Abstract: It is the worldwide problem that the recycled PVB is
not recycled and it is wildly stored in landfills. However, PVB has
similar chemical properties such as PVC. Moreover, both of these
polymers are plasticized. Therefore, the study of thermal properties
of plasticized PVC and the recycled PVB obtained by recycling of
windshields is carried out. This work has done in order to find nondegradable
processing conditions applicable for both polymers.
Tested PVC contained 38% of plasticizer diisononyl phthalate
(DINP) and PVB was plasticized with 28% of triethylene glycol,
bis(2-ethylhexanoate) (3GO). The thermal and thermo-oxidative
decomposition of both vinyl polymers are compared by calorimetric
analysis and by tensile strength analysis.
Abstract: The mechanical properties of blends consisting of
plasticized poly(vinyl butyral) (PVB) and plasticized poly(vinyl
chloride) (PVC) are studied, in order to evaluate the possibility of
using recycled PVB waste derived from windshields. PVC was
plasticized with 38% of diisononyl phthalate (DINP), while PVB was
plasticized with 28% of triethylene glycol, bis(2-ethylhexanoate)
(3GO). The optimal process conditions for the PVB/PVC blend in 1:1
ratio were determined. Entropy was used in order to theoretically
predict the blends miscibility. The PVB content of each blend
composition used was ranging from zero to 100%. Tensile strength
and strain were tested. In addition, a comparison between recycled
and original PVB, used as constituents of the blend, was performed.