Abstract: Superabsorbent polymers received much attention and
are used in many fields because of their superior characters to
traditional absorbents, e.g., sponge and cotton. So, it is very
important but challenging to prepare highly and fast-swelling
superabsorbents. A reliable, efficient and low-cost technique for
removing heavy metal ions from wastewater is the adsorption using
bio-adsorbents obtained from biological materials, such as
polysaccharides-based hydrogels superabsorbents. In this study, novel multi-functional superabsorbent composites
type semi-interpenetrating polymer networks (Semi-IPNs) were
prepared via graft polymerization of acrylamide onto chitosan
backbone in presence of gelatin, CTS-g-PAAm/Ge, using potassium
persulfate and N,N’-methylene bisacrylamide as initiator and
crosslinker, respectively. These hydrogels were also partially
hydrolyzed to achieve superabsorbents with ampholytic properties
and uppermost swelling capacity. The formation of the grafted
network was evidenced by Fourier Transform Infrared Spectroscopy
(ATR-FTIR) and Thermogravimetric Analysis (TGA). The porous
structures were observed by Scanning Electron Microscope (SEM).
From TGA analysis, it was concluded that the incorporation of the Ge
in the CTS-g-PAAm network has marginally affected its thermal
stability. The effect of gelatin content on the swelling capacities of
these superabsorbent composites was examined in various media
(distilled water, saline and pH-solutions). The water absorbency was
enhanced by adding Ge in the network, where the optimum value was
reached at 2 wt. % of Ge. Their hydrolysis has not only greatly
optimized their absorption capacity but also improved the swelling
kinetic.These materials have also showed reswelling ability. We
believe that these super-absorbing materials would be very effective
for the adsorption of harmful metal ions from wastewater.
Abstract: Intermittent behavior near the boundary of phase
synchronization in the presence of noise is studied. In certain range of
the coupling parameter and noise intensity the intermittency of eyelet
and ring intermittencies is shown to take place. Main results are
illustrated using the example of two unidirectional coupled Rössler
systems. Similar behavior is shown to take place in two
hydrodynamical models of Pierce diode coupled unidirectional.
Abstract: The fatigue life of tubular joints commonly found in
offshore industry is not only dependent on the value of hot-spot stress
(HSS), but is also significantly influenced by the through-thethickness
stress distribution characterized by the degree of bending
(DoB). The determination of DoB values in a tubular joint is essential
for improving the accuracy of fatigue life estimation using the stresslife
(S–N) method and particularly for predicting the fatigue crack
growth based on the fracture mechanics (FM) approach. In the
present paper, data extracted from finite element (FE) analyses of
tubular KT-joints, verified against experimental data and parametric
equations, was used to investigate the effects of geometrical
parameters on DoB values at the crown 0°, saddle, and crown 180°
positions along the weld toe of central brace in tubular KT-joints
subjected to axial loading. Parametric study was followed by a set of
nonlinear regression analyses to derive DoB parametric formulas for
the fatigue analysis of KT-joints under axial loads. The tubular KTjoint
is a quite common joint type found in steel offshore structures.
However, despite the crucial role of the DoB in evaluating the fatigue
performance of tubular joints, this paper is the first attempt to study
and formulate the DoB values in KT-joints.
Abstract: The concentrations of heavy metals in sediments of
Qua Iboe River Estuary (QIRE) were monitored at four different
sampling locations in wet and dry seasons. A preliminary survey to
determine the four sampling stations along the river continuum
showed that the area spanned between
Abstract: This paper presents two types of microstrip bandpass
filter (BPF) at microwave frequencies. The first one is a tunable BPF
using planar patch resonators based on a varactor diode. The filter is
formed by a triple mode circular patch resonator with two pairs of
slots, in which the varactor diodes are connected. Indeed, this filter is
initially centered at 2.4 GHz; the center frequency of the tunable
patch filter could be tuned up to 1.8 GHz simultaneously with the
bandwidth, reaching high tuning ranges. Lossless simulations were
compared to those considering the substrate dielectric, conductor
losses and the equivalent electrical circuit model of the tuning
element in order to assess their effects. Within these variations,
simulation results showed insertion loss better than 2 dB and return
loss better than 10 dB over the passband. The second structure is a
BPF for ultra-wideband (UWB) applications based on multiple-mode
resonator (MMR) and rectangular-shaped defected ground structure
(DGS). This filter, which is compact size of 25.2 x 3.8 mm2, provides
in the pass band an insertion loss of 0.57 dB and a return loss greater
than 12 dB. The proposed filters presents good performances and the
simulation results are in satisfactory agreement with the
experimentation ones reported elsewhere.
Abstract: The legends about “user-friendly” and “easy-to-use”
birotical tools (computer-related office tools) have been spreading
and misleading end-users. This approach has led us to the extremely
high number of incorrect documents, causing serious financial losses
in the creating, modifying, and retrieving processes. Our research
proved that there are at least two sources of this underachievement:
(1) The lack of the definition of the correctly edited, formatted
documents. Consequently, end-users do not know whether their
methods and results are correct or not. They are not aware of their
ignorance. They are so ignorant that their ignorance does not allow
them to realize their lack of knowledge. (2) The end-users’ problem
solving methods. We have found that in non-traditional programming
environments end-users apply, almost exclusively, surface approach
metacognitive methods to carry out their computer related activities,
which are proved less effective than deep approach methods.
Based on these findings we have developed deep approach
methods which are based on and adapted from traditional
programming languages. In this study, we focus on the most popular
type of birotical documents, the text based documents. We have
provided the definition of the correctly edited text, and based on this
definition, adapted the debugging method known in programming.
According to the method, before the realization of text editing, a
thorough debugging of already existing texts and the categorization
of errors are carried out. With this method in advance to real text
editing users learn the requirements of text based documents and also
of the correctly formatted text.
The method has been proved much more effective than the
previously applied surface approach methods. The advantages of the
method are that the real text handling requires much less human and
computer sources than clicking aimlessly in the GUI (Graphical User
Interface), and the data retrieval is much more effective than from
error-prone documents.
Abstract: The Simulation based VLSI Implementation of
FELICS (Fast Efficient Lossless Image Compression System)
Algorithm is proposed to provide the lossless image compression and
is implemented in simulation oriented VLSI (Very Large Scale
Integrated). To analysis the performance of Lossless image
compression and to reduce the image without losing image quality
and then implemented in VLSI based FELICS algorithm. In FELICS
algorithm, which consists of simplified adjusted binary code for
Image compression and these compression image is converted in
pixel and then implemented in VLSI domain. This parameter is used
to achieve high processing speed and minimize the area and power.
The simplified adjusted binary code reduces the number of arithmetic
operation and achieved high processing speed. The color difference
preprocessing is also proposed to improve coding efficiency with
simple arithmetic operation. Although VLSI based FELICS
Algorithm provides effective solution for hardware architecture
design for regular pipelining data flow parallelism with four stages.
With two level parallelisms, consecutive pixels can be classified into
even and odd samples and the individual hardware engine is
dedicated for each one. This method can be further enhanced by
multilevel parallelisms.
Abstract: The Quad Tree Decomposition based performance
analysis of compressed image data communication for lossy and
lossless through wireless sensor network is presented. Images have
considerably higher storage requirement than text. While transmitting
a multimedia content there is chance of the packets being dropped
due to noise and interference. At the receiver end the packets that
carry valuable information might be damaged or lost due to noise,
interference and congestion. In order to avoid the valuable
information from being dropped various retransmission schemes have
been proposed. In this proposed scheme QTD is used. QTD is an
image segmentation method that divides the image into homogeneous
areas. In this proposed scheme involves analysis of parameters such
as compression ratio, peak signal to noise ratio, mean square error,
bits per pixel in compressed image and analysis of difficulties during
data packet communication in Wireless Sensor Networks. By
considering the above, this paper is to use the QTD to improve the
compression ratio as well as visual quality and the algorithm in
MATLAB 7.1 and NS2 Simulator software tool.
Abstract: Medical imaging produces human body pictures in
digital form. Since these imaging techniques produce prohibitive
amounts of data, compression is necessary for storage and
communication purposes. Many current compression schemes
provide a very high compression rate but with considerable loss of
quality. On the other hand, in some areas in medicine, it may be
sufficient to maintain high image quality only in region of interest
(ROI). This paper discusses a contribution to the lossless
compression in the region of interest of Scintigraphic images based
on SPIHT algorithm and global transform thresholding using
Huffman coding.
Abstract: This paper presents the voltage problem location
classification using performance of Least Squares Support Vector
Machine (LS-SVM) and Learning Vector Quantization (LVQ) in
electrical power system for proper voltage problem location
implemented by IEEE 39 bus New- England. The data was collected
from the time domain simulation by using Power System Analysis
Toolbox (PSAT). Outputs from simulation data such as voltage, phase
angle, real power and reactive power were taken as input to estimate
voltage stability at particular buses based on Power Transfer Stability
Index (PTSI).The simulation data was carried out on the IEEE 39 bus
test system by considering load bus increased on the system. To verify
of the proposed LS-SVM its performance was compared to Learning
Vector Quantization (LVQ). The results showed that LS-SVM is faster
and better as compared to LVQ. The results also demonstrated that the
LS-SVM was estimated by 0% misclassification whereas LVQ had
7.69% misclassification.
Abstract: This paper presents a study on the effect of
second-order slip on forced convection through a long isoflux heated
or cooled planar microchannel. The fully developed solutions of flow
and thermal fields are analytically obtained on the basis of the
second-order Maxwell-Burnett slip and local heat flux boundary
conditions. Results reveal that when the average flow velocity
increases or the wall heat flux amount decreases, the role of thermal
creep becomes more insignificant, while the effect of second-order slip
becomes larger. The second-order term in the Deissler slip boundary
condition is found to contribute a positive velocity slip and then to lead
to a lower pressure drop as well as a lower temperature rise for the
heated-wall case or to a higher temperature rise for the cooled-wall
case. These findings are contrary to predictions made by the
Karniadakis slip model.
Abstract: This paper presents the experimental results on role of
ionic solutions affect water treeing propagation in cross-linked
polyethylene insulation for high voltage cable. To study the water
treeing expansion due to the ionic solutions, discs of 4mm thickness
and 4cm diameter were taken from 115 kV XLPE insulation cable
and were used as test specimen in this study. Ionic solutions
composed of CuSO4, FeSO4, Na2SO4 and K2SO4 were used. Each
specimen was immersed in 0.1 mole ionic solutions and was tested
for 120 hrs. under a voltage stress at 7 kV AC rms, 1000 Hz. The
results show that Na2SO4 and CuSO4solutions play an important role
in the expansion of water treeing and cause degradation of the crosslinked
polyethylene (XLPE) in the presence of the applied electric
field.
Abstract: When we prefer to make the data secure from various attacks and fore integrity of data, we must encrypt the data before it is transmitted or stored. This paper introduces a new effective and lossless image encryption algorithm using a natural logarithmic function. The new algorithm encrypts an image through a three stage process. In the first stage, a reference natural logarithmic function is generated as the foundation for the encryption image. The image numeral matrix is then analyzed to five integer numbers, and then the numbers’ positions are transformed to matrices. The advantages of this method is useful for efficiently encrypting a variety of digital images, such as binary images, gray images, and RGB images without any quality loss. The principles of the presented scheme could be applied to provide complexity and then security for a variety of data systems such as image and others.
Abstract: The main goal of this study was to find simple and industrially applicable production of ion exchangers based on nanofibrous polystyrene matrix and characterization of prepared material. Starting polystyrene nanofibers were sulfonated and crosslinked under appropriate conditions at the same time by sulfuric acid. Strongly acidic cation exchanger was obtained in such a way. The polymer matrix was made from polystyrene nanofibers prepared by NanospiderTM technology.
Various types postpolymerization reactions and other methods of crosslinking were studied. Greatly different behavior between nano- and microsize materials was observed. The final nanofibrous material was characterized and compared to common granular ion exchangers and available microfibrous ion exchangers. The sorption properties of nanofibrous ion exchangers were compared with the granular ion exchangers. For nanofibrous ion exchangers of comparable ion exchange capacity was observed considerably faster adsorption kinetics.
Abstract: A proton exchange membrane has been developed for
direct methanol fuel cell (DMFC). The nanofiber network composite
membranes were prepared by interconnected network of Nafion
(perfuorosulfonic acid) nanofibers that have been embedded in an
uncharged and inert polymer matrix, by electro-spinning. The
spinning solution of Nafion with a low concentration (1 wt%
compared to Nafion) of high molecular weight poly(ethylene oxide),
as a carrier polymer. The interconnected network of Nafion
nanofibers with average fiber diameter in the range of 160-700nm,
were used to make the membranes, with the nanofiber occupying up
to 85% of the membrane volume. The matrix polymer was
crosslinked with Norland Optical Adhesive 63 under UV. The
resulting membranes showed proton conductivity of 0.10 S/cm at
25°C and 80% RH; and methanol permeability of 3.6 x 10-6 cm2/s.
Abstract: Rice grain is Sierra Leone’s staple food and the nation
imports over 120,000 metric tons annually due to a shortfall in its
cultivation. Thus, the insufficient level of the crop's cultivation in
Sierra Leone is caused by many problems and this led to the
endlessly widening supply and demand for the crop within the
country. Consequently, this has instigated the government to spend
huge money on the importation of this grain that would have been
otherwise cultivated domestically at a cheaper cost. Hence, this
research attempts to explore the response of rice supply with respect
to its demand in Sierra Leone within the period 1980-2010.
The Nerlovian adjustment model to the Sierra Leone rice data set
within the period 1980-2010 was used. The estimated trend equations
revealed that time had significant effect on output, productivity
(yield) and area (acreage) of rice grain within the period 1980-2010
and this occurred generally at the 1% level of significance. The
results showed that, almost the entire growth in output had the
tendency to increase in the area cultivated to the crop. The time trend
variable that was included for government policy intervention
showed an insignificant effect on all the variables considered in this
research. Therefore, both the short-run and long-run price response
was inelastic since all their values were less than one.
From the findings above, immediate actions that will lead to
productivity growth in rice cultivation are required.
To achieve the above, the responsible agencies should provide
extension service schemes to farmers as well as motivating them on
the adoption of modern rice varieties and technology in their rice
cultivation ventures.
Abstract: Environmental and toxicological characteristics of formulated pesticides may substantially differ from those of their active ingredients or other components alone. This phenomenon is demonstrated in the case of the herbicide active ingredient glyphosate. Due to its extensive application, this active ingredient was found in surface and ground water samples collected in Békés County, Hungary, in the concentration range of 0.54–0.98 ng/ml. The occurrence of glyphosate appeared to be somewhat higher at areas under intensive agriculture, industrial activities and public road services, but the compound was detected at areas under organic (ecological) farming or natural grasslands, indicating environmental mobility. Increased toxicity of the formulated herbicide product Roundup compared to that of glyphosate was observed on the indicator aquatic organism Daphnia magna Straus. Acute LC50 values of Roundup and its formulating adjuvant polyethoxylated tallowamine (POEA) exceeded 20 and 3.1 mg/ml, respectively, while that of glyphosate (as isopropyl salt) was found to be substantially lower (690-900 mg/ml) showing good agreement with literature data. Cytotoxicity of Roundup, POEA and glyphosate has been determined on the neuroectodermal cell line, NE-4C measured both by cell viability test and holographic microscopy. Acute toxicity (LC50) of Roundup, POEA and glyphosate on NE-4C cells was found to be 0.013±0.002%, 0.017±0.009% and 6.46±2.25%, respectively (in equivalents of diluted Roundup solution), corresponding to 0.022±0.003 and 53.1±18.5 mg/ml for POEA and glyphosate, respectively, indicating no statistical difference between Roundup and POEA and 2.5 orders of magnitude difference between these and glyphosate. The same order of cellular toxicity seen in average cell area has been indicated under quantitative cell visualization. The results indicate that toxicity of the formulated herbicide is caused by the formulating agent, but in some parameters toxicological synergy occurs between POEA and glyphosate.
Abstract: Grasslands of Iran are encountered with a vast
desertification and destruction. Some legumes are plants of forage
importance with high palatability. Studied legumes in this project are
Onobrychis, Medicago sativa (alfalfa) and Trifolium repens. Seeds
were cultivated in research field of Kaboutarabad (33 km East of
Isfahan, Iran) with an average 80 mm. annual rainfall. Plants were
cultivated in a split plot design with 3 replicate and two water
treatments (weekly irrigation, and under stress with same amount per
15 days interval). Water entrance to each plots were measured by
Partial flow. This project lasted 20 weeks. Destructive samplings
(1m2 each time) were done weekly. At each sampling plants were
gathered and weighed separately for each vegetative parts. An Area
Meter (Vista) was used to measure root surface and leaf area. Total
shoot and root fresh and dry weight, leaf area index and soil coverage
were evaluated too. Dry weight was achieved in 750c oven after 24
hours. Statgraphic and Harvard Graphic software were used to
formulate and demonstrate the parameters curves due to time. Our
results show that Trifolium repens has affected 60 % and Medicago
sativa 18% by water stress. Onobrychis total fresh weight was
reduced 45%. Dry weight or Biomass in alfalfa is not so affected by
water shortage. This means that in alfalfa fields we can decrease the
irrigation amount and have some how same amount of Biomass.
Onobrychis show a drastic decrease in Biomass. The increases in
total dry matter due to time in studied plants are formulated. For
Trifolium repens if removal or cattle entrance to meadows do not
occurred at perfect time, it will decrease the palatability and water
content of the shoots. Water stress in a short period could develop the
root system in Trifolium repens, but if it last more than this other
ecological and soil factors will affect the growth of this plant. Low
level of soil water is not so important for studied legume forges. But
water shortage affect palatability and water content of aerial parts.
Leaf area due to time in studied legumes is formulated. In fact leaf
area is decreased by shortage in available water. Higher leaf area
means higher forage and biomass production. Medicago and
Onobrychis reach to the maximum leaf area sooner than Trifolium
and are able to produce an optimum soil cover and inhibit the
transpiration of soil water of meadows. Correlation of root surface to
Total biomass in studied plants is formulated. Medicago under water
stress show a 40% decrease in crown cover while at optimum
condition this amount reach to 100%. In order to produce forage in
areas without soil erosion Medicago is the best choice even with a
shortage in water resources. It is tried to represent the growth
simulation of three famous Forage Legumes. By growth simulation
farmers and range managers could better decide to choose best plant
adapted to water availability without designing different time and
labor consuming field experiments.
Abstract: Preparation of hydrogel based on carrageenan
extracted from Kappaphycus alvarezii was conducted with film
immersion in glutaraldehyde solution (GA 4%w/w) for 2min and
then followed by thermal curing at 110°C for 25min. The method of
carrageenan recovery strongly determines the properties of
crosslinked carrageenan. Hydrogel obtained from alkali treated
carrageenan showed higher swelling ability compared to hydrogel
from nonalkali treated carrageenan. Hydrogel from alkali treated
showed the ability of sensitive to pH media.
Abstract: Swietenia mahagoni have been used in traditional
medicine for treatment of different diseases. Present study was
performed to evaluate anti-ulcerogenic activity of ethanol seed
extract against ethanol induced gastric mucosal injury in rats. Six
groups of rats were orally pre-treated respectively with
carboxymethyl cellulose, omeprazole 20 mg/kg, 50, 100, 200 and 400
mg/kg plant extract one hour before oral administration of absolute
ethanol to generate gastric mucosal injury. After additional hour, rats
were sacrificed and ulcer areas of gastric walls were determined.
Grossly, carboxymethyl cellulose group exhibited severe mucosal
injury, whereas pre-treatment with plant extract exhibited significant
protection of gastric mucosa. Histology, carboxymethyl cellulose
group exhibited severe damage of gastric mucosa; edema and
leucocytes infiltration of sub mucosa compared to plant extract which
showed gastric protection. Acute toxicity study did not manifest any
toxicological signs in rats. Conclusions, results suggest that S.
mahagoni promotes ulcer protection as ascertained grossly and
histologically.