Abstract: The temperature dependence of wettability (wetting
angle, Θ (T)) for Ag-based melts on graphite and Al2O3 substrates is
compared. Typical alloying effects are found, as the Ag host metal is
gradually replaced by various metallic elements. The essence of
alloying lies in the change of the electron/atom (e/a) ratio. This ratio
is also manifested in the shift of wetting angles on the same substrate.
Nevertheless, the effects are partially smeared by other
(metallurgical) factors, like the interaction between the oxygenalloying
elements and by the graphite substrate-oxygen interaction. In
contrast, such effects are not pronounced in the case of Al2O3
substrates. As a consequence, Θ(T) exhibits an opposite trend in the
case of two substrates. Crossovers of the Θ(T) curves were often
found. The positions of crossovers depend on the chemical character
and concentration of solute atoms. Segregation and epitaxial texture
formation after solidification were also observed in certain alloy
drops, especially in high concentration range. This phenomenon is
not yet explained in every detail.
Abstract: Pyrite (FeS2) is a promising candidate for cathode
materials in batteries because of it`s high theoretical capacity, low
cost and non-toxicity. In this study, nano size iron disulfide thin film
was prepared on graphite substrate through a new method as battery
cathode. In this way, acetylene black and poly vinylidene fluoride
were used as electron conductor and binder, respectively. Fabricated
thin films were analyzed by XRD and SEM. These results and
electrochemical data confirm improvement of battery discharge
capacity in comparison with commercial type of pyrite.
Abstract: This research study the application of the immobilized
TiO2 layer and Cu-TiO2 layer on graphite substrate as a negative
electrode or anode for Li-ion battery. The titania layer was produced
through chemical bath deposition method, meanwhile Cu particles
were deposited electrochemically. A material can be used as an
electrode as it has capability to intercalates Li ions into its crystal
structure. The Li intercalation into TiO2/Graphite and Cu-
TiO2/Graphite were analyzed from the changes of its XRD pattern
after it was used as electrode during discharging process. The XRD
patterns were refined by Le Bail method in order to determine the
crystal structure of the prepared materials. A specific capacity and the
cycle ability measurement were carried out to study the performance
of the prepared materials as negative electrode of the Li-ion battery.
The specific capacity was measured during discharging process from
fully charged until the cut off voltage. A 300 was used as a load.
The result shows that the specific capacity of Li-ion battery with
TiO2/Graphite as negative electrode is 230.87 ± 1.70mAh.g-1 which is
higher than the specific capacity of Li-ion battery with pure graphite
as negative electrode, i.e 140.75 ±0.46mAh.g-1. Meanwhile
deposition of Cu onto TiO2 layer does not increase the specific
capacity, and the value even lower than the battery with
TiO2/Graphite as electrode. The cycle ability of the prepared battery
is only two cycles, due to the Li ribbon which was used as cathode
became fragile and easily broken.