to consider to understand
such defect. This research studied the defect of edge waviness for SS
400 of metal sheet manufacture. Defect of metal sheets were divided
into two groups. The specimens were investigated on chemical
composition and mechanical properties to find the difference. The
results of investigation showed that the difference was not significant.
Therefore the roll mill machine should be used to adjust to support
another location on a roller to avoide edge waviness.
Abstract: Many of the ever-growing elderly population require
exercise, such as running, for health management. One important
element of a runner’s training is the choice of shoes for exercise; shoes
are important because they provide the interface between the feet and
road. When we purchase shoes, we may instinctively choose a pair
after trying on many different pairs of shoes. Selecting the shoes
instinctively may work, but it does not guarantee a suitable fit for
running activities. Therefore, if we could select suitable shoes for each
runner from the viewpoint of brain activities, it would be helpful for
validating shoe selection. In this paper, we describe how brain
activities show different characteristics during particular task,
corresponding to different properties of shoes. Using five subjects, we
performed a verification experiment, applying weight, softness, and
flexibility as shoe properties. In order to affect the shoe property’s
differences to the brain, subjects run for 10 min. Before and after
running, subjects conducted a paced auditory serial addition task
(PASAT) as the particular task; and the subjects’ brain activities
during the PASAT are evaluated based on oxyhemoglobin and
deoxyhemoglobin relative concentration changes, measured by
near-infrared spectroscopy (NIRS). When the brain works actively,
oxihemoglobin and deoxyhemoglobin concentration drastically
changes; therefore, we calculate the maximum values of concentration
changes. In order to normalize relative concentration changes after
running, the maximum value are divided by before running maximum
value as evaluation parameters. The classification of the groups of
shoes is expressed on a self-organizing map (SOM). As a result,
deoxyhemoglobin can make clusters for two of the three types of
shoes.
Abstract: Carbon nanotube is one of the most attractive materials
for the potential applications of nanotechnology due to its excellent
mechanical, thermal, electrical and optical properties. In this paper we
report a supercapacitor made of nickel foil electrodes, coated with
multiwall carbon nanotubes (MWCNTs) thin film using
electrophoretic deposition (EPD) method. Chemical vapor deposition
method was used for the growth of MWCNTs and ethanol was used as
a hydrocarbon source. High graphitic multiwall carbon nanotube was
found at 750oC analyzing by Raman spectroscopy. We observed the
electrochemical performance of supercapacitor by cyclic
voltammetry. The electrodes of supercapacitor fabricated from
MWCNTs exhibit considerably small equivalent series resistance
(ESR), and a high specific power density. Electrophoretic deposition
is an easy method in fabricating MWCNT electrodes for high
performance supercapacitor.
Abstract: This paper investigates the joint effect of the
interconnected (n,k)-star network topology and Multi-Agent
automated control on restoration and reconfiguration of power
systems. With the increasing trend in development in Multi-Agent
control technologies applied to power system reconfiguration
in presence of faulty components or nodes. Fault tolerance is
becoming an important challenge in the design processes of the
distributed power system topology. Since the reconfiguration of a
power system is performed by agent communication, the (n,k)-star
interconnected network topology is studied and modeled in this
paper to optimize the process of power reconfiguration. In this paper,
we discuss the recently proposed (n,k)-star topology and examine its
properties and advantages as compared to the traditional multi-bus
power topologies. We design and simulate the topology model for
distributed power system test cases. A related lemma based on the
fault tolerance and conditional diagnosability properties is presented
and proved both theoretically and practically. The conclusion is
reached that (n,k)-star topology model has measurable advantages
compared to standard bus power systems while exhibiting fault
tolerance properties in power restoration, as well as showing
efficiency when applied to power system route discovery.