Abstract: Land Use Land Cover (LULC) changes due to human
activities and natural causes have become a major environmental
concern. Assessment of temporal remote sensing data provides
information about LULC impacts on environment. Land Surface
Temperature (LST) is one of the important components for modeling
environmental changes in climatological, hydrological, and
agricultural studies. In this study, LULC changes (September 7, 1984
and July 8, 2014) especially in agricultural lands together with
population changes (1985-2014) and LST status were investigated
using remotely sensed and census data in South Marmara Watershed,
Turkey. LULC changes were determined using Landsat TM and
Landsat OLI data acquired in 1984 and 2014 summers. Six-band TM
and OLI images were classified using supervised classification
method to prepare LULC map including five classes including Forest
(F), Grazing Land (G), Agricultural Land (A), Water Surface (W),
Residential Area-Bare Soil (R-B) classes. The LST image was also
derived from thermal bands of the same dates.
LULC classification results showed that forest areas, agricultural
lands, water surfaces and residential area-bare soils were increased as
65751 ha, 20163 ha, 1924 ha and 20462 ha respectively. In
comparison, a dramatic decrement occurred in grazing land (107985
ha) within three decades. The population increased 29% between
years 1984-2014 in whole study area. Along with the natural causes,
migration also caused this increase since the study area has an
important employment potential. LULC was transformed among the
classes due to the expansion in residential, commercial and industrial
areas as well as political decisions. In the study, results showed that
agricultural lands around the settlement areas transformed to
residential areas in 30 years.
The LST images showed that mean temperatures were ranged
between 26-32°C in 1984 and 27-33°C in 2014. Minimum
temperature of agricultural lands was increased 3°C and reached to
23°C. In contrast, maximum temperature of A class decreased to
41°C from 44°C. Considering temperatures of the 2014 R-B class and
1984 status of same areas, it was seen that mean, min and max
temperatures increased by 2°C.
As a result, the dynamism of population, LULC and LST resulted
in increasing mean and maximum surface temperatures, living
spaces/industrial areas and agricultural lands.
Abstract: In this paper, we investigated the athermal pressure
behavior of the structural and elastic properties of scheelite BaWO4
phase up to 7 GPa using the ab initio pseudo-potential method. The
calculated lattice parameters pressure relation have been compared
with the experimental values and found to be in good agreement with
these results. Moreover, we present for the first time the investigation
of the elastic properties of this compound using the density functional
perturbation theory (DFPT). It is shown that this phase is
mechanically stable up to 7 GPa after analyzing the calculated elastic
constants. Other relevant quantities such as bulk modulus, pressure
derivative of bulk modulus, shear modulus; Young’s modulus,
Poisson’s ratio, anisotropy factors, Debye temperature and sound
velocity have been calculated. The obtained results, which are
reported for the first time to the best of the author’s knowledge, can
facilitate assessment of possible applications of the title material.
Abstract: Experimental investigations of the DC electric field effect on thermal decomposition of biomass, formation of the axial flow of volatiles (CO, H2, CxHy), mixing of volatiles with swirling airflow at low swirl intensity (S ≈ 0.2-0.35), their ignition and on formation of combustion dynamics are carried out with the aim to understand the mechanism of electric field influence on biomass gasification, combustion of volatiles and heat energy production. The DC electric field effect on combustion dynamics was studied by varying the positive bias voltage of the central electrode from 0.6 kV to 3 kV, whereas the ion current was limited to 2 mA. The results of experimental investigations confirm the field-enhanced biomass gasification with enhanced release of volatiles and the development of endothermic processes at the primary stage of thermochemical conversion of biomass determining the field-enhanced heat energy consumption with the correlating decrease of the flame temperature and heat energy production at this stage of flame formation. Further, the field-enhanced radial expansion of the flame reaction zone correlates with a more complete combustion of volatiles increasing the combustion efficiency by 3% and decreasing the mass fraction of CO, H2 and CxHy in the products, whereas by 10% increases the average volume fraction of CO2 and the heat energy production downstream the combustor increases by 5-10%
Abstract: This paper presents a computational study of steady
state three dimensional very high turbulent flow and heat transfer
characteristics in a constant temperature-surfaced circular duct fitted
with 900 hemispherical inline baffles. The computations are based on
realizable k-ɛ model with standard wall function considering the
finite volume method, and the SIMPLE algorithm has been
implemented. Computational Study are carried out for Reynolds
number, Re ranging from 80000 to 120000, Prandtl Number, Pr of
0.73, Pitch Ratios, PR of 1,2,3,4,5 based on the hydraulic diameter of
the channel, hydrodynamic entry length, thermal entry length and the
test section. Ansys Fluent 15.0 software has been used to solve the
flow field. Study reveals that circular pipe having baffles has a higher
Nusselt number and friction factor compared to the smooth circular
pipe without baffles. Maximum Nusselt number and friction factor
are obtained for the PR=5 and PR=1 respectively. Nusselt number
increases while pitch ratio increases in the range of study; however,
friction factor also decreases up to PR 3 and after which it becomes
almost constant up to PR 5. Thermal enhancement factor increases
with increasing pitch ratio but with slightly decreasing Reynolds
number in the range of study and becomes almost constant at higher
Reynolds number. The computational results reveal that optimum
thermal enhancement factor of 900 inline hemispherical baffle is
about 1.23 for pitch ratio 5 at Reynolds number 120000.It also shows
that the optimum pitch ratio for which the baffles can be installed in
such very high turbulent flows should be 5. Results show that pitch
ratio and Reynolds number play an important role on both fluid flow
and heat transfer characteristics.
Abstract: Biodiesel as an alternative diesel fuel is steadily gaining more attention and significance. However, there are some drawbacks while using biodiesel regarding its properties that requires it to be blended with petrol based diesel and/or additives to improve the fuel characteristics. This study analyses thermal cracking as an alternative technology to improve biodiesel characteristics in which, FAME based biodiesel produced by transesterification of castor oil is fed into a continuous thermal cracking reactor at temperatures range of 450-500°C and flowrate range of 20-40 g/hr. Experiments designed by response surface methodology and subsequent statistical studies show that temperature and feed flowrate significantly affect the products yield. Response surfaces were used to study the impact of temperature and flowrate on the product properties. After each experiment, the produced crude bio-oil was distilled and diesel cut was separated. As shorter chain molecules are produced through thermal cracking, the distillation curve of the diesel cut fitted more with petrol based diesel curve in comparison to the biodiesel. Moreover, the produced diesel cut properties adequately pose within property ranges defined by the related standard of petrol based diesel. Cold flow properties, high heating value as the main drawbacks of the biodiesel are improved by this technology. Thermal cracking decreases kinematic viscosity, Flash point and cetane number.
Abstract: Based on an indoor environmental quality (IEQ) index established by previous work that indicates the overall IEQ acceptance from the prospect of an occupant in residential buildings in terms of four IEQ factors - thermal comfort, indoor air quality, visual and aural comforts, this study develops a user-friendly IEQ calculator for iOS and Android users to calculate the occupant acceptance and compare the relative performance of IEQ in apartments. “IEQ calculator” is easy to use and it preliminarily illustrates the overall indoor environmental quality on the spot. Users simply input indoor parameters such as temperature, number of people and windows are opened or closed for the mobile application to calculate the scores in four areas: the comforts of temperature, brightness, noise and indoor air quality. The calculator allows the prediction of the best IEQ scenario on a quantitative scale. Any indoor environments under the specific IEQ conditions can be benchmarked against the predicted IEQ acceptance range. This calculator can also suggest how to achieve the best IEQ acceptance among a group of residents.
Abstract: A dip-coating process has been used to form an
asymmetric silica membrane with improved membrane performance
and reproducibility. First, we deposited repeatedly silica on top of a
commercial alumina membrane support to improve its structural
make up. The membrane is further processed under clean room
conditions to avoid dust impurity and subsequent drying in an oven
for high thermal, chemical and physical stability. The resulting
asymmetric membrane exhibits a gradual change in the membrane
layer thickness. Compared to the support, the dual-layer process
improves the gas flow rates. For the scientific applications for natural
gas purification, CO2, CH4 and H2 gas flow rates were. In addition,
the membrane selectively separated hydrogen.
Abstract: It is the worldwide problem that the recycled PVB is
not recycled and it is wildly stored in landfills. However, PVB has
similar chemical properties such as PVC. Moreover, both of these
polymers are plasticized. Therefore, the study of thermal properties
of plasticized PVC and the recycled PVB obtained by recycling of
windshields is carried out. This work has done in order to find nondegradable
processing conditions applicable for both polymers.
Tested PVC contained 38% of plasticizer diisononyl phthalate
(DINP) and PVB was plasticized with 28% of triethylene glycol,
bis(2-ethylhexanoate) (3GO). The thermal and thermo-oxidative
decomposition of both vinyl polymers are compared by calorimetric
analysis and by tensile strength analysis.
Abstract: Bringing forth a survey on recent higher order spline
techniques for solving boundary value problems in ordinary
differential equations. Here we have discussed the summary of the
articles since 2000 till date based on higher order splines like Septic,
Octic, Nonic, Tenth, Eleventh, Twelfth and Thirteenth Degree
splines. Comparisons of methods with own critical comments as
remarks have been included.
Abstract: The novel 3D SnO cabbages self-assembled by
nanosheets were successfully synthesized via template-free
hydrothermal growth method under facile conditions. The XRD
results manifest that the as-prepared SnO is tetragonal phase. The
TEM and HRTEM results show that the cabbage nanosheets are
polycrystalline structure consisted of considerable single-crystalline
nanoparticles. Two typical Raman modes A1g=210 and Eg=112 cm-1
of SnO are observed by Raman spectroscopy. Moreover, galvanostatic
cycling tests has been performed using the SnO cabbages as anode
material of lithium ion battery and the electrochemical results suggest
that the synthesized SnO cabbage structures are a promising anode
material for lithium ion batteries.
Abstract: Atmospheric carbon dioxide emissions are considered
as the greatest environmental challenge the world is facing today.
The tasks to control the emissions include the recovery of CO2 from
flue gas. This concern has been improved due to recent advances in
materials process engineering resulting in the development of
inorganic gas separation membranes with excellent thermal and
mechanical stability required for most gas separations. This paper,
therefore, evaluates the performance of a highly selective inorganic
membrane for CO2 recovery applications. Analysis of results
obtained is in agreement with experimental literature data. Further
results show the prediction performance of the membranes for gas
separation and the future direction of research. The materials
selection and the membrane preparation techniques are discussed.
Method of improving the interface defects in the membrane and its
effect on the separation performance has also been reviewed and in
addition advances to totally exploit the potential usage of this
innovative membrane.
Abstract: Potassium borates, which are widely used in welding
and metal refining industry, as a lubricating oil additive, cement
additive, fiberglass additive and insulation compound, are one of the
important groups of borate minerals. In this study the production of a
potassium borate mineral via hydrothermal method is aimed. The
potassium source of potassium nitrate (KNO3) was used along with a
sodium source of sodium hydroxide (NaOH) and boron source of
boric acid (H3BO3). The constant parameters of reaction temperature
and reaction time were determined as 80°C and 1 h, respectively. The
molar ratios of 1:1:3 (as KNO3:NaOH:H3BO3), 1:1:4, 1:1:5, 1:1:6
and 1:1:7 were used. Following the synthesis the identifications of
the produced products were conducted by X-Ray Diffraction (XRD),
Fourier Transform Infrared Spectroscopy (FT-IR) and Raman
Spectroscopy. The results of the experiments and analysis showed in
the ratio of 1:1:6, the Santite mineral with powder diffraction file
number (pdf no.) of 01-072-1688, which is known as potassium
pentaborate (KB5O8·4H2O) was synthesized as best.
Abstract: The objective of this study is to conduct computational
fluid dynamic (CFD) simulations for evaluating the cooling efficacy
from vegetation implanted in a public park in the Taipei, Taiwan. To
probe the impacts of park renewal by means of adding three pavilions
and supplementary green areas on urban microclimates, the simulated
results have revealed that the park having a higher percentage of green
coverage ratio (GCR) tended to experience a better cooling effect.
These findings can be used to explore the effects of different greening
modifications on urban environments for achieving an effective
thermal comfort in urban public spaces.
Abstract: To understand the friction stir welding process, it is
very important to know the nature of the material flow in and around
the tool. The process is a combination of both thermal as well as
mechanical work i.e. it is a coupled thermo-mechanical process.
Numerical simulations are very much essential in order to obtain a
complete knowledge of the process as well as the physics underlying
it. In the present work a model based approach is adopted in order to
study material flow. A thermo-mechanical based CFD model is
developed using a Finite Element package, Comsol Multiphysics.
The fluid flow analysis is done. The model simultaneously predicts
shear strain fields, shear strain rates and shear stress over the entire
workpiece for the given conditions. The flow fields generated by the
streamline plot give an idea of the material flow. The variation of
dynamic viscosity, velocity field and shear strain fields with various
welding parameters is studied. Finally the result obtained from the
above mentioned conditions is discussed elaborately and concluded.
Abstract: This paper analyses the heat transfer performance and
fluid flow using different nanofluids in a square enclosure. The
energy equation and Navier-Stokes equation are solved numerically
using finite volume scheme. The effect of volume fraction
concentration on the enhancement of heat transfer has been studied
icorporating the Brownian motion; the influence of effective thermal
conductivity on the enhancement was also investigated for a range of
volume fraction concentration. The velocity profile for different
Rayleigh number. Water-Cu, water AL2O3 and water-TiO2 were
tested.
Abstract: The article presents a plasma chemical technology for
processing solid fuels, using examples of bituminous and brown
coals. Thermodynamic and experimental investigation of the
technology was made. The technology allows producing synthesis
gas from the coal organic mass and valuable components (technical
silicon, ferrosilicon, aluminum, and carbon silicon, as well as
microelements of rare metals, such as uranium, molybdenum,
vanadium, etc.) from the mineral mass. The thusly produced highcalorific
synthesis gas can be used for synthesis of methanol, as a
high-calorific reducing gas instead of blast-furnace coke as well as
power gas for thermal power plants.
Abstract: In the present study, the kinetics of thermal
degradation of a phenolic and lignin reinforced phenolic foams, and
the lignin used as reinforcement were studied and the activation
energies of their degradation processes were obtained by a DAEM
model. The average values for five heating rates of the mean
activation energies obtained were: 99.1, 128.2, and 144.0 kJ.mol-1 for
the phenolic foam; 109.5, 113.3, and 153.0 kJ.mol-1 for the lignin
reinforcement; and 82.1, 106.9, and 124.4 kJ.mol-1 for the lignin
reinforced phenolic foam. The standard deviation ranges calculated
for each sample were 1.27-8.85, 2.22-12.82, and 3.17-8.11 kJ.mol-1
for the phenolic foam, lignin and the reinforced foam, respectively.
The DAEM model showed low mean square errors (
Abstract: Non contact evaluation of the thickness of paint
coatings can be attempted by different destructive and nondestructive
methods such as cross-section microscopy, gravimetric mass
measurement, magnetic gauges, Eddy current, ultrasound or
terahertz. Infrared thermography is a nondestructive and non-invasive
method that can be envisaged as a useful tool to measure the surface
thickness variations by analyzing the temperature response. In this
paper, the thermal quadrupole method for two layered samples heated
up with a pulsed excitation is firstly used. By analyzing the thermal
responses as a function of thermal properties and thicknesses of both
layers, optimal parameters for the excitation source can be identified.
Simulations show that a pulsed excitation with duration of ten
milliseconds allows obtaining a substrate-independent thermal
response. Based on this result, an experimental setup consisting of a
near-infrared laser diode and an Infrared camera was next used to
evaluate the variation of paint coating thickness between 60 μm and
130 μm on two samples. Results show that the parameters extracted
for thermal images are correlated with the estimated thicknesses by
the Eddy current methods. The laser pulsed thermography is thus an
interesting alternative nondestructive method that can be moreover
used for nonconductive substrates.
Abstract: This study is about the structural transformations of
aluminium examining with the Dynamic Mechanical Thermal
Analyzer (DMTA). It is a faster and simpler measuring method to
make consequence about the metal’s structural transformations. The
device measures the changing of the mechanical characteristics
depending on the heating rate, and concludes certain transformations.
This measuring method fast and shows clean-cut results comparing
the conventional ways.
Applying polymer measuring devices for metal investigations is
not widespread method. One of the adaptable ways is shown in this
study. The article compares the results of the small specimen test and
the DMTA method, considering the temperature and the forming
dependence of recrystallization temperature.
Abstract: A chromium-loaded ash originating from incineration of tannery sludge under anoxic conditions was mixed with low grade soda-lime glass powder coming from commercial glass bottles. The relative weight proportions of ash over glass powder tested were 30/70, 40/60 and 50/50. The solid mixtures, formed in green state compacts, were sintered at the temperature range of 800o C up to 1200o C. The resulting products were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray spectrometry (EDXS) and micro-indentation. The above methods were employed to characterize the various phases, microstructure and hardness of the produced materials. Thermal treatment at 800o C and 1000o C produced opaque ceramic products composed of a variety of chromium-containing and chromium-free crystalline phases. Thermal treatment at 1200o C gave rise to composite products, where only chromium-containing crystalline phases were detected. Hardness results suggest that specific products are serious candidates for structural applications.