Abstract: Newly synthesized Polypropylene-g-Polyethylene
glycol polymer was first time used for a compartment-less enzymatic
fuel cell. Working electrodes based on Polypropylene-g-Polyethylene
glycol were operated as unmediated and mediated system (with
ferrocene and gold/cobalt oxide nanoparticles). Glucose oxidase and
bilirubin oxidase was selected as anodic and cathodic enzyme,
respectively. Glucose was used as fuel in a single-compartment and
membrane-less cell. Maximum power density was obtained as 0.65
nW cm-2, 65 nW cm-2 and 23500 nW cm-2 from the unmediated,
ferrocene and gold/cobalt oxide modified polymeric film,
respectively. Power density was calculated to be ~16000 nW cm-2 for
undiluted wastewater sample with gold/cobalt oxide nanoparticles
including system.