Novel Glycopolymers Containing Carbohydrate Moiety: Copolymerization and Thermal Properties
Polymers are one of the most widely used materials in our every day life. The subject of renewable resources has attracted great attention in the last period of time. New polymeric materials derived from renewable resources, like carbohydrates draw attention to public eye especially because of their biocompatibility and biodegradability. The aim of our paper was to obtain environmentally compatible polymers from monosaccharides. Novel glycopolymers based on D-glucose have been obtained from copolymerization of a new monomer carrying carbohydrate moiety with methyl methacrylate (MMA) via free radical bulk polymerization. Differential scanning calorimetry (DSC) was performed in order to study the copolymerization process of the monomer into the chosen co-monomer; the activation energy of this process was evaluated using Ozawa method. The copolymers obtained were characterized using ATR-FTIR spectroscopy. The thermal stability of the obtained products was studied by thermogravimetry (TG).
[1] O. D. Satyanarayanaa, P. R. Chatterjia, "Biodegradable Polymers: Challenges and Strategies", Polymer Reviews, 33:3, 1993, pp. 349 -368.
[2] X. Wang, X. Geng, L. Ye, A-y Zhang, Z-g Feng, "Synthesis and
characterization of novel glucose- and lactose-containing methacrylatebased
radiopaque glycopolymers", Reactive & Functional Polymers 69,
2009, pp. 857-863.
[3] R. Cuervo-Rodr├¡guez, V. Bordegé, M. Fern├índez-Garc├¡a, "Synthesis
and characterization of novel glycopolymers based on ethyl
hydroxy methylacrylate", Carbohydrate Polymers, 68, 2007, pp. 89-94.
[4] S. Slavin, J. Burns, D. M. Haddleton, C. Remzi Becer. "Synthesis of
glycopolymers via click reactions", European Polymer Journal, 47,
2011, pp. 435-446.
[5] A. M. Panâ, V. Gherman, P. Sfarloaga, G. Bandur, L. M. Stefan, M.
Popa, L. M. Rusnac, "Thermal stability and biodegradation of novel DMannose
based glycopolymers", Polymer Testing 31, 2012, pp. 384-
392.
[6] K. Van de Velde, P. Kiekens, "Biopolymers: overview of several
properties and consequence on their applications", Polymer Testing, 21,
2002, pp. 433-442.
[7] H. Yang, T. Y. Guo, D. Zhou, "Surface modification with well-defined
glycopolymer for protein imprinting matrix", International Journal of
Biological macromolecules, 48, 2011, pp. 432-438.
[8] Q. Shi, C. Chen, L. Gao, H. Xu, W. Guo, "Physical and degradation
properties of binary or ternary blands composed of poly(lactic acid),
thermoplastic starch and GMA grafted POE", Polymer Degradation and
stability, 96, 2011, pp. 175-182.
[9] M. Khalid, C. T. Ratnam, C. A Luqman, A. Salmiaton, T. S. Y. Choong,
and H. Jalaludin, "Thermal and Dynamic Mechanical Behavior of
Cellulose- and Oil Palm Empty Fruit Bunch (OPEFB)-Filled
Polypropylene Biocomposites", Polymer-Plastics Technology and
Engineering, 48:12, 2009, pp. 1244-1251.
[10] H. Tian, Z. Tang, X.. Zhuang, X. Chen "Preparation, functionalization
and biomedical application", Progress in Polymer Science, 2011, to be
published.
[11] A. M. Panâ, L. Rusnac, G. Bandur, E. ┼×i┼ƒu, V. Badea, M. Silion,
"Synthesis and Characterization of New Glycopolymers Based on
Monosachharides and Maleic Anhydride I. Glucose derivatives",
Materiale Plastice, Bucure┼ƒti, 47(1), ´Çá2010.
[12] L. M ┼×tefan., A. M. Panâ., M. C. Pascariu, E. Sisu, G. Bandur, L. M.
Rusnac, "Synthesis and Characterization of a new methacrylic
glycomonomer", Turkish Journal of Chemistry, 35, 2011, pp. 757-767.
[13] J. Menczel, P. R. Bruce, Thermal Analysis of Polymers Fundamentals
and Applications. John Wiley and Sons. New Jersey, USA. 2009, pp. 7-
150.
[14] H. E. Kissinger, Anal . Chem., 1957, pp. 1702-1706.
[1] O. D. Satyanarayanaa, P. R. Chatterjia, "Biodegradable Polymers: Challenges and Strategies", Polymer Reviews, 33:3, 1993, pp. 349 -368.
[2] X. Wang, X. Geng, L. Ye, A-y Zhang, Z-g Feng, "Synthesis and
characterization of novel glucose- and lactose-containing methacrylatebased
radiopaque glycopolymers", Reactive & Functional Polymers 69,
2009, pp. 857-863.
[3] R. Cuervo-Rodr├¡guez, V. Bordegé, M. Fern├índez-Garc├¡a, "Synthesis
and characterization of novel glycopolymers based on ethyl
hydroxy methylacrylate", Carbohydrate Polymers, 68, 2007, pp. 89-94.
[4] S. Slavin, J. Burns, D. M. Haddleton, C. Remzi Becer. "Synthesis of
glycopolymers via click reactions", European Polymer Journal, 47,
2011, pp. 435-446.
[5] A. M. Panâ, V. Gherman, P. Sfarloaga, G. Bandur, L. M. Stefan, M.
Popa, L. M. Rusnac, "Thermal stability and biodegradation of novel DMannose
based glycopolymers", Polymer Testing 31, 2012, pp. 384-
392.
[6] K. Van de Velde, P. Kiekens, "Biopolymers: overview of several
properties and consequence on their applications", Polymer Testing, 21,
2002, pp. 433-442.
[7] H. Yang, T. Y. Guo, D. Zhou, "Surface modification with well-defined
glycopolymer for protein imprinting matrix", International Journal of
Biological macromolecules, 48, 2011, pp. 432-438.
[8] Q. Shi, C. Chen, L. Gao, H. Xu, W. Guo, "Physical and degradation
properties of binary or ternary blands composed of poly(lactic acid),
thermoplastic starch and GMA grafted POE", Polymer Degradation and
stability, 96, 2011, pp. 175-182.
[9] M. Khalid, C. T. Ratnam, C. A Luqman, A. Salmiaton, T. S. Y. Choong,
and H. Jalaludin, "Thermal and Dynamic Mechanical Behavior of
Cellulose- and Oil Palm Empty Fruit Bunch (OPEFB)-Filled
Polypropylene Biocomposites", Polymer-Plastics Technology and
Engineering, 48:12, 2009, pp. 1244-1251.
[10] H. Tian, Z. Tang, X.. Zhuang, X. Chen "Preparation, functionalization
and biomedical application", Progress in Polymer Science, 2011, to be
published.
[11] A. M. Panâ, L. Rusnac, G. Bandur, E. ┼×i┼ƒu, V. Badea, M. Silion,
"Synthesis and Characterization of New Glycopolymers Based on
Monosachharides and Maleic Anhydride I. Glucose derivatives",
Materiale Plastice, Bucure┼ƒti, 47(1), ´Çá2010.
[12] L. M ┼×tefan., A. M. Panâ., M. C. Pascariu, E. Sisu, G. Bandur, L. M.
Rusnac, "Synthesis and Characterization of a new methacrylic
glycomonomer", Turkish Journal of Chemistry, 35, 2011, pp. 757-767.
[13] J. Menczel, P. R. Bruce, Thermal Analysis of Polymers Fundamentals
and Applications. John Wiley and Sons. New Jersey, USA. 2009, pp. 7-
150.
[14] H. E. Kissinger, Anal . Chem., 1957, pp. 1702-1706.
@article{"International Journal of Chemical, Materials and Biomolecular Sciences:52011", author = "Liliana M. Ştefan and Ana M. Pană and Geza Bandur and Marcel Popa and Lucian M. Rusnac", title = "Novel Glycopolymers Containing Carbohydrate Moiety: Copolymerization and Thermal Properties", abstract = "Polymers are one of the most widely used materials in our every day life. The subject of renewable resources has attracted great attention in the last period of time. New polymeric materials derived from renewable resources, like carbohydrates draw attention to public eye especially because of their biocompatibility and biodegradability. The aim of our paper was to obtain environmentally compatible polymers from monosaccharides. Novel glycopolymers based on D-glucose have been obtained from copolymerization of a new monomer carrying carbohydrate moiety with methyl methacrylate (MMA) via free radical bulk polymerization. Differential scanning calorimetry (DSC) was performed in order to study the copolymerization process of the monomer into the chosen co-monomer; the activation energy of this process was evaluated using Ozawa method. The copolymers obtained were characterized using ATR-FTIR spectroscopy. The thermal stability of the obtained products was studied by thermogravimetry (TG).
", keywords = "DSC, glycopolymer, monosaccarides, TG.", volume = "6", number = "4", pages = "274-4", }
