Nanocrystalline Na0.1V2O5.nH2O Xerogel Thin Film for Gas Sensing

Nanocrystalline thin film of Na0.1V2O5.nH2O xerogel
obtained by sol gel synthesis was used as gas sensor. Gas sensing
properties of different gases such as hydrogen, petroleum and
humidity were investigated. Applying XRD and TEM the size of the
nanocrystals is found to be 7.5 nm. SEM shows a highly porous
structure with submicron meter-sized voids present throughout the
sample. FTIR measurement shows different chemical groups
identifying the obtained series of gels. The sample was n-type
semiconductor according to the thermoelectric power and electrical
conductivity. It can be seen that the sensor response curves from
130oC to 150oC show a rapid increase in sensitivity for all types of
gas injection, low response values for heating period and the rapid
high response values for cooling period. This result may suggest that
this material is able to act as gas sensor during the heating and
cooling process.





References:
[1] P.T. Moseley, B.C. Toefield (Eds.), e , Adam Hilger,Bristol, 1987.
[2] Y.T. Lima, J.Y.Sonb,n, J.-S.Rhee, "Vertical ZnOnanorodarray as an
effective hydrogen gas sensor," Ceramics International 39 (2013) 887.
[3] S.S. Sunu, E. Prabhu, V. Jayaraman, K.I. Gnanasekar, T.Gnanasekaran,
"Gas sensing properties of PLD made MoO3 films," Sensors and
Actuators B 94 (2003) 189.
[4] O. Schilling, K. Colbow,"mechanism for sensing reducing gases with
vanadium pentoxide films,"Sensors and Actuators A,B 21 (1994) 151.
[5] A.A. Bahgat, F.A. Ibrahim, M.M. El-Desoky, "Nanocrystalline
Vanadium PentoxideXerogelProperties,and Hydrogen Sensing," AIP
Conf. Proc. 1370, 61-67 (2011); doi: 10.1063/1.3638083
[6] K. Lai, A. Kong, F.Yang, B. Chen, H. Ding, Y.Shan, S.Huang,
"Intercalation of alkylviologendications into thelayered vanadium
pentoxide,"Inorganica ChimicaActa359 (2006) 1050.
[7] J. Muster, G.T. Kim, J.G. Park, Y.W. Park, S. Roth, M. Burghard,
"Electrical Transport Through Individual Vanadium Pentoxide,"
Nanowires Adv. Mater. 12 (2000) 420.
[8] A.Z. Sadek, J.G. Partridge, D.G. McCulloch, Y.X. Li, X.F.Yu , W.
Wlodarskia, K. Kalantar-zadeh, "Nanoporous TiO2 thin film based
conductometric H2 sensor," Thin SolidFilms 518 (2009) 1294.
[9] W. Jin, B. Dong, W. Chen, C. Zhao, L. Mai, Y.Dai,"Synthesis and gas
sensing properties of Fe2O3nanoparticles activated V2O5 nanotubes,"
Sensors and Actuators B 145 (2010) 211
[10] N.F. Mott, "Conduction in glasses containing transition metal ions," J.
Non - Cryst. Solids 1 (1968)1-17.
[11] I.G. Austin, N.F. Mott, "Polarons in crystalline and non-crystalline
materials,"Adv. Phys. 18 (1969)41-102.
[12] M.S. Al-Assiri, M.M. El-Desoky, A. Alyamani, A. Al-Hajry, A. Al-
Mogeeth, A.A. Bahgat, "Structural andtransport properties of Li-
intercalated vanadiumpentoxide nanocrystalline films," Phil.
Mag.25(2010)3421-3439.
[13] A.A. Bahgat , H.A. Mady, S.S. Abdel moghny, A. S. Abd-Rabo, S. E.
Negm, "Transport Properties of KxV2O5·nH2ONanocrystalline
Films,"J.Mater. Sci. Technol. 27(2011)865-872.
[14] Hoda A. Mady, S.E. Negm, A.S. Abdel Moghny, A.S.Abd-Rabo, A. A.
Bahgat, "Study of optical properties ofhighly oriented nanocrystalline
V2O5·nH2O films dopedwith K ions," J Sol-Gel SciTechnol
62(2012)18.
[15] H. Liu, Y. P. Wu, E. Rahm, R. Holzem, H. Q. Wu, "Cathode materials
for lithium ion batteries prepared by sol-gelmethods," J. Solid State
Eletrochem, DOI 10.1007/s10008-004-0521-1.
[16] M.S. Al-Assiri, M.M. El-Desoky, A. Alyamani, A. Al-Hajry, A. Al-
Mogeeth, A.A. Bahgat, "Spectroscopic studyof nanocrystalline
V2O5.nH2O films doped with Li ions,"Optics & Laser Technology 42
(2010) 994.
[17] A. A. Bahgat, F. A. Ibrahim, M. M. El-Desoky, "Electrical and optical
properties of highly oriented nanocrystallinevanadium pentoxide," Thin
Solid Films, 489 (2005) 68-73.
[18] D. Lou , N. Audebrand, Advances in x-ray analysis, 41(1997) 556.
[19] M. M. El-Desoky, F. A. Ibrahim, "Synthesis, structural and transport
properties of Li-doped molybdenum andvanadium oxide nanocrystalline
films," J. Sol-Gel Sci.Technol., DOI 10.1007/s10971-011-2537-1.
[20] B. A. Marinkovic, P. M. Jardim, A. Saavedra, L. Y. Lau, C. Baehtz, R.
R. de Avillez, F. Rizzo, "Negative thermal expansion in hydrated
HZSM-5 orthorhombic zeolite,Microporous,"Mesoporous Mater.71
(2004) 117.
[21] A.A. Bahgat, A. Al-Hajry, M.M. El-Desoky, "Giant extrinsic negative
thermal expansion in vanadiumpentoxidenanocrystalline films," Phys.
Status solidi (a), 203 (2006)1999.
[22] R..R. Heikes and R.W. Ure (Eds.), Thermoelectricity, Interscience, New
York, 1961.
[23] S. Benkara, S. Zerkout, H.Ghamri, "Synthesis of Sn doped
ZnO/TiO2 nanocomposite film and their application to H2 gas sensing
properties," Mater. Sci. Semi.Processing 16(2013) 1271.
[24] Y. Qin, G. Fan, K. Liu, M. Hu, "Vanadium pentoxide hierarchical
structure networks for high performance ethanol gas sensor with dual
working temperature characteristic," Sensors and Actuators B 190
(2014) 141.
[25] R. S. Gaikwad, G. R. Patil, B.N. Pawar, R.S. Maneb, S. Han, "Liquefied
petroleum gas sensing properties of sprayed nanocrystalline zinc oxide
thin films," Sensors and Actuators A 189 (2013) 339.