Abstract: Durability of Membrane Electrode Assembly for
Proton Exchange Membrane Fuel Cells was evaluated in both steady
state and accelerated decay modes. Steady state mode was carried out
at constant current of 800mA/cm2 for 2500 hours using air as cathode
feed and pure hydrogen as anode feed. The degradation of the cell
voltage was 0.015V after such 2500 hrs operation. The degradation
rate was therefore calculated to be 6uV/hr. Continuously Vigorous
fluctuation of the cell voltage, which was switched between OCV and
0.2V, was employed for the accelerated decay mode. No obvious
change in performance of the MEA was observed after 10000 cycles
of such operation.
Abstract: The iron environment in Fe-doped Vycor Anode was
investigated with EXAFS using Brookhaven Synchrotron Light
Source. The iron-reducing Shewanella oneidensis culture was grown
in a microbial fuel cell under anaerobic respiration. The Fe bond
length was found to decrease and correlate with the amount of
biofilm growth on the Fe-doped Vycor Anode. The data suggests that
Fe-doped Vycor Anode would be a good substrate to study the
Shewanella oneidensis nanowire structure using EXAFS.
Abstract: Polymer Electrolyte Membrane Fuel Cell (PEMFC) is
such a time-vary nonlinear dynamic system. The traditional linear
modeling approach is hard to estimate structure correctly of PEMFC
system. From this reason, this paper presents a nonlinear modeling of
the PEMFC using Neural Network Auto-regressive model with
eXogenous inputs (NNARX) approach. The multilayer perception
(MLP) network is applied to evaluate the structure of the NNARX
model of PEMFC. The validity and accuracy of NNARX model are
tested by one step ahead relating output voltage to input current from
measured experimental of PEMFC. The results show that the obtained
nonlinear NNARX model can efficiently approximate the dynamic
mode of the PEMFC and model output and system measured output
consistently.
Abstract: This paper presents dynamic models of distributed
generators (DG) and investigates dynamic behavior of the DG units
in the micro grid system. The DG units include photovoltaic and fuel
cell sources. The voltage source inverter is adopted since the
electronic interface which can be equipped with its controller to keep
stability of the micro grid during small signal dynamics. This paper
also introduces power management strategies and implements the DG
load sharing concept to keep the micro grid operation in gridconnected
and islanding modes of operation. The results demonstrate
the operation and performance of the photovoltaic and fuel cell as
distributed generators in a micro grid. The entire control system in
the micro grid is developed by combining the benefits of the power
control and the voltage control strategies. Simulation results are all
reported, confirming the validity of the proposed control technique.
Abstract: This paper discusses the design and analysis of a
hybrid PV-Fuel cell energy system destined to power a DC load. The
system is composed of a photovoltaic array, a fuel cell, an
electrolyzer and a hydrogen tank. HOMER software is used in this
study to calculate the optimum capacities of the power system
components that their combination allows an efficient use of solar
resource to cover the hourly load needs. The optimal system sizing
allows establishing the right balance between the daily electrical
energy produced by the power system and the daily electrical energy
consumed by the DC load using a 28 KW PV array, a 7.5 KW fuel
cell, a 40KW electrolyzer and a 270 Kg hydrogen tank. The variation
of powers involved into the DC bus of the hybrid PV-fuel cell system
has been computed and analyzed for each hour over one year: the
output powers of the PV array and the fuel cell, the input power of
the elctrolyzer system and the DC primary load. Equally, the annual
variation of stored hydrogen produced by the electrolyzer has been
assessed. The PV array contributes in the power system with 82%
whereas the fuel cell produces 18%. 38% of the total energy
consumption belongs to the DC primary load while the rest goes to
the electrolyzer.
Abstract: Microbial fuel cells (MFCs) represent a promising
technology for simultaneous bioelectricity generation and wastewater
treatment. Catalysts are significant portions of the cost of microbial
fuel cell cathodes. Many materials have been tested as aqueous
cathodes, but air-cathodes are needed to avoid energy demands for
water aeration. The sluggish oxygen reduction reaction (ORR) rate at
air cathode necessitates efficient electrocatalyst such as carbon
supported platinum catalyst (Pt/C) which is very costly. Manganese
oxide (MnO2) was a representative metal oxide which has been
studied as a promising alternative electrocatalyst for ORR and has
been tested in air-cathode MFCs. However the single MnO2 has poor
electric conductivity and low stability. In the present work, the MnO2
catalyst has been modified by doping Pt nanoparticle. The goal of the
work was to improve the performance of the MFC with minimum Pt
loading. MnO2 and Pt nanoparticles were prepared by hydrothermal
and sol gel methods, respectively. Wet impregnation method was
used to synthesize Pt/MnO2 catalyst. The catalysts were further used
as cathode catalysts in air-cathode cubic MFCs, in which anaerobic
sludge was inoculated as biocatalysts and palm oil mill effluent
(POME) was used as the substrate in the anode chamber. The asprepared
Pt/MnO2 was characterized comprehensively through field
emission scanning electron microscope (FESEM), X-Ray diffraction
(XRD), X-ray photoelectron spectroscopy (XPS), and cyclic
voltammetry (CV) where its surface morphology, crystallinity,
oxidation state and electrochemical activity were examined,
respectively. XPS revealed Mn (IV) oxidation state and Pt (0)
nanoparticle metal, indicating the presence of MnO2 and Pt.
Morphology of Pt/MnO2 observed from FESEM shows that the
doping of Pt did not cause change in needle-like shape of MnO2
which provides large contacting surface area. The electrochemical
active area of the Pt/MnO2 catalysts has been increased from 276 to
617 m2/g with the increase in Pt loading from 0.2 to 0.8 wt%. The
CV results in O2 saturated neutral Na2SO4 solution showed that
MnO2 and Pt/MnO2 catalysts could catalyze ORR with different
catalytic activities. MFC with Pt/MnO2 (0.4 wt% Pt) as air cathode
catalyst generates a maximum power density of 165 mW/m3, which
is higher than that of MFC with MnO2 catalyst (95 mW/m3). The
open circuit voltage (OCV) of the MFC operated with MnO2 cathode
gradually decreased during 14 days of operation, whereas the MFC
with Pt/MnO2 cathode remained almost constant throughout the
operation suggesting the higher stability of the Pt/MnO2 catalyst.
Therefore, Pt/MnO2 with 0.4 wt% Pt successfully demonstrated as an
efficient and low cost electrocatalyst for ORR in air cathode MFC with higher electrochemical activity, stability and hence enhanced
performance.
Abstract: Newly synthesized Polypropylene-g-Polyethylene
glycol polymer was first time used for a compartment-less enzymatic
fuel cell. Working electrodes based on Polypropylene-g-Polyethylene
glycol were operated as unmediated and mediated system (with
ferrocene and gold/cobalt oxide nanoparticles). Glucose oxidase and
bilirubin oxidase was selected as anodic and cathodic enzyme,
respectively. Glucose was used as fuel in a single-compartment and
membrane-less cell. Maximum power density was obtained as 0.65
nW cm-2, 65 nW cm-2 and 23500 nW cm-2 from the unmediated,
ferrocene and gold/cobalt oxide modified polymeric film,
respectively. Power density was calculated to be ~16000 nW cm-2 for
undiluted wastewater sample with gold/cobalt oxide nanoparticles
including system.
Abstract: This review summarizes the potential of starch
agroindustrial residues as substrate for biohydrogen production.
Types of potential starch agroindustrial residues, recent developments
and bio-processing conditions for biohydrogen production will be
discussed. Biohydrogen is a clean energy source with great potential
to be an alternative fuel, because it releases energy explosively in
heat engines or generates electricity in fuel cells producing water as
only by-product. Anaerobic hydrogen fermentation or dark
fermentation seems to be more favorable, since hydrogen is yielded
at high rates and various organic waste enriched with carbohydrates
as substrate result in low cost for hydrogen production. Abundant
biomass from various industries could be source for biohydrogen
production where combination of waste treatment and energy
production would be an advantage. Carbohydrate-rich nitrogendeficient
solid wastes such as starch residues can be used for
hydrogen production by using suitable bioprocess technologies.
Alternatively, converting biomass into gaseous fuels, such as
biohydrogen is possibly the most efficient way to use these
agroindustrial residues.
Abstract: This paper presents a new method to design nonlinear
feedback linearization controller for PEMFCs (Polymer Electrolyte
Membrane Fuel Cells). A nonlinear controller is designed based on
nonlinear model to prolong the stack life of PEMFCs. Since it is
known that large deviations between hydrogen and oxygen partial
pressures can cause severe membrane damage in the fuel cell,
feedback linearization is applied to the PEMFC system so that the
deviation can be kept as small as possible during disturbances or load
variations. To obtain an accurate feedback linearization controller,
tuning the linear parameters are always important. So in proposed
study NSGA (Non-Dominated Sorting Genetic Algorithm)-II method
was used to tune the designed controller in aim to decrease the
controller tracking error. The simulation result showed that the
proposed method tuned the controller efficiently.
Abstract: A proton exchange membrane has been developed for
direct methanol fuel cell (DMFC). The nanofiber network composite
membranes were prepared by interconnected network of Nafion
(perfuorosulfonic acid) nanofibers that have been embedded in an
uncharged and inert polymer matrix, by electro-spinning. The
spinning solution of Nafion with a low concentration (1 wt%
compared to Nafion) of high molecular weight poly(ethylene oxide),
as a carrier polymer. The interconnected network of Nafion
nanofibers with average fiber diameter in the range of 160-700nm,
were used to make the membranes, with the nanofiber occupying up
to 85% of the membrane volume. The matrix polymer was
crosslinked with Norland Optical Adhesive 63 under UV. The
resulting membranes showed proton conductivity of 0.10 S/cm at
25°C and 80% RH; and methanol permeability of 3.6 x 10-6 cm2/s.
Abstract: Nowadays the use of Hybrid Electric Vehicles (HEV) is increasing dramatically. The HEV is mainly dependent on electricity and there is always a need for storage of charge. Fuel Cell (FC), Batteries and Ultra Capacitor are being used for the proposed HEV as an electric power source or as an energy storage unit. The aim of developing an energy management technique is to utilize the sources according to the requirement of the vehicle with help of controller. This increases the efficiency of hybrid electric vehicle to reduce the fuel consumption and unwanted emission. The Maximum Power Point Tracking (MPPT) in FC is done using (Perturb & Observe) algorithm. In this paper, the control of automobiles at variable speed is achieved effectively.
Abstract: Thermal radiation plays a very important role in the heat transfer combination through the various components of the SOFC fuel cell operating at high temperatures. Lattice Boltzmann method is used for treating conduction-radiation heat transfer in the electrolyte. The thermal radiation heat transfer is coupled to the overall energy conservation equations through the divergence of the local radiative flux. The equation of energy in one dimension is numerically resolved by using the Lattice Boltzmann method. A computing program (FORTRAN) is developed locally for this purpose in order to obtain fields of temperature in every element of the cell. The parameters investigated are: functioning temperature, cell voltages and electrolyte thickness. The results show that the radiation effect increases with increasing the electrolyte thickness, also increases with increasing the functioning temperature and decreases with the increase of the voltage of the cell.
Abstract: In order to further understand the behavior of PEM fuel cell and optimize their performance, it is necessary to perform measurements in real time. The internal impedance measurement by electrochemical impedance spectroscopy (EIS) is of great importance. In this work, we present the impedance measurement method of a PEM fuel cell by electrochemical impedance spectroscopy method and the realization steps of electronic load for this measuring technique implementation. The theoretical results are obtained from the simulation of software PSPICE® and experimental tests are carried out using the Ballard Nexa™ PEM fuel cell system.
Abstract: The radiation effect within the solid anode, electrolyte, and cathode SOFC layers problem has been investigated in this paper. Energy equation is solved by the Lattice Boltzmann method (LBM). The Rosseland method is used to model the radiative transfer in the electrodes. The Schuster-Schwarzschild method is used to model the radiative transfer in the electrolyte. Without radiative effect, the found results are in good agreement with those published. The obtained results show that the radiative effect can be neglected.
Abstract: In this paper a hybrid distributed generation (DG) system connected to isolated load is studied. The DG system consisting of photo voltaic (PV) system, fuel cells, aqua electrolyzer, diesel engine generator and a battery energy storage system. The ambient temperature value of PV is taken as constant to make the output power of PV is directly proportional to the radiation and output power of other DG sources and frequency of the system is controlled by simple integral (I), proportional plus integral (PI), and proportional plus integral and derivative(PID) controllers. A maiden attempt is made to apply a more recent and powerful optimization technique named as bacterial foraging technique for optimization of controllers gains of the proposed hybrid DG system. The system responses with bacterial foraging based controllers are compared with that of classical method. Investigations reveal that bacterial foraging based controllers gives better responses than the classical method and also PID controller is best. Sensitivity analysis is carried out which demonstrates the robustness of the optimized gain values for system loading condition.
Abstract: The Proton Exchange Membranes (PEM) are largely studied because they operate at low temperatures and they are suitable for mobile applications. However, there are some deficiencies in their operation, mainly those that use ethanol as a hydrogen source, that require a certain attention. Therefore, this research aimed to develop Nafion® composite membranes, mixing clay minerals, kaolin and halloysite to the polymer matrix in order to improve the ethanol molecule retentions and, at the same time, to keep the system’s protonic conductivity. The modified Nafion/Kaolin, Nafion/Halloysite composite membranes were prepared in weight proportion of 0.5, 1.0 and 1.5. The membranes obtained were characterized as to their ethanol permeability, protonic conductivity and water absorption. The composite morphology and structure are characterized by SEM and EDX and the thermal behavior is determined by TGA and DSC. The analysis of the results shows ethanol permeability reduction from 48% to 63%. However, the protonic conductivity results are lower in relation to pure Nafion®. As to the thermal behavior, the Nafion® composite membranes were stable up to a temperature of 325ºC.
Abstract: The development of alternative energy is interesting in the present especially, hydrogen production because it is an important energy resource in the future. This paper studied the hydrogen production from catalytic dehydrogenation of ethanol through via low temperature (
Abstract: This article deals with the carbon nanotubes (CNT) synthesized from a novel precursor, sugar cane and Anodic Aluminum Oxide (AAO). The objective was to produce CNTs to be used as catalyst supports for Proton Exchange Membranes. The influence of temperature, inert gas flow rate and concentration of the precursor is presented. The CNTs prepared were characterized using TEM, XRD, Raman Spectroscopy, and the surface area determined by BET. The results show that it is possible to form CNT from sugar cane by pyrolysis and the CNTs are the type multi-walled carbon nanotubes. The MWCNTs are short and closed at the two ends with very small surface area of SBET= 3.691m,/g.
Abstract: The electrical power systems of aircrafts have made
serious progress in recent years because the aircrafts depend more
and more on the electricity. There is a trend in the aircraft industry to
replace hydraulic and pneumatic systems with electrical systems,
achieving more comfort and monitoring features and enlarging the
energetic efficiency. Thus, was born the concept More Electric
Aircraft. In this paper is analyzed the integration of a fuel cell into
the existing electrical generation and distribution systems of an
aircraft. The dynamic characteristics of fuel cell systems necessitate
an adaptation of the electrical power system. The architecture studied
in this paper consists of a 50kW fuel cell, a dc to dc converter and
several loads. The dc to dc converter is used to step down the fuel
cell voltage from about 625Vdc to 28Vdc.
Abstract: In recent years fuel cell vehicles are rapidly appearing
all over the globe. In less than 10 years, fuel cell vehicles have gone
from mere research novelties to operating prototypes and demonstration
models. At the same time, government and industry in development
countries have teamed up to invest billions of dollars in partnerships
intended to commercialize fuel cell vehicles within the early
years of the 21st century.
The purpose of this study is evaluation of model and performance
of fuel cell hybrid electric vehicle in different drive cycles. A fuel
cell system model developed in this work is a semi-experimental
model that allows users to use the theory and experimental relationships
in a fuel cell system. The model can be used as part of a complex
fuel cell vehicle model in advanced vehicle simulator (ADVISOR).
This work reveals that the fuel consumption and energy efficiency
vary in different drive cycles. Arising acceleration and speed in a
drive cycle leads to Fuel consumption increase. In addition, energy
losses in drive cycle relates to fuel cell system power request. Parasitic
power in different parts of fuel cell system will increase when
power request increases. Finally, most of energy losses in drive cycle
occur in fuel cell system because of producing a lot of energy by fuel
cell stack.