Hydrothermal Fabrication of Iodine Doped Titanium Oxide Films on Ti Substrate
Titanium oxide films with different morphologies have for the first time been fabricated through hydrothermal reactions between a titanium substrate and iodine powder in water or ethanol. SEM revealed that iodine supported titanium (Ti-I2) surface shows different morphologies with variable treatment conditions. The mean surface roughness (Ra) was increased in the different groups. Use of surfactant has a role to increase the roughness of the film. The surface roughness was in the range of 0.15 μm-0.42 μm. Furthermore, the electrochemical examinations showed that the Ti-I2 surface fabricated in alcoholic medium has high corrosion resistance than in aqueous medium.
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Hallen, "Osseointegrated implants in the edentulous jaw. Experience
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[3] B. Seiji, I. Yukari, K. Hiroshi, and S. Hideo, "Surface modification of
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22, pp. 1115-1120, 2006.
[4] M. H. Mohammad, and G. Wei, "How is the surface treatments influence
on the roughness of biocompatibility?," Trends in Biomaterials and
Artificial Organs, vol. 22(3), pp. 144-157, 2008.
[5] C. Xiaobo, and S. M. Samuel, "Titanium oxide nanomaterials: Synthesis,
properties, modifications, and applications," Chemical Reviews, vol. 107, pp. 2891-2959.
[6] L. F. Cooper, Y. Zhou, J, Takebe, J. Guo, A. Abron, and A. Holmen,
"Fluoride modification effects on osteoblast behavior and bone formation
at TiO2 grit-blasted c. p. titanium endosseous implants," Biomaterials,
vol. 27, pp. 926-936, 2006.
[7] J. W. Park, J. Y. Suh, and H. J. Chung, "Effects of calcium ion incorporation on osteoblast gene expression in MC3T3-E1 cells cultured
on microstructured titanium surfaces," Journal of Biomedical Materials
Research A, vol. 86, pp. 116-127, 2008.
[8] J. W. Park, J. H. Jang, C. S. Lee, and T. Hanawa, "Osteoconductivity of
hydrophilic microstructured titanium implants with phosphate ion chemistry," Acta Biomaterialia, vol. 5, pp. 2311-2321, 2009.
[9] G. Zhao, Z. Schwartz, M. Wieland, F. Rupp, J. Geis-Gerstorfer, and D. L.
Cochran, "High surface energy enhances cell response to titanium
substrate microstructure," Journal of Biomedical Materials Research A,
vol. 74, pp. 49-58, 2005.
[10] D. Buser, N. Broggini, M. Wieland, R. K. Schenk, A. J. Denzer, and D. L.
Cochran, "Enhanced bone apposition to a chemically modified SLA
titanium surface," Journal of Dental Research, vol. 83, pp. 529-533, 2004.
[11] H. Zitter, and H. Jr Plenk, “The electrochemical behavior of metallic
implant materials as an indicator of their biocompatibility,” Journal of
Biomedical Materials Research, vol. 21, pp. 881–896, 1987.
[12] L. Bren, J. Drelich, L. English, J. Fogarty, N. Istephanous, and R.
Policoro, “ Effect of surface characteristics of metallic biomaterials on
interaction with osteoblast cells,” Proceedings of the 7th World
Biomaterials Congress, pp. 1121, 2004.
[13] J. C. Keller, G. B. Schneider, C. M. Standford, and B. Kellog, “Effects of
implant microtopography on osteoblast cell attachment,” Implant
Dentistry, vol. 12, pp. 175–181, 2003.
[14] Z. Xiaolong, K. Kyo-Han, and J. Yongsoo, “Anodic oxide films
containing Ca and P of titanium biomaterial,” Biomaterials, vol. 22, pp.
2199–2206, 2001.
[15] B. Segomotso, T. Baozhu, C. Feng, and Z. Jinlong, “Synthesis,
characterization and application of iodine modified titanium dioxide in
photocatalytical reactions under visible light irradiation,” Applied Surface
Science, vol. 258, pp. 3927–3935, 2012.
[16] C. C. Mohan, P. R. Sreerekha, V. V. Divyarani, S. Nair, K. Chennazhi,
and D. Menon, “Influence of titania nanotopography on human vascular
cell functionality and its proliferation in vitro,” Journal of Materials
Chemistry, doi: 10.1039/c1jm13726c, 2012.
[1] P. I. Branemark, Hansson, R. Adell, U. Breine, J. Lindstrom, and O.
Hallen, "Osseointegrated implants in the edentulous jaw. Experience
from a 10 year period," Scandinavian Journal of Plastics and
Reconstructive Surgery, vol. 11, pp. 39, 1977.
[2] D. M. Brunette, P. Tengvall, M. Textor, and P. Thomsen, "Titanium in
medicine," Berlin: Springer; 2001.
[3] B. Seiji, I. Yukari, K. Hiroshi, and S. Hideo, "Surface modification of
titanium by etching in concentrated sulfuric acid," Dental Materials, vol.
22, pp. 1115-1120, 2006.
[4] M. H. Mohammad, and G. Wei, "How is the surface treatments influence
on the roughness of biocompatibility?," Trends in Biomaterials and
Artificial Organs, vol. 22(3), pp. 144-157, 2008.
[5] C. Xiaobo, and S. M. Samuel, "Titanium oxide nanomaterials: Synthesis,
properties, modifications, and applications," Chemical Reviews, vol. 107, pp. 2891-2959.
[6] L. F. Cooper, Y. Zhou, J, Takebe, J. Guo, A. Abron, and A. Holmen,
"Fluoride modification effects on osteoblast behavior and bone formation
at TiO2 grit-blasted c. p. titanium endosseous implants," Biomaterials,
vol. 27, pp. 926-936, 2006.
[7] J. W. Park, J. Y. Suh, and H. J. Chung, "Effects of calcium ion incorporation on osteoblast gene expression in MC3T3-E1 cells cultured
on microstructured titanium surfaces," Journal of Biomedical Materials
Research A, vol. 86, pp. 116-127, 2008.
[8] J. W. Park, J. H. Jang, C. S. Lee, and T. Hanawa, "Osteoconductivity of
hydrophilic microstructured titanium implants with phosphate ion chemistry," Acta Biomaterialia, vol. 5, pp. 2311-2321, 2009.
[9] G. Zhao, Z. Schwartz, M. Wieland, F. Rupp, J. Geis-Gerstorfer, and D. L.
Cochran, "High surface energy enhances cell response to titanium
substrate microstructure," Journal of Biomedical Materials Research A,
vol. 74, pp. 49-58, 2005.
[10] D. Buser, N. Broggini, M. Wieland, R. K. Schenk, A. J. Denzer, and D. L.
Cochran, "Enhanced bone apposition to a chemically modified SLA
titanium surface," Journal of Dental Research, vol. 83, pp. 529-533, 2004.
[11] H. Zitter, and H. Jr Plenk, “The electrochemical behavior of metallic
implant materials as an indicator of their biocompatibility,” Journal of
Biomedical Materials Research, vol. 21, pp. 881–896, 1987.
[12] L. Bren, J. Drelich, L. English, J. Fogarty, N. Istephanous, and R.
Policoro, “ Effect of surface characteristics of metallic biomaterials on
interaction with osteoblast cells,” Proceedings of the 7th World
Biomaterials Congress, pp. 1121, 2004.
[13] J. C. Keller, G. B. Schneider, C. M. Standford, and B. Kellog, “Effects of
implant microtopography on osteoblast cell attachment,” Implant
Dentistry, vol. 12, pp. 175–181, 2003.
[14] Z. Xiaolong, K. Kyo-Han, and J. Yongsoo, “Anodic oxide films
containing Ca and P of titanium biomaterial,” Biomaterials, vol. 22, pp.
2199–2206, 2001.
[15] B. Segomotso, T. Baozhu, C. Feng, and Z. Jinlong, “Synthesis,
characterization and application of iodine modified titanium dioxide in
photocatalytical reactions under visible light irradiation,” Applied Surface
Science, vol. 258, pp. 3927–3935, 2012.
[16] C. C. Mohan, P. R. Sreerekha, V. V. Divyarani, S. Nair, K. Chennazhi,
and D. Menon, “Influence of titania nanotopography on human vascular
cell functionality and its proliferation in vitro,” Journal of Materials
Chemistry, doi: 10.1039/c1jm13726c, 2012.
@article{"International Journal of Medical, Medicine and Health Sciences:60617", author = "M. P. Neupane and T. S. N. Sankara Narayanan and J. E. Park and Y. K. Kim and I. S. Park and K. Y. Song and T. S. Bae and M. H. Lee", title = "Hydrothermal Fabrication of Iodine Doped Titanium Oxide Films on Ti Substrate", abstract = "Titanium oxide films with different morphologies have for the first time been fabricated through hydrothermal reactions between a titanium substrate and iodine powder in water or ethanol. SEM revealed that iodine supported titanium (Ti-I2) surface shows different morphologies with variable treatment conditions. The mean surface roughness (Ra) was increased in the different groups. Use of surfactant has a role to increase the roughness of the film. The surface roughness was in the range of 0.15 μm-0.42 μm. Furthermore, the electrochemical examinations showed that the Ti-I2 surface fabricated in alcoholic medium has high corrosion resistance than in aqueous medium.
", keywords = "Corrosion, Hydrothermal, Surface roughness, Titanium oxide.", volume = "6", number = "10", pages = "498-4", }
