Abstract: In this study, multiwall carbon nanotubes (MWNTs)
were modified with nitric acid chemically and by dielectric barrier
discharge (DBD) plasma in an oxygen-based atmosphere. Used
carbon nanotubes (CNTs) were prepared by chemical vapour
deposition (CVD) floating catalyst method. For removing amorphous
carbon and metal catalyst, MWNTs were exposed to dry air and
washed with hydrochloric acid. Heating purified CNTs under helium
atmosphere caused elimination of acidic functional groups. Fourier
transformed infrared spectroscopy (FTIR) shows formation of
oxygen containing groups such as C=O and COOH. Brunauer,
Emmett, Teller (BET) analysis revealed that functionalization causes
generation of defects on the sidewalls and opening of the ends of
CNTs. Results of temperature-programmed desorption (TPD) and gas
chromatography(GC) indicate that nitric acid treatment create more
acidic groups than plasma treatment.
Abstract: The effects of ethylene (C2H4) feed position and
O2/C2H4 feed molar ratio on ethylene epoxidation in a parallel
dielectric barrier discharge (DBD) were studied. The results showed
that the ethylene feed position fraction of 0.5 and the feed molar
ratio of O2/C2H4 of 0.2:1 gave the highest EO selectivity of 34.3%
and the highest EO yield of 5.28% with low power consumptions of
2.11×10-16 Ws/molecule of ethylene converted and 6.34×10-16
Ws/molecule of EO produced when the DBD system was operated
under the best conditions: an applied voltage of 19 kV, an input
frequency of 500 Hz and a total feed flow rate of 50 cm3/min. The
separate ethylene feed system provided much higher epoxidation
activity as compared to the mixed feed system which gave EO
selectivity of 15.5%, EO yield of 2.1% and the power consumption of
EO produced of 7.7×10-16 Ws/molecule.
Abstract: In this paper a numerical simulation of electric and
hydrodynamic fields distribution in an electrofilter for dielectric
liquids cell is made. The simulation is made with the purpose to
determine the trajectory of particles that moves under the action of
external force in an electric and hydrodynamic field created inside of
an electrofilter for dielectric liquids. Particle trajectory is analyzed
for a dielectric liquid-solid particles suspension.
Abstract: Dielectric sheet perturbation to the dominant TE111
mode resonant frequency of a circular cavity is studied and presented
in this paper. The dielectric sheet, placed at the middle of the airfilled
cavity, introduces discontinuities and disturbs the configuration
of electromagnetic fields in the cavity. For fixed dimensions of cavity
and fixed thickness of the loading dielectric, the dominant resonant
frequency varies quite linearly with the permittivity of the dielectric.
This quasi-linear relationship is plotted using Maple software and
verified using 3D electromagnetic simulations. Two probes are used
in the simulation for wave excitation into and from the cavity. The
best length of probe is found to be 3 mm, giving the closest resonant
frequency to the one calculated using Maple. A total of fourteen
different dielectrics of permittivity ranging from 1 to 12.9 are tested
one by one in the simulation. The works show very close agreement
between the results from Maple and the simulation. A constant
difference of 0.04 GHz is found between the resonant frequencies
collected during simulation and the ones from Maple. The success of
this project may lead to the possibility of using the middle loaded
cavity at TE111 mode as a microwave non-destructive testing of solid
materials.
Abstract: Recently, bianisotropic media again received
increasing importance in electromagnetic theory because of advances
in material science which enable the manufacturing of complex
bianisotropic materials. By using Maxwell's equations and
corresponding boundary conditions, the electromagnetic field
distribution in bianisotropic solenoid coils is determined and the
influence of the bianisotropic behaviour of coil to the impedance and
Q-factor is considered. Bianisotropic media are the largest class of
linear media which is able to describe the macroscopic material
properties of artificial dielectrics, artificial magnetics, artificial chiral
materials, left-handed materials, metamaterials, and other composite
materials. Several special cases of coils, filled with complex
substance, have been analyzed. Results obtained by using the
analytical approach are compared with values calculated by
numerical methods, especially by our new hybrid EEM/BEM method
and FEM.
Abstract: The mechanism of microwave heating is essentially
that of dielectric heating. After exposing the emulsion to the
microwave Electromagnetic (EM) field, molecular rotation and ionic
conduction due to the penetration of (EM) into the emulsion are
responsible for the internal heating. To determine the capability of
microwave technology in demulsification of crude oil emulsions,
microwave demulsification method was applied in a 50-50 % and 20-
80 % water-in-oil emulsions with microwave exposure time varied
from 20-180 sec. Transient temperature profiles of water-in-oil
emulsions inside a cylindrical container were measured. The
temperature rise at a given location was almost horizontal (linear).
The average rates of temperature increase of 50-50 % and 20-80 %
water-in-oil emulsions are 0.351 and 0.437 oC/sec, respectively. The
rate of temperature increase of emulsions decreased at higher
temperature due to decreasing dielectric loss of water. These results
indicate that microwave demulsification of water-in-oil emulsions
does not require chemical additions. Microwave has the potential to
be used as an alternative way in the demulsification process.
Abstract: The computer modeling is carried out for parameter of
sensitivity of optoelectronic chemical and biosensors, using
phenomena of surface plasmon resonance (SPR). The physical model
of SPR-sensor-s is described with (or without) of modifications of
sensitive gold film surface by a dielectric layer. The variants of
increasing of sensitivity for SPR-biosensors, constructed on the
principle gold – dielectric – biomolecular layer are considered. Two
methods of mathematical treatment of SPR-curve are compared –
traditional, with estimation of sensor-s response as shift of the SPRcurve
minimum and proposed, for system with dielectric layer, using
calculating of the derivative in the point of SPR-curve half-width.
Abstract: In this paper we discuss the behaviour of the longitudinal modes of a magnetized non collisional plasma subjected to an external electromagnetic field. We apply a semiclassical formalism, with the electrons being studied in a quantum mechanical viewpoint whereas the electromagnetic field in the classical context. We calculate the dielectric function in order to obtains the modes and found that, unlike the Bernstein modes, the presence of radiation induces oscillations around the cyclotron harmonics, which are smoothed as the energy stored in the radiation field becomes small compared to the thermal energy of the electrons. We analyze the influence of the number of photon involved in the electronic transitions between the Landau levels and how the parameters such as the external fields strength, plasma density and temperature affect the dispersion relation
Abstract: In this paper, gate leakage current has been mitigated
by the use of novel nanoscale MOSFET with Source/Drain-to-Gate
Non-overlapped and high-k spacer structure for the first time. A
compact analytical model has been developed to study the gate
leakage behaviour of proposed MOSFET structure. The result
obtained has found good agreement with the Sentaurus Simulation.
Fringing gate electric field through the dielectric spacer induces
inversion layer in the non-overlap region to act as extended S/D
region. It is found that optimal Source/Drain-to-Gate Non-overlapped
and high-k spacer structure has reduced the gate leakage current to
great extent as compared to those of an overlapped structure. Further,
the proposed structure had improved off current, subthreshold slope
and DIBL characteristic. It is concluded that this structure solves the
problem of high leakage current without introducing the extra series
resistance.
Abstract: In this paper we investigate the electrical
characteristics of a new structure of gate all around strained silicon
nanowire field effect transistors (FETs) with dual dielectrics by
changing the radius (RSiGe) of silicon-germanium (SiGe) wire and
gate dielectric. Indeed the effect of high-κ dielectric on Field Induced
Barrier Lowering (FIBL) has been studied. Due to the higher electron
mobility in tensile strained silicon, the n-type FETs with strained
silicon channel have better drain current compare with the pure Si
one. In this structure gate dielectric divided in two parts, we have
used high-κ dielectric near the source and low-κ dielectric near the
drain to reduce the short channel effects. By this structure short
channel effects such as FIBL will be reduced indeed by increasing
the RSiGe, ID-VD characteristics will be improved. The leakage
current and transfer characteristics, the threshold-voltage (Vt), the
drain induced barrier height lowering (DIBL), are estimated with
respect to, gate bias (VG), RSiGe and different gate dielectrics. For
short channel effects, such as DIBL, gate all around strained silicon
nanowire FET have similar characteristics with the pure Si one while
dual dielectrics can improve short channel effects in this structure.
Abstract: High voltage generators are being subject to higher
voltage rating and are being designed to operate in harsh conditions.
Stator windings are the main component of generators in which
Electrical, magnetically and thermal stresses remain major failures
for insulation degradation accelerated aging. A large number of
generators failed due to stator winding problems, mainly insulation
deterioration. Insulation degradation assessment plays vital role in the
asset life management. Mostly the stator failure is catastrophic
causing significant damage to the plant. Other than generation loss,
stator failure involves heavy repair or replacement cost. Electro
thermal analysis is the main characteristic for improvement design of
stator slot-s insulation. Dielectric parameters such as insulation
thickness, spacing, material types, geometry of winding and slot are
major design consideration. A very powerful method available to
analyze electro thermal performance is Finite Element Method
(FEM) which is used in this paper. The analysis of various stator coil
and slot configurations are used to design the better dielectric system
to reduce electrical and thermal stresses in order to increase the
power of generator in the same volume of core. This paper describes
the process used to perform classical design and improvement
analysis of stator slot-s insulation.
Abstract: The electromagnetic imaging of inhomogeneous
dielectric cylinders buried in a slab medium by transverse electric
(TE) wave illumination is investigated. Dielectric cylinders of
unknown permittivities are buried in second space and scattered a
group of unrelated waves incident from first space where the scattered
field is recorded. By proper arrangement of the various unrelated
incident fields, the difficulties of ill-posedness and nonlinearity are
circumvented, and the permittivity distribution can be reconstructed
through simple matrix operations. The algorithm is based on the
moment method and the unrelated illumination method. Numerical
results are given to demonstrate the capability of the inverse
algorithm. Good reconstruction is obtained even in the presence of
additive Gaussian random noise in measured data. In addition, the
effect of noise on the reconstruction result is also investigated.
Abstract: A time-domain numerical model within the
framework of transmission line modeling (TLM) is developed to
simulate electromagnetic pulse propagation inside multiple
microcavities forming photonic crystal (PhC) structures. The model
developed is quite general and is capable of simulating complex
electromagnetic problems accurately. The field quantities can be
mapped onto a passive electrical circuit equivalent what ensures that
TLM is provably stable and conservative at a local level.
Furthermore, the circuit representation allows a high level of
hybridization of TLM with other techniques and lumped circuit
models of components and devices. A photonic crystal structure
formed by rods (or blocks) of high-permittivity dieletric material
embedded in a low-dielectric background medium is simulated as an
example. The model developed gives vital spatio-temporal
information about the signal, and also gives spectral information over
a wide frequency range in a single run. The model has wide
applications in microwave communication systems, optical
waveguides and electromagnetic materials simulations.
Abstract: Air bubbles have been detected in human circulation
of end-stage renal disease patients who are treated by hemodialysis.
The consequence of air embolism, air bubbles, is under recognized
and usually overlooked in daily practice. This paper shows results of
a capacitor based detection method that capable of detecting the
presence of air bubbles in the blood stream in different frequencies.
The method is based on a parallel plates capacitor made of platinum
with an area of 1.5 cm2 and a distance between the two plates is 1cm.
The dielectric material used in this capacitor is Dextran70 solution
which mimics blood rheology. Simulations were carried out using
RC circuit at two frequencies 30Hz and 3 kHz and results compared
with experiments and theory. It is observed that by injecting air
bubbles of different diameters into the device, there were significant
changes in the capacitance of the capacitor. Furthermore, it is
observed that the output voltage from the circuit increased with
increasing air bubble diameter. These results demonstrate the
feasibility of this approach in improving air bubble detection in
Hemodialysis.
Abstract: In the past decade, the development of microstrip
sensor application has evolved tremendously. Although cut and trial
method was adopted to develop microstrip sensing applications in the
past, Computer-Aided-Design (CAD) is a more effective as it ensures
less time is consumed and cost saving is achieved in developing
microstrip sensing applications. Therefore microstrip sensing
applications has gained popularity as an effective tool adopted in
continuous sensing of moisture content particularly in products that is
administered mainly by liquid content. In this research, the Cole-Cole
representation of reactive relaxation is applied to assess the
performance of the microstrip sensor devices. The microstrip sensor
application is an effective tool suitable for sensing the moisture
content of dielectric material. Analogous to dielectric relaxation
consideration of Cole-Cole diagrams as applied to dielectric
materials, a “reactive relaxation concept” concept is introduced to
represent the frequency-dependent and moisture content
characteristics of microstrip sensor devices.
Abstract: Hydrogen is an important chemical in many industries
and it is expected to become one of the major fuels for energy
generation in the future. Unfortunately, hydrogen does not exist in its
elemental form in nature and therefore has to be produced from
hydrocarbons, hydrogen-containing compounds or water.
Above its critical point (374.8oC and 22.1MPa), water has lower
density and viscosity, and a higher heat capacity than those of
ambient water. Mass transfer in supercritical water (SCW) is
enhanced due to its increased diffusivity and transport ability. The
reduced dielectric constant makes supercritical water a better solvent
for organic compounds and gases. Hence, due to the aforementioned
desirable properties, there is a growing interest toward studies
regarding the gasification of organic matter containing biomass or
model biomass solutions in supercritical water.
In this study, hydrogen and biofuel production by the catalytic
gasification of 2-Propanol in supercritical conditions of water was
investigated. Pt/Al2O3and Ni/Al2O3were the catalysts used in the
gasification reactions. All of the experiments were performed under a
constant pressure of 25MPa. The effects of five reaction temperatures
(400, 450, 500, 550 and 600°C) and five reaction times (10, 15, 20,
25 and 30 s) on the gasification yield and flammable component
content were investigated.
Abstract: The operating control parameters of injection
flushing type of electrical discharge machining process on stainless
steel 304 workpiece using copper tools are being optimized
according to its individual machining characteristic i.e. Electrode
Wear Ratio (EWR). Higher EWR would give bad dimensional
precision for the EDM machined workpiece because of high
electrode wear. Hence, the quality characteristic for EWR is set to
lower-the-better to achieve the optimum dimensional precision for
the machined workpiece. Taguchi method has been used for the
construction, layout and analysis of the experiment for EWR
machining characteristic. The use of Taguchi method in the
experiment saves a lot of time and cost of preparing and machining
the experiment samples. Therefore, an L18 Orthogonal array
which was the fundamental component in the statistical design of
experiments has been used to plan the experiments and Analysis of
Variance (ANOVA) is used to determine the optimum machining
parameters for this machining characteristic. The control
parameters selected for this optimization experiments are polarity,
pulse on duration, discharge current, discharge voltage, machining
depth, machining diameter and dielectric liquid pressure. The
result had shown that negative polarity machining parameter
setting will decreases EWR.
Abstract: A power cable is widely used for power supply in
power distributing networks and power transmission lines. Due to
limitations in the production, delivery and setting up power cables,
they are produced and delivered in several separate lengths. Cable
itself, consists of two cable terminations and arbitrary number of
cable joints, depending on the cable route length. Electrical stress
control is needed to prevent a dielectric breakdown at the end of the
insulation shield in both the air and cable insulation. Reliability of
cable joint depends on its materials, design, installation and operating
environment. The paper describes design and performance results for
new modeled cable joints. Design concepts, based on numerical
calculations, must be correct. An Equivalent Electrodes
Method/Boundary Elements Method-hybrid approach that allows
electromagnetic field calculations in multilayer dielectric media,
including inhomogeneous regions, is presented.
Abstract: High performance Resistive Random Access Memory
(RRAM) based on HfOx has been prepared and its temperature
instability has been investigated in this work. With increasing
temperature, it is found that: leakage current at high resistance state
increases, which can be explained by the higher density of traps
inside dielectrics (related to trap-assistant tunneling), leading to a
smaller On/Off ratio; set and reset voltages decrease, which may be
attributed to the higher oxygen ion mobility, in addition to the
reduced potential barrier to create / recover oxygen ions (or oxygen
vacancies); temperature impact on the RRAM retention degradation
is more serious than electrical bias.
Abstract: Three reactor types were explored and successfully
used for pigment production by Monascus: shake flasks, and shaken
and stirred miniaturized reactors. Also, the use of dielectric
spectroscopy for the on-line measurement of biomass levels was
explored. Shake flasks gave good pigment yields, but scale up is
difficult, and they cannot be automated. Shaken bioreactors were less
successful with pigment production than stirred reactors.
Experiments with different impeller speeds in different volumes of
liquid in the reactor confirmed that this is most likely due oxygen
availability. The availability of oxygen appeared to affect biomass
levels less than pigment production; red pigment production in
particular needed very high oxygen levels. Dielectric spectroscopy
was effectively used to continuously measure biomass levels during
the submerged fungal fermentation in the shaken and stirred
miniaturized bioreactors, despite the presence of the solid substrate
particles. Also, the capacitance signal gave useful information about
the viability of the cells in the culture.