Mechanical Properties of Recycled Plasticized PVB/PVC Blends
The mechanical properties of blends consisting of
plasticized poly(vinyl butyral) (PVB) and plasticized poly(vinyl
chloride) (PVC) are studied, in order to evaluate the possibility of
using recycled PVB waste derived from windshields. PVC was
plasticized with 38% of diisononyl phthalate (DINP), while PVB was
plasticized with 28% of triethylene glycol, bis(2-ethylhexanoate)
(3GO). The optimal process conditions for the PVB/PVC blend in 1:1
ratio were determined. Entropy was used in order to theoretically
predict the blends miscibility. The PVB content of each blend
composition used was ranging from zero to 100%. Tensile strength
and strain were tested. In addition, a comparison between recycled
and original PVB, used as constituents of the blend, was performed.
[1] I.V. Ivanov, "Analysis, modeling, and optimization of laminated lasses
as plane beam”, Inter Jour Solid and Structures, vol. 43, pp. 6887-6907,
2006.
[2] U. Keller, H. Mortelmans,"Adhesion in laminated safety glass–what
makes it work”, Glass Processing Days 8, pp. 353-356, June 1999
[3] D. Merinska, M. Tupy, V. Kasparkova,” Degradation of plasticized PVB
during reprocessing by kneading”, Macrom Symposia, vol 286, pp. 107-
115, 2009.
[4] R. Iwasaki, C. Sato, "The influence of strain rate on the interfacial
fracture toughness between PVB and laminated glass”, JourPhys IV, vol
134, pp. 1153-1158, 2006
[5] M. Tupy, D. Merinska, P. Svoboda,"Effect of Water and Acid–Base
Reactants on Adhesive Properties of Various Plasticized Poly(vinyl
butyral) Sheets”, JourApplPolymSci, vol. 127, issue 5,pp. 3474-3484,
2013
[6] J. Svoboda, M. Balazs, J. Sedlar, ”Industry glass, Glass union concern:
Research and developing institute of industrial glass in Teplice, vol. C,
issue 1, 1988
[7] IOCA, The International Organization of Motor Vehicle Manufacturers,
Displayed in: http://www.oica.net/category/production-statistics/, 2010
[8] M. Tupy, P. Mokrejs, D. Merinska, P. Svoboda, J. Zvonicek,
"Windshield recycling focused on effective separation of PVB sheet”,
JourApplPolymSci, vol. 131, issue 4, article in press
[9] A.K. Dhaliwal, J.N. Hay, "The characterization of poly(vinyl butyral) by
thermal analysis’’, JourThermochemacta, vol. 391, pp. 245-255, 2002
[10] M. Tupy, D. Merinska, P. Svoboda, J. Zvonicek, "Influence of water and
magnesium ion on the optical properties in various plasticized poly(vinyl
butyral) sheets”, JourApplPolymSci, vol. 118, pp. 2100-2008, 2010
[11] A. Bendaoud, Ch. Carrot, J. Charbonnier, C. Pillon, "Blends of
Plasticized Polyvinyl Butyral and Polyvinyl Chloride: Morphology
Analysis in View of Recycling, Macromol Symp Eng, vol. 298, pp.
1259-1268, 2013
[12] B. Papenfuhs, M. Steuer, "Plasticizer-containing polyvinylbutyrals,
method for producing the same and the use thereof, especially for
producing films for use in laminated safety glasses”, US Patent
6,984,679, Dec 22, 2001
[13] B.E. Wade, J.J. D'errico, H.M. Thompson, M.K. Yu, "Polymer sheets
and methods of controlling adhesion of polymer sheets to glass”, US
Patent Application US 20050208315, Mar 16, 2004
[14] M. Tupy, D. Merinska, V. Kasparkova, PVB sheet Recycling and
Degradation, Recycling / Book 1, 1st ed. Rieka: Intech, 2012, ch. 5.
[15] PVC molecular weight correlations, Displayed in:
http://www.resintek.com/PVC%20Molecular%20Weight%20Conversio
n%20Chart.pdf, 2014
[16] J. Burke, Hansen Solubility Parameters: Theory and Application,
Displayed in: http://www.cool.conservation-us.org/byauth/burke/solpar/
solpar6.html , 2014
[1] I.V. Ivanov, "Analysis, modeling, and optimization of laminated lasses
as plane beam”, Inter Jour Solid and Structures, vol. 43, pp. 6887-6907,
2006.
[2] U. Keller, H. Mortelmans,"Adhesion in laminated safety glass–what
makes it work”, Glass Processing Days 8, pp. 353-356, June 1999
[3] D. Merinska, M. Tupy, V. Kasparkova,” Degradation of plasticized PVB
during reprocessing by kneading”, Macrom Symposia, vol 286, pp. 107-
115, 2009.
[4] R. Iwasaki, C. Sato, "The influence of strain rate on the interfacial
fracture toughness between PVB and laminated glass”, JourPhys IV, vol
134, pp. 1153-1158, 2006
[5] M. Tupy, D. Merinska, P. Svoboda,"Effect of Water and Acid–Base
Reactants on Adhesive Properties of Various Plasticized Poly(vinyl
butyral) Sheets”, JourApplPolymSci, vol. 127, issue 5,pp. 3474-3484,
2013
[6] J. Svoboda, M. Balazs, J. Sedlar, ”Industry glass, Glass union concern:
Research and developing institute of industrial glass in Teplice, vol. C,
issue 1, 1988
[7] IOCA, The International Organization of Motor Vehicle Manufacturers,
Displayed in: http://www.oica.net/category/production-statistics/, 2010
[8] M. Tupy, P. Mokrejs, D. Merinska, P. Svoboda, J. Zvonicek,
"Windshield recycling focused on effective separation of PVB sheet”,
JourApplPolymSci, vol. 131, issue 4, article in press
[9] A.K. Dhaliwal, J.N. Hay, "The characterization of poly(vinyl butyral) by
thermal analysis’’, JourThermochemacta, vol. 391, pp. 245-255, 2002
[10] M. Tupy, D. Merinska, P. Svoboda, J. Zvonicek, "Influence of water and
magnesium ion on the optical properties in various plasticized poly(vinyl
butyral) sheets”, JourApplPolymSci, vol. 118, pp. 2100-2008, 2010
[11] A. Bendaoud, Ch. Carrot, J. Charbonnier, C. Pillon, "Blends of
Plasticized Polyvinyl Butyral and Polyvinyl Chloride: Morphology
Analysis in View of Recycling, Macromol Symp Eng, vol. 298, pp.
1259-1268, 2013
[12] B. Papenfuhs, M. Steuer, "Plasticizer-containing polyvinylbutyrals,
method for producing the same and the use thereof, especially for
producing films for use in laminated safety glasses”, US Patent
6,984,679, Dec 22, 2001
[13] B.E. Wade, J.J. D'errico, H.M. Thompson, M.K. Yu, "Polymer sheets
and methods of controlling adhesion of polymer sheets to glass”, US
Patent Application US 20050208315, Mar 16, 2004
[14] M. Tupy, D. Merinska, V. Kasparkova, PVB sheet Recycling and
Degradation, Recycling / Book 1, 1st ed. Rieka: Intech, 2012, ch. 5.
[15] PVC molecular weight correlations, Displayed in:
http://www.resintek.com/PVC%20Molecular%20Weight%20Conversio
n%20Chart.pdf, 2014
[16] J. Burke, Hansen Solubility Parameters: Theory and Application,
Displayed in: http://www.cool.conservation-us.org/byauth/burke/solpar/
solpar6.html , 2014
@article{"International Journal of Architectural, Civil and Construction Sciences:54438", author = "Michael Tupý and Dagmar Měřínská and Alice Tesaříková-Svobodová and Christian Carrot and Caroline Pillon and Vít Petránek", title = "Mechanical Properties of Recycled Plasticized PVB/PVC Blends", abstract = "The mechanical properties of blends consisting of
plasticized poly(vinyl butyral) (PVB) and plasticized poly(vinyl
chloride) (PVC) are studied, in order to evaluate the possibility of
using recycled PVB waste derived from windshields. PVC was
plasticized with 38% of diisononyl phthalate (DINP), while PVB was
plasticized with 28% of triethylene glycol, bis(2-ethylhexanoate)
(3GO). The optimal process conditions for the PVB/PVC blend in 1:1
ratio were determined. Entropy was used in order to theoretically
predict the blends miscibility. The PVB content of each blend
composition used was ranging from zero to 100%. Tensile strength
and strain were tested. In addition, a comparison between recycled
and original PVB, used as constituents of the blend, was performed.
", keywords = "Poly(vinyl butyral), poly(vinyl chloride), windshield,
polymer waste, mechanical properties.", volume = "8", number = "9", pages = "955-6", }
