Abstract: Here, we have shown the reaction of [Cr(ArN(CH2)3NAr)2Cl2] (1) where (Ar = 2,6-Pri
2C6H3) and in presence of NaCp (2) (Cp= C5H5 = cyclopentadien), with a center
coordination η5 interaction between Cp as co-ligand and chromium
metal center, for optimization we used density functional theory
(DFT), under methods, explicitly including electrons correlations, for
the final calculations as MB3LYP (Becke) (Lee–Yang–Parr) level of
theory we used to obtain more exact results. This complex was
calculated as electronic energy for molecular system, because the
calculation accounting all electrons correlations interactions. The
optimised of [Cr(ArN(CH2)3NAr)2(η5-Cp)] (Ar = 2,6-Pri2C6H3 and Cp = C5H5) was found to be thermally stable. By using Dewar-Chatt-Duncanson model, as a basis of the molecular orbital (MO) analysis
and showed the highest occupied molecular orbital (HOMO) and
lowest occupied molecular orbital LUMO.
Abstract: Parboiled rice was developed to produce rice, which
has a low glycemic index for diabetics. However, diabetics also have
a chromium (Cr) deficiency. Thus, it is important to fortify rice with
Cr to increase the Cr content. Moreover, parboiled rice becomes
rancid easily and has a musty odor, rendering the rice unfavorable.
Natural herbs such as pandan leaves (Pandanus amaryllifolius
Roxb.), bay leaves (Syzygium polyanthum [Wigh] Walp) and
cinnamon bark powder (Cinnamomon cassia) are commonly added to
food as aroma enhancers. Previous research has shown that these
herbs could improve insulin sensitivity. The purpose of this study
was to evaluate the effect of herbal extract coatings on the cooking
quality and the preference level of chromium fortified - parboiled rice
(CFPR). The rice grain variety used for this experiment was Ciherang
and the fortificant was CrCl3. The three herbal extracts used for
coating the CFPR were cinnamon, pandan and bay leaf, with
concentration variations of 3%, 6%, and 9% (w/w) for each of the
extracts. The samples were analyzed for their alkali spreading value,
cooking time, elongation, water uptake ratio, solid loss, colour and
lightness; and their sensory properties were determined by means of
an organoleptic test. The research showed that coating the CFPR with
pandan and cinnamon extracts at a concentration of 3% each
produced a preferred CFPR. When coated with those herbal extracts
the CFPR had the following cooking quality properties: alkali
spreading value 5 (intermediate gelatinization temperature), cooking
time, 26-27 min, color value, 14.95-15.00, lightness, 42.30 – 44.06,
elongation, 1.53 – 1.54, water uptake ratio , 4.05-4.06, and solid loss,
0.09/100 g – 0.13 g/100 g.
Abstract: This paper expands on the role of the professor by detailing the origins of the profession, adding some of the unique contributions of North American universities as well as some of the best practice recommendations to the unique tripartite role of the professor. It describes current challenges to the profession including the ever-controversial student rating of professors. It continues with the significance of empowerment to the role of the professor. It concludes with a predictive prescription for the future of the professoriate and the role of the university-level educational administrator toward that end.
Abstract: During machining process, chatter is an unavoidable
phenomenon. Boring bars possess the cantilever shape and due to
this, it is subjected to chatter. The adverse effect of chatter includes
the increase in temperature which will leads to excess tool wear. To
overcome these problems, in this investigation, Cartridge brass (Cu –
70% and Zn – 30%) is passively fixed on the boring bar and also
clearance is provided in order to reduce the displacement, tool wear
and cutting temperature. A conventional all geared lathe is attached
with vibrometer and pyrometer is used to measure the displacement
and temperature. The influence of input parameters such as cutting
speed, depth of cut and clearance on temperature, tool wear and
displacement are investigated for various cutting conditions. From
the result, the optimum conditions to obtain better damping in boring
process for chatter reduction is identified.
Abstract: The last two decades witnessed a movement towards
harmonization of international financial reporting standards (IFRS)
throughout the global economy. This investigation seeks to identify
the factors that could explain the adoption of IFRS by poor
jurisdictions. While there has been a considerable amount of
literature published on the effects and key drivers of IFRS adoption
in both developed and developing countries, little attention has been
paid to jurisdictions with less developed capital markets and low
income levels exclusively. Drawing upon the Institutional Isomorphism theory and analyzing
a sample of 45 poor jurisdictions between 2008 and 2013, the study
empirically shows that poor jurisdictions are driven by legitimacy
concerns rather than by economic reasoning to adopt an international
accounting perspective. This in turn has implications for the IASB, as
it should seek to influence institutional pressures within a particular
jurisdiction in order to promote IFRS adoption.
Abstract: This paper presents the advantages of fuzzy control use in technological processes control. The paper presents a real application of the Linguistic Fuzzy-Logic Control, developed at the University of Ostrava for the control of physical models in the Intelligent Systems Laboratory. The paper presents an example of a sensitive non-linear model, such as a magnetic levitation model and obtained results which show how modern information technologies can help to solve actual technical problems. A special method based on the LFLC controller with partial components is presented in this paper followed by the method of automatic context change, which is very helpful to achieve more accurate control results. The main advantage of the used system is its robustness in changing conditions demonstrated by comparing with conventional PID controller. This technology and real models are also used as a background for problem-oriented teaching, realized at the department for master students and their collaborative as well as individual final projects.
Abstract: Revenue leakages are one of the major challenges
manufacturers face in production processes, as most of the input
materials that should emanate as products from the lines are lost as
waste. Rather than generating income from material input which is
meant to end-up as products, losses are further incurred as costs in
order to manage waste generated. In addition, due to the lack of a
clear view of the flow of resources on the lines from input to output
stage, acquiring information on the true cost of waste generated have
become a challenge. This has therefore given birth to the
conceptualization and implementation of waste minimization
strategies by several manufacturing industries. This paper reviews the
principles and applications of three environmental management
accounting tools namely Activity-based Costing (ABC), Life-Cycle
Assessment (LCA) and Material Flow Cost Accounting (MFCA) in
the manufacturing industry and their effectiveness in curbing revenue
leakages. The paper unveils the strengths and limitations of each of
the tools; beaming a searchlight on the tool that could allow for
optimal resource utilization, transparency in production process as
well as improved cost efficiency. Findings from this review reveal
that MFCA may offer superior advantages with regards to the
provision of more detailed information (both in physical and
monetary terms) on the flow of material inputs throughout the
production process compared to the other environmental accounting
tools. This paper therefore makes a case for the adoption of MFCA as
a viable technique for the identification and reduction of waste in
production processes, and also for effective decision making by
production managers, financial advisors and other relevant
stakeholders.
Abstract: This paper presents a model predictive control (MPC)
of a utility interactive three phase inverter (TPI) for a photovoltaic
(PV) system at commercial level. The proposed model uses phase
locked loop (PLL) to synchronize the TPI with the power electric
grid (PEG) and performs MPC control in a dq reference frame. TPI
model consists of a boost converter (BC), maximum power point
tracking (MPPT) control, and a three-leg voltage source inverter
(VSI). The operational model of VSI is used to synthesize the
sinusoidal current and track the reference. The model is validated
using a 35.7 kW PV system in Matlab/Simulink. Implementation
results show simplicity and accuracy, as well as reliability of the
model.
Abstract: Government reports and published research have
flagged and brought to public attention the deteriorating condition of
a large percentage of bridges in Canada and the United States. With
the increasing number of deteriorated bridges in the US, Canada, and
around the globe, condition assessment techniques of concrete
bridges are evolving. Investigation for bridges’ defects such as
cracks, spalls, and delamination and their level of severity are the
main objectives of condition assessment. Inspection and
rehabilitation programs are being implemented to monitor and
maintain deteriorated bridge infrastructure. This paper highlights the
state-of-the art of current practices being performed for concrete
bridge inspection. The information is gathered from the literature and
through a distributed questionnaire. The current practices in concrete
bridge inspection rely on the use of hummer sounding and chain
dragging tests. Non-Destructive Testing (NDT) techniques are not
being utilized fully in the process. Nonetheless, they are being
partially utilized by the recommendation of the bridge inspector after
conducting visual inspection. Lanes are usually closed during the
performance of visual inspection and bridge inspection in general.
Abstract: The aim of this study is to identify the suitability of
Virtual Learning Environment (VLE) in welding simulator
application towards Computer-Based Training (CBT) in developing
skills upon new students at the Advanced Technology Training
Center (ADTEC) Batu Pahat, Johor, Malaysia and GIATMARA,
Batu Pahat, Johor, Malaysia. The significance of the study is to create
a computer-based skills development approach in welding technology
among new students in ADTEC and GIATMARA as well as to
cultivate the elements of general skills among them. This study is
also important in elevating the number of individual knowledge
workers (K-workers) working in manufacturing industry in order to
achieve a national vision which is to be an industrial nation in the
year of 2020. The design of the study is a survey type of research
which using questionnaires as the instruments and some 136 students
from ADTEC and GIATMARA were interviewed. Descriptive
analysis is used to identify the frequency and mean values. The
findings of the study show that the welding technology has developed
skills in the students because of the application of VLE simulated at a
high level and the respondents agreed that the skills could be
embedded through the application of the VLE simulator. In summary,
the VLE simulator is suitable in welding skills development training
in terms of exposing new students with the relevant characteristics of
welding skills and at the same time spurring the students’ interest
towards learning more about the skills.
Abstract: Nowadays, the reflection on competence management
is the basic for new competitive strategies. It is considered as the core
of the problems of the global supply chain. It interact a variety of
actors: information, physical and activities flows, etc. Even though
competence management is seen as the key factor for any business
success, the existing approaches demonstrate the deficiencies and
limitations of the competence concept. This research has two
objectives: The first is to make a contribution by focusing on the
development of a competence approach, based on continuous
improvement. It allows the enterprise to spot key competencies,
mobilize them in order to serve its strategic objectives and to develop
future competencies. The second is to propose a method to evaluate
the Level of Collective Competence. The approach was confirmed
through an application carried out at an automotive company.
Abstract: This study was conducted to investigate the extent
with which knowledge of results influences the performance of
cricket players. A sample of 160 fresh students in the Department of
Physical and Health Education who are novice in the game were
randomly assigned into two groups. The first group of eighty (80)
subjects was classified as experimental group while the second group
of eighty (80) subjects was the control group. Subjects in both groups
were asked to bowl and bat ten times each for a period of six weeks.
After the first round, the subjects in the experimental group were
allowed feedback on their performance in the first trial while those in
the control group were denied feedback. Two null hypotheses
generated for the study were tested using percentages and chi-square
statistical analysis at 0.05 level of significance. Analysis of data
showed that knowledge of results influenced the performance of
cricket players. It was concluded that knowledge of results is
pertinent for effective skill acquisition and could enhance better
performance among unskilled cricket players. Hence, it is suggested
that immediate feedback on the level of skill acquisition by the
prospective and unskilled cricket players would inspire them for
better performance in cricket tournaments.
Abstract: Fresh water is one of the resources which is getting
depleted day by day. A wise method to address this issue is by the
application of renewable energy-sun irradiation and by means of
decentralized, cheap, energetically self-sufficient, robust and simple
to operate plants, distillates can be obtained from sea, river or even
sewage. Solar desalination is a technique used to desalinate water
using solar energy. The present work deals with the comprehensive
design and simulation of solar tracking system using LabVIEW,
temperature and mass flow rate control of the solar desalination plant
using LabVIEW and also analysis of single phase inverter circuit
with LC filters for solar pumping system in MATLAB. The main
objective of this work is to improve the performance of solar
desalination system using automatic tracking system, output control
using temperature and mass flow rate control system and also to
reduce the harmonic distortion in the solar pumping system by means
of LC filters. The simulation of single phase inverter was carried out
using MATLAB and the output waveforms were analyzed.
Simulations were performed for optimum output temperature control,
which in turn controls the mass flow rate of water in the thermal
collectors. Solar tracking system was accomplished using LABVIEW
and was tested successfully. The thermal collectors are tracked in
accordance with the sun’s irradiance levels, thereby increasing the
efficiency of the thermal collectors.
Abstract: This study, tries to suggest a design method based on
displacement using finite difference numerical modeling in
reinforcing soil retaining wall with steel strip. In this case, dynamic
loading characteristics such as duration, frequency, peak ground
acceleration, geometrical characteristics of reinforced soil structure
and type of the site are considered to correct the pseudo static method
and finally introduce the pseudo static coefficient as a function of
seismic performance level and peak ground acceleration. For this
purpose, the influence of dynamic loading characteristics,
reinforcement length, height of reinforced system and type of the site
are investigated on seismic behavior of reinforcing soil retaining wall
with steel strip. Numerical results illustrate that the seismic response
of this type of wall is highly dependent to cumulative absolute
velocity, maximum acceleration, and height and reinforcement length
so that the reinforcement length can be introduced as the main factor
in shape of failure. Considering the loading parameters, geometric parameters of the
wall and type of the site showed that the used method in this study
leads to efficient designs in comparison with other methods, which
are usually based on limit-equilibrium concept. The outputs show the
over-estimation of equilibrium design methods in comparison with
proposed displacement based methods here.
Abstract: Household waste form a larger proportion of waste
generated across the state, accumulation of organic waste is an
apparent problem and the existing dump sites could be overstress.
Niger state has abundant arable land and water resources thus should
be one of the highest producers of agricultural crops in the country.
However, the major challenge to agricultural sector today is loss of
soil nutrient coupled with high cost of fertilizer. These have
continued to increase the use of fertilizer and decomposed solid waste
for enhance agricultural yield, which have varying effects on the soil
as well a threat to human livelihood. Consequently, vegetable yield
samples from poultry droppings, decomposed household waste
manure, NPK treatments and control from each replication were
subjected to proximate analysis to determine the nutritional and antinutritional
component as well as heavy metal concentration. Data
collected was analyzed using SPSS software and Randomized
complete Block Design means were compared. The result shows that
the treatments do not devoid the concentrations of any nutritional
components while the anti-nutritional analysis proved that NPK had
higher oxalate content than control and organic treats. The
concentration of lead and cadmium are within safe permissible level
while the mercury level exceeded the FAO/WHO maximum
permissible limit for the entire treatments depicts the need for urgent
intervention to minimize mercury levels in soil and manure in order
to mitigate its toxic effect. Thus, eco-agriculture should be widely
accepted and promoted by the stakeholders for soil amendment,
higher yield, strategies for sustainable environmental protection, food
security, poverty eradication, attainment of sustainable development
and healthy livelihood.
Abstract: The Greater Athens Area (GAA) faces photochemical
and particulate pollution episodes as a result of the combined effects
of local pollutant emissions, regional pollution transport, synoptic
circulation and topographic characteristics. The area has undergone
significant changes since the Athens 2004 Olympic Games because
of large scale infrastructure works that lead to the shift of population
to areas previously characterized as rural, the increase of the traffic
fleet and the operation of highways. However, few recent modelling
studies have been performed due to the lack of an accurate, updated
emission inventory. The photochemical modelling system
MM5/CAMx was applied in order to study the photochemical and
particulate pollution characteristics above the GAA for two distinct
ten-day periods in the summer of 2006 and 2010, where air pollution
episodes occurred. A new updated emission inventory was used
based on official data. Comparison of modeled results with
measurements revealed the importance and accuracy of the new
Athens emission inventory as compared to previous modeling
studies. The model managed to reproduce the local meteorological
conditions, the daily ozone and particulates fluctuations at different
locations across the GAA. Higher ozone levels were found at
suburban and rural areas as well as over the sea at the south of the
basin. Concerning PM10, high concentrations were computed at the
city centre and the southeastern suburbs in agreement with measured
data. Source apportionment analysis showed that different sources
contribute to the ozone levels, the local sources (traffic, port
activities) affecting its formation.
Abstract: This study focuses on the hydro-geology and chemical
constituents analysis of Ikogosi Warm Spring waters in South West
Nigeria. Ikogosi warm spring is a global tourist attraction because it
has both warm and cold spring sources. Water samples from the cold
spring, warm spring and the meeting point were collected, analyzed
and the result shows close similarity in temperature, hydrogen iron
concentration (pH), alkalinity, hardness, Calcium, Magnesium,
Sodium, Iron, total dissolved solid and heavy metals. The measured
parameters in the water samples are within World Health
Organisation standards for fresh water. The study of the geology of
the warm spring reveals that the study area is underlain by a group of
slightly migmatised to non-migmatised paraschists and meta-igneous
rocks. Also, concentration levels of selected heavy metals, (Copper,
Cadmium, Zinc, Arsenic and Cromium) were determined in the water
(ppm) samples. Chromium had the highest concentration value of
1.52ppm (an average of 49.67%) and Cadmium had the lowest
concentration with value of 0.15ppm (an average of 4.89%).
Comparison of these results showed that, their mean levels are within
the standard values obtained in Nigeria. It can be concluded that both
warm and spring water are safe for drinking.
Abstract: This paper presents an extensive review of literature
relevant to the modelling techniques adopted in sediment yield and
hydrological modelling. Several studies relating to sediment yield are
discussed. Many research areas of sedimentation in rivers, runoff and
reservoirs are presented. Different types of hydrological models,
different methods employed in selecting appropriate models for
different case studies are analysed. Applications of evolutionary
algorithms and artificial intelligence techniques are discussed and
compared especially in water resources management and modelling.
This review concentrates on Genetic Programming (GP) and fully
discusses its theories and applications. The successful applications of
GP as a soft computing technique were reviewed in sediment
modelling. Some fundamental issues such as benchmark,
generalization ability, bloat, over-fitting and other open issues
relating to the working principles of GP are highlighted. This paper
concludes with the identification of some research gaps in
hydrological modelling and sediment yield.
Abstract: The advancements in technology allow the
development of a new system that can continuously measure surface
soil erosion. Continuous soil erosion measurements are required in
order to comprehend the erosional processes and propose effective
and efficient conservation measures to mitigate surface erosion.
Mitigating soil erosion, especially in Mediterranean countries such as
Greece, is essential in order to maintain environmental and
agricultural sustainability. In this paper, we present the Automated
Soil Erosion Monitoring System (ASEMS) that measures surface soil
erosion along with other factors that impact erosional process.
Specifically, this system measures ground level changes (surface soil
erosion), rainfall, air temperature, soil temperature, and soil moisture.
Another important innovation is that the data will be collected by
remote communication. In addition, stakeholder’s awareness is a key
factor to help reduce any environmental problem. The different
dissemination activities that were utilized are described. The overall
outcomes were the development of a new innovative system that can
measure erosion very accurately. These data from the system help
study the process of erosion and find the best possible methods to
reduce erosion. The dissemination activities enhance the stakeholders
and public's awareness on surface soil erosion problems and will lead
to the adoption of more effective soil erosion conservation practices
in Greece.
Abstract: In recent years, the power system has been changed
and a flexible power pricing system such as demand response has been
sought in Japan. The demand response system works simply in the
household sector and the owner as the decision-maker, can benefit
from power saving. On the other hand, the execution of demand
response in the office building is more complex than in the household
because various people such as owners, building administrators and
occupants are involved in the decision-making process. While the
owners benefit from demand saving, the occupants are exposed to
restricted benefits of a demand-saved environment. One of the reasons
is that building systems are usually under centralized management and
each occupant cannot choose freely whether to participate in demand
response or not. In addition, it is unclear whether incentives give
occupants the motivation to participate. However, the recent
development of IT and building systems enables the personalized
control of the office environment where each occupant can control the
lighting level or temperature individually. Therefore, it can be possible
to have a system which each occupant can make a decision of whether
or not to participate in demand response in the office building. This study investigates personal responses to demand response
requests, under the condition where each occupant can adjust their
brightness individually in their workspace. Once workers participate
in the demand response, their desk-lights are automatically turned off.
The participation rates in the demand response events are compared
among four groups, which are divided by different motivation, the
presence, or absence of incentives and the method of participation. The
result shows that there are significant differences of participation rates
in demand response event between four groups. The method of
participation has a large effect on the participation rate. The “Opt-out”
groups where the occupants are automatically enrolled in a demand
response event if they do not express non-participation have the
highest participation rate in the four groups. Incentives also have an
effect on the participation rate. This study also reports on the impact of low illumination office
environment on the occupants, such as stress or fatigue. The
electrocardiogram and the questionnaire are used to investigate the
autonomic nervous activity and subjective fatigue symptoms of the
occupants. There is no big difference between dim workspace during
demand response event and bright workspace in autonomic nervous
activity and fatigue.