Abstract: Degradative solvent extraction is the method developed for biomass upgrading by dewatering and fractionation of biomass under the mild condition. However, the conversion mechanism of the degradative solvent extraction method has not been fully understood so far. The rice straw was treated in 1-methylnaphthalene (1-MN) at a different solvent-treatment temperature varied from 250 to 350 oC with the residence time for 60 min. The liquid membrane-Fourier Transform Infrared Spectroscopy (FTIR) technique is applied to study the processing mechanism in-depth without separation of the solvent. It has been found that the strength of the oxygen-hydrogen stretching (3600-3100 cm-1) decreased slightly with increasing temperature in the range of 300-350 oC. The decrease of the hydroxyl group in the solvent soluble suggested dehydration reaction taking place between 300 and 350 oC. FTIR spectra in the carbonyl stretching region (1800-1600 cm-1) revealed the presence of esters groups, carboxylic acid and ketonic groups in the solvent-soluble of biomass. The carboxylic acid increased in the range of 200 to 250 oC and then decreased. The prevailing of aromatic groups showed that the aromatization took place during extraction at above 250 oC. From 300 to 350 oC, the carbonyl functional groups in the solvent-soluble noticeably decreased. The removal of the carboxylic acid and the decrease of esters into the form of carbon dioxide indicated that the decarboxylation reaction occurred during the extraction process.
Abstract: Present study investigates the effect of unsteady wakes on heat transfer in blade tip. Heat/mass transfer was measured in blade tip region depending on a variety of strouhal number by naphthalene sublimation technique. Naphthalene sublimation technique measures heat transfer using a heat/mass transfer analogy. Experiments are performed in linear cascade which is composed of five turbine blades and rotating rods. Strouhal number of inlet flow are changed ranging from 0 to 0.22. Reynolds number is 100,000 based on 11.4 m/s of outlet flow and axial chord length. Three different squealer tip geometries such as base squealer tip, vertical rib squealer tip, and camber line squealer tip are used to study how unsteady wakes affect heat transfer on a blade tip. Depending on squealer tip geometry, different flow patterns occur on a blade tip. Also, unsteady wakes cause reduced tip leakage flow and turbulent flow. As a result, as strouhal number increases, heat/mass transfer coefficients decrease due to the reduced leakage flow. As strouhal number increases, heat/ mass transfer coefficients on a blade tip increase in vertical rib squealer tip.
Abstract: A novel sensing system has been designed for
naphthalene detection based on the quenched fluorescence signal of
CdS quantum dots. The fluorescence intensity of the system reduced
significantly after adding CdS quantum dots to the water pollution
model because of the fluorescent static quenching f mechanism.
Herein, we have demonstrated the facile methodology can offer a
convenient and low analysis cost with the recovery rate as
97.43%-103.2%, which has potential application prospect.
Abstract: Fresh concrete has one of dynamic properties known
as slump. Slump of concrete is design to compatible with placing
method. Due to hydration reaction of cement, the slump of concrete
is loss through time. Therefore, delayed concrete probably get reject
because slump is unacceptable. In order to recover the slump of
delayed concrete the second dose of superplasticizer (naphthalene
based type F) is added into the system, the slump recovery can be
done as long as the concrete is not setting. By adding superplasticizer
as solution for recover unusable slump loss concrete may affects
other concrete properties. Therefore, this paper was observed setting
times and compressive strength of concrete after being re-dose with
chemical admixture type F (superplasticizer, naphthalene based) for
slump recovery. The concrete used in this study was fly ash concrete
with fly ash replacement of 0%, 30% and 50% respectively. Concrete
mix designed for test specimen was prepared with paste content (ratio
of volume of cement to volume of void in the aggregate) of 1.2 and
1.3, water-to-binder ratio (w/b) range of 0.3 to 0.58, initial dose of
superplasticizer (SP) range from 0.5 to 1.6%. The setting times of
concrete were tested both before and after re-dosed with different
amount of second dose and time of dosing. The research was
concluded that addition of second dose of superplasticizer would
increase both initial and final setting times accordingly to dosage of
addition. As for fly ash concrete, the prolongation effect was higher
as the replacement of fly ash increase. The prolongation effect can
reach up to maximum about 4 hours. In case of compressive strength,
the re-dosed concrete has strength fluctuation within acceptable range
of ±10%.
Abstract: This paper aimed to introduce the solution of concrete
slump recovery using chemical admixture type-F (superplasticizer,
naphthalene base) to the practice in order to solve unusable concrete
problem due to concrete loss its slump, especially for those tropical
countries that have faster slump loss rate. In the other hand, randomly
adding superplasticizer into concrete can cause concrete to segregate.
Therefore, this paper also develops the estimation model used to
calculate amount of second dose of superplasticizer need for concrete
slump recovery. Fresh properties of ordinary Portland cement
concrete with volumetric ratio of paste to void between aggregate
(paste content) of 1.1-1.3 with water-cement ratio zone of 0.30 to
0.67 and initial superplasticizer (naphthalene base) of 0.25%-1.6%
were tested for initial slump and slump loss for every 30 minutes for
one and half hour by slump cone test. Those concretes with slump
loss range from 10% to 90% were re-dosed and successfully
recovered back to its initial slump. Slump after re-dosed was tested
by slump cone test. From the result, it has been concluded that, slump
loss was slower for those mix with high initial dose of
superplasticizer due to addition of superplasticizer will disturb
cement hydration. The required second dose of superplasticizer was
affected by two major parameters, which were water-cement ratio
and paste content, where lower water-cement ratio and paste content
cause an increase in require second dose of superplasticizer. The
amount of second dose of superplasticizer is higher as the solid
content within the system is increase, solid can be either from cement
particles or aggregate. The data was analyzed to form an equation use
to estimate the amount of second dosage requirement of
superplasticizer to recovery slump to its original.
Abstract: Low Temperature Matrix Isolation - Electron
Paramagnetic Resonance (LTMI-EPR) Spectroscopy was utilized to
identify the species of iron oxide nanoparticles generated during the
oxidative pyrolysis of 1-methylnaphthalene (1-MN). The otherwise
gas-phase reactions of 1--MN were impacted by a polypropylenimine
tetra-hexacontaamine dendrimer complexed with iron (III) nitrate
nonahydrate diluted in air under atmospheric conditions. The EPR
fine structure of Fe (III)2O3 nanoparticles clusters, characterized by gfactors
of 2.00, 2.28, 3.76 and 4.37 were detected on a cold finger
maintained at 77 K after accumulation over a multitude of
experiments. Additionally, a high valence Fe (IV) paramagnetic
intermediate and superoxide anion-radicals, O2•- adsorbed on
nanoparticle surfaces in the form of Fe (IV) --- O2•- were detected
from the quenching area of Zone 1 in the gas-phase.
Abstract: Polycyclic aromatic hydrocarbons (PAHs) are formed
during the pyrolysis of scrap tyres to produce tyre pyrolytic oil
(TPO). Due to carcinogenic, mutagenic, and toxic properties PAHs
are priority pollutants. Hence it is essential to remove PAHs from
TPO before utilising TPO as a petroleum fuel alternative (to run the
engine). Agricultural wastes have promising future to be utilized as
biosorbent due to their cost effectiveness, abundant availability, high
biosorption capacity and renewability. Various low cost adsorbents
were prepared from natural sources. Uptake of PAHs present in tyre
pyrolytic oil was investigated using various low-cost adsorbents of
natural origin including sawdust (shisham), coconut fiber, neem bark,
chitin, activated charcoal. Adsorption experiments of different PAHs
viz. naphthalene, acenaphthalene, biphenyl and anthracene have been
carried out at ambient temperature (25°C) and at pH 7. It was
observed that for any given PAH, the adsorption capacity increases
with the lignin content. Freundlich constant Kf and 1/n have been
evaluated and it was found that the adsorption isotherms of PAHs
were in agreement with a Freundlich model, while the uptake
capacity of PAHs followed the order: activated charcoal> saw dust
(shisham) > coconut fiber > chitin. The partition coefficients in
acetone-water, and the adsorption constants at equilibrium, could be
linearly correlated with octanol–water partition coefficients. It is
observed that natural adsorbents are good alternative for PAHs
removal. Sawdust of Dalbergia sissoo, a by-product of sawmills was
found to be a promising adsorbent for the removal of PAHs present in
TPO. It is observed that adsorbents studied were comparable to those
of some conventional adsorbents.
Abstract: Amyloid aggregation of polypeptides is related to a
growing number of pathologic states known as amyloid disorders. In
recent years, blocking or reversing amyloid aggregation via the use of
small compounds are considered as two useful approaches in
hampering the development of these diseases. In this research, we
have compared the ability of several manganese-salen derivatives, as
synthetic compounds, and apigenin, as a natural flavonoid, to inhibit
of hen egg-white lysozyme (HEWL) aggregation, as an in vitro
model system.
Different spectroscopic analyses such as Thioflavin T (ThT) and
Anilinonaphthalene-8-sulfonic acid (ANS) fluorescence, Congo red
(CR) absorbance along with transmission electron microscopy were
used in this work to monitor the HEWL aggregation kinetic and
inhibition. Our results demonstrated that both type of compounds
were capable to prevent the formation of lysozyme amyloid
aggregation in vitro. In addition, our data indicated that synthetic
compounds had higher activity to inhibit of the β-sheet structures
relative to natural compound. Regarding the higher antioxidant
activities of the salen derivatives, it can be concluded that in addition
to aromatic rings of each of the compounds, the potent antioxidant
properties of salen derivatives contributes to lower lysozyme fibril
accumulation.
Abstract: Quercetin and (+)-catechin are metabolites present in Phyllanthus niruri plant, have potential in medicinal uses as anticancer and antioxidant agents. Studies on production of quercetin and (+)-catechin from P. niruri callus culture via in vitro technique were carried out and the results were compared to the intact plant. P. niruri explants were cultured on Murashige and Skoog (MS) solidified media supplemented with several phytohormone combinations for one month. The metabolites were extracted from P. niruri callus and intact plant by using carbon dioxide supercritical fluid extraction (SFE) with ethanol as modifier and solvent extraction techniques. The extracts were analyzed by means of HPLC method. Results showed that P. niruri callus culture was successfully established. The highest content of quercetin (1.72%) was found from P. niruri callus grown in media supplemented with 0.8mg/L kinetin and 0.2mg/L 2,4-dicholophenoxyacetic acid (2,4-D), which was 1.2 fold higher than intact plant. Meanwhile, the highest amounts of (+)-catechin (0.63%) was found from P. niruri callus grown in media with addition of 0.2mg/L 1-naphthalene acetic acid (NAA) and 0.8mg/L 2,4-D. The SFE condition in this study showed better extraction efficiency when higher contents of selected metabolites were found in all SFE extracts compared to the common solvent extracts.
Abstract: Chemical vapor deposition method was used to
produce carbon nanotubes on an iron based catalyst from acetylene.
Gas-phase samples collected from the different positions of the tubular reactor were analyzed by GC/MS. A variety of species ranging from hydrogen to naphthalene were observed and changes in their concentrations were plotted against the reactor position. Briefly benzene, toluene, styrene, indene and naphthalene were the main
higher molecular weight species and vinylacetylene and diacetylene were the important intermediates. Nanotube characterization was performed by scanning electron microscopy and transmission electron microscopy.
Abstract: Sediment and mangrove root samples from Iko River
Estuary, Nigeria were analyzed for microbial and polycyclic
aromatic hydrocarbon (PAH) content. The total heterotrophic
bacterial (THB) count ranged from 1.1x107 to 5.1 x107 cfu/g, total
fungal (TF) count ranged from 1.0x106 to 2.7x106 cfu/g, total
coliform (TC) count ranged from 2.0x104 to 8.0x104cfu/g while
hydrocarbon utilizing bacterial (HUB) count ranged from 1.0x 105 to
5.0 x 105cfu/g. There was a range of positive correlation (r = 0.72 to
0.93) between THB count and total HUB count, respectively. The
organisms were Staphylococcus aureus, Bacillus cereus,
Flavobacterium breve, Pseudomonas aeruginosa, Erwinia
amylovora, Escherichia coli, Enterobacter sp, Desulfovibrio sp,
Acinetobacter iwoffii, Chromobacterium violaceum, Micrococcus
sedentarius, Corynebacterium sp, and Pseudomonas putrefaciens.
The PAH were Naphthalene, 2-Methylnaphthalene, Acenapthylene,
Acenaphthene, Fluorene, Phenanthene, Anthracene, Fluoranthene,
Pyrene, Benzo(a)anthracene, Chrysene, Benzo(b)fluoranthene,
Benzo(k)fluoranthene, Benzo(a)pyrene, Dibenzo(a,h)anthracene,
Benzo(g,h,l)perylene ,Indeno(1,2,3-d)pyrene with individual PAH
concentrations that ranged from 0.20mg/kg to 1.02mg/kg, 0.20mg/kg
to 1.07mg/kg and 0.2mg/kg to 4.43mg/kg in the benthic sediment,
epipellic sediment and mangrove roots, respectively. Total PAH
ranged from 6.30 to 9.93mg/kg, 6.30 to 9.13mg/kg and 9.66 to
16.68mg/kg in the benthic sediment, epipellic sediment and
mangrove roots, respectively. The high concentrations in the
mangrove roots are indicative of bioaccumulation of the pollutant in
the plant tissue. The microorganisms are of ecological significance
and the detectable quantities of polycyclic aromatic hydrocarbon
could be partitioned and accumulated in tissues of infaunal and
epifaunal organisms in the study area.
Abstract: Abstract–Indoor air (VOCs) samples were collected
simultaneously from variety of indoors (e.g. living rooms, baby-s
rooms) and outdoor environments which were voluntarily selected
from the houses in which pregnant residents live throughout Ankara.
This is the first comprehensive study done in Turkey starting from
prenatal period and continued till the babies had one year old. VOCs
levels were measured over 76 homes. Air samples were collected in
Tenax TA sorbent filled tubes with active sampling method and
analyzed with Thermal Desorber and Gas Chromatography/Mass
spectrometry (TD-GC/MS). At the first sampling period in the baby-s
rooms maximum concentration of toluene was measured about
240.77μg.m-3 and in the living rooms maximum concentration of
naphthalene was 180.24μg.m-3. At the second sampling period in the
baby-s rooms maximum concentration of toluene was measured
about 144.97μg.m-3 and in the living rooms maximum concentration
of naphthalene was 247.89μg.m-3. Concentration of TVOCs in the
first period was generally higher than the second period.