Abstract: Wet chemistry methods are used to prepare the
SiO2/Au nanoshells. The purpose of this research was to synthesize
gold coated SiO2 nanoshells for biomedical applications. Tunable
nanoshells were prepared by using different colloidal concentrations.
The nanoshells are characterized by FTIR, XRD, UV-Vis
spectroscopy and atomic force microscopy (AFM). The FTIR results
confirmed the functionalization of the surfaces of silica nanoparticles
with NH2 terminal groups. A tunable absorption was observed
between 470-600 nm with a maximum range of 530-560 nm. Based
on the XRD results three main peaks of Au (111), (200) and (220)
were identified. Also AFM results showed that the silica core
diameter was about 100 nm and the thickness of gold shell about 10
nm.
Abstract: Cement, the most widely used construction material
is very brittle and characterized by low tensile strength and strain
capacity. Macro to nano fibers are added to cement to provide
tensile strength and ductility to it. Carbon Nanotube (CNT), one of
the nanofibers, has proven to be a promising reinforcing material in
the cement composites because of its outstanding mechanical
properties and its ability to close cracks at the nano level. The
experimental investigations for CNT reinforced cement is costly,
time consuming and involves huge number of trials. Mathematical
modeling of CNT reinforced cement can be done effectively and
efficiently to arrive at the mechanical properties and to reduce the
number of trials in the experiments. Hence, an attempt is made to
numerically study the effective mechanical properties of CNT
reinforced cement numerically using Representative Volume
Element (RVE) method. The enhancement in its mechanical
properties for different percentage of CNTs is studied in detail.
Abstract: Nanoemulsions are a class of emulsions with a droplet
size in the range of 50–500 nm and have attracted a great deal of
attention in recent years because it is unique characteristics. The
physicochemical properties of nanoemulsion suggests that it can be
successfully used to recover the residual oil which is trapped in the
fine pore of reservoir rock by capillary forces after primary and
secondary recovery. Oil-in-water nanoemulsion which can be formed
by high-energy emulsification techniques using specific surfactants
can reduce oil-water interfacial tension (IFT) by 3-4 orders of
magnitude. The present work is aimed on characterization of oil-inwater
nanoemulsion in terms of its phase behavior, morphological
studies; interfacial energy; ability to reduce the interfacial tension and
understanding the mechanisms of mobilization and displacement of
entrapped oil blobs by lowering interfacial tension both at the
macroscopic and microscopic level. In order to investigate the
efficiency of oil-water nanoemulsion in enhanced oil recovery
(EOR), experiments were performed to characterize the emulsion in
terms of their physicochemical properties and size distribution of the
dispersed oil droplet in water phase. Synthetic mineral oil and a series
of surfactants were used to prepare oil-in-water emulsions.
Characterization of emulsion shows that it follows pseudo-plastic
behaviour and drop size of dispersed oil phase follows lognormal
distribution. Flooding experiments were also carried out in a
sandpack system to evaluate the effectiveness of the nanoemulsion as
displacing fluid for enhanced oil recovery. Substantial additional
recoveries (more than 25% of original oil in place) over conventional
water flooding were obtained in the present investigation.
Abstract: fibers of pure cellulose can be made from some bacteria such as acetobacter xylinum. Bacterial cellulose fibers are very pure, tens of nm across and about 0.5 micron long. The fibers are very stiff and, although nobody seems to have measured the strength of individual fibers. Their stiffness up to 70 GPa. Fundamental strengths should be at least greater than those of the best commercial polymers, but best bulk strength seems to about the same as that of steel. They can potentially be produced in industrial quantities at greatly lowered cost and water content, and with triple the yield, by a new process. This article presents a critical review of the available information on the bacterial cellulose as a biological nonwoven fabric with special emphasis on its fermentative production and applications. Characteristics of bacterial cellulose biofabric with respect to its structure and physicochemical properties are discussed. Current and potential applications of bacterial cellulose in textile, nonwoven cloth, paper, films synthetic fiber coating, food, pharmaceutical and other industries are also presented.
Abstract: The effect of concentration of reduction agent of
sodium borohydrate (NaBH4) on the properties of silicon
nanoparticles synthesized via microemulsion route is reported. In
this work, the concentration of the silicon tetrachloride (SiCl4) that
served as silicon source with sodium hydroxide (NaOH) and
polyethylene glycol (PEG) as stabilizer and surfactant, respectively,
are keep fixed. Four samples with varied concentration of NaBH4
from 0.05 M to 0.20 M were synthesized. It was found that the lowest
concentration of NaBH4 gave better formation of silicon
nanoparticles.
Abstract: Molecular dynamics simulation of annular flow
boiling in a nanochannel with 70000 particles is numerically
investigated. In this research, an annular flow model is developed to
predict the superheated flow boiling heat transfer characteristics in a
nanochannel. To characterize the forced annular boiling flow in a
nanochannel, an external driving force F ext ranging from 1to12PN
(PN= Pico Newton) is applied along the flow direction to inlet fluid
particles during the simulation. Based on an annular flow model
analysis, it is found that saturation condition and superheat degree
have great influences on the liquid-vapor interface. Also, the results
show that due to the relatively strong influence of surface tension in
small channel, the interface between the liquid film and vapor core is
fairly smooth, and the mean velocity along the stream-wise direction
does not change anymore.
Abstract: This study presents the improvement of thermal
performance of heat pipe using copper nanofluid with aqueous
solution of n-Butanol. The nanofluids kept in the suspension of
conventional fluids have the potential of superior heat transfer
capability than the conventional fluids due to their improved thermal
conductivity. In this work, the copper nanofluid which has a 40 nm
size with a concentration of 100 mg/lit is kept in the suspension of
the de-ionized (DI) water and an aqueous solution of n-Butanol and
these fluids are used as a working medium in the heat pipe. The study
discusses about the effect of heat pipe inclination, type of working
fluid and heat input on the thermal efficiency and thermal resistance.
The experimental results are evaluated in terms of its performance
metrics and are compared with that of DI water.
Abstract: This paper presents an adaptive technique for generation
of data required for construction of artificial neural network-based
performance model of nano-scale CMOS inverter circuit. The training
data are generated from the samples through SPICE simulation. The
proposed algorithm has been compared to standard progressive sampling
algorithms like arithmetic sampling and geometric sampling.
The advantages of the present approach over the others have been
demonstrated. The ANN predicted results have been compared with
actual SPICE results. A very good accuracy has been obtained.
Abstract: In this study concept of experimental design is
successfully applied for the determination of optimum condition to
produce PP/SWCNT (Polypropylene/Single wall carbon nanotube)
nanocomposite. Central composite design as one of experimental
design techniques is employed for the optimization and statistical
determination of the significant factors influencing on the tensile
modulus and yield stress as mechanical properties of this
nanocomposite. The significant factors are SWCNT weight fraction
and acid treatment time for functionalizing the nanoparticles.
Optimum conditions are in 0.7 % of SWCNT weight fraction and 210
min as acid treatment time for 1112.75 ± 28 MPa as maximum tensile
modulus and in 216 min and 0.65 % as acid treatment time and
SWCNT weight fraction respectively for 40.26 ± 0.3 MPa as
maximum yield stress. Also after setting new experiments for test
these optimum conditions, found excelent agreement with predicted
values.
Abstract: Nanostructured materials have attracted many
researchers due to their outstanding mechanical and physical
properties. For example, carbon nanotubes (CNTs) or carbon
nanofibres (CNFs) are considered to be attractive reinforcement
materials for light weight and high strength metal matrix composites.
These composites are being projected for use in structural
applications for their high specific strength as well as functional
materials for their exciting thermal and electrical characteristics. The
critical issues of CNT-reinforced MMCs include processing
techniques, nanotube dispersion, interface, strengthening mechanisms
and mechanical properties. One of the major obstacles to the effective
use of carbon nanotubes as reinforcements in metal matrix
composites is their agglomeration and poor distribution/dispersion
within the metallic matrix. In order to tap into the advantages of the
properties of CNTs (or CNFs) in composites, the high dispersion of
CNTs (or CNFs) and strong interfacial bonding are the key issues
which are still challenging. Processing techniques used for synthesis
of the composites have been studied with an objective to achieve
homogeneous distribution of carbon nanotubes in the matrix.
Modified mechanical alloying (ball milling) techniques have emerged
as promising routes for the fabrication of carbon nanotube (CNT)
reinforced metal matrix composites. In order to obtain a
homogeneous product, good control of the milling process, in
particular control of the ball movement, is essential. The control of
the ball motion during the milling leads to a reduction in grinding
energy and a more homogeneous product. Also, the critical inner
diameter of the milling container at a particular rotational speed can
be calculated. In the present work, we use conventional and modified
mechanical alloying to generate a homogenous distribution of 2 wt.
% CNT within Al powders. 99% purity Aluminium powder (Acros,
200mesh) was used along with two different types of multiwall
carbon nanotube (MWCNTs) having different aspect ratios to
produce Al-CNT composites. The composite powders were processed
into bulk material by compaction, and sintering using a cylindrical
compaction and tube furnace. Field Emission Scanning electron
microscopy (FESEM), X-Ray diffraction (XRD), Raman
spectroscopy and Vickers macro hardness tester were used to
evaluate CNT dispersion, powder morphology, CNT damage, phase
analysis, mechanical properties and crystal size determination.
Despite the success of ball milling in dispersing CNTs in Al powder,
it is often accompanied with considerable strain hardening of the Al
powder, which may have implications on the final properties of the
composite. The results show that particle size and morphology vary
with milling time. Also, by using the mixing process and sonication
before mechanical alloying and modified ball mill, dispersion of the
CNTs in Al matrix improves.
Abstract: This paper proposes, for the first time, how the
challenges facing the guard-band designs including the margin
assist-circuits scheme for the screening-test in the coming process
generations should be addressed. The increased screening error
impacts are discussed based on the proposed statistical analysis
models. It has been shown that the yield-loss caused by the
misjudgment on the screening test would become 5-orders of
magnitude larger than that for the conventional one when the
amplitude of random telegraph noise (RTN) caused variations
approaches to that of random dopant fluctuation. Three fitting methods
to approximate the RTN caused complex Gamma mixtures
distributions by the simple Gaussian mixtures model (GMM) are
proposed and compared. It has been verified that the proposed
methods can reduce the error of the fail-bit predictions by 4-orders of
magnitude.
Abstract: During the last decade ultrafine grained (UFG) and nano-structured (NS) materials have experienced a rapid development. In this research work finite element analysis has been carried out to investigate the plastic strain distribution in equal channel angular process (ECAP). The magnitudes of Standard deviation (S. D.) and inhomogeneity index (Ci) were compared for different ECAP passes. Verification of a three-dimensional finite element model was performed with experimental tests. Finally the mechanical property including impact energy of ultrafine grained pure commercially pure Aluminum produced by severe plastic deformation method has been examined. For this aim, equal channel angular pressing die with the channel angle, outer corner angle and channel diameter of 90°, 20° and 20mm had been designed and manufactured. Commercial pure Aluminum billets were ECAPed up to four passes by route BC at the ambient temperature. The results indicated that there is a great improvement at the hardness measurement, yield strength and ultimate tensile strength after ECAP process. It is found that the magnitudes of HV reach 67HV from 21HV after the final stage of process. Also, about 330% and 285% enhancement at the YS and UTS values have been obtained after the fourth pass as compared to the as-received conditions, respectively. On the other hand, the elongation to failure and impact energy have been reduced by 23% and 50% after imposing four passes of ECAP process, respectively.
Abstract: Composite nanostructures of metal
core/semiconductor shell (Au/CdS) configuration were prepared
using organometalic method. UV-Vis spectra for the Au/CdS colloids
show initially two well separated bands, corresponding to surface
plasmon of the Au core, and the exciton of CdS shell. The absorption
of CdS shell is enhanced, while the Au plasmon band is suppressed
as the shell thickness increases. The shell sizes were estimated from
the optical spectra using the effective mass approximation model
(EMA), and compared to the sizes of the Au core and CdS shell
measured by high resolution transmission electron microscope
(HRTEM). The changes in the absorption features are discussed in
terms of gradual increase in the coupling strength of the Au core
surface plasmon and the exciton in the CdS. leading to charge
transfer and modification of electron oscillation in Au core.
Abstract: The aim of this study was to investigate whether
magnetite nanoparticles affect the viability of Bradyrhizobium
japanicum cells residing on the surface of soybean seeds during
desiccation. Different concentrations of nanoparticles suspended in
liquid medium, mixed with and adhering to Bradyrhizobium
japanicum, were investigated at two temperatures, using both
soybean seeds and glass beads as surrogates. Statistical design was a
complete randomized block (CRB) in a factorial 6×2×2×6
experimental arrangement with four replications. The most important
variable was the viability of Bradyrhizobium on the surface of the
seeds. The nanoparticles increased Bradyrhizobium viability and
inoculated seeds stored at low temperature had greater viability when
nanoparticles had been added. At the optimum nanoparticle
concentration, 50% bacterium viability on the seeds was retained
after 5 days at 4ºC. Possible explanations for the observed effects are
proposed.
Abstract: A facile vapour deposition method of synthesis of vertically aligned ZnO nanowires on carbon seed layer was developed. The received samples were investigated on electronic microscope JSM-6490 LA JEOL and x-ray diffractometer X, pert MPD PRO. The photoluminescence spectra (PL) of obtained ZnO samples at a room temperature were studied using He-Cd laser (325 nm line) as excitation source.
Abstract: ZnO nanocrystals with mean diameter size 14 nm
have been prepared by precipitation method, and examined as
photocatalyst for the UV-induced degradation of insecticide diazinon
as deputy of organic pollutant in aqueous solution. The effects of
various parameters, such as illumination time, the amount of
photocatalyst, initial pH values and initial concentration of
insecticide on the photocatalytic degradation diazinon were
investigated to find desired conditions. In this case, the desired
parameters were also tested for the treatment of real water containing
the insecticide. Photodegradation efficiency of diazinon was
compared between commercial and prepared ZnO nanocrystals. The
results indicated that UV/ZnO process applying prepared
nanocrystalline ZnO offered electrical energy efficiency and
quantum yield better than commercial ZnO. The present study, on the
base of Langmuir-Hinshelwood mechanism, illustrated a pseudo
first-order kinetic model with rate constant of surface reaction equal
to 0.209 mg l-1 min-1 and adsorption equilibrium constant of 0.124 l
mg-1.
Abstract: In this paper, the effect of modified clay on the
mechanical efficiency of epoxy resin is examined. Studies by X ray
diffraction and microscopic transient electron method show that
modified clay distribution in polymer area is intercalated kind.
Examination the results of mechanical tests shows that existence of
modified clay in epoxy area increases pressure yield strength, tension
module and nano composite fracture toughness in relate of pure
epoxy. By microscopic examinations it is recognized too that the
action of toughness growth of this kind of nano composite is due to
crack deflection, formation of new surfaces and fracture of clay piles.
Abstract: This paper presents a linear stability analysis of
natural convection in a horizontal layer of a viscoelastic
nanofluid. The Oldroyd B model was utilized to describe the
rheological behavior of a viscoelastic nanofluid. The model
used for the nanofluid incorporated the effects of Brownian
motion and thermophoresis. The onset criterion for stationary
and oscillatory convection was derived analytically. The effects
of the Deborah number, retardation parameters, concentration
Rayleigh number, Prandtl number, and Lewis number on the
stability of the system were investigated. Results indicated that
there was competition among the processes of thermophoresis,
Brownian diffusion, and viscoelasticity which caused
oscillatory rather than stationary convection to occur.
Oscillatory instability is possible with both bottom- and
top-heavy nanoparticle distributions. Regimes of stationary and
oscillatory convection for various parameters were derived and
are discussed in detail.
Abstract: Carrier mobility has become the most important
characteristic of high speed low dimensional devices. Due to
development of very fast switching semiconductor devices, speed of
computer and communication equipment has been increasing day by
day and will continue to do so in future. As the response of any
device depends on the carrier motion within the devices, extensive
studies of carrier mobility in the devices has been established
essential for the growth in the field of low dimensional devices.
Small-signal ac transport of degenerate two-dimensional hot
electrons in GaAs quantum wells is studied here incorporating
deformation potential acoustic, polar optic and ionized impurity
scattering in the framework of heated drifted Fermi-Dirac carrier
distribution. Delta doping is considered in the calculations to
investigate the effects of double delta doping on millimeter and submillimeter
wave response of two dimensional hot electrons in GaAs
nanostructures. The inclusion of delta doping is found to enhance
considerably the two dimensional electron density which in turn
improves the carrier mobility (both ac and dc) values in the GaAs
quantum wells thereby providing scope of getting higher speed
devices in future.
Abstract: In the present study, development of salbutamol
sulphate nanoparticles that adhere to gastric mucus was investigated.
Salbutamol sulphate has low bioavailability due to short transit time in
gastric. It also has a positive surface charge that provides hurdles to be
encapsulated by the positively strong mucoadhesive polymer of
chitosan. To overcome the difficulties, the surface charge of active
ingredient was modified using several nonionic and anionic
stomach-specific polymers. The nanoparticles were prepared using
ionotropic gelation technique. The evaluation involved determination
of particle size, zeta potential, entrapment efficiency, in vitro drug
release and in vitro mucoadhesion test. Results exhibited that the use
of anionic alginate polymer was more satisfactory than that of
nonionic polymer. Characteristics of the particles was nano-size, high
encapsulation efficiency, fulfilled the drug release requirements and
adhesive towards stomach for around 11 hours. This result shows that
the salbutamol sulphate nanoparticles can be utilized for improvement
its delivery.