Abstract: The production of devices in nanoscale with specific
molecular rectifying function is one of the most significant goals in
state-of-art technology. In this work we show by ab initio quantum
mechanics calculations coupled with non-equilibrium Green
function, the design of an organic two-terminal device. These
molecular structures have molecular source and drain with several
bridge length (from five up to 11 double bonds). Our results are
consistent with significant features as a molecular rectifier and can be
raised up as: (a) it can be used as bi-directional symmetrical rectifier;
(b) two devices integrated in one (FET with one operational region,
and Thyristor thiristor); (c) Inherent stability due small intrinsic
capacitance under forward/reverse bias. We utilize a scheme for the
transport mechanism based on previous properties of ¤Ç bonds type
that can be successfully utilized to construct organic nanodevices.
Abstract: This paper presents the experimental results of
comparison between leakage currents and discharge currents. The leakage currents were obtained on polluted porcelain insulator.
Whereas, the discharge currents were obtained on lightly artificial
polluted porcelain specimen. The conducted measurements were
leakage current or discharge current and applied voltage. The insulator or specimen was in a hermetically sealed chamber, and the
current waveforms were analyzed using FFT.
The result indicated that the leakage current (LC) on low RH condition the fifth harmonic would be visible, and followed by the
seventh harmonic. The insulator had capacitive property. Otherwise,
on 99% relative humidity, the fifth harmonic would also be visible,
and the phase angle reached up to 12.2 degree. Whereas, on discharge current, the third harmonic would be visible, and followed
by fifth harmonic. The third harmonic would increase as pressure reduced. On this condition, the specimen had a non-linear characteristics
Abstract: The National Blood Center, Thai Red Cross Society is
responsible for providing blood to hospitals all over the country.
When any hospital needs blood, it will have to send the vehicle to
pick up at the NBC. There are a lot of vehicles to pick up blood at the
NBC every day. Each vehicle is usually empty for inbound trip and a
little loaded for outbound. The NBC realized such waste or loss and
there have been the third party offered to distribute blood and charge
for fee. This paper proposes to apply the vehicle routing problem
(VRP) for estimating the fair price. The idea is tested with the real
data during seven-day period of 6 – 12 July 2010 to estimate the fair
price for transporting blood in Bangkok Metropolitan Region.
Abstract: Many applications require surface modification and
micro-structuring of polymers. For these purposes is mainly used
ultraviolet (UV) radiation from excimer lamps or excimer lasers.
However, these sources have a decided disadvantage - degrading the
polymer deep inside due to relatively big radiation penetration depth
which may exceed 100 μm. In contrast, extreme ultraviolet (EUV)
radiation is absorbed in a layer approximately 100 nm thick only. In
this work, the radiation from a discharge-plasma EUV source (with
wavelength 46.9 nm) based on a capillary discharge driver is focused
with a spherical Si/Sc multilayer mirror for surface modification of
PMMA sample or thin gold layer (thickness about 40 nm). It was
found that the focused EUV laser beam is capable by one shot to
ablate PMMA or layer of gold, even if the focus is significantly
influenced by astigmatism.
Abstract: The growth of the aquaculture industry has been
associated with negative environmental impacts through the
discharge of raw effluents into the adjacent receiving water bodies.
Macrophytes from natural saline lakes, which have adaptability to the
high salinity, can be suitable for saline effluent treatment. Eight
emergent species from natural saline area were planted in an
experimental gravel bed hydroponic mesocosm (GBH) which was
treated with effluent water from an intensive fish farm using
geothermal water. In order to examine the applicability of the
halophytes in treatment processes, we tested the relative efficacy of
total nitrogen (TN), total phosphorus (TP), potassium (K), sodium
(Na), magnesium (Mg) and calcium (Ca) removal for the saline
wastewater treatment. Four of the eight species, which were
Phragmites australis, Typha angustifolia, Glyceria maxima, Scirpus
lacustris spp. tabernaemontani could survive and contribute the
experimental treatment.
Abstract: This research study the application of the immobilized
TiO2 layer and Cu-TiO2 layer on graphite substrate as a negative
electrode or anode for Li-ion battery. The titania layer was produced
through chemical bath deposition method, meanwhile Cu particles
were deposited electrochemically. A material can be used as an
electrode as it has capability to intercalates Li ions into its crystal
structure. The Li intercalation into TiO2/Graphite and Cu-
TiO2/Graphite were analyzed from the changes of its XRD pattern
after it was used as electrode during discharging process. The XRD
patterns were refined by Le Bail method in order to determine the
crystal structure of the prepared materials. A specific capacity and the
cycle ability measurement were carried out to study the performance
of the prepared materials as negative electrode of the Li-ion battery.
The specific capacity was measured during discharging process from
fully charged until the cut off voltage. A 300 was used as a load.
The result shows that the specific capacity of Li-ion battery with
TiO2/Graphite as negative electrode is 230.87 ± 1.70mAh.g-1 which is
higher than the specific capacity of Li-ion battery with pure graphite
as negative electrode, i.e 140.75 ±0.46mAh.g-1. Meanwhile
deposition of Cu onto TiO2 layer does not increase the specific
capacity, and the value even lower than the battery with
TiO2/Graphite as electrode. The cycle ability of the prepared battery
is only two cycles, due to the Li ribbon which was used as cathode
became fragile and easily broken.
Abstract: This paper introduces a high-gain observer based state of charge(SOC) estimator for lithium-Ion batteries. The proposed SOC estimator has a high-gain observer(HGO) structure. The HGO scheme enhances the transient response speed and diminishes the effect of uncertainties. Furthermore, it guarantees that the output feedback controller recovers the performance of the state feedback controller when the observer gain is sufficiently high. In order to show the effectiveness of the proposed method, the linear RC battery model in ADVISOR is used. The performance of the proposed method is compared with that of the conventional linear observer(CLO) and some simulation result is given.
Abstract: In this paper we present the modeling, design, and
experimental testing of a nerve cuff multi-electrode system for
diameter-selective vagus nerve stimulation.
The multi-electrode system contained ninety-nine platinum
electrodes embedded within a self-curling spiral silicone sheet. The
electrodes were organized in a matrix having nine parallel groups,
each containing eleven electrodes.
Preliminary testing of the nerve cuff was performed in an isolated
segment of a swinish left cervical vagus nerve. For selective vagus
nerve stimulation, precisely defined current quasitrapezoidal,
asymmetric and biphasic stimulating pulses were applied to
preselected locations along the left vagus segment via appointed
group of three electrodes within the cuff. Selective stimulation was
obtained by anodal block. However, these pulses may not be safe for
a long-term application because of a frequently used high imbalance
between the cathodic and anodic part of the stimulating pulse.
Preliminary results show that the cuff was capable of exciting A
and B-fibres, and, that for a certain range of parameters used in
stimulating pulses, the contribution of A-fibres to the CAP was
slightly reduced and the contribution of B-fibres was slightly larger.
Results also showed that measured CAPs are not greatly
influenced by the imbalance between a charge Qc injected in cathodic
and Qa in anodic phase of quasitrapezoidal, asymmetric and biphasic
pulses.
Abstract: Cavitation, usually known as a destructive
phenomenon, involves turbulent unsteady two-phase flow. Having
such features, cavitating flows have been turned to a challenging
topic in numerical studies and many researches are being done for
better understanding of bubbly flows and proposing solutions to
reduce its consequent destructive effects. Aeration may be regarded
as an effective protection against cavitation erosion in many
hydraulic structures, like gated tunnels. The paper concerns
numerical simulation of flow in discharge gated tunnel of a dam
using ing RNG k -ε model coupled with the volume of fluid (VOF)
method and the zone which is susceptible of cavitation inception in
the tunnel is predicted. In the second step, a vent is considered in the
mentioned zone for aeration and the numerical simulation is done
again to study the effects of aeration. The results show that aeration
is an impressively useful method to exclude cavitation in mentioned
tunnels.
Abstract: Ovshinsky initiated scientific research in the field of
amorphous and disordered materials that continues to this day. The
Ovshinsky Effect where the resistance of thin GST films is
significantly reduced upon the application of low voltage is of
fundamental importance in phase-change - random access memory
(PC-RAM) devices.GST stands for GdSbTe chalcogenide type
glasses.However, the Ovshinsky Effect is not without controversy.
Ovshinsky thought the resistance of GST films is reduced by the
redistribution of charge carriers; whereas, others at that time including
many PC-RAM researchers today argue that the GST resistance
changes because the GST amorphous state is transformed to the
crystalline state by melting, the heat supplied by external heaters. In
this controversy, quantum mechanics (QM) asserts the heat capacity of
GST films vanishes, and therefore melting cannot occur as the heat
supplied cannot be conserved by an increase in GST film
temperature.By precluding melting, QM re-opens the controversy
between the melting and charge carrier mechanisms. Supporting
analysis is presented to show that instead of increasing GST film
temperature, conservation proceeds by the QED induced creation of
photons within the GST film, the QED photons confined by TIR. QED
stands for quantum electrodynamics and TIR for total internal
reflection. The TIR confinement of QED photons is enhanced by the
fact the absorbedheat energy absorbed in the GST film is concentrated
in the TIR mode because of their high surface to volume ratio. The
QED photons having Planck energy beyond the ultraviolet produce
excitons by the photoelectric effect, the electrons and holes of which
reduce the GST film resistance.
Abstract: This paper addresses modeling and optimization of process parameters in powder mixed electrical discharge machining (PMEDM). The process output characteristics include metal removal rate (MRR) and electrode wear rate (EWR). Grain size of Aluminum powder (S), concentration of the powder (C), discharge current (I) pulse on time (T) are chosen as control variables to study the process performance. The experimental results are used to develop the regression models based on second order polynomial equations for the different process characteristics. Then, a genetic algorithm (GA) has been employed to determine optimal process parameters for any desired output values of machining characteristics.
Abstract: Electrophoretic motion of a liquid droplet within an
uncharged cylindrical pore is investigated theoretically in this study. It
is found that the boundary effect in terms of the reduction of droplet
mobility (droplet velocity per unit strength of the applied electric field)
is very significant when the double layer surrounding the droplet is
thick, and diminishes as it gets very thin. Moreover, the viscosity ratio
of the ambient fluid to the internal one, σ, is a crucial factor in
determining its electrophoretic behavior. The boundary effect is less
significant as the viscosity ratio gets high. Up to 70% mobility
reduction is observed when this ratio is low (σ = 0.01), whereas only
40% reduction when it is high (σ = 100). The results of this study can
be utilized in various fields of biotechnology, such as a biosensor or a
lab-on-a-chip device.
Abstract: Titanium nitride (TiN) has been synthesized using the
sheet plasma negative ion source (SPNIS). The parameters used for
its effective synthesis has been determined from previous
experiments and studies. In this study, further enhancement of the
deposition rate of TiN synthesis and advancement of the SPNIS
operation is presented. This is primarily achieved by the addition of
Sm-Co permanent magnets and a modification of the configuration in
the TiN deposition process. The magnetic enhancement is aimed at
optimizing the sputtering rate and the sputtering yield of the process.
The Sm-Co permanent magnets are placed below the Ti target for
better sputtering by argon. The Ti target is biased from –250V to –
350V and is sputtered by Ar plasma produced at discharge current of
2.5–4A and discharge potential of 60–90V. Steel substrates of
dimensions 20x20x0.5mm3 were prepared with N2:Ar volumetric
ratios of 1:3, 1:5 and 1:10. Ocular inspection of samples exhibit
bright gold color associated with TiN. XRD characterization
confirmed the effective TiN synthesis as all samples exhibit the (200)
and (311) peaks of TiN and the non-stoichiometric Ti2N (220) facet.
Cross-sectional SEM results showed increase in the TiN deposition
rate of up to 0.35μm/min. This doubles what was previously obtained
[1]. Scanning electron micrograph results give a comparative
morphological picture of the samples. Vickers hardness results gave
the largest hardness value of 21.094GPa.
Abstract: This paper estimates the economic values of
household preference for enhanced solid waste disposal services in
Malaysia. The contingent valuation (CV) method estimates an
average additional monthly willingness-to-pay (WTP) in solid waste
management charges of Ôé¼0.77 to 0.80 for improved waste disposal
services quality. The finding of a slightly higher WTP from the
generic CV question than that of label-specific, further reveals a
higher WTP for sanitary landfill, at Ôé¼0.90, than incineration, at Ôé¼0.63.
This suggests that sanitary landfill is a more preferred alternative.
The logistic regression estimation procedure reveals that household-s
concern of where their rubbish is disposed, age, ownership of house,
household income and format of CV question are significant factors
in influencing WTP.
Abstract: Resistive switching of aluminum nitride (AlNx) thin film was demonstrated in a TaN/AlNx/TiN memory cell that was prepared by sputter deposition techniques. The memory cell showed bipolar switching of resistance between +3.5 V and –3.5 V. The resistance ratio of high resistance state (HRS) to low resistance state (HRS), RHRS/RLRS, was about 2 over 100 cycles of endurance test. Both the LRS and HRS of the memory cell exhibited ohmic conduction at low voltages and Poole-Frenkel emission at high voltages. The electrical conduction in the TaN/AlNx/TiN memory cell was possibly attributed to the interactions between charges and defects in the AlNx film.
Abstract: Active Power Filters (APFs) are today the most
widely used systems to eliminate harmonics compensate power
factor and correct unbalanced problems in industrial power plants.
We propose to improve the performances of conventional APFs by
using artificial neural networks (ANNs) for harmonics estimation.
This new method combines both the strategies for extracting the
three-phase reference currents for active power filters and DC link
voltage control method. The ANNs learning capabilities to
adaptively choose the power system parameters for both to compute
the reference currents and to recharge the capacitor value requested
by VDC voltage in order to ensure suitable transit of powers to
supply the inverter. To investigate the performance of this
identification method, the study has been accomplished using
simulation with the MATLAB Simulink Power System Toolbox. The
simulation study results of the new (SAPF) identification technique
compared to other similar methods are found quite satisfactory by
assuring good filtering characteristics and high system stability.
Abstract: In this work, we used the single Langmuir probe to
measure the plasma density distribution in an geometrically
asymmetric capacitive coupled plasma discharge system. Because of
the frame structure of powered electrode, the plasma density was not
homogeneous in the discharge volume. It was higher under the frame,
but lower in the centre. Finite element simulation results showed a
good agreement with the experiment results. To increase the electron
density in the central volume and improve the homogeneity of the
plasma, we added an auxiliary electrode, powered by DC voltage, in
the simulation geometry. The simulation results showed that the
auxiliary electrode could alter the potential distribution and improve
the density homogeneity effectively.
Abstract: In this study, multiwall carbon nanotubes (MWNTs)
were modified with nitric acid chemically and by dielectric barrier
discharge (DBD) plasma in an oxygen-based atmosphere. Used
carbon nanotubes (CNTs) were prepared by chemical vapour
deposition (CVD) floating catalyst method. For removing amorphous
carbon and metal catalyst, MWNTs were exposed to dry air and
washed with hydrochloric acid. Heating purified CNTs under helium
atmosphere caused elimination of acidic functional groups. Fourier
transformed infrared spectroscopy (FTIR) shows formation of
oxygen containing groups such as C=O and COOH. Brunauer,
Emmett, Teller (BET) analysis revealed that functionalization causes
generation of defects on the sidewalls and opening of the ends of
CNTs. Results of temperature-programmed desorption (TPD) and gas
chromatography(GC) indicate that nitric acid treatment create more
acidic groups than plasma treatment.
Abstract: Conventionally the selection of parameters depends
intensely on the operator-s experience or conservative technological
data provided by the EDM equipment manufacturers that assign
inconsistent machining performance. The parameter settings given by
the manufacturers are only relevant with common steel grades. A
single parameter change influences the process in a complex way.
Hence, the present research proposes artificial neural network (ANN)
models for the prediction of surface roughness on first commenced
Ti-15-3 alloy in electrical discharge machining (EDM) process. The
proposed models use peak current, pulse on time, pulse off time and
servo voltage as input parameters. Multilayer perceptron (MLP) with
three hidden layer feedforward networks are applied. An assessment
is carried out with the models of distinct hidden layer. Training of the
models is performed with data from an extensive series of
experiments utilizing copper electrode as positive polarity. The
predictions based on the above developed models have been verified
with another set of experiments and are found to be in good
agreement with the experimental results. Beside this they can be
exercised as precious tools for the process planning for EDM.
Abstract: Off-grid Photovoltaic (PV) systems are empowering
technology in underdeveloped countries like Ethiopia where many
people live far away from the modern world. Where there is
relatively low energy consumption, providing energy from grid
systems is not commercially cost-effective. As a result, significant
people groups worldwide stay without access to electricity. One
remote village in northern Ethiopia was selected by the United
Nations for a pilot project to improve its living conditions. As part of
this comprehensive project, an intelligent charge controller circuit for
Off-grid PV systems was designed for the clinic in that village. In
this paper, design aspects of an intelligent charge controller unit and
its load driver circuits are discussed for an efficient utilization of PVbased
supply systems.