Steady State and Accelerated Decay Rate Evaluations of Membrane Electrode Assembly of PEM Fuel Cells
Durability of Membrane Electrode Assembly for
Proton Exchange Membrane Fuel Cells was evaluated in both steady
state and accelerated decay modes. Steady state mode was carried out
at constant current of 800mA/cm2 for 2500 hours using air as cathode
feed and pure hydrogen as anode feed. The degradation of the cell
voltage was 0.015V after such 2500 hrs operation. The degradation
rate was therefore calculated to be 6uV/hr. Continuously Vigorous
fluctuation of the cell voltage, which was switched between OCV and
0.2V, was employed for the accelerated decay mode. No obvious
change in performance of the MEA was observed after 10000 cycles
of such operation.
[1] E. Antolini, J. Appl. Electrochem. 34 (2004) 563–576.
[2] M. Conte, A. Iacobazzi, M. Ronchetti, R. Vellone, J. Power Sources 100
(2001) 171–187.
[3] F. Jing, M. Hou, W. Shi, J. Fu, H. Yu, P. Ming, B. Yi, J. Power Sources
166 (2007) 172–176.
[4] S. Litster, G. McLean, J. Power Sources 130 (2004) 61–76.
[5] S. Maass, F. Finsterwalder, G. Frank, R. Hartmann, C. Merten, J. Power
Sources, 176 (2008) 444–451.
[6] Mehta, J.S. Cooper, J. Power Sources 114 (2003) 32–53.
[7] K. Scott, A.K. Shukla, Rev. Environ. Sci. Bio/Technology 3 (2004)
273–280.
[8] D.P. Wilkinson, J. St-Pierre, in Handbook of Fuel Cells, vol. 3, John
Wiley & Sons Ltd., 2003, pp.611-626.
[9] O. Yamazaki, M. Echigo, T. Tabata, Abstracts from Fuel Cell Seminar,
2002, Palm Springs, CA, November, 2002, pp. 105–108.
[10] M. Hicks, D. Ylitalo, Abstracts from Fuel Cell Seminar 2003, Miami
Beach, FL, November, 2003, pp. 97–99.
[11] S.J.C. Cleghorn, J.A. Kolde, Abstract from Fuel Cell Seminar 2003,
Miami Beach, FL, November 2003, pp. 832–835.
[12] M. Takahashi, N. Kusunose, M. Aoki, A. Seya, Abstracts from Fuel Cell
Seminar 2002, Palm Springs, CA, November 2002, pp. 74–77.
[13] S.D. Knight, K.M. Colbow, J. St-Pierre, D. Wilkinson, J. Power Sources
127 (2004) 127–134.
[14] C. Iojoiu, E. Guilminot, F. Maillard, M. Chatenet, J.-Y. Sanchez, E.
Claude, E. Rossinot, J. Electrochem. Soc. 154 (2007) B1115–B1120.
[15] C. Chen, G. Levitin, D.W. Hess, T.F. Fuller, J. Power Sources 169
(2007) 288–295.
[16] E. Guilminot, A. Corcella, M. Chatenet, F. Maillard, F. Charlot, G.
Berthome, C. Iojoiu, J.-Y. Sanchez, E. Rossinot, E. Claude, J.
Electrochem. Soc. 154 (2007) B1106–B1114.
[17] J. Healy, C.Hayden, T. Xie, K. Olson, R.Waldo, M. Brundage, H.
Gasteiger, J.Abbott, Fuel Cells 5 (2005) 302–308.
[18] T. Kinumoto, M. Inaba, Y. Nakayama, K. Ogata, R. Umebayashi, A.
Tasaka, Y. Iriyama, T. Abe, Z. Ogumi, J. Power Sources 158 (2006)
1222–1228.
[19] S. Kundu,M.W. Fowler, L.C. Simon, S. Grot, J. Power Sources 157
(2006) 650–656.
[20] S. Kundu, L.C. Simon, M.W. Fowler, Polym. Degrad. Stab. 93 (2008)
214–224.
[21] H. Tang, S. Peikang, S.P. Jiang, F. Wang, M. Pan, J. Power Sources 170
(2007) 85–92.
[22] V.A. Sethuraman, J.W. Weidner, A.T. Haug, L.V. Protsailob, J.
Electrochem. Soc. 155 (2008) B119–B124.
[23] J. St-Pierre, N. Jia, J. New Mater. Electrochem. Syst. 5 (2002) 263–271.
[24] S.J.C. Cleghorn ∗, D.K. Mayfield D.A. Moore, J.C. Moore, G. Rusch,
T.W. Sherman, N.T. Sisofo, U. Beuscher, Journal of Power Sources 158
(2006) 446–454.
[1] E. Antolini, J. Appl. Electrochem. 34 (2004) 563–576.
[2] M. Conte, A. Iacobazzi, M. Ronchetti, R. Vellone, J. Power Sources 100
(2001) 171–187.
[3] F. Jing, M. Hou, W. Shi, J. Fu, H. Yu, P. Ming, B. Yi, J. Power Sources
166 (2007) 172–176.
[4] S. Litster, G. McLean, J. Power Sources 130 (2004) 61–76.
[5] S. Maass, F. Finsterwalder, G. Frank, R. Hartmann, C. Merten, J. Power
Sources, 176 (2008) 444–451.
[6] Mehta, J.S. Cooper, J. Power Sources 114 (2003) 32–53.
[7] K. Scott, A.K. Shukla, Rev. Environ. Sci. Bio/Technology 3 (2004)
273–280.
[8] D.P. Wilkinson, J. St-Pierre, in Handbook of Fuel Cells, vol. 3, John
Wiley & Sons Ltd., 2003, pp.611-626.
[9] O. Yamazaki, M. Echigo, T. Tabata, Abstracts from Fuel Cell Seminar,
2002, Palm Springs, CA, November, 2002, pp. 105–108.
[10] M. Hicks, D. Ylitalo, Abstracts from Fuel Cell Seminar 2003, Miami
Beach, FL, November, 2003, pp. 97–99.
[11] S.J.C. Cleghorn, J.A. Kolde, Abstract from Fuel Cell Seminar 2003,
Miami Beach, FL, November 2003, pp. 832–835.
[12] M. Takahashi, N. Kusunose, M. Aoki, A. Seya, Abstracts from Fuel Cell
Seminar 2002, Palm Springs, CA, November 2002, pp. 74–77.
[13] S.D. Knight, K.M. Colbow, J. St-Pierre, D. Wilkinson, J. Power Sources
127 (2004) 127–134.
[14] C. Iojoiu, E. Guilminot, F. Maillard, M. Chatenet, J.-Y. Sanchez, E.
Claude, E. Rossinot, J. Electrochem. Soc. 154 (2007) B1115–B1120.
[15] C. Chen, G. Levitin, D.W. Hess, T.F. Fuller, J. Power Sources 169
(2007) 288–295.
[16] E. Guilminot, A. Corcella, M. Chatenet, F. Maillard, F. Charlot, G.
Berthome, C. Iojoiu, J.-Y. Sanchez, E. Rossinot, E. Claude, J.
Electrochem. Soc. 154 (2007) B1106–B1114.
[17] J. Healy, C.Hayden, T. Xie, K. Olson, R.Waldo, M. Brundage, H.
Gasteiger, J.Abbott, Fuel Cells 5 (2005) 302–308.
[18] T. Kinumoto, M. Inaba, Y. Nakayama, K. Ogata, R. Umebayashi, A.
Tasaka, Y. Iriyama, T. Abe, Z. Ogumi, J. Power Sources 158 (2006)
1222–1228.
[19] S. Kundu,M.W. Fowler, L.C. Simon, S. Grot, J. Power Sources 157
(2006) 650–656.
[20] S. Kundu, L.C. Simon, M.W. Fowler, Polym. Degrad. Stab. 93 (2008)
214–224.
[21] H. Tang, S. Peikang, S.P. Jiang, F. Wang, M. Pan, J. Power Sources 170
(2007) 85–92.
[22] V.A. Sethuraman, J.W. Weidner, A.T. Haug, L.V. Protsailob, J.
Electrochem. Soc. 155 (2008) B119–B124.
[23] J. St-Pierre, N. Jia, J. New Mater. Electrochem. Syst. 5 (2002) 263–271.
[24] S.J.C. Cleghorn ∗, D.K. Mayfield D.A. Moore, J.C. Moore, G. Rusch,
T.W. Sherman, N.T. Sisofo, U. Beuscher, Journal of Power Sources 158
(2006) 446–454.
@article{"International Journal of Chemical, Materials and Biomolecular Sciences:70383", author = "Yingjeng James Li and Lung-Yu Sung and Andrew S. Lin and Huan-Jyun Ciou", title = "Steady State and Accelerated Decay Rate Evaluations of Membrane Electrode Assembly of PEM Fuel Cells", abstract = "Durability of Membrane Electrode Assembly for
Proton Exchange Membrane Fuel Cells was evaluated in both steady
state and accelerated decay modes. Steady state mode was carried out
at constant current of 800mA/cm2 for 2500 hours using air as cathode
feed and pure hydrogen as anode feed. The degradation of the cell
voltage was 0.015V after such 2500 hrs operation. The degradation
rate was therefore calculated to be 6uV/hr. Continuously Vigorous
fluctuation of the cell voltage, which was switched between OCV and
0.2V, was employed for the accelerated decay mode. No obvious
change in performance of the MEA was observed after 10000 cycles
of such operation.", keywords = "Durability, lifetime, membrane electrode assembly,
proton exchange membrane fuel cells.", volume = "9", number = "8", pages = "976-4", }