Abstract: In the past many uneconomic solutions for limitation
and interruption of short-circuit currents in low power applications
have been introduced, especially polymer switch based on the
positive temperature coefficient of resistance (PCTR) concept.
However there are many limitations in the active material, which
consists of conductive fillers. This paper presents a significantly
improved and simplified approach that replaces the existing current
limiters with faster switching elements. Its elegance lies in the
remarkable simplicity and low-cost processes of producing the device
using polyaniline (PANI) doped with methane-sulfonic acid (MSA).
Samples characterized as lying in the metallic and critical regimes of
metal insulator transition have been studied by means of electrical
performance in the voltage range from 1V to 5 V under different
environmental conditions. Moisture presence is shown to increase the
resistivity and also improved its current limiting performance.
Additionally, the device has also been studied for electrical resistivity
in the temperature range 77 K-300 K. The temperature dependence of
the electrical conductivity gives evidence for a transport mechanism
based on variable range hopping in three dimensions.
Abstract: Perturbed-Chain Statistical Association Fluid Theory (PC-SAFT) equation of state (EOS) is a modified SAFT EOS with three pure component specific parameters: segment number (m), diameter (σ) and energy (ε). These PC-SAFT parameters need to be determined for each component under the conditions of interest by fitting experimental data, such as vapor pressure, density or heat capacity. PC-SAFT parameters for propane, ethylene and hydrogen in supercritical region were successfully estimated by fitting experimental density data available in literature. The regressed PCSAFT parameters were compared with the literature values by means of estimating pure component density and calculating average absolute deviation between the estimated and experimental density values. PC-SAFT parameters available in literature especially for ethylene and hydrogen estimated density in supercritical region reasonably well. However, the regressed PC-SAFT parameters performed better in supercritical region than the PC-SAFT parameters from literature.
Abstract: A mathematical model of the surface roughness
has been developed by using response surface methodology
(RSM) in grinding of AISI D2 cold work tool steels. Analysis
of variance (ANOVA) was used to check the validity of the
model. Low and high value for work speed and feed rate are
decided from design of experiment. The influences of all
machining parameters on surface roughness have been
analyzed based on the developed mathematical model. The
developed prediction equation shows that both the feed rate
and work speed are the most important factor that influences
the surface roughness. The surface roughness was found to be
the lowers with the used of low feed rate and low work speed.
Accuracy of the best model was proved with the testing data.
Abstract: In this study, hydroxyapatite (HA) composites are
prepared on addition of 30%CaO-30%P2O5-40%Na2 O based glass to
pure HA, in proportion of 2, 5, and 10 wt %. Each composition was
sintered over a range of temperatures. The quantitative phase
analysis was carried out using XRD and the microstructures were
studied using SEM. The density, microhardness, and compressive
strength have shown increase with the increasing amount of glass
addition. The resulting composites have chemical compositions that
are similar to the inorganic constituent of the mineral part of bone,
and constitutes trace elements like Na. X-ray diffraction showed no
decomposition of HA to secondary phases, however, the glass
reinforced-HA composites contained a HA phase and variable
amounts of tricalcium phosphate phase, depending on the amount of
bioglass added. The HA-composite material exhibited higher
compressive strength compared to sintered HA. The HA composite
reinforced with 10 wt % bioglass showed highest bioactivity level.
Abstract: In this research sodium bicarbonate (NaHCO3) was introduced to generate carbon dioxide gas (CO2) to the existing nitrogen gas (N2) of elastomeric foam, to lower thermal conductivity (K). Various loadings of NaHCO3 (0 to 60 phr) were added into the azodicarbonamide (AZC)-containing compound and its properties were then determined. Two vulcanization methods, i.e., hot air and infrared (IR), were employed and compared in this study. Results revealed that compound viscosity tended to increase slightly with increasing NaHCO3 content but cure time was delayed. The effect of NaHCO3 content on thermal conductivity depended on the vulcanization method. For hot air method, the thermal conductivity was insignificantly changed with increasing NaHCO3 up to 40 phr whereas it tended to decrease gradually for IR method. At higher NaHCO3 content (60 phr), unexpected increase of thermal conductivity was observed. The water absorption was also determined and foam structures were then used to explain the results.
Abstract: Commercial hydroxyapatite (HA) was reinforced by
adding 2, 5, and 10 wt % of 28.5%CaO-28.5%P2O5-38%Na2 O-
5%CaF2 based glass and then sintered. Although HA shows good
biocompatibility with the human body, its applications are limited to
non load-bearing areas and coatings due to its poor mechanical
properties. These mechanical properties can be improved
substantially with addition of glass ceramics by sintering. In this
study, the effects of sintering hydroxyapatite with above specified
phosphate glass additions are quantified. Each composition was
sintered over a range of temperatures. Scanning electron microscopy
and x-ray diffraction were used to characterize the microstructure and
phases of the composites. The density, microhardness, and
compressive strength were measured using Archimedes Principle,
Vickers Microhardness Tester (at 0.98 N), and Instron Universal
Testing Machine (cross speed of 0.5 mm/min) respectively. These
results were used to indicate which composition provided suitable
material for use in hard tissue replacement. Composites containing 10
wt % glass additions formed dense HA/TCP (tricalcium phosphate)
composite materials possessing good compressive strength and
hardness than HA. In-vitro bioactivity was assessed by evaluating
changes in pH and Ca2+ ion concentration of SBF-simulated body
fluid on immersion of these composites in it for two weeks.
Abstract: The effect of chemical treatment in CdCl2 and thermal
annealing in 400°C, on the defect structures of potentially useful
ZnS\CdS solar cell thin films deposited onto quartz substrate and
prepared by vacuum deposition method was studied using the
Thermoluminesence (TL) techniques. A series of electron and hole
traps are found in the various deposited samples studied. After
annealing, however, it was observed that the intensity and activation
energy of TL signal increases with loss of the low temperature
electron traps.
Abstract: In present study, two kinds of thermal power plant ashes; one the fly ash and the other waste ash are mixed with adhesive tragacanth and cement to produce new composite materials. 48 new samples are produced by varying the percentages of the fly ash, waste ash, cement and tragacanth. The new samples are subjected to some tests to find out their properties such as thermal conductivity, compressive strength, tensile strength and sucking capability of water. It is found that; the thermal conductivity decreases with increasing amount of tragacanth in the mixture. The compressive, tensile strength increases when the rate of tragacanth is up to 1%, whilst as the amount of tragacanth increases up to 1.5%, the compressive, tensile strength decreases slightly. The rate of water absorption of samples was more than 30%. From this result, it is concluded that these materials can not be used as external plaster or internal plaster material that faces to water. They can be used in internal plaster unless touching water and they can be used as cover plaster under roof and riprap material in sandwich panels. It is also found that, these materials can be cut with saw, drilled with screw and painted with any kind of paint.
Abstract: Titanium oxide hollow microspheres were synthesized from organic precursor titanium tetraisopropoxide (TTIP) using continuous spray pyrolysis reactor. Effects of precursor concentration, applied voltage and annealing have been investigated. It was observed that the annealing of the as-synthesized TiO2 hollow microspheres at 2500C, which had an average external diameter of 200 nm, leads to an increase in the size and also more spherical shape. The precursor concentration was found to have a direct impact on the size of the microspheres, which is also evident in the absorption spectrum. The as-prepared TiO2 hollow microspheres exhibited good photocatalytic activity for the degradation of MO.
Abstract: The photoluminescence (PL) at 1.55 μm from
semiconducting β-FeSi2 has attracted a noticeable interest for
silicon-based optoelectronic applications. Moreover, its high optical
absorption coefficient (higher than 105 cm-1 above 1.0 eV) allows this
semiconducting material to be used as photovoltanics devices.
A clear PL spectrum for β-FeSi2 was observed by Cu or Au coating
on Si(001). High-crystal-quality β-FeSi2 with a low-level nonradiative
center was formed on a Cu- or Au- reated Si layer. This method of
deposition can be applied to other materials requiring high crystal
quality.
Abstract: Exploding concentrated underwater charges to
damage underwater structures such as ship hulls is a part of naval
warfare strategies. Adding small amounts of foreign particles (like
clay or silica) of nanosize significantly improves the engineering
properties of the polymers. In the present work the clay in terms 1, 2
and 3 percent by weight was surface treated with a suitable silane
agent. The hybrid nanocomposite was prepared by the hand lay-up
technique. Mathematical regression models have been employed for
theoretical prediction. This will result in considerable savings in terms of project time, effort and cost.
Abstract: Polymers are one of the most widely used materials in our every day life. The subject of renewable resources has attracted great attention in the last period of time. New polymeric materials derived from renewable resources, like carbohydrates draw attention to public eye especially because of their biocompatibility and biodegradability. The aim of our paper was to obtain environmentally compatible polymers from monosaccharides. Novel glycopolymers based on D-glucose have been obtained from copolymerization of a new monomer carrying carbohydrate moiety with methyl methacrylate (MMA) via free radical bulk polymerization. Differential scanning calorimetry (DSC) was performed in order to study the copolymerization process of the monomer into the chosen co-monomer; the activation energy of this process was evaluated using Ozawa method. The copolymers obtained were characterized using ATR-FTIR spectroscopy. The thermal stability of the obtained products was studied by thermogravimetry (TG).
Abstract: Fabrication and efficiency enhancement of non-mercury, high efficiency and green field emission lamps using carbon nano-materials such as carbon nanotubes as cathode field emitters was studied. Phosphor was coated on the ITO glass or metal substrates as the anode. The luminescence efficiency enhancement was carried out by upgrading the uniform of the emitters, improving electron and thermal conductivity of the phosphor and the optimization of the design of different cathode/anode configurations. After evaluation of the aforementioned parameters, the luminescence efficiency of the field emission lamps was raised.
Abstract: Combined experimental and computational analysis of
hygrothermal performance of an interior thermal insulation system
applied on a brick wall is presented in the paper. In the experimental
part, the functionality of the insulation system is tested at simulated
difference climate conditions using a semi-scale device. The
measured temperature and relative humidity profiles are used for the
calibration of computer code HEMOT that is finally applied for a
long-term hygrothermal analysis of the investigated structure.
Abstract: Lanthanum oxide is to be recovered from monazite,
which contains about 13.44% lanthanum oxide. The principal
objective of this study is to be able to extract lanthanum oxide from
monazite of Moemeik Myitsone Area. The treatment of monazite in
this study involves three main steps; extraction of lanthanum
hydroxide from monazite by using caustic soda, digestion with nitric
acid and precipitation with ammonium hydroxide and calcination of
lanthanum oxalate to lanthanum oxide.
Abstract: Compacted clay liners (CCLs) are the main materials
used in waste disposal landfills due to their low permeability. In this
study, the effect on the shear resistant of clays with inorganic salt
solutions as permeate fluid was experimentally investigated. For this
purpose, NaCl inorganic salt solution at concentrations of 2, 5, 10%
and deionized water were used. Laboratory direct shear and Vane
shear tests were conducted on three compacted clays with low,
medium and high plasticity. Results indicated that the solutions type
and its concentration affect the shear properties of the mixture. In the
light of this study, the influence magnitude of these inorganic salts in
varies concentrations in different clays were determined and more
suitable compacted clay with the compare of plasticity were found.
Abstract: In this study, an ablation, mechanical and thermal properties of a rocket motor insulation from phenolic/ fiber matrix composites forming a laminate with different fiber between fiberglass and locally available synthetic fibers. The phenolic/ fiber matrix composites was mechanics and thermal properties by means of tensile strength, ablation, TGA and DSC. The design of thermal insulation involves several factors.Determined the mechanical properties according to MIL-I-24768: Density >1.3 g/cm3, Tensile strength >103 MPa and Ablation
Abstract: Localized surface plasmon resonance (LSPR) is the
coherent oscillation of conductive electrons confined in noble
metallic nanoparticles excited by electromagnetic radiation, and
nanosphere lithography (NSL) is one of the cost-effective methods to
fabricate metal nanostructures for LSPR. NSL can be categorized
into two major groups: dispersed NSL and closely pack NSL. In
recent years, gold nanocrescents and gold nanoholes with vertical
sidewalls fabricated by dispersed NSL, and silver nanotriangles and
gold nanocaps on silica nanospheres fabricated by closely pack NSL,
have been reported for LSPR biosensing. This paper introduces
several novel gold nanostructures fabricated by NSL in LSPR
applications, including 3D nanostructures obtained by evaporating
gold obliquely on dispersed nanospheres, nanoholes with slant
sidewalls, and patchy nanoparticles on closely packed nanospheres,
all of which render satisfactory sensitivity for LSPR sensing. Since
the LSPR spectrum is very sensitive to the shape of the metal
nanostructures, formulas are derived and software is developed for
calculating the profiles of the obtainable metal nanostructures by
NSL, for different nanosphere masks with different fabrication
conditions. The simulated profiles coincide well with the profiles of
the fabricated gold nanostructures observed under scanning electron
microscope (SEM) and atomic force microscope (AFM), which
proves that the software is a useful tool for the process design of
different LSPR nanostructures.
Abstract: In this paper, in order to categorize ORL database face
pictures, principle Component Analysis (PCA) and Kernel Principal
Component Analysis (KPCA) methods by using Elman neural
network and Support Vector Machine (SVM) categorization methods
are used. Elman network as a recurrent neural network is proposed
for modeling storage systems and also it is used for reviewing the
effect of using PCA numbers on system categorization precision rate
and database pictures categorization time. Categorization stages are
conducted with various components numbers and the obtained results
of both Elman neural network categorization and support vector
machine are compared. In optimum manner 97.41% recognition
accuracy is obtained.
Abstract: Construction of portable device for fast analysis of energetic materials is described in this paper. The developed analytical system consists of two main parts: a miniaturized microcolumn liquid chromatograph of unique construction and original chemiluminescence detector. This novel portable device is able to determine selectively most of nitramine- and nitroester-based explosives as well as inorganic nitrates at trace concentrations in water or soil extracts in less than 8 minutes.