Abstract: MOSCAPs of various combinations of Hafnium
oxide and Titanium oxide of varying thickness with Aluminum as gate electrode have been fabricated and electrically characterized.
The effects of voltage stress on the I-V characteristics for prolonged time durations have been studied and compared. Results showed
hard breakdown and negligible degradation of reliability under stress.
Abstract: The hard clam (meretrix lusoria) cultivated industry
has been developed vigorously for recent years in Taiwan, and
seawater quality determines the cultivated environment. The pH
concentration variation affects survival rate of meretrix lusoria
immediately. In order to monitor seawater quality, solid-state sensing
electrode of ruthenium-doped titanium dioxide (TiO2:Ru) is developed
to measure hydrogen ion concentration in different cultivated
solutions. Because the TiO2:Ru sensing electrode has high chemical
stability and superior sensing characteristics, thus it is applied as a pH
sensor. Response voltages of TiO2:Ru sensing electrode are readout by
instrument amplifier in different sample solutions. Mean sensitivity
and linearity of TiO2:Ru sensing electrode are 55.20 mV/pH and 0.999
from pH1 to pH13, respectively. We expect that the TiO2:Ru sensing
electrode can be applied to real environment measurement, therefore
we collect two sample solutions by different meretrix lusoria
cultivated ponds in the Yunlin, Taiwan. The two sample solutions are
both measured for 200 seconds after calibration of standard pH buffer
solutions (pH7, pH8 and pH 9). Mean response voltages of sample 1
and sample 2 are -178.758 mV (Standard deviation=0.427 mV) and
-180.206 mV (Standard deviation =0.399 mV), respectively. Response
voltages of the two sample solutions are between pH 8 and pH 9 which
conform to weak alkali range and suitable meretrix lusoria growth. For
long-term monitoring, drift of cultivated solutions (sample 1 and
sample 2) are 1.16 mV/hour and 1.03 mV/hour, respectively.
Abstract: Friction Stir Welding is a solid state welding technique which can be used to produce sound welds between similar and dissimilar materials. Dissimilar welds which include welds between the different series of aluminium alloys, aluminium to magnesium, steel and titanium has been successfully produced by many researchers. This review covers the work conducted in the above mentioned materials and further concludes by showing the need to fully understand the FSW process in order to expand the latter industrially.
Abstract: Today automobile and aerospace industries realise Laser Beam Welding for a clean and non contact source of heating and fusion for joining of sheets. The welding performance is mainly based on by the laser welding parameters. Some concepts related to Artificial Neural Networks and how can be applied to model weld bead geometry and mechanical properties in terms of equipment parameters are reported in order to evaluate the accuracy and compare it with traditional modeling schemes. This review reveals the output features of Titanium and Aluminium weld bead geometry and mechanical properties such as ultimate tensile strength, yield strength, elongation and reduction of the area of the weld using Artificial Neural Network.
Abstract: Thermally insulating ceramic coatings also known as
thermal barrier coatings (TBCs) have been essential technologies to
improve the performance and efficiency of advanced gas turbines in
service at extremely high temperatures. The damage mechanisms of
air-plasma sprayed YSZ thermal barrier coatings (TBC) with various
microstructures were studied by microscopic techniques after thermal
cycling. The typical degradation of plasma TBCs that occurs during
cyclic furnace testing of an YSZ and alumina coating on a Titanium
alloy are analyzed. During the present investigation the effects of
topcoat thickness, bond coat oxidation, thermal cycle lengths and test
temperature are investigated using thermal cycling. These results
were correlated with stresses measured by a spectroscopic technique
in order to understand specific damage mechanism. The failure
mechanism of former bond coats was found to involve fracture
initiation at the thermally grown oxide (TGO) interface and at the
TGO bond coat interface. The failure mechanism of the YZ was
found to involve combination of fracture along the interface between
TGO and bond coat.
Abstract: Carbon fibers have specific characteristics in
comparison with industrial and structural materials used in different
applications. Special properties of carbon fibers make them attractive
for reinforcing and fabrication of composites. These fibers have been
utilized for composites of metals, ceramics and plastics. However,
it-s mainly used in different forms to reinforce lightweight polymer
materials such as epoxy resin, polyesters or polyamides. The
composites of carbon fiber are stronger than steel, stiffer than
titanium, and lighter than aluminum and nowadays they are used in a
variety of applications. This study explains applications of carbon
fibers in different fields such as space, aviation, transportation,
medical, construction, energy, sporting goods, electronics, and the
other commercial/industrial applications. The last findings of
composites with polymer, metal and ceramic matrices containing
carbon fibers and their applications in the world investigated.
Researches show that carbon fibers-reinforced composites due to
unique properties (including high specific strength and specific
modulus, low thermal expansion coefficient, high fatigue strength,
and high thermal stability) can be replaced with common industrial
and structural materials.
Abstract: Copper based composites reinforced with WC and Ti
particles were prepared using planetary ball-mill. The experiment
was designed by using Taguchi technique and milling was carried out
in an air for several hours. The powder was characterized before and
after milling using the SEM, TEM and X-ray for microstructure and
for possible new phases. Microstructures show that milled particles
size and reduction in particle size depend on many parameters. The
distance d between planes of atoms estimated from X-ray powder
diffraction data and TEM image. X-ray diffraction patterns of the
milled powder did not show clearly any new peak or energy shift, but
the TEM images show a significant change in crystalline structure of
corporate on titanium in the composites.
Abstract: Titanium alloys like Ti-6Al-2Sn-4Zr-6Mo (Ti-
6246) are widely used in aerospace applications. Component
manufacturing, however, is difficult and expensive as their
machinability is extremely poor. A thorough understanding of the
chip formation process is needed to improve related metal cutting
operations.In the current study, orthogonal cutting experiments have
been performed and theresulting chips were analyzed by optical
microscopy and scanning electron microscopy.Chips from aTi-
6246ingot were produced at different cutting speeds and cutting
depths. During the experiments, depending of the cutting conditions,
continuous or segmented chips were formed. Narrow, highly
deformed and grain oriented zones, the so-called shear zone,
separated individual segments. Different material properties have
been measured in the shear zones and the segments.
Abstract: In the present research, the titanium-catalyzed
ethylene dimerization and more specifically, the concomitant byproducts
and polymer formation have been studied in the presence of 2,5-dimethoxytetrahydrofuran as an electron donor compound in the
combination with triethylaluminium (TEA) as activator. Then, we
added ethylene chlorobromide as a new efficient promoter to the
relevant catalyst system. Finally, the behavior of novel homogeneous
[Titanium tetrabutoxide (Ti(OC4H9)4)/2,5-dimethoxytetrahydrofuran/
TEA/ethylene chlorobromide] was investigated in the various
operating conditions for the optimum production of 1-butene. In the
optimum conditions, a very high ethylene conversion (almost 90.77
%), a relative high selectivity to 1-butene (79.00 %), yield of reaction equal to 71.70 % and a significant productivity (turnover frequency
equal to 1370 h-1) were achieved.
Abstract: Ti-6Al-4V alloy has demonstrated a high strength to
weight ratio as well as good properties at high temperature. The
successful application of the alloy in some important areas depends
on suitable joining techniques. Friction welding has many
advantageous features to be chosen for joining Titanium alloys. The
present work investigates the feasibility of producing similar metal
joints of this Titanium alloy by rotary friction welding method. The
joints are produced at three different speeds and the performances of
the welded joints are evaluated by conducting microstructure studies,
Vickers Hardness and tensile tests at the joints. It is found that the
weld joints produced are sound and the ductile fractures in the tensile
weld specimens occur at locations away from the welded joints. It is
also found that a rotational speed of 1500 RPM can produce a very
good weld, with other parameters kept constant.
Abstract: Titanium dioxide coatings were deposited by utilizing
atmospheric plasma spraying (APS) system. The agglomerated nanopowder
and different spraying parameters were used to determine
their influences on the microstructure surface feature and photoabsorption
of the coatings. The microstructure of as-sprayed TiO2
coatings were characterized by scanning electron microscope (SEM).
Surface characteristics were investigated by Fourier Transform
Infrared (FT-IR). The photo absorption was determined by UV-VIS
spectrophotometer. It is found that the spray parameters have an
influence on the microstructure, surface feature and photo-absorption
of the TiO2 coatings.
Abstract: Micro power sources are required to be used in autonomous microelectromechanical system (MEMS). In this paper,
we designed and fabricated a three dimensional (3D) MEMS supercapacitor, which is consisting of conformal silicon
dioxide/titanium/polypyrrole (PPy) layers on silicon substrate. At first, ''through-structure'' was fabricated on the silicon substrate by high-aspect-ratio deep reactive ion etching (DRIE) method, which enlarges the available surface area significantly. Then the SiO2/Ti/PPy layers grew sequentially on the ³through-structure´. Finally, the supercapacitor was investigated by electrochemical methods.
Abstract: Ultrasonic machining (USM) is a non-traditional
machining process being widely used for commercial machining of
brittle and fragile materials such as glass, ceramics and
semiconductor materials. However, USM could be a viable
alternative for machining a tough material such as titanium; and this
aspect needs to be explored through experimental research. This
investigation is focused on exploring the use of ultrasonic machining
for commercial machining of pure titanium (ASTM Grade-I) and
evaluation of tool wear rate (TWR) under controlled experimental
conditions. The optimal settings of parameters are determined
through experiments planned, conducted and analyzed using Taguchi
method. In all, the paper focuses on parametric optimization of
ultrasonic machining of pure titanium metal with TWR as response,
and validation of the optimized value of TWR by conducting
confirmatory experiments.
Abstract: Titanium oxide films with different morphologies have for the first time been fabricated through hydrothermal reactions between a titanium substrate and iodine powder in water or ethanol. SEM revealed that iodine supported titanium (Ti-I2) surface shows different morphologies with variable treatment conditions. The mean surface roughness (Ra) was increased in the different groups. Use of surfactant has a role to increase the roughness of the film. The surface roughness was in the range of 0.15 μm-0.42 μm. Furthermore, the electrochemical examinations showed that the Ti-I2 surface fabricated in alcoholic medium has high corrosion resistance than in aqueous medium.
Abstract: The control of oxygen flow rate during growth of
titanium dioxide by mass flow controller in DC plasma sputtering
growth system is studied. The impedance of TiO2 films for inductance
effect is influenced by annealing time and oxygen flow rate. As
annealing time is increased, the inductance of TiO2 film is the more.
The growth condition of optimum and maximum inductance for TiO2
film to serve as sensing device are oxygen flow rate of 15 sccm and
large annealing time. The large inductance of TiO2 film will be
adopted to fabricate the biosensor to obtain the high sensitivity of
sensing in biology.
Abstract: Anodizing is an electrochemical process that converts the metal surface into a decorative, durable, corrosion-resistant, anodic oxide finish. Aluminum is ideally suited to anodizing, although other nonferrous metals, such as magnesium and titanium, also can be anodized. The anodic oxide structure originates from the aluminum substrate and is composed entirely of aluminum oxide. This aluminum oxide is not applied to the surface like paint or plating, but is fully integrated with the underlying aluminum substrate, so cannot chip or peel. It has a highly ordered, porous structure that allows for secondary processes such as coloring and sealing. In this experimental paper, we focus on a reliable method for fabricating nanoporous alumina with high regularity. Starting from study of nanostructure materials synthesize methods. After that, porous alumina fabricate in the laboratory by anodization of aluminum oxide. Hard anodization processes are employed to fabricate the nanoporous alumina using 0.3M oxalic acid and 90, 120 and 140 anodized voltages. The nanoporous templates were characterized by SEM and FFT. The nanoporous templates using 140 voltages have high ordered. The pore formation, influence of the experimental conditions on the pore formation, the structural characteristics of the pore and the oxide chemical reactions involved in the pore growth are discuss.
Abstract: In this article, using finite element analysis (FEA)
and an X-ray diffractometer (XRD), cold-sprayed titanium particles
on a steel substrate is investigated in term of cooling time and the
development of residual strains. Three cooling-down models of
sprayed particles after deposition stage are simulated and discussed:
the first model (m1) considers conduction effect to the substrate only,
the second model (m2) considers both conduction as well as
convection effect to the environment, and the third model (m3) which
is the same as the second model but with the substrate heated to a
near particle temperature before spraying. Thereafter, residual strains
developed in the third model is compared with the experimental
measurement of residual strains, which involved a Bruker D8
Advance Diffractometer using CuKa radiation (40kV, 40mA)
monochromatised with a graphite sample monochromator. For
deposition conditions of this study, a good correlation was found to
exist between the FEA results and XRD measurements of residual
strains.
Abstract: Greenhouse gases (GHG) emissions impose major
threat to global warming potential (GWP). Unfortunately
manufacturing sector is one of the major sources that contribute
towards the rapid increase in greenhouse gases (GHG) emissions. In
manufacturing sector electric power consumption is the major driver
that influences CO2 emission. Titanium alloys are widely utilized in
aerospace, automotive and petrochemical sectors because of their
high strength to weight ratio and corrosion resistance. Titanium
alloys are termed as difficult to cut materials because of their poor
machinability rating. The present study analyzes energy consumption
during cutting with reference to material removal rate (MRR).
Surface roughness was also measured in order to optimize energy
consumption.
Abstract: In present work, prediction the effect of nose radius, rz (mm) on the equivalent strain (PEEQ) and surface finish during the machining of titanium alloy (Ti-6Al-4V) through orthogonal cutting process. The results were performed at several of the nose radiuses, rz (mm) while the cutting speed, vc (m/min), feed rate, f (mm/tooth) and depth of cut, d (mm) were remained constant. The equivalent plastic strain (PEEQ) was estimated by using finite element modeling (FEM) and applied through ABAQUS/EXPLICIT software. The simulation results led to conclude that the equivalent plastic strain (PEEQ) was increased and surface roughness (Ra) decreased when increasing nose radius, rz (mm) during the machining of titanium alloy (Ti–6Al–4V) in dry cutting conditions.
Abstract: The psychological and physical trauma associated with the loss of a human limb can severely impact on the quality of life of an amputee rendering even the most basic of tasks very difficult. A prosthetic device can be of great benefit to the amputee in the performance of everyday human tasks. This paper outlines a proposed mechanical design of a 12 degree-of-freedom SMA actuated artificial hand. It is proposed that the SMA wires be embedded intrinsically within the hand structure which will allow for significant flexibility for use either as a prosthetic hand solution, or as part of a complete lower arm prosthetic solution. A modular approach is taken in the design facilitating ease of manufacture and assembly, and more importantly, also allows the end user to easily replace SMA wires in the event of failure. A biomimetric approach has been taken during the design process meaning that the artificial hand should replicate that of a human hand as far as is possible with due regard to functional requirements. The proposed design has been exposed to appropriate loading through the use of finite element analysis (FEA) to ensure that it is structurally sound. Theoretical analysis of the mechanical framework was also carried out to establish the limits of the angular displacement and velocity of the finger tip as well finger tip force generation. A combination of various polymers and Titanium, which are suitably lightweight, are proposed for the manufacture of the design.