Abstract: ZnO nanostructures including nanowires, nanorods,
and nanoneedles were successfully deposited on GaAs substrates,
respectively, by simple two-step chemical method for the first time. A
ZnO seed layer was firstly pre-coated on the O2-plasma treated
substrate by sol-gel process, followed by the nucleation of ZnO
nanostructures through hydrothermal synthesis. Nanostructures with
different average diameter (15-250 nm), length (0.9-1.8 μm), density
(0.9-16×109 cm-2) were obtained via adjusting the growth time and
concentration of precursors. From the reflectivity spectra, we
concluded ordered and taper nanostructures were preferential for
photovoltaic applications. ZnO nanoneedles with an average diameter
of 106 nm, a moderate length of 2.4 μm, and the density of 7.2×109
cm-2 could be synthesized in the concentration of 0.04 M for 18 h.
Integrated with the nanoneedle array, the power conversion efficiency
of single junction solar cell was increased from 7.3 to 12.2%,
corresponding to a 67% improvement.
Abstract: Nanocrystalline thin film of Na0.1V2O5.nH2O xerogel
obtained by sol gel synthesis was used as gas sensor. Gas sensing
properties of different gases such as hydrogen, petroleum and
humidity were investigated. Applying XRD and TEM the size of the
nanocrystals is found to be 7.5 nm. SEM shows a highly porous
structure with submicron meter-sized voids present throughout the
sample. FTIR measurement shows different chemical groups
identifying the obtained series of gels. The sample was n-type
semiconductor according to the thermoelectric power and electrical
conductivity. It can be seen that the sensor response curves from
130oC to 150oC show a rapid increase in sensitivity for all types of
gas injection, low response values for heating period and the rapid
high response values for cooling period. This result may suggest that
this material is able to act as gas sensor during the heating and
cooling process.
Abstract: In this research work, poly (acrylonitrile-butadienestyrene)/
polypropylene (ABS/PP) blends were processed by melt
compounding in a twin-screw extruder. Upgrading of the thermal
characteristics of the obtained materials was attempted by the
incorporation of organically modified montmorillonite (OMMT), as
well as, by the addition of two types of compatibilizers;
polypropylene grafted with maleic anhydride (PP-g-MAH) and ABS
grafted with maleic anhydride (ABS-g-MAH). The effect of the
above treatments was investigated separately and in combination.
Increasing the PP content in ABS matrix seems to increase the
thermal stability of their blend and the glass transition temperature
(Tg) of SAN phase of ABS. From the other part, the addition of ABS
to PP promotes the formation of its β-phase, which is maximum at 30
wt% ABS concentration, and increases the crystallization temperature
(Tc) of PP. In addition, it increases the crystallization rate of PP.The
β-phase of PP in ABS/PP blends is reduced by the addition of
compatibilizers or/and organoclay reinforcement. The incorporation
of compatibilizers increases the thermal stability of PP and reduces
its melting (ΔΗm) and crystallization (ΔΗc) enthalpies. Furthermore it
decreases slightly the Tgs of PP and SAN phases of ABS/PP blends.
Regarding the storage modulus of the ABS/PP blends, it presents a
change in their behavior at about 10°C and return to their initial
behavior at ~110°C. The incorporation of OMMT to no compatibilized
and compatibilized ABS/PP blends enhances their storage modulus.
Abstract: The objective of the present work is to conduct
investigations leading to a more complete explanation of single phase
natural convective heat transfer in an enclosure with fin utilizing
nano fluids. The nano fluid used, which is composed of Aluminum
oxide nano particles in suspension of Ethylene glycol, is provided at
various volume fractions. The study is carried out numerically for a
range of Rayleigh numbers, fin heights and aspect ratio. The flow and
temperature distributions are taken to be two-dimensional. Regions
with the same velocity and temperature distributions are identified as
symmetry of sections. One half of such a rectangular region is chosen
as the computational domain taking into account the symmetry about
the fin. Transport equations are modeled by a stream functionvorticity
formulation and are solved numerically by finite-difference
schemes. Comparisons with previously published works on the basis
of special cases are done. Results are presented in the form of
streamline, vector and isotherm plots as well as the variation of local
Nusselt number along the fin under different conditions.
Abstract: 16-Mercaptohexadecanoic acid (MHDA) and tripeptide glutathione conjugated with gold nanoparticles (Au-NPs) are characterized by Fourier Transform InfaRared (FTIR) spectroscopy combined with Surface-enhanced Raman scattering (SERS) spectroscopy. Surface Plasmon Resonance (SPR) technique based on FTIR spectroscopy has become an important tool in biophysics, which is perspective for the study of organic compounds. FTIR-spectra of MHDA shows the line at 2500 cm-1 attributed to thiol group which is modified by presence of Au-NPs, suggesting the formation of bond between thiol group and gold. We also can observe the peaks originate from characteristic chemical group. A Raman spectrum of the same sample is also promising. Our preliminary experiments confirm that SERS-effect takes place for MHDA connected with Au-NPs and enable us to detected small number (less than 106 cm-2) of MHDA molecules. Combination of spectroscopy methods: FTIR and SERS – enable to study optical properties of Au- NPs and immobilized bio-molecules in context of a bio-nano-sensors.
Abstract: Bacterial magnetic nanoparticles have great useful potential in biotechnological and biomedical applications. In this study, a liquid growth medium was modified for cultivation a fastidious magnetotactic bacterium that has been isolated from Anzali
lagoon, Iran in our previous research. These modifications include
change in vitamin, mineral, carbon sources and etcetera. In our
experience, the serum bottles and designed air-tight laboratory bottles
were used to create microaerobic conditions in order to development
of a method for scale-up experiment. This information may serve as a
guide to green chemistry based biological protocols for the synthesis
of magnetic nanoparticles with control over the chemical
composition, morphology and size.
Abstract: Aim of this work was to compare the efficacy of two
loading methods of proteins onto polymeric nanocarriers: adsorption
and encapsulation methods. Preliminary studies of protein loading
were done using Bovine Serum Albumin (BSA) as model protein.
Nanocarriers were prepared starting from polylactic co-glycolic acid
(PLGA) polymer; production methods used are two different variants
of emulsion evaporation method. Nanoparticles obtained were
analyzed in terms of dimensions by Dynamic Light Scattering and
Loading Efficiency of BSA by Bradford Assay. Loaded
nanoparticles were then submitted to in-vitro protein dissolution test
in order to study the effect of the delivery system on the release rate
of the protein.
Abstract: Stress-strain curve of inter-tube connected carbon nanotube (CNT) reinforced polymer composite under axial loading generated from molecular dynamics simulation is presented. Comparison of the response to axial mechanical loading between this composite system with composite systems reinforced by long, continuous CNTs (replicated via periodic boundary conditions) and short, discontinuous CNTs has been made. Simulation results showed that the inter-tube connection improved the mechanical properties of short discontinuous CNTs dramatically. Though still weaker than long CNT/polymer composite, more remarkable increase in the stiffness relative to the polymer was observed in the inter-tube connected CNT/polymer composite than in the discontinuous CNT/polymer composite. The manually introduced bridge break process resulted in a stress-strain curve of ductile fracture mode, which is consistent with the experimental result.
Abstract: In this paper, we present a vertical wire NMOS
device fabricated using CMOS compatible processes. The
impact of temperature on various device parameters is
investigated in view of usual increase in surrounding
temperature with device density.
Abstract: A new dual-fluid concept was studied that could eventually find application for cold-gas propulsion for small space satellites or other constant flow applications. In basic form, the concept uses two different refrigerant working fluids, each having a different saturation vapor pressure. The higher vapor pressure refrigerant remains in the saturation phase and is used to pressurize the lower saturation vapor pressure fluid (the propellant) which remains in the compressed liquid phase. A demonstration thruster concept based on this principle was designed and built to study its operating characteristics. An automotive-type electronic fuel injector was used to meter and deliver the propellant. Ejected propellant mass and momentum were measured for several combinations of refrigerants and hydrocarbon fluids. The thruster has the advantage of delivering relatively large total impulse at low tank pressure within a small volume.
Abstract: Chemical and physical functionalization of multiwalled
carbon nanotubes (MWCNT) has been commonly practiced to
achieve better dispersion of carbon nanotubes (CNTs) in polymer
matrix. This work describes various functionalization methods (acidtreatment,
non-ionic surfactant treatment with TritonX-100),
fabrication of MWCNT/PP nanocomposites via melt blending and
characterization of mechanical properties. Microscopy analysis
(FESEM, TEM, XPS) showed effective purification of MWCNTs
under acid treatment, and better dispersion under both chemical and
physical functionalization techniques combined, in their respective
order. Tensile tests showed increase in tensile strength for the
nanocomposites that contain MWCNTs up to 2 wt%. A decrease in
tensile strength was seen in samples that contain 4 wt% of MWCNTs
for both raw and Triton X-100 functionalized, signifying MWCNT
degradation/rebundling at composition with higher content of
MWCNTs. For the acid-treated MWCNTs, however, the tensile
results showed slight improvement even at 4wt%, indicating effective
dispersion of MWCNTs.
Abstract: The nanosized polymeric micelles release the drug
due to acoustic cavitation, which is enhanced in dual frequency
ultrasonic fields. In this study, adult female Balb/C mice were
transplanted with spontaneous breast adenocarcinoma tumors and
were injected with a dose of 1.3 mg/kg doxorubicin in one of three
forms: free doxorubicin, micellar doxorubicin without sonication and
micellar doxorubicin with sonication. To increase cavitation yield,
the tumor region was sonicated with low level dual frequency of 3
MHz and 28 kHz. The animals were sacrificed 24 h after injection,
and their tumor, heart, spleen, liver, kidneys and plasma were
separated and homogenized. The drug content in their tumor, heart,
spleen, liver, kidneys and plasma was determined using tissue
fluorimetry. The results show that in the group that received micellar
doxorubicin with sonication, the drug concentration in the tumor
tissue was nine and three times higher than in the free doxorubicin
group and the micellar doxorubicin without sonication group,
respectively. In the micellar doxorubicin with sonication group, the
drug concentration in other tissues was lower than other groups
(p
Abstract: The photocatalytic activity efficiency of TiO2 for the degradation of Toluene in photoreactor can be enhanced by nano- TiO2/LDPE composite film. Since the amount of TiO2 affected the efficiency of the photocatalytic activity, this work was mainly concentrated on the effort to embed the high amount of TiO2 in the Polyethylene matrix. The developed photocatalyst was characterized by XRD, UV-Vis spectrophotometer and SEM. The SEM images revealed the high homogeneity of the deposition of TiO2 on the polyethylene matrix. The XRD patterns interpreted that TiO2 embedded in the PE matrix exhibited mainly in anatase form. In addition, the photocatalytic results show that the toluene removal efficiencies of 30±5%, 49±4%, 68±5%, 42±6% and 33±5% were obtained when using the catalyst loading at 0%, 10%, 15%, 25% and 50% (wt. cat./wt. film), respectively.
Abstract: This work relates the development of an optical fiber
(OF) sensor for the detection and quantification of single walled
carbon nanotubes in aqueous solutions. The developed OF displays a
compact design, it requires less expensive materials and equipment
as well as low volume of sample (0.2 mL). This methodology was
also validated by the comparison of its analytical performance with
that of a standard methodology based on ultraviolet-visible
spectroscopy. The developed OF sensor follows the general SDS
calibration proposed for OF sensors as a more suitable calibration
fitting compared with classical calibrations.
Abstract: Article devoted to the development of technologies
for medicine and agroecology by using plant organelle – spherosome.
Technological method of purification and isolation of this organelle
by using novel nanostructured carbon sorbent – “nanocarbosorb"
ARK type are presented. Also the methods of preparation of
nanocontainers based on using of spherosome with loaded isosorbide
dinitrate, piroxicam or diclofenak are exhibited. We found that the
spherosome could be applied for ecological aims as bioregulator and
also as biosensor for determination of ammonia ions in water
reservoirs at concentration range 1mM to 100mM.
Abstract: We study the typical domain size and configuration
character of a randomly perturbed system exhibiting continuous
symmetry breaking. As a model system we use rod-like objects
within a cubic lattice interacting via a Lebwohl–Lasher-type
interaction. We describe their local direction with a headless unit
director field. An example of such systems represents nematic LC or
nanotubes. We further introduce impurities of concentration p, which
impose the random anisotropy field-type disorder to directors. We
study the domain-type pattern of molecules as a function of p,
anchoring strength w between a neighboring director and impurity,
temperature, history of samples. In simulations we quenched the
directors either from the random or homogeneous initial
configuration. Our results show that a history of system strongly
influences: i) the average domain coherence length; and ii) the range
of ordering in the system. In the random case the obtained order is
always short ranged (SR). On the contrary, in the homogeneous case,
SR is obtained only for strong enough anchoring and large enough
concentration p. In other cases, the ordering is either of quasi long
range (QLR) or of long range (LR). We further studied memory
effects for the random initial configuration. With increasing external
ordering field B either QLR or LR is realized.
Abstract: Bode stability analysis based on transmission line
modeling (TLM) for single wall carbon nanotube (SWCNT)
interconnects used in 3D-VLSI circuits is investigated for the first
time. In this analysis, the dependence of the degree of relative
stability for SWCNT interconnects on the geometry of each tube has
been acquired. It is shown that, increasing the length and diameter of
each tube, SWCNT interconnects become more stable.
Abstract: The importance for manipulating an incorporated
scaffold and directing cell behaviors is well appreciated for tissue
engineering. Here, we developed newly nano-topographic oxidized
silicon nanosponges capable of being various chemical modifications
to provide much insight into the fundamental biology of how cells
interact with their surrounding environment in vitro. A wet etching
technique is exerted to allow us fabricated the silicon nanosponges in a
high-throughput manner. Furthermore, various organo-silane
chemicals enabled self-assembled on the surfaces by vapor deposition.
We have found that Chinese hamster ovary (CHO) cells displayed
certain distinguishable morphogenesis, adherent responses, and
biochemical properties while cultured on these chemical modified
nano-topographic structures in compared with the planar oxidized
silicon counterparts, indicating that cell behaviors can be influenced
by certain physical characteristic derived from nano-topography in
addition to the hydrophobicity of contact surfaces crucial for cell
adhesion and spreading. Of particular, there were predominant
nano-actin punches and slender protrusions formed while cells were
cultured on the nano-topographic structures. This study shed potential
applications of these nano-topographic biomaterials for controlling
cell development in tissue engineering or basic cell biology research.
Abstract: In this study, synthesis of biomemitic patterned nano
hydroxyapatite-starch biocomposites using different concentration of
starch to evaluate effect of polymer alteration on biocomposites
structural properties has been reported. Formation of hydroxyapatite
nano particles was confirmed by X-ray diffraction (XRD) and Fourier
transform infrared spectroscopy (FT-IR). Size and morphology of the
samples were characterized using scanning and transmission electron
microscopy (SEM and TEM). It seems that by increasing starch
content, the more active site of polymer (oxygen atoms) can be
provided for interaction with Ca2+ followed by phosphate and
hydroxyl group.
Abstract: Each new semiconductor technology node
brings smaller transistors and wires. Although this makes
transistors faster, wires get slower. In nano-scale regime, the
standard copper (Cu) interconnect will become a major hurdle
for FPGA interconnect due to their high resistivity and
electromigration. This paper presents the comprehensive
evaluation of mixed CNT bundle interconnects and
investigates their prospects as energy efficient and high speed
interconnect for future FPGA routing architecture. All
HSPICE simulations are carried out at operating frequency of
1GHz and it is found that mixed CNT bundle implemented in
FPGAs as interconnect can potentially provide a substantial
delay and energy reduction over traditional interconnects at
32nm process technology.