Abstract: Polyaniline is an indispensible component in lightemitting
devices (LEDs), televisions, cellular telephones, automotive,
corrosion-resistant coatings, actuators etc. The electrical conductivity
properties was found be increased by introduction of metal nano
particles. In the present study, an attempt has been made to utilize
platinum nano particles to achieve the improved electrical properties.
Polyaniline and Pt-polyaniline composite are synthesized by
electrochemical routes. X-ray diffractometer confirms the amorphous
nature of polyaniline. The Bragg’s diffraction peaks correspond to
platinum nanoparticles in Pt-polyaniline composite and
thermogravimetric analyzer indicates its decomposition at certain
temperature. The Scanning Electron Micrographs of colloidal
platinum nanoparticles were spherical, uniform shape in the
composite. The current-voltage (I-V) characteristics of the PANI and
composites were also studied which indicate a significant decreasing
resistivity than PANI-Platinum after introduction of pt nanoparticles
in the matrix of polyaniline (PANI).
Abstract: Ceramic Waste Aggregates (CWAs) were made from
electric porcelain insulator wastes supplied from an electric power
company, which were crushed and ground to fine aggregate sizes. In
this study, to develop the CWA mortar as an eco–efficient, ground
granulated blast–furnace slag (GGBS) as a Supplementary
Cementitious Material (SCM) was incorporated. The water–to–binder
ratio (W/B) of the CWA mortars was varied at 0.4, 0.5, and 0.6. The
cement of the CWA mortar was replaced by GGBS at 20 and 40% by
volume (at about 18 and 37% by weight). Mechanical properties of
compressive and splitting tensile strengths, and elastic modulus were
evaluated at the age of 7, 28, and 91 days. Moreover, the chloride
ingress test was carried out on the CWA mortars in a 5.0% NaCl
solution for 48 weeks. The chloride diffusion was assessed by using an
electron probe microanalysis (EPMA). To consider the relation of the
apparent chloride diffusion coefficient and the pore size, the pore size
distribution test was also performed using a mercury intrusion
porosimetry at the same time with the EPMA. The compressive
strength of the CWA mortars with the GGBS was higher than that
without the GGBS at the age of 28 and 91 days. The resistance to the
chloride ingress of the CWA mortar was effective in proportion to the
GGBS replacement level.
Abstract: DNA Barcode provides good sources of needed
information to classify living species. The classification problem has
to be supported with reliable methods and algorithms. To analyze
species regions or entire genomes, it becomes necessary to use the
similarity sequence methods. A large set of sequences can be
simultaneously compared using Multiple Sequence Alignment which
is known to be NP-complete. However, all the used methods are still
computationally very expensive and require significant computational
infrastructure. Our goal is to build predictive models that are highly
accurate and interpretable. In fact, our method permits to avoid the
complex problem of form and structure in different classes of
organisms. The empirical data and their classification performances
are compared with other methods. Evenly, in this study, we present
our system which is consisted of three phases. The first one, is called
transformation, is composed of three sub steps; Electron-Ion
Interaction Pseudopotential (EIIP) for the codification of DNA
Barcodes, Fourier Transform and Power Spectrum Signal Processing.
Moreover, the second phase step is an approximation; it is
empowered by the use of Multi Library Wavelet Neural Networks
(MLWNN). Finally, the third one, is called the classification of DNA
Barcodes, is realized by applying the algorithm of hierarchical
classification.
Abstract: In this study, to clarify the effectiveness of an
aluminum/chromium/tungsten-based-coated tool for cutting sintered
steel, tool wear was experimentally investigated. The sintered steel
was turned with the (Al60,Cr25,W15)N-, (Al60,Cr25,W15)(C,N)- and
(Al64,Cr28,W8)(C,N)-coated cemented carbide tools according to the
physical vapor deposition (PVD) method. Moreover, the tool wear of
the aluminum/chromium/tungsten-based-coated item was compared
with that of the (Al,Cr)N coated tool. Furthermore, to clarify the tool
wear mechanism of the aluminum/chromium/tungsten-coating film for
cutting sintered steel, Scanning Electron Microscope observation and
Energy Dispersive x-ray Spectroscopy mapping analysis were
conducted on the abraded surface. The following results were
obtained: (1) The wear progress of the (Al64,Cr28,W8)(C,N)-coated
tool was the slowest among that of the five coated tools. (2) Adding
carbon (C) to the aluminum/chromium/tungsten-based-coating film
was effective for improving the wear-resistance. (3) The main wear
mechanism of the (Al60,Cr25,W15)N-, the (Al60,Cr25,W15)(C,N)-
and the (Al64,Cr28,W8)(C,N)-coating films was abrasive wear.
Abstract: Superabsorbent polymers received much attention and
are used in many fields because of their superior characters to
traditional absorbents, e.g., sponge and cotton. So, it is very
important but challenging to prepare highly and fast-swelling
superabsorbents. A reliable, efficient and low-cost technique for
removing heavy metal ions from wastewater is the adsorption using
bio-adsorbents obtained from biological materials, such as
polysaccharides-based hydrogels superabsorbents. In this study, novel multi-functional superabsorbent composites
type semi-interpenetrating polymer networks (Semi-IPNs) were
prepared via graft polymerization of acrylamide onto chitosan
backbone in presence of gelatin, CTS-g-PAAm/Ge, using potassium
persulfate and N,N’-methylene bisacrylamide as initiator and
crosslinker, respectively. These hydrogels were also partially
hydrolyzed to achieve superabsorbents with ampholytic properties
and uppermost swelling capacity. The formation of the grafted
network was evidenced by Fourier Transform Infrared Spectroscopy
(ATR-FTIR) and Thermogravimetric Analysis (TGA). The porous
structures were observed by Scanning Electron Microscope (SEM).
From TGA analysis, it was concluded that the incorporation of the Ge
in the CTS-g-PAAm network has marginally affected its thermal
stability. The effect of gelatin content on the swelling capacities of
these superabsorbent composites was examined in various media
(distilled water, saline and pH-solutions). The water absorbency was
enhanced by adding Ge in the network, where the optimum value was
reached at 2 wt. % of Ge. Their hydrolysis has not only greatly
optimized their absorption capacity but also improved the swelling
kinetic.These materials have also showed reswelling ability. We
believe that these super-absorbing materials would be very effective
for the adsorption of harmful metal ions from wastewater.
Abstract: Processing of Al-19.4Si alloy by high intensive
electron beam has been carried out and multiple increases in fatigue
life of the material have been revealed. Investigations of structure and
surface modified layer destruction of Al-19.4Si alloy subjected to
multicycle fatigue tests to fracture have been carried out by methods
of scanning electron microscopy. The factors responsible for the
increase of fatigue life of Al-19.4Si alloy have been revealed and
analyzed.
Abstract: The work aims to develop a robot in the form of
autonomous vehicle to detect, inspection and mapping of
underground pipelines through the ATmega328 Arduino platform.
Hardware prototyping is very similar to C / C ++ language that
facilitates its use in robotics open source, resembles PLC used in
large industrial processes. The robot will traverse the surface
independently of direct human action, in order to automate the
process of detecting buried pipes, guided by electromagnetic
induction. The induction comes from coils that send the signal to the
Arduino microcontroller contained in that will make the difference in
intensity and the treatment of the information, and then this
determines actions to electrical components such as relays and
motors, allowing the prototype to move on the surface and getting the
necessary information. This change of direction is performed by a
stepper motor with a servo motor. The robot was developed by
electrical and electronic assemblies that allowed test your application.
The assembly is made up of metal detector coils, circuit boards and
microprocessor, which interconnected circuits previously developed
can determine, process control and mechanical actions for a robot
(autonomous car) that will make the detection and mapping of buried
pipelines plates. This type of prototype can prevent and identifies
possible landslides and they can prevent the buried pipelines suffer an
external pressure on the walls with the possibility of oil leakage and
thus pollute the environment.
Abstract: Let us consider that the entire universe is composed of
a single hydrogen atom within which the electron is moving around
the proton. In this case, according to classical theories of physics,
radiation, photons respectively, should be absorbed by the electron.
Depending on the number of photons absorbed, the electron radius of
rotation around the proton is established. Until now, the principle of
photons absorption by electrons and the electron transition to a new
energy level, namely to a higher radius of rotation around the proton,
is not clarified in physics. This paper aims to demonstrate that
radiation, photons respectively, have mass and negative electrostatic
charge similar to electrons but infinitely smaller. The experiments
which demonstrate this theory are simple: thermal expansion,
photoelectric effect and thermonuclear reaction.
Abstract: The Figaro AM-1 sensor module which employs TGS
2600 model gas sensor in air quality assessment was used. The
system was coupled with a microprocessor that enables sensor
module to create warning message via telephone. This low cot sensor
system’s performance was compared with a DiagNose II commercial
electronic nose system. Both air quality sensor and electronic nose
system employ metal oxide chemical gas sensors. In the study
experimental setup, data acquisition methods for electronic nose
system, and performance of the low cost air quality system were
evaluated and explained.
Abstract: The future and the development of science is therefore
seen in interdisciplinary areas such as biomedical engineering. Selfassembled
structures, similar to stem cell niches would inhibit fast
division process and subsequently capture the stem cells from the
blood flow. By means of surface topography and the stiffness as well
as microstructure progenitor cells should be differentiated towards
the formation of endothelial cells monolayer which effectively will
inhibit activation of the coagulation cascade. The idea of the material
surface development met the interest of the clinical institutions,
which support the development of science in this area and are waiting
for scientific solutions that could contribute to the development of
heart assist systems. This would improve the efficiency of the
treatment of patients with myocardial failure, supported with artificial
heart assist systems. Innovative materials would enable the redesign,
in the post project activity, construction of ventricular heart assist.
Abstract: Using the quantum hydrodynamic (QHD) model the
nonlinear properties of ion-acoustic waves in are lativistically
degenerate quantum plasma is investigated by deriving a nonlinear
Spherical Kadomtsev–Petviashvili (SKP) equation using the
standard reductive perturbation method equation. It was found that
the electron degeneracy parameter significantly affects the linear
and nonlinear properties of ion-acoustic waves in quantum plasma.
Abstract: Aluminium matrix composites with alumina
reinforcements give superior mechanical & physical properties. Their
applications in several fields like automobile, aerospace, defense,
sports, electronics, bio-medical and other industrial purposes are
becoming essential for the last several decades. In the present work,
fabrication of hybrid composite was done by Stir casting technique
using Al 6061 as a matrix with alumina and silicon carbide (SiC) as
reinforcement materials. The weight percentage of alumina is varied
from 2 to 4% and the silicon carbide weight percentage is maintained
constant at 2%. Hardness and wear tests are performed in the as cast
and heat treated conditions. Age hardening treatment was performed
on the specimen with solutionizing at 550°C, aging at two
temperatures (150 and 200°C) for different time durations. Hardness
distribution curves are drawn and peak hardness values are recorded.
Hardness increase was very sensitive with respect to the decrease in
aging temperature. There was an improvement in wear resistance of
the peak aged material when aged at lower temperature. Also
increase in weight percent of alumina, increases wear resistance at
lower temperature but opposite behavior was seen when aged at
higher temperature.
Abstract: The nanoindentation behaviour and phase
transformation of annealed single-crystal silicon wafers are examined.
The silicon specimens are annealed at temperatures of 250, 350 and
450ºC, respectively, for 15 minutes and are then indented to maximum
loads of 30, 50 and 70 mN. The phase changes induced in the indented
specimens are observed using transmission electron microscopy
(TEM) and micro-Raman scattering spectroscopy (RSS). For all
annealing temperatures, an elbow feature is observed in the unloading
curve following indentation to a maximum load of 30 mN. Under
higher loads of 50 mN and 70 mN, respectively, the elbow feature is
replaced by a pop-out event. The elbow feature reveals a complete
amorphous phase transformation within the indented zone, whereas
the pop-out event indicates the formation of Si XII and Si III phases.
The experimental results show that the formation of these crystalline
silicon phases increases with an increasing annealing temperature and
indentation load. The hardness and Young’s modulus both decrease as
the annealing temperature and indentation load are increased.
Abstract: In the present research work we present the optical
emission studies of the Indium (In) – Tin (Sn) plasma produced by
the first (1064 nm) harmonic of an Nd: YAG nanosecond pulsed
laser. The experimentally observed line profiles of neutral Indium (In
I) and Tin (SnI) are used to extract the electron temperature (Te)
using the Boltzmann plot method. Whereas, the electron number
density (Ne) has been determined from the Stark broadening line
profile method. The Te is calculated by varying the distance from the
target surface along the line of propagation of plasma plume and also
by varying the laser irradiance. Beside we have studied the variation
of Ne as a function of laser irradiance as well as its variation with
distance from the target surface.
Abstract: Development of new generation bio-tribological,
multilayer coatings opens an avenue for fabrication of future hightech
functional surfaces. In the presented work, nano-composite,
Cr/CrN+[Cr/ a-C:H implanted by metallic nanocrystals] multilayer
coatings have been developed for surface protection of medical tools.
Thin films were fabricated by a hybrid Pulsed Laser Deposition
technique. Complex microstructure analysis of nanomultilayer
coatings, subjected to mechanical and biological tests, were
performed by means of transmission electron microscopy (TEM).
Microstructure characterization revealed the layered arrangement of
Cr23C6 nanoparticles in multilayer structure. Influence of deposition
conditions on bio-tribological properties of the coatings was studied.
The bio-tests were used as a screening tool for the analyzed
nanomultilayer coatings before they could be deposited on medical
tools. Bio-medical tests were done using fibroblasts. The mechanical
properties of the coatings were investigated by means of a ball-ondisc
mechanical test. The micro hardness was done using Berkovich
indenter. The scratch adhesion test was done using Rockwell
indenter. From the bio-tribological point of view, the optimal
properties had the C106_1 material.
Abstract: The effect of partially substitution of magnetic
impurity Fe for Cu to the magnetic and transport properties in
electron-doped superconducting cuprates of
Eu1.85+yCe0.15-yCu1-yFeyO4+α-δ (ECCFO) with y = 0, 0.010, 0.020, and
0.050 has been studied, in order to investigate the mechanism of
magnetic and transport properties of ECCFO in normal-state.
Magnetic properties are investigated by DC magnetic-susceptibility
measurements that carried out at low temperatures down to 2 K using a
standard SQUID magnetometer in a magnetic field of 5 Oe on field
cooling. Transport properties addressed to electron mobility, are
extracted from radius of electron localization calculated from
temperature dependence of resistivity. For y = 0, temperature
dependence of dc magnetic-susceptibility (χ) indicated the change of
magnetic behavior from paramagnetic to diamagnetic below 15 K.
Above 15 K, all samples show paramagnetic behavior with the values
of magnetic moment in every volume unit increased with increasing y.
Electron mobility decreased with increasing y.
Abstract: This paper presents the design and characterization of
analog readout interface circuits for ion sensitive field effect
transistor (ISFET) and ion selective electrode (ISE) based sensor.
These interface circuits are implemented using MIMOS’s 0.35um
CMOS technology and experimentally characterized under 24-leads
QFN package. The characterization evaluates the circuit’s
functionality, output sensitivity and output linearity. Commercial
sensors for both ISFET and ISE are employed together with glass
reference electrode during testing. The test result shows that the
designed interface circuits manage to readout signals produced by
both sensors with measured sensitivity of ISFET and ISE sensor are
54mV/pH and 62mV/decade, respectively. The characterized output
linearity for both circuits achieves above 0.999 Rsquare. The readout
also has demonstrated reliable operation by passing all qualifications
in reliability test plan.
Abstract: Intermetallic materials are among advanced
technology materials that have outstanding mechanical and physical
properties for high temperature applications. Especially creep
resistance, low density and high hardness properties stand out in such
intermetallics. The microstructure, mechanical properties of %88Ni-
%10Cr and %2Mn powders were investigated using specimens
produced by tube furnace sintering at 900-1300°C temperature. A
composite consisting of ternary additions, a metallic phase, Fe, Cr
and Mn have been prepared under Ar shroud and then tube furnace
sintered. XRD, SEM (Scanning Electron Microscope), were
investigated to characterize the properties of the specimens.
Experimental results carried out for composition %88Ni-%10Cr and
%2Mn at 1300°C suggest that the best properties as 138,80HV and
6,269/cm3 density were obtained at 1300°C.
Abstract: The aim of this study is to investigate formability of
Al based closed cell metallic foams at high temperature. The foam
specimens with rectangular section were produced from
AlMg1Si0.6TiH20.8 alloy preform material. Bending and free
bending tests based on gravity effect were applied to foam specimens
at high temperatures. During the tests, the time-angular deformation
relationships with various temperatures were determined.
Deformation types formed in cell walls were investigated by means
of Scanning Electron Microscopy (SEM) and optical microscopy.
Bending deformation about 90° was achieved without any defect at
high temperatures. The importance of a critical temperature and
deformation rate was emphasized in maintaining the deformation.
Significant slip lines on surface of cell walls at tensile zones of
bending specimen were observed. At high strain rates, the microcrack
formation in boundaries of elongated grains was determined.
Abstract: The secondary alloy A226 is used for many
automotive casting produced by mould casting and high pressure die
casting. This alloy has excellent castability, good mechanical
properties and cost-effectiveness. Production of primary aluminium
alloys belong to heavy source fouling of life environs. The European
Union calls for the emission reduction and reduction in energy
consumption therefore increase production of recycled (secondary)
aluminium cast alloys. The contribution is deal with influence of
recycling on the quality of the casting made from A226 in automotive
industry. The properties of the casting made from secondary
aluminium alloys were compared with the required properties of
primary aluminium alloys. The effect of recycling on microstructure
was observed using combination different analytical techniques (light
microscopy upon black-white etching, scanning electron microscopy
- SEM upon deep etching and energy dispersive X-ray analysis -
EDX). These techniques were used for the identification of the
various structure parameters, which was used to compare secondary
alloy microstructure with primary alloy microstructure.