Abstract: There are currently many people living with limb loss in the USA. The main causes for amputation can range from vascular disease, to trauma, or cancer. This number is expected increase over the next decade. Many patients have a single prosthetic for the first year but end up getting a second one to accommodate their changing physique. Afterwards, the prosthesis gets replaced every three to five years depending on how often it is used. This could cost the patient up to $500,000 throughout their lifetime. Complications do not end there, however. Due to the absence of nerves, it becomes more difficult to traverse terrain with a prosthetic. Moving on an incline or decline becomes difficult, thus curbs and stairs can be a challenge. Certain physical activities, such as cycling, could be even more strenuous. It will need to be relearned to accommodate for the change in weight, center of gravity, and transfer of energy from the leg to the pedal. The purpose of this research project is to develop a new, alternate below-knee cycling prosthetic using Dieter & Schmidt’s design process approach. It will be subjected to fatigue analysis under dynamic loading to observe the limitations as well as the strengths and weaknesses of the prosthetic. Benchmark comparisons will be made between existing prosthetics and the proposed one, examining the benefits and disadvantages. The resulting prosthetic will be 3D printed using acrylonitrile butadiene styrene (ABS) or polycarbonate (PC) plastic.
Abstract: Power generation effect, obtained by inserting a piezo- electric sheet in the backlash clearance of a circular arc helical gear, is evaluated. Such type of screw gear is preferred since, in comparison with the involute tooth profile, the circular arc profile leads to reduced stress-concentration effects, and improved life of the piezoelectric film. Firstly, geometry of the circular arc helical gear, and properties of the piezoelectric sheet are presented. Then, description of the test-rig, consisted of a right-hand thread gear meshing with a left-hand thread gear, and the voltage measurement procedure are given. After creating the tridimensional (3D) model of the meshing gears in SolidWorks, they are 3D-printed in acrylonitrile butadiene styrene (ABS) resin. Variation of the generated voltage versus time, during a meshing cycle of the circular arc helical gear, is measured for various values of the center distance. Then, the change of the maximal, minimal, and peak-to-peak voltage versus the center distance is illustrated. Optimal center distance of the gear, to achieve voltage maximization, is found and its significance is discussed. Such results prove that the contact pressure of the meshing gears can be measured, and also, the electrical power can be generated by employing the proposed technique.
Abstract: Electrospinning is the most widely utilized method to create nanofibers because of the direct setup, the capacity to mass-deliver consistent nanofibers from different polymers, and the ability to produce ultrathin fibers with controllable diameters. Smooth and much arranged ultrafine Polyacrylonitrile (PAN) nanofibers with diameters going from submicron to nanometer were delivered utilizing Electrospinning technique. PAN powder was used as a precursor to prepare the solution utilized as a part of this process. At the point when the electrostatic repulsion contradicted surface tension, a charged stream of polymer solution was shot out from the head of the spinneret and along these lines ultrathin nonwoven fibers were created. The effect of electrospinning parameter such as applied voltage, feed rate, concentration of polymer solution and tip to collector distance on the morphology of electrospun PAN nanofibers were investigated. The nanofibers were heat treated for carbonization to examine the changes in properties and composition to make for electrical application. Scanning Electron Microscopy (SEM) was performed before and after carbonization to study electrical conductivity and morphological characterization. The SEM images have shown the uniform fiber diameter and no beads formation. The average diameter of the PAN fiber observed 365nm and 280nm for flat plat and rotating drum collector respectively. The four probe strategy was utilized to inspect the electrical conductivity of the nanofibers and the electrical conductivity is significantly improved with increase in oxidation temperature exposed.
Abstract: Commercially available poly(acrylonitrile-co-vinyl acetate) P(AN-VA) or poly(acrylonitrile-co-methyl acrylate) P(AN-MA) are not satisfactory to meet the demand in flame and fire-resistance. In this work, vinylphosphonic acid is used during polymerization of acrylonitrile, vinyl acetate, methacrylic acid to produce fire-retardant polymers. These phosphorus containing polymers are successfully spun in the form of nanofibers. Properties such as water absorption of polymers are also determined and compared with commercial polymers.
Abstract: Nowadays, a great concern is placed on the harmfulness of ultraviolet radiation (UVR) which attacks human bodies. Nanocarbon materials, such as carbon nanotubes (CNTs), carbon nanofibers (CNFs) and graphene, have been considered promising alternatives to shielding materials because of their excellent electrical conductivities, very high surface areas and low densities. In the present work, carbon nanofibers have been synthesized from solutions of Polyacrylonitrile (PAN)/ N,N-dimethylformamide (DMF) by electrospinning method. The carbon nanofibers have been stabilized by oxidation at 250 °C for 2 h in air and carbonized at 750 °C for 1 h in H2/N2. We present the fabrication and characterization of transparent and ultraviolet (UV) shielding CNF/polymer composites. The content of CNF filler has been varied from 0.2% to 0.6 % by weight. UV Spectroscopy has been performed to study the effect of composition on the transmittance of polymer composites.
Abstract: Ceramic, polymer and composite nanofibers are nowadays begun to be utilized in many fields of nanotechnology. By the means of dimensions, these fibers are as small as nano scale but because of having large surface area and microstructural characteristics, they provide unique mechanic, optical, magnetic, electronic and chemical properties. In terms of nanofiber production, electrospinning has been the most widely used technique in recent years. In this study, carbon nanofibers have been synthesized from solutions of Polyacrylonitrile (PAN)/ N,N-dimethylformamide (DMF) by electrospinning method. The carbon nanofibers have been stabilized by oxidation at 250 °C for 2 h in air and carbonized at 750 °C for 1 h in H2/N2. Images of carbon nanofibers have been taken with scanning electron microscopy (SEM). The images have been analyzed to study the fiber morphology and to determine the distribution of the fiber diameter using FibraQuant 1.3 software. Then polymer composites have been produced from mixture of carbon nanofibers and silicone polymer. The final polymer composites have been characterized by X-ray diffraction method and scanning electron microscopy (SEM) energy dispersive X-ray (EDX) measurements. These results have been reported and discussed. At result, homogeneous carbon nanofibers with 100-167 nm of diameter were obtained with optimized electrospinning conditions.
Abstract: The flue gas from fossil fuels combustion contains harmful pollutants dangerous for human health and environment. One of the air pollution control methods to restrict the emission of these pollutants is based on using the nanoparticle in adsorption process. In the present research, gamma nano-alumina particle is added to polyacrylonitrile (PAN) polymer through simple loading method, and the adsorption capacity of the wet spun fiber is investigated. The results of exposure the fiber to the acid gases including SO2, CO, NO2, NO, and CO2 show the noticeable increase of gas adsorption capacity on fiber contains nanoparticle. The research has been conducted in Acrylic II Plant of Polyacryl Iran Corporation.
Abstract: Nanofibers are defined as fibers with diameters less
than 100 nanometers. In this study, behaviours of activated carbon
nanofiber (ACNF), carbon nanofiber (CNF), polyacrylonitrile/ carbon
nanotube (PAN/CNT), polyvinyl alcohol/nanosilver (PVA/Ag) in
proton exchange membrane (PEM) fuel cells are investigated
experimentally. This material was used as gas diffusion layer (GDL)
in PEM fuel cells. In this study, the electrical conductivities of
nanofiber and nanofiber/nanoparticles have been studied to
understand their effects on PEM fuel cell performance. According to
the experimental results, the maximum electrical conductivity
performance of the fuel cell with nanofiber was found to be at
PVA/Ag (at UConn condition). The electrical conductivities of CNF,
ACNF, PAN/CNT are lower for PEM. The resistance of cell with
PVA/Ag is lower than the resistance of cell with PAN/CNT, ACNF,
CNF.
Abstract: Polymeric micro-cantilevers (Cs) are rapidly
becoming popular for MEMS applications such as chemo- and biosensing
as well as purely electromechanical applications such as
microrelays. Polymer materials present suitable physical and
chemical properties combined with low-cost mass production. Hence,
micro-cantilevers made of polymers indicate much more
biocompatibility and adaptability of rapid prototyping along with
mechanical properties. This research studies the effects of three
process and one size factors on the filling behaviour in micro cavity,
and the role of each in the replication of micro parts using different
polymer materials i.e. polypropylene (PP) SABIC 56M10 and
acrylonitrile butadiene styrene (ABS) Magnum 8434 . In particular,
the following factors are considered: barrel temperature, mould
temperature, injection speed and the thickness of micro features. The
study revealed that the barrel temperature and the injection speed are
the key factors affecting the flow length of micro features replicated
in PP and ABS. For both materials, an increase of feature sizes
improves the melt flow. However, the melt fill of micro features does
not increase linearly with the increase of their thickness.
Abstract: This study focuses on a novel method for dispersion
and distribution of reinforcement under high intensive shear stress to
produce metal composites. The polyacrylonitrile (PAN)-based short
carbon fiber (Csf) and Nextel 610 alumina fiber were dispersed under
high intensive shearing at mushy zone in semi-solid of A356 by a
novel method. The bundles and clusters were embedded by
infiltration of slurry into the clusters, thus leading to a uniform
microstructure. The fibers were embedded homogenously into the
aluminum around 576-580°C with around 46% of solid fraction.
Other experiments at 615°C and 568°C which are contained 0% and
90% solid respectively were not successful for dispersion and
infiltration of aluminum into bundles of Csf. The alumina fiber has
been cracked by high shearing load. The morphologies and
crystalline phase were evaluated by SEM and XRD. The adopted
thixo-process effectively improved the adherence and distribution of
Csf into Al that can be developed to produce various composites by
thixomixing.
Abstract: PAN nanofibers reinforced with amine functionalized
carbon nanotubes. The effect of amine functionalization and the
effect of concentration of CNT on the conductivity and mechanical
and morphological properties of composite nanofibers were
examined. 1%CNT-NH2 loaded PAN/CNT nanofiber showed the best
mechanical properties. Conductivity increased with the incorporation
of carbon nanotubes. While an increase of concentration of CNT
increases the diameter of nanofiber, the use of functionalized CNT
results to decrease of diameter of nanofiber.
Abstract: Polymer composite nano-fibers including (1, 3 wt %)
silver nano-particles have been produced by electrospinning method.
Polyacrylonitrile/N,N-dimethylformamide (PAN/DMF) solution have
been prepared and the amount of silver nitrate have been adjusted to
PAN weight. Silver nano-particles were obtained from reduction of
silver ions into silver nano-particles by chemical reduction by
hydrazine hydroxide (N2H5OH). The different amount of silver salt
was loaded into polymer matrix to obtain polyacrylonitrile composite
nano-fiber containing silver nano-particles. The effect of the amount
of silver nano-particles on the properties of composite nano-fiber web
was investigated. Electrical conductivity, mechanical properties,
thermal properties were examined by Microtest LCR Meter 6370
(0.01 mΩ-100 MΩ), Tensile tester, Differential scanning calorimeter
DSC (Q10) and SEM respectively. Also antimicrobial efficiency test
(ASTM E2149-10) was done against to Staphylococcus aureus
bacteria. It has been seen that breaking strength, conductivity,
antimicrobial effect, enthalpy during cyclization increase by use of
silver nano-particles while the diameter of nano-fiber decreases.
Abstract: Carbon fibers have specific characteristics in
comparison with industrial and structural materials used in different
applications. Special properties of carbon fibers make them attractive
for reinforcing and fabrication of composites. These fibers have been
utilized for composites of metals, ceramics and plastics. However,
it-s mainly used in different forms to reinforce lightweight polymer
materials such as epoxy resin, polyesters or polyamides. The
composites of carbon fiber are stronger than steel, stiffer than
titanium, and lighter than aluminum and nowadays they are used in a
variety of applications. This study explains applications of carbon
fibers in different fields such as space, aviation, transportation,
medical, construction, energy, sporting goods, electronics, and the
other commercial/industrial applications. The last findings of
composites with polymer, metal and ceramic matrices containing
carbon fibers and their applications in the world investigated.
Researches show that carbon fibers-reinforced composites due to
unique properties (including high specific strength and specific
modulus, low thermal expansion coefficient, high fatigue strength,
and high thermal stability) can be replaced with common industrial
and structural materials.
Abstract: novel and simple method is introduced for rapid and
highly efficient water treatment by reverse osmosis (RO) method using
multi-walled carbon nanotubes (MWCNTs) / polyacrylonitrile (PAN)
polymer as a flexible, highly efficient, reusable and semi-permeable
mixed matrix membrane (MMM). For this purpose, MWCNTs were
directly synthesized and on-line purified by chemical vapor deposition
(CVD) process, followed by directing the MWCNT bundles towards an
ultrasonic bath, in which PAN polymer was simultaneously suspended
inside a solid porous silica support in water at temperature to ~70 οC.
Fabrication process of MMM was finally completed by hot isostatic
pressing (HIP) process. In accordance with the analytical figures of
merit, the efficiency of fabricated MMM was ~97%. The rate of water
treatment process was also evaluated to 6.35 L min-1. The results reveal
that, the CNT-based MMM is suitable for rapid treatment of different
forms of industrial, sea, drinking and well water samples.
Abstract: In the present study, the incorporation of graphene
into blends of acrylonitrile-butadiene-styrene terpolymer with
polypropylene (ABS/PP) was investigated focusing on the
improvement of their thermomechanical characteristics and the effect
on their rheological behavior. The blends were prepared by melt
mixing in a twin-screw extruder and were characterized by measuring
the MFI as well as by performing DSC, TGA and mechanical tests.
The addition of graphene to ABS/PP blends tends to increase their
melt viscosity, due to the confinement of polymer chains motion.
Also, graphene causes an increment of the crystallization temperature
(Tc), especially in blends with higher PP content, because of the
reduction of surface energy of PP nucleation, which is a consequence
of the attachment of PP chains to the surface of graphene through the
intermolecular CH-π interaction. Moreover, the above nanofiller
improves the thermal stability of PP and increases the residue of
thermal degradation at all the investigated compositions of blends,
due to the thermal isolation effect and the mass transport barrier
effect. Regarding the mechanical properties, the addition of graphene
improves the elastic modulus, because of its intrinsic mechanical
characteristics and its rigidity, and this effect is particularly strong in
the case of pure PP.
Abstract: In this research work, poly (acrylonitrile-butadienestyrene)/
polypropylene (ABS/PP) blends were processed by melt
compounding in a twin-screw extruder. Upgrading of the thermal
characteristics of the obtained materials was attempted by the
incorporation of organically modified montmorillonite (OMMT), as
well as, by the addition of two types of compatibilizers;
polypropylene grafted with maleic anhydride (PP-g-MAH) and ABS
grafted with maleic anhydride (ABS-g-MAH). The effect of the
above treatments was investigated separately and in combination.
Increasing the PP content in ABS matrix seems to increase the
thermal stability of their blend and the glass transition temperature
(Tg) of SAN phase of ABS. From the other part, the addition of ABS
to PP promotes the formation of its β-phase, which is maximum at 30
wt% ABS concentration, and increases the crystallization temperature
(Tc) of PP. In addition, it increases the crystallization rate of PP.The
β-phase of PP in ABS/PP blends is reduced by the addition of
compatibilizers or/and organoclay reinforcement. The incorporation
of compatibilizers increases the thermal stability of PP and reduces
its melting (ΔΗm) and crystallization (ΔΗc) enthalpies. Furthermore it
decreases slightly the Tgs of PP and SAN phases of ABS/PP blends.
Regarding the storage modulus of the ABS/PP blends, it presents a
change in their behavior at about 10°C and return to their initial
behavior at ~110°C. The incorporation of OMMT to no compatibilized
and compatibilized ABS/PP blends enhances their storage modulus.
Abstract: This paper presents the results of an experimental study on the performance of a triboelectric separator of plastic mixtures used for recycling. The separator consists of four cylindrical electrodes. The principle behind the separation technique is based on the difference in the Coulomb force acting on the plastic particles after triboelectric charging. The separation of mixtures of acrylonitrile butadiene styrene (ABS) and polystyrene (PS) using this method was studied. The effects of the triboelectric charging time and applied voltage on the separation efficiency were investigated. The experimental results confirm that it is possible to obtain a high purity and recovery rate for the initial compositions considered in this study.
Abstract: Moulded parts contribute to more than 70% of
components in products. However, common defects particularly in
plastic injection moulding exist such as: warpage, shrinkage, sink
marks, and weld lines. In this paper Taguchi experimental design
methods are applied to reduce the warpage defect of thin plate
Acrylonitrile Butadiene Styrene (ABS) and are demonstrated in two
levels; namely, orthogonal arrays of Taguchi and the Analysis of
Variance (ANOVA). Eight trials have been run in which the optimal
parameters that can minimize the warpage defect in factorial
experiment are obtained. The results obtained from ANOVA
approach analysis with respect to those derived from MINITAB
illustrate the most significant factors which may cause warpage in
injection moulding process. Moreover, ANOVA approach in
comparison with other approaches like S/N ratio is more accurate and
with the interaction of factors it is possible to achieve higher and the
better outcomes.
Abstract: Carbon fibers are fabricated from different materials,
such as special polyacrylonitrile (PAN) fibers, rayon fibers and pitch.
Among these three groups of materials, PAN fibers are the most
widely used precursor for the manufacture of carbon fibers. The
process of fabrication carbon fibers from special PAN fibers includes
two steps; oxidative stabilization at low temperature and
carbonization at high temperatures in an inert atmosphere. Due to the
high price of raw materials (special PAN fibers), carbon fibers are
still expensive.
In the present work the main goal is making carbon fibers from
low price commercial PAN fibers with modified chemical
compositions. The results show that in case of conducting completes
stabilization process, it is possible to produce carbon fibers with
desirable tensile strength from this type of PAN fibers. To this
matter, thermal characteristics of commercial PAN fibers were
investigated and based upon the obtained results, with some changes
in conventional procedure of stabilization in terms of temperature
and time variables; the desirable conditions of complete stabilization
is achieved.
Abstract: Paper presents knowledge about types of test in area
of materials properties of selected methods of rapid prototyping
technologies. In today used rapid prototyping technologies for
production of models and final parts are used materials in initial state
as solid, liquid or powder material structure. In solid state are used
various forms such as pellets, wire or laminates. Basic range
materials include paper, nylon, wax, resins, metals and ceramics. In
Fused Deposition Modeling (FDM) rapid prototyping technology are
mainly used as basic materials ABS (Acrylonitrile Butadiene
Styrene), polyamide, polycarbonate, polyethylene and polypropylene.
For advanced FDM applications are used special materials as silicon
nitrate, PZT (Piezoceramic Material - Lead Zirconate Titanate),
aluminium oxide, hydroxypatite and stainless steel.