Abstract: In order to detect and quantify the phenolic contents
of a wastewater with biosensors, two working electrodes based on
modified Poly(Pyrrole) films were fabricated. Enzyme horseradish
peroxidase was used as biomolecule of the prepared electrodes.
Various phenolics were tested at the biosensor. Phenol detection was
realized by electrochemical reduction of quinones produced by
enzymatic activity. Analytical parameters were calculated and the
results were compared with each other.
Abstract: Newly synthesized Polypropylene-g-Polyethylene
glycol polymer was first time used for a compartment-less enzymatic
fuel cell. Working electrodes based on Polypropylene-g-Polyethylene
glycol were operated as unmediated and mediated system (with
ferrocene and gold/cobalt oxide nanoparticles). Glucose oxidase and
bilirubin oxidase was selected as anodic and cathodic enzyme,
respectively. Glucose was used as fuel in a single-compartment and
membrane-less cell. Maximum power density was obtained as 0.65
nW cm-2, 65 nW cm-2 and 23500 nW cm-2 from the unmediated,
ferrocene and gold/cobalt oxide modified polymeric film,
respectively. Power density was calculated to be ~16000 nW cm-2 for
undiluted wastewater sample with gold/cobalt oxide nanoparticles
including system.