Abstract: Today, the pollution due to non-degradable material
such as plastics, has led to studies about the development of
environmental-friendly material. Because of biodegradability
obtained from natural sources, polylactid acid (PLA) and ijuk fiber
are interesting to modify into a composite. This material is also
expected to reduce the impact of environmental pollution. Surface
modification of ijuk fiber through alkalinization with 0.25 M NaOH
solution for 30 minutes was aimed to enhance its compatibility to
PLA, in order to improve properties of the composite such as the
mechanical properties. Alkalinization of the ijuk fibers annihilates
some surface components such as lignin, wax and hemicelloluse, so
the pore on the surface clearly appeared, decreasing of the density
and diameter of the ijuk fibers. The change of the ijuk fiber properties
leads to increase the mechanical properties of PLA composites
reinforced the ijuk fibers through strengthening of the mechanical
interlocking with the PLA matrix. An addition to enhance the
distribution of the fibers in the PLA matrix, the stirring during DCM
solvent evaporation from the mixture of the ijuk fibers and the
dissolved-PLA can reduce amount of the trapped-voids and fibers
pull-out phenomena, which can decrease the mechanical properties of
the composite.
Abstract: Chitosan has been an attractive biopolymer for
decades, but its processability is lowered by its poor solubility,
especially in physiological pH values. Freeze concentrated reactions
of chitosan with several organic acids including acrylic, citraconic,
itaconic, and maleic acid revealed improved solubility and
morphological properties. Solubility traits were assessed with a
modified ninhydrin test. Chitosan derivatives were characterized by
ATR-FTIR and morphological characteristics were determined by
SEM. This study is a unique approach to chemically modify chitosan
to enhance water solubility.
Abstract: Diminished antioxidant defense or increased
production of reactive oxygen species in the biological system can
result in oxidative stress which may lead to various
neurodegenerative diseases including Alzheimer’s disease (AD).
Microglial activation also contributes to the progression of AD by
producing several proinflammatory cytokines, nitric oxide (NO) and
prostaglandin E2 (PGE2). Oxidative stress and inflammation have
been reported to be possible pathophysiological mechanisms
underlying AD. In addition, the cholinergic hypothesis postulates that
memory impairment in patient with AD is also associated with the
deficit of cholinergic function in the brain. Although a number of
drugs have been approved for the treatment of AD, most of these
synthetic drugs have diverse side effects and yield relatively modest
benefits. Marine algae have great potential in pharmaceutical and
biomedical applications as they are valuable sources of bioactive
properties such as anticoagulation, antimicrobial, antioxidative,
anticancer and anti-inflammatory. Hence, this study aimed to provide
an overview of the properties of Malaysian seaweeds (Padina
australis, Sargassum polycystum and Caulerpa racemosa) in
inhibiting oxidative stress, neuroinflammation and cholinesterase
enzymes. These seaweeds significantly exhibited potent DPPH and
moderate superoxide anion radical scavenging ability (P
Abstract: The elastic period has a primary role in the seismic
assessment of buildings. Reliable calculations and/or estimates of the
fundamental frequency of a building and its site are essential during
analysis and design process. Various code formulas based on
empirical data are generally used to estimate the fundamental
frequency of a structure. For existing structures, in addition to code
formulas and available analytical tools such as modal analyses,
various methods of testing including ambient and forced vibration
testing procedures may be used to determine dynamic characteristics.
In this study, the dynamic properties of the 32 buildings located in
the Madinah of Saudi Arabia were identified using ambient motions
recorded at several, spatially-distributed locations within each
building. Ambient vibration measurements of buildings have been
analyzed and the fundamental longitudinal and transverse periods for
all tested buildings are presented. The fundamental mode of vibration
has been compared in plots with codes formulae (Saudi Building
Code, EC8, and UBC1997). The results indicate that measured
periods of existing buildings are shorter than that given by most
empirical code formulas. Recommendations are given based on the
common design and construction practice in Madinah city.
Abstract: In this paper 3D FEM analysis was carried out on
double lap bonded joint with composite adherents subjected to
dynamic shear. The adherents are made of Carbon/Epoxy while the
adhesive is epoxy Araldite 2031. The maximum average shear stress
and the stress homogeneity in the adhesive layer were examined.
Three fibers textures were considered: UD; 2.5D and 3D with same
volume fiber then a parametric study based on changing the thickness
and the type of fibers texture in 2.5D was accomplished. Moreover,
adherents’ dissimilarity was also investigated. It was found that the
main parameter influencing the behavior is the longitudinal stiffness
of the adherents. An increase in the adherents’ longitudinal stiffness
induces an increase in the maximum average shear stress in the
adhesive layer and an improvement in the shear stress homogeneity
within the joint. No remarkable improvement was observed for
dissimilar adherents.
Abstract: Polycyclic aromatic hydrocarbons (PAHs) are formed
during the pyrolysis of scrap tyres to produce tyre pyrolytic oil
(TPO). Due to carcinogenic, mutagenic, and toxic properties PAHs
are priority pollutants. Hence it is essential to remove PAHs from
TPO before utilising TPO as a petroleum fuel alternative (to run the
engine). Agricultural wastes have promising future to be utilized as
biosorbent due to their cost effectiveness, abundant availability, high
biosorption capacity and renewability. Various low cost adsorbents
were prepared from natural sources. Uptake of PAHs present in tyre
pyrolytic oil was investigated using various low-cost adsorbents of
natural origin including sawdust (shisham), coconut fiber, neem bark,
chitin, activated charcoal. Adsorption experiments of different PAHs
viz. naphthalene, acenaphthalene, biphenyl and anthracene have been
carried out at ambient temperature (25°C) and at pH 7. It was
observed that for any given PAH, the adsorption capacity increases
with the lignin content. Freundlich constant Kf and 1/n have been
evaluated and it was found that the adsorption isotherms of PAHs
were in agreement with a Freundlich model, while the uptake
capacity of PAHs followed the order: activated charcoal> saw dust
(shisham) > coconut fiber > chitin. The partition coefficients in
acetone-water, and the adsorption constants at equilibrium, could be
linearly correlated with octanol–water partition coefficients. It is
observed that natural adsorbents are good alternative for PAHs
removal. Sawdust of Dalbergia sissoo, a by-product of sawmills was
found to be a promising adsorbent for the removal of PAHs present in
TPO. It is observed that adsorbents studied were comparable to those
of some conventional adsorbents.
Abstract: This work introduces a simple device designed to
perform in-situ direct shear and sinkage tests on granular materials
as sand, clays, or regolith. It consists of a box nested within a larger
box. Both have open bottoms, allowing them to be lowered into the
material. Afterwards, two rotating plates on opposite sides of the
outer box will rotate outwards in order to clear regolith on either
side, providing room for the inner box to move relative to the plates
and perform a shear test without the resistance of the surrounding
soil. From this test, Coulomb parameters, including cohesion and
internal friction angle, as well as, Bekker parameters can be inferred.
This device has been designed for a laboratory setting, but with few
modifications, could be put on the underside of a rover for use in
a remote location. The goal behind this work is to ultimately create
a compact, but accurate measuring tool to put onto a rover or any
kind of exploratory vehicle to test for regolith properties of celestial
bodies.
Abstract: Maize constitutes a major agrarian production for use
by the vast population but despite its economic importance; it has not
been produced to meet the economic needs of the country. Achieving
optimum yield in maize can meaningfully be supported by land
suitability analysis in order to guarantee self-sufficiency for future
production optimization. This study examines land suitability for
maize production through the analysis of the physicochemical
variations in soil properties and other land attributes over space using
a Geographic Information System (GIS) framework.
Physicochemical parameters of importance selected include slope,
landuse, physical and chemical properties of the soil, and climatic
variables. Landsat imagery was used to categorize the landuse,
Shuttle Radar Topographic Mapping (SRTM) generated the slope and
soil samples were analyzed for its physical and chemical components.
Suitability was categorized into highly, moderately and marginally
suitable based on Food and Agricultural Organisation (FAO)
classification, using the Analytical Hierarchy Process (AHP)
technique of GIS. This result can be used by small scale farmers for
efficient decision making in the allocation of land for maize
production.
Abstract: Established objective and subjective preconditions for
entrepreneurship, forming the business organically related whole, are
the necessary condition of successful entrepreneurial activities.
Objective preconditions for entrepreneurship are developed by
market economy that should stimulate entrepreneurship by allowing
the use of economic opportunities for all those who want to do
business in respective field while providing guarantees to all owners
and creating a stable business environment for entrepreneurs.
Subjective preconditions of entrepreneurship are formed primarily by
personal characteristics of the entrepreneur. These are his properties,
abilities, skills, physiological and psychological preconditions which
may be inherited, inborn or sequentially developed and obtained
during his life on the basis of education and influences of
surrounding environment. The paper is dealing with issues of
objective and subjective preconditions for entrepreneurship and
provides their analysis in view of the current situation in Slovakia. It
presents risks of the business environment in Slovakia that the Slovak
managers considered the most significant in 2014 and defines the
dominant attributes of the entrepreneur in the current business
environment in Slovakia.
Abstract: Analysis of the properties of coconut (Cocos nucifera)
and its oil was evaluated in this work using standard analytical
techniques. The analyses carried out include proximate composition
of the fruit, extraction of oil from the fruit using different process
parameters and physicochemical analysis of the extracted oil. The
results showed the percentage (%) moisture, crude lipid, crude
protein, ash and carbohydrate content of the coconut as 7.59, 55.15,
5.65, 7.35 and 19.51 respectively. The oil from the coconut fruit was
odourless and yellowish liquid at room temperature (30oC). The
treatment combinations used (leaching time, leaching temperature
and solute: solvent ratio) showed significant differences (P
Abstract: The Cone Penetration Test (CPT) is a common in-situ
test which generally investigates a much greater volume of soil more
quickly than possible from sampling and laboratory tests. Therefore,
it has the potential to realize both cost savings and assessment of soil
properties rapidly and continuously. The principle objective of this
paper is to demonstrate the feasibility and efficiency of using
artificial neural networks (ANNs) to predict the soil angle of internal
friction (Φ) and the soil modulus of elasticity (E) from CPT results
considering the uncertainties and non-linearities of the soil. In
addition, ANNs are used to study the influence of different
parameters and recommend which parameters should be included as
input parameters to improve the prediction. Neural networks discover
relationships in the input data sets through the iterative presentation
of the data and intrinsic mapping characteristics of neural topologies.
General Regression Neural Network (GRNN) is one of the powerful
neural network architectures which is utilized in this study. A large
amount of field and experimental data including CPT results, plate
load tests, direct shear box, grain size distribution and calculated data
of overburden pressure was obtained from a large project in the
United Arab Emirates. This data was used for the training and the
validation of the neural network. A comparison was made between
the obtained results from the ANN's approach, and some common
traditional correlations that predict Φ and E from CPT results with
respect to the actual results of the collected data. The results show
that the ANN is a very powerful tool. Very good agreement was
obtained between estimated results from ANN and actual measured
results with comparison to other correlations available in the
literature. The study recommends some easily available parameters
that should be included in the estimation of the soil properties to
improve the prediction models. It is shown that the use of friction
ration in the estimation of Φ and the use of fines content in the
estimation of E considerable improve the prediction models.
Abstract: The detection of the polymer melt state during
manufacture process is regarded as an efficient way to control the
molded part quality in advance. Online monitoring rheological
property of polymer melt during processing procedure provides an
approach to understand the melt state immediately. Rheological
property reflects the polymer melt state at different processing
parameters and is very important in injection molding process
especially. An approach that demonstrates how to calculate
rheological property of polymer melt through in-process
measurement, using injection molding as an example, is proposed in
this study. The system consists of two sensors and a data acquisition
module can process the measured data, which are used for the
calculation of rheological properties of polymer melt. The rheological
properties of polymer melt discussed in this study include shear rate
and viscosity which are investigated with respect to injection speed
and melt temperature. The results show that the effect of injection
speed on the rheological properties is apparent, especially for high
melt temperature and should be considered for precision molding
process.
Abstract: Micro-alloyed steel components are used in
automotive industry for the necessity to make the manufacturing
process cycles shorter when compared to conventional steel by
eliminating heat treatment cycles, so an important saving of costs and
energy can be reached by reducing the number of operations. Microalloying
elements like vanadium, niobium or titanium have been
added to medium carbon steels to achieve grain refinement with or
without precipitation strengthening along with uniform
microstructure throughout the matrix. Present study reports the
applicability of medium carbon vanadium micro-alloyed steel in hot
forging. Forgeability has been determined with respect to different
cooling rates, after forging in a hydraulic press at 50% diameter
reduction in temperature range of 900-11000C. Final microstructures,
hardness, tensile strength, and impact strength have been evaluated.
The friction coefficients of different lubricating conditions, viz.,
graphite in hydraulic oil, graphite in furnace oil, DF 150 (Graphite,
Water-Based) die lubricant and dry or without any lubrication were
obtained from the ring compression test for the above micro-alloyed
steel. Results of ring compression tests indicate that graphite in
hydraulic oil lubricant is preferred for free forging and dry lubricant
is preferred for die forging operation. Exceptionally good forgeability
and high resistance to fracture, especially for faster cooling rate has
been observed for fine equiaxed ferrite-pearlite grains, some amount
of bainite and fine precipitates of vanadium carbides and
carbonitrides. The results indicated that the cooling rate has a
remarkable effect on the microstructure and mechanical properties at
room temperature.
Abstract: In this research (using induction furnace process)
nodular iron with three different percentages of copper (residual,
0.5% and 1,2%) was obtained. Chemical analysis was performed by
mass spectrometry and microstructures were characterized by Optical
Microscopy (ASTM E3) and Scanning Electron Microscopy (SEM).
The study of mechanical behavior was carried out in a mechanical
test machine (ASTM E8) and a Pin on disk tribometer (ASTM G99)
was used to assess wear resistance. It is observed that the dissolution
of copper in crystal lattice increases the pearlite structure improving
the wear and hardness behavior, but producing a contrary effect on
the energy absorption.
Abstract: A quartz crystal microbalance (QCM) nanosensor was developed to detect lysozyme enzyme by functionalizing its gold surface with the attachment of poly(methacroyl-L-phenylalanine) (PMAPA) nanoparticles. PMAPA was chosen as a hydrophobic matrix. The hydrophobic nanoparticles were synthesized by micro-emulsion polymerization method. Hydrophobic QCM nanosensor was tested for real time detection of lysozyme enzyme from aqueous solution. The kinetic and affinity studies were determined by using lysozyme solutions with different concentrations. The responses related with mass (Δm) and frequency (Δf) shifts were used to evaluate adsorption properties.
Abstract: In recent years, the hair building fiber has become
popular, in other words, it is an effective method which helps people
who suffer hair loss or sparse hair since the hair building fiber is
capable to create a natural look of simulated hair rapidly. In the
markets, there are a lot of hair fiber brands that have been designed to
formulate an intense bond with hair strands and make the hair appear
more voluminous instantly. However, those products have their own
set of properties. Thus, in this report, some measurement techniques
are proposed to identify those products. Up to five different brands of
hair fiber are tested. The electrostatic and dielectric properties of the
hair fibers are macroscopically tested using design DC and high
frequency microwave techniques. Besides, the hair fibers are
microscopically analysis by magnifying the structures of the fiber
using scanning electron microscope (SEM). From the SEM photos,
the comparison of the uniformly shaped and broken rate of the hair
fibers in the different bulk samples can be observed respectively.
Abstract: For centuries humans have used the antimicrobial
properties of copper to their advantage. Yet, after all these years the
underlying mechanisms of copper mediated cell death in various
microbes remain unclear. We had explored the hypothesis that copper
mediated increased levels of lipid peroxidation in the membrane fatty
acids is responsible for increased killing in Escherichia coli. In this
study we show that in both gram positive (Staphylococcus aureus)
and gram negative (Pseudomonas aeruginosa) bacteria there is a
strong correlation between copper mediated cell death and increased
levels of lipid peroxidation. Interestingly, the non-spore forming
gram positive bacteria as well as gram negative bacteria show similar
patterns of cell death, increased levels of lipid peroxidation, as well
as genomic DNA degradation, however there is some difference in
loss in membrane integrity upon exposure to copper alloy surface.
Abstract: Sustainability and eco-friendly requirement of
engineering materials are sort for in recent times, thus giving rise to
the development of bio-composites. However, the natural fibres to
matrix interface interactions remain a key issue in getting the desired
mechanical properties from such composites. Treatment of natural
fibres is essential in improving matrix to filler adhesion, hence
improving its mechanical properties. In this study, investigations
were carried out to determine the effect of sodium hydroxide
treatment on the tensile, flexural, impact and hardness properties of
crushed and uncrushed Luffa cylindrica fibre reinforced recycled low
density polyethylene composites. The LC (Luffa cylindrica) fibres
were treated with 0%, 2%, 4%, 6%, 8% and 10% wt. sodium
hydroxide (NaOH) concentrations for a period of 24 hours under
room temperature conditions. A formulation ratio of 80/20 g (matrix
to reinforcement) was maintained for all developed samples. Analysis
of the results showed that the uncrushed luffa fibre samples gave
better mechanical properties compared with the crushed luffa fibre
samples. The uncrushed luffa fibre composites had a maximum
tensile and flexural strength of 7.65 MPa and 17.08 Mpa respectively
corresponding to a young modulus and flexural modulus of 21.08
MPa and 232.22 MPa for the 8% and 4% wt. NaOH concentration
respectively. Results obtained in the research showed that NaOH
treatment with the 8% NaOH concentration improved the mechanical
properties of the LC fibre reinforced composites when compared with
other NaOH treatment concentration values.
Abstract: The borate glasses are known by their structural
characterized by existence of unit’s structural composed by triangles
and tetrahedrons boron in different configurations depending on the
percentage of B2O3 in the glass chemical composition. In this paper,
effect of lithium oxide addition on the thermal and physical
properties of an alumina borate glass, was investigated. It was found
that the boron abnormality has a significant effect in the change of
glass properties according to the addition rate of lithium oxide.
Abstract: Composite material based on Fe3Si micro-particles
and Mn-Zn nano-ferrite was prepared using powder metallurgy
technology. The sol-gel followed by autocombustion process was
used for synthesis of Mn0.8Zn0.2Fe2O4 ferrite. 3 wt.% of mechanically
milled ferrite was mixed with Fe3Si powder alloy. Mixed micro-nano
powder system was homogenized by the Resonant Acoustic Mixing
using ResodynLabRAM Mixer. This non-invasive homogenization
technique was used to preserve spherical morphology of Fe3Si
powder particles. Uniaxial cold pressing in the closed die at pressure
600 MPa was applied to obtain a compact sample. Microwave
sintering of green compact was realized at 800°C, 20 minutes, in air.
Density of the powders and composite was measured by
Hepycnometry. Impulse excitation method was used to measure
elastic properties of sintered composite. Mechanical properties were
evaluated by measurement of transverse rupture strength (TRS) and
Vickers hardness (HV). Resistivity was measured by 4 point probe
method. Ferrite phase distribution in volume of the composite was
documented by metallographic analysis.
It has been found that nano-ferrite particle distributed among
micro- particles of Fe3Si powder alloy led to high relative density
(~93%) and suitable mechanical properties (TRS >100 MPa, HV
~1GPa, E-modulus ~140 GPa) of the composite. High electric
resistivity (R~6.7 ohm.cm) of prepared composite indicate their
potential application as soft magnetic material at medium and high
frequencies.