Abstract: The paper is focused on testing of the poly(vinyl butyral) (PVB) layer which had the function of a CO2 insulating protection against concrete and mortar carbonation. The barrier efficiency of PVB was verified by the measurement of diffusion characteristics. Two different types of PVB were tested; original extruded PVB sheet and PVB sheet made from PVB dispersion which was obtained from recycled windshields. The work deals with the testing CO2 diffusion when polymer sheets were exposed to a CO2 atmosphere (10% v/v CO2) with 0% RH. The excellent barrier capability against CO2 permeability of original and also recycled types of PVB layers was observed. This application of PVB waste can bring advantageous use in civil engineering and significant environmental contribution.
Abstract: The mechanical properties of blends consisting of
plasticized poly(vinyl butyral) (PVB) and plasticized poly(vinyl
chloride) (PVC) are studied, in order to evaluate the possibility of
using recycled PVB waste derived from windshields. PVC was
plasticized with 38% of diisononyl phthalate (DINP), while PVB was
plasticized with 28% of triethylene glycol, bis(2-ethylhexanoate)
(3GO). The optimal process conditions for the PVB/PVC blend in 1:1
ratio were determined. Entropy was used in order to theoretically
predict the blends miscibility. The PVB content of each blend
composition used was ranging from zero to 100%. Tensile strength
and strain were tested. In addition, a comparison between recycled
and original PVB, used as constituents of the blend, was performed.