Abstract: This study is concerned with pH solution detection
using 2 × 4 flexible sensor array based on a plastic polyethylene
terephthalate (PET) substrate that is coated a conductive layer and a
ruthenium dioxide (RuO2) sensitive membrane with the technologies
of screen-printing and RF sputtering. For data analysis, we also
prepared a dynamic measurement system for acquiring the response
voltage and analyzing the characteristics of the working electrodes
(WEs), such as sensitivity and linearity. In this condition, an array
measurement system was designed to acquire the original signal from
sensor array, and it is based on the method of digital signal processing
(DSP). The DSP modifies the unstable acquisition data to a direct
current (DC) output using the technique of digital filter. Hence, this
sensor array can obtain a satisfactory yield, 62.5%, through the design
measurement and analysis system in our laboratory.
Abstract: The hard clam (meretrix lusoria) cultivated industry
has been developed vigorously for recent years in Taiwan, and
seawater quality determines the cultivated environment. The pH
concentration variation affects survival rate of meretrix lusoria
immediately. In order to monitor seawater quality, solid-state sensing
electrode of ruthenium-doped titanium dioxide (TiO2:Ru) is developed
to measure hydrogen ion concentration in different cultivated
solutions. Because the TiO2:Ru sensing electrode has high chemical
stability and superior sensing characteristics, thus it is applied as a pH
sensor. Response voltages of TiO2:Ru sensing electrode are readout by
instrument amplifier in different sample solutions. Mean sensitivity
and linearity of TiO2:Ru sensing electrode are 55.20 mV/pH and 0.999
from pH1 to pH13, respectively. We expect that the TiO2:Ru sensing
electrode can be applied to real environment measurement, therefore
we collect two sample solutions by different meretrix lusoria
cultivated ponds in the Yunlin, Taiwan. The two sample solutions are
both measured for 200 seconds after calibration of standard pH buffer
solutions (pH7, pH8 and pH 9). Mean response voltages of sample 1
and sample 2 are -178.758 mV (Standard deviation=0.427 mV) and
-180.206 mV (Standard deviation =0.399 mV), respectively. Response
voltages of the two sample solutions are between pH 8 and pH 9 which
conform to weak alkali range and suitable meretrix lusoria growth. For
long-term monitoring, drift of cultivated solutions (sample 1 and
sample 2) are 1.16 mV/hour and 1.03 mV/hour, respectively.
Abstract: A measurement system was successfully fabricated to
detect ion concentrations (hydrogen and chlorine) in this study.
PIC18F4520, the microcontroller was used as the control unit in the
measurement system. The measurement system was practically used
to sense the H+ and Cl- in different examples, and the pH and pCl
values were exhibited on real-time LCD display promptly. In the study,
the measurement method is used to judge whether the response voltage
is stable. The change quantity is smaller than 0.01%, that the present
response voltage compares with next response voltage for H+
measurement, and the above condition is established only 6 sec.
Besides, the change quantity is smaller than 0.01%, that the present
response voltage compares with next response voltage for Clmeasurement,
and the above condition is established only 5 sec.
Furthermore, the average error quantities would also be considered,
and they are 0.05 and 0.07 for measurements of pH and pCl values,
respectively.
Abstract: A measurement system for pH array sensors is
introduced to increase accuracy, and decrease non-ideal effects
successfully. An array readout circuit reads eight potentiometric
signals at the same time, and obtains an average value. The deviation
value or the extreme value is counteracted and the output voltage is a
relatively stable value. The errors of measuring pH buffer solutions are
decreased obviously with this measurement system, and the non-ideal
effects, drift and hysteresis, are lowered to 1.638mV/hr and 1.118mV,
respectively. The efficiency and stability are better than single sensor.
The whole sensing characteristics are improved.