Abstract: Co metal supported on SiO2 and Al2O3 catalysts with
a metal loading varied from 30 of 70 wt.% were evaluated for
decomposition of methane to COx free hydrogen and carbon
nanomaterials. The catalytic runs were carried out from 550-800oC
under atmospheric pressure using fixed bed vertical flow reactor. The
fresh and spent catalysts were characterized by BET surface area
analyzer, XRD, SEM, TEM and TG analysis. The data showed that
50% Co/Al2O3 catalyst exhibited remarkable higher activity at 800oC
with respect to H2 production compared to rest of the catalysts.
However, the catalytic activity and durability was greatly declined at
higher temperature. The main reason for the catalytic inhibition of Co
containing SiO2 catalysts is the higher reduction temperature of
Co2SiO4. TEM images illustrate that the carbon materials with
various morphologies, carbon nanofibers (CNFs), helical-shaped
CNFs and branched CNFs depending on the catalyst composition and
reaction temperature were obtained.
Abstract: Bamboo is extensively used in construction industry.
Low durability of bamboo due to fungus infestation and termites
attack under storage puts certain constrains for it usage as modern
structural material. Looking at many chemical formulations for
bamboo treatment leading to severe harmful environment effects,
research on eco-friendly preservatives for bamboo treatment has been
initiated world-over. In the present studies, eco-friendly preservative
for bamboo treatment has been developed. To validate its application
for structural purposes, investigation of effect of treatment on
compressive strength has been investigated. Neemoil (25%)
integrated with copper naphthenate (0.3%) on dilution with kerosene
oil impregnated into bamboo culm at 2 bar pressure, has shown
weight loss of only 3.15% in soil block analysis method. The results
from compressive strength analysis using HEICO Automatic
Compression Testing Machine reveal that preservative treatment has
not altered the structural properties of bamboo culms. Compressive
strength of control (11.72 N/mm2) and above treated samples (11.71
N/mm2) was found to be comparable.