Abstract: A large amount of blast furnace slag is generated in
China. Most ground granulated blast furnace slag (GGBS) however
ends up in low-grade applications. Blast furnace slag, ground to an
appropriate fineness, can be used as a partial replacement of
cementitious material in concrete. The potential for using GGBS in
structural concrete, e.g. concrete beams and columns is investigated
at Xi’an Jiaotong-Liverpool University (XJTLU). With 50% of CEM
I cement replaced with GGBS, peak hydration temperatures
determined in a suspended concrete slab reduced by 20%. This
beneficiary effect has not been further improved with 70% of CEM I
replaced with GGBS. Partial replacement of CEM I with GGBS has a
retardation effect on the early-age strength of concrete. More GGBS
concrete mixes will be conducted to identify an ‘optimum’
replacement level which will lead to a reduced thermal loading,
without significantly compromising the early-age strength of
concrete.
Abstract: A numerical model has been developed to investigate the thermally triggered release kinetics for drug delivery using phase change material as shell of microcapsules. Biocompatible material n-Eicosane is used as demonstration. PCM shell of microcapsule will remain in solid form after the drug is taken, so the drug will be encapsulated by the shell, and will not be released until the target body part of lesion is exposed to external heat source, which will thermally trigger the release kinetics, leading to solid-to-liquid phase change. The findings can lead to better understanding on the key effects influencing the phase change process for drug delivery applications. The facile approach to release drug from core/shell structure of microcapsule can be well integrated with organic solvent free fabrication of microcapsules, using double emulsion as template in microfluidic aqueous two phase system.
Abstract: Hydrothermal liquefaction (HTL) is a technique for obtaining clean biofuel from biomass in the presence of heat and pressure in an aqueous medium which leads to a decomposition of this biomass to the formation of various products. A role of operating conditions is essential for the bio-oil and other products’ yield and also quality of the products. The effects of these parameters were investigated in regards to the composition and yield of the products. Chlorellaceae microalgae were tested under different HTL conditions to clarify suitable conditions for extracting bio-oil together with value-added co-products. Firstly, different microalgae loading rates (5-30%) were tested and found that this parameter has not much significant to product yield. Therefore, 10% microalgae loading rate was selected as a proper economical solution for conditioned schedule at 250oC and 30 min-reaction time. Next, a range of temperature (210-290oC) was applied to verify the effects of each parameter by keeping the reaction time constant at 30 min. The results showed no linkage with the increase of the reaction temperature and some reactions occurred that lead to different product yields. Moreover, some nutrients found in the aqueous product are possible to be utilized for nutrient recovery.
Abstract: The present work attempts to investigate the
combustion, performance and emission characteristics of an existing
single-cylinder four-stroke compression-ignition engine operated in
dual-fuel mode with hydrogen as an alternative fuel. Environmental
concerns and limited amount of petroleum fuels have caused interests
in the development of alternative fuels like hydrogen for internal
combustion (IC) engines. In this experimental investigation, a diesel
engine is made to run using hydrogen in dual fuel mode with diesel,
where hydrogen is introduced into the intake manifold using an LPGCNG
injector and pilot diesel is injected using diesel injectors. A
Timed Manifold Injection (TMI) system has been developed to vary
the injection strategies. The optimized timing for the injection of
hydrogen was 10^0 CA after top dead center (ATDC). From the study
it was observed that with increasing hydrogen rate, enhancement in
brake thermal efficiency (BTHE) of the engine has been observed
with reduction in brake specific energy consumption (BSEC).
Furthermore, Soot contents decrease with an increase in indicated
specific NOx emissions with the enhancement of hydrogen flow rate.
Abstract: A cold, thin film of liquid impinging on an isothermal
hot, horizontal surface has been investigated. An approximate
solution for the velocity and temperature distributions in the flow
along the horizontal surface is developed, which exploits the
hydrodynamic similarity solution for thin film flow. The approximate
solution may provide a valuable basis for assessing flow and heat
transfer in more complex settings.
Abstract: The thermal performance of a solar water heating with
1.00 m2 flat plate collectors in Cascavel - PR, is which presented in
this article, paper presents the solution to leverage the marketing of
solar heating systems through detailed constituent materials of the
solar collector studies, these abundant materials in construction, such
as expanded polyethylene, PVC, aluminum and glass tubes, mixing
them with new materials to minimize loss of efficiency while
decreasing its cost. The system was tested during months and the
collector obtained maximum recorded temperature of outlet fluid of
55°C, while the maximum temperature of the water at the bottom of
the hot water tank was 35°C. The average daily energy collected was
19.6 MJ/d; the energy supplied by the solar plate was 16.2 MJ/d; the
loss in the feed pipe was 3.2 MJ/d; the solar fraction was 32.2%, the
efficiency of the collector was 45.6% and the efficiency of the system
was 37.8%.
Abstract: This paper deals with the theoretical and numerical
investigation of magneto hydrodynamic boundary layer flow of a
nanofluid past a wedge shaped wick in heat pipe used for the cooling
of electronic components and different type of machines. To
incorporate the effect of nanoparticle diameter, concentration of
nanoparticles in the pure fluid, nanothermal layer formed around the
nanoparticle and Brownian motion of nanoparticles etc., appropriate
models are used for the effective thermal and physical properties of
nanofluids. To model the rotation of nanoparticles inside the base
fluid, microfluidics theory is used. In this investigation ethylene
glycol (EG) based nanofluids, are taken into account. The non-linear
equations governing the flow and heat transfer are solved by using a
very effective particle swarm optimization technique along with
Runge-Kutta method. The values of heat transfer coefficient are
found for different parameters involved in the formulation viz.
nanoparticle concentration, nanoparticle size, magnetic field and
wedge angle etc. It is found that, the wedge angle, presence of
magnetic field, nanoparticle size and nanoparticle concentration etc.
have prominent effects on fluid flow and heat transfer characteristics
for the considered configuration.
Abstract: By textile science incorporating with electronic
industry, developed textile products start to take part in different
areas such as industry, military, space, medical etc. for health,
protection, defense, communication and automation. Electronic
textiles (e-textiles) are fabrics that contain electronics and
interconnections with them. In this study, two types of base yarns
(cotton and acrylic) and three types of conductive steel yarns with
different linear resistance values (14Ω/m, 30Ω/m, 70Ω/m) were used
to investigate the effect of base yarn type and linear resistance of
conductive yarns on thermal behavior of e-textile structures. Thermal
behavior of samples was examined by thermal camera.
Abstract: This paper presents the design and fabrication of an
optical window for an optical modulator toward image sensing
applications. An optical window consists of micrometer-order SiO2
capillaries (porous solid) that can modulate transmission light
intensity by moving the liquid in and out of porous solid. A high
optical transmittance of the optical window can be achieved due to
refractive index matching when the liquid is penetrated into the
porous solid. Otherwise, its light transmittance is lower because of
light reflection and scattering by air holes and capillary walls. Silicon
capillaries fabricated by deep reactive ion etching (DRIE) process are
completely oxidized to form the SiO2 capillaries. Therefore, high
aspect ratio SiO2 capillaries can be achieved based on silicon
capillaries formed by DRIE technique. Large compressive stress of
the oxide causes bending of the capillary structure, which is reduced
by optimizing the design of device structure. The large stress of the
optical window can be released via thin supporting beams. A 7.2 mm
x 9.6 mm optical window area toward a fully integrated with the
image sensor format is successfully fabricated and its optical
transmittance is evaluated with and without inserting liquids (ethanol
and matching oil). The achieved modulation range is approximately
20% to 35% with and without liquid penetration in visible region
(wavelength range from 450 nm to 650 nm).
Abstract: Depositional environment and source potential of the
different organic-rich levels of Devonian age (up to 990m thick) from
the onshore EC-1 well (Southern Tunisia) were investigated based on
the analysis of more than 130 cutting samples by different
geochemical techniques (Rock-Eval pyrolysis, GC-MS). The
obtained results including Rock Eval Pyrolysis data and biomarker
distribution (terpanes, steranes and aromatics) have been used to
describe the depositional environment and to assess the thermal
maturity of the Devonian organic matter. These results show that the
Emsian deposits exhibit poor to fair TOC contents. The associated
organic matter is composed of mixed kerogen (type II/III), as
indicated by the predominance of C29 steranes over C27 and C28
homologous, that was deposited in a slightly reduced environment
favoring organic matter preservation. Thermal maturity assessed from
Tmax, TNR and MPI-1 values shows a mature stage of organic
matter. The Middle Devonian (Eifelian) shales are rich in type II
organic matter that was deposited in an open marine depositional
environment. The TOC values are high and vary between 2 and 7%
indicating good to excellent source rock. The relatively high HI
values (reaching 547 mg HC/g TOC) and the low values of t19/t23
tricyclic terpane ratio (< 0.2) confirm the marine origin of the organic
matter (type II). During the Upper Devonian, the organic matter was
deposited under variable redox conditions, oxic to suboxic which is
clearly indicated by the low C35/C34 hopanes ratio, immature to
marginally mature with the vitrinite reflectance ranging from 0.5 to
0.7 Ro and Tmax value of 426°C-436 °C and the TOC values range
between 0.8% to 4%.
Abstract: Problems insulation of building structures is often
closely connected with the problem of moisture remediation. In the
case of historic buildings or if only part of the redevelopment of
envelope of structures, it is not possible to apply the classical external
thermal insulation composite systems. This application is mostly
effective thermal insulation plasters with high porosity and controlled
capillary properties which assures improvement of thermal properties
construction, its diffusion openness towards the external environment
and suitable treatment capillary properties of preventing the
penetration of liquid moisture and salts thereof toward the outer
surface of the structure.
With respect to the current trend of reducing the energy
consumption of building structures and reduce the production of CO2
is necessary to develop capillary-active materials characterized by
their low density, low thermal conductivity while maintaining good
mechanical properties. The aim of researchers at the Faculty of Civil
Engineering, Brno University of Technology is the development and
study of hygrothermal behaviour of optimal materials for thermal
insulation and rehabilitation of building structures with the possible
use of alternative, less energy demanding binders in comparison with
conventional, frequently used binder, which represents cement.
The paper describes the evaluation of research activities aimed at
the development of thermal insulation and repair materials using
lightweight aggregate and alternative binders such as metakaolin and
finely ground fly ash.
Abstract: In this paper, we introduced a gradient-based inverse
solver to obtain the missing boundary conditions based on the
readings of internal thermocouples. The results show that the method
is very sensitive to measurement errors, and becomes unstable when
small time steps are used. The artificial neural networks are shown to
be capable of capturing the whole thermal history on the run-out
table, but are not very effective in restoring the detailed behavior of
the boundary conditions. Also, they behave poorly in nonlinear cases
and where the boundary condition profile is different.
GA and PSO are more effective in finding a detailed
representation of the time-varying boundary conditions, as well as in
nonlinear cases. However, their convergence takes longer. A
variation of the basic PSO, called CRPSO, showed the best
performance among the three versions. Also, PSO proved to be
effective in handling noisy data, especially when its performance
parameters were tuned. An increase in the self-confidence parameter
was also found to be effective, as it increased the global search
capabilities of the algorithm. RPSO was the most effective variation
in dealing with noise, closely followed by CRPSO. The latter
variation is recommended for inverse heat conduction problems, as it
combines the efficiency and effectiveness required by these
problems.
Abstract: Incineration of municipal solid waste (MSW) is one of
the key scopes in the global clean energy strategy. A computational
fluid dynamics (CFD) model was established in order to reveal these
features of the combustion process in a fixed porous bed of MSW.
Transporting equations and process rate equations of the waste bed
were modeled and set up to describe the incineration process,
according to the local thermal conditions and waste property
characters. Gas phase turbulence was modeled using k-ε turbulent
model and the particle phase was modeled using the kinetic theory of
granular flow. The heterogeneous reaction rates were determined
using Arrhenius eddy dissipation and the Arrhenius-diffusion
reaction rates. The effects of primary air flow rate and temperature in
the burning process of simulated MSW are investigated
experimentally and numerically. The simulation results in bed are
accordant with experimental data well. The model provides detailed
information on burning processes in the fixed bed, which is otherwise
very difficult to obtain by conventional experimental techniques.
Abstract: Parabolic solar trough systems have seen limited
deployments in cold northern climates as they are more suitable for
electricity production in southern latitudes. A numerical dynamic
model is developed to simulate troughs installed in cold climates and
validated using a parabolic solar trough facility in Winnipeg. The
model is developed in Simulink and will be utilized to simulate a trigeneration
system for heating, cooling and electricity generation in
remote northern communities. The main objective of this simulation
is to obtain operational data of solar troughs in cold climates and use
the model to determine ways to improve the economics and address
cold weather issues.
In this paper the validated Simulink model is applied to simulate a
solar assisted absorption cooling system along with electricity
generation using Organic Rankine Cycle (ORC) and thermal storage.
A control strategy is employed to distribute the heated oil from solar
collectors among the above three systems considering the
temperature requirements. This modelling provides dynamic
performance results using measured meteorological data recorded
every minute at the solar facility location. The purpose of this
modeling approach is to accurately predict system performance at
each time step considering the solar radiation fluctuations due to
passing clouds. Optimization of the controller in cold temperatures is
another goal of the simulation to for example minimize heat losses in
winter when energy demand is high and solar resources are low.
The solar absorption cooling is modeled to use the generated heat
from the solar trough system and provide cooling in summer for a
greenhouse which is located next to the solar field.
The results of the simulation are presented for a summer day in
Winnipeg which includes comparison of performance parameters of
the absorption cooling and ORC systems at different heat transfer
fluid (HTF) temperatures.
Abstract: The development of active and stable catalysts
without noble metals for low temperature oxidation of exhaust gases
remains a significant challenge. The purpose of this study is to
determine the influence of the preparation method on the catalytic
activity of the supported copper-manganese mixed oxides in terms of
VOCs oxidation. The catalysts were prepared by impregnation of γ-
Al2O3 with copper and manganese nitrates and acetates and the
possibilities for CO, CH3OH and dimethyl ether (DME) oxidation
were evaluated using continuous flow equipment with a four-channel
isothermal stainless steel reactor. Effect of the support, Cu/Mn mole
ratio, heat treatment of the precursor and active component loading
were investigated. Highly active alumina supported Cu-Mn catalysts
for CO and VOCs oxidation were synthesized. The effect of
preparation conditions on the activity behavior of the catalysts was
discussed.
The synergetic interaction between copper and manganese species
increases the activity for complete oxidation over mixed catalysts.
Type of support, calcination temperature and active component
loading along with catalyst composition are important factors,
determining catalytic activity. Cu/Mn molar ratio of 1:5, heat
treatment at 450oC and 20 % active component loading are the best
compromise for production of active catalyst for simultaneous
combustion of CO, CH3OH and DME.
Abstract: The formulated problem of optimization of the
technological process of water treatment for thermal power plants is
considered in this article. The problem is of multiparametric nature.
To optimize the process, namely, reduce the amount of waste water, a
new technology was developed to reuse such water. A mathematical
model of the technology of wastewater reuse was developed.
Optimization parameters were determined. The model consists of a
material balance equation, an equation describing the kinetics of ion
exchange for the non-equilibrium case and an equation for the ion
exchange isotherm. The material balance equation includes a
nonlinear term that depends on the kinetics of ion exchange. A direct
problem of calculating the impurity concentration at the outlet of the
water treatment plant was numerically solved. The direct problem
was approximated by an implicit point-to-point computation
difference scheme. The inverse problem was formulated as relates to
determination of the parameters of the mathematical model of the
water treatment plant operating in non-equilibrium conditions. The
formulated inverse problem was solved. Following the results of
calculation the time of start of the filter regeneration process was
determined, as well as the period of regeneration process and the
amount of regeneration and wash water. Multi-parameter
optimization of water treatment process for thermal power plants
allowed decreasing the amount of wastewater by 15%.
Abstract: Considering palm oil as non-drying oil owing to its
low iodine value, an attempt was taken to increase the unsaturation in
the fatty acid chains of palm oil for the preparation of alkyds. To
increase the unsaturation in the palm oil, sulphuric acid (SA) and
para-toluene sulphonic acid (PTSA) was used prior to alcoholysis for
the dehydration process. The iodine number of the oil samples was
checked for the unsaturation measurement by Wijs method. Alkyd
resin was prepared using the dehydrated palm oil by following
alcoholysis and esterification reaction. To improve the film properties
0.5wt.% multi-wall carbon nano tubes (MWCNTs) were used to
manufacture polymeric film. The properties of the resins were
characterized by various physico-chemical properties such as density,
viscosity, iodine value, saponification value, etc. Structural
elucidation was confirmed by Fourier transform of infrared
spectroscopy and proton nuclear magnetic resonance; surfaces of the
films were examined by field-emission scanning electron microscope.
In addition, pencil hardness and chemical resistivity was also
measured by using standard methods. The effect of enhancement of
the unsaturation in the fatty acid chain found significant and
motivational. The resin prepared with dehydrated palm oil showed
improved properties regarding hardness and chemical resistivity
testing. The incorporation of MWCNTs enhanced the thermal
stability and hardness of the films as well.
Abstract: The paper presents a thermodynamic cycle analysis
for three turboshaft engines. The first cycle is a Brayton cycle,
describing the evolution of a classical turboshaft, based on the
Klimov TV2 engine. The other four cycles aim at approaching an
Ericsson cycle, by replacing the Brayton cycle adiabatic expansion in
the turbine by quasi-isothermal expansion. The maximum quasi-
Ericsson cycles temperature is set to a lower value than the maximum
Brayton cycle temperature, equal to the Brayton cycle power turbine
inlet temperature, in order to decrease the engine NOx emissions.
Also, the power/expansion ratio distribution over the stages of the gas
generator turbine is maintained the same. In two of the considered
quasi-Ericsson cycles, the efficiencies of the gas generator turbine, as
well as the power/expansion ratio distribution over the stages of the
gas generator turbine are maintained the same as for the reference
case, while for the other two cases, the efficiencies are increased in
order to obtain the same shaft power as in the reference case. For the
two cases respecting the first condition, both the shaft power and the
thermodynamic efficiency of the engine decrease, while for the other
two, the power and efficiency are maintained, as a result of assuming
new, more efficient gas generator turbines.
Abstract: Interaction of Schiff base complexes of Iron and
Manganese: Iron [N, N’ Bis (5- (triphenyl phosphonium methyl)
salicylidene) -1, 2 ethanediamine) chloride, [Fe Salen]Cl; Manganese
[N, N’ Bis (5- (triphenyl phosphonium methyl) salicylidene) -1, 2
ethanediamine) acetate, were investigated by spectroscopic and
isothermal titration calorimetry techniques (ITC).
The absorbance spectra of complexes have shown hyper and
hypochromism in the presence of DNA that is indication of
interaction of complexes with DNA. The linear dichroism (LD)
measurements confirmed the bending of DNA in the presence of
complexes.
Furthermore, Isothermal titration calorimetry experiments
approved that complexes bound to DNA on the base of both
electrostatic and hydrophobic interactions. More, ITC profile exhibits
the existence of two binding phases for the complexes. Antibacterial
activity of ligand and complexes were tested in vitro to evaluate their
activity against the gram positive and negative bacteria.
Abstract: The thermal control in many systems is widely
accomplished applying mixed convection process due to its low cost,
reliability and easy maintenance. Typical applications include the
aircraft electronic equipment, rotating-disc heat exchangers, turbo
machinery, and nuclear reactors, etc. Natural convection in an inclined
square enclosure heated via wall heater has been studied numerically.
Finite volume method is used for solving momentum and energy
equations in the form of stream function–vorticity. The right and left
walls are kept at a constant temperature, while the other parts are
adiabatic. The range of the inclination angle covers a whole revolution.
The method is validated for a vertical cavity. A general power law
dependence of the Nusselt number with respect to the Rayleigh
number with the coefficient and exponent as functions of the
inclination angle is presented. For a fixed Rayleigh number, the
inclination angle increases or decreases is found.