Abstract: A biocompatible ferrofluid have been prepared by coprecipitation
of FeCl2.4H2O and FeCl3.6H2O under ultrasonic
irradiation and with NaOH as alkaline agent. Cystein was also used
as capping agent in the solution. Magnetic properties of the produced
ferrofluid were then determined by VSM test and magnetite
nanoparticles were characterized by XRD and TEM techniques. The
effect of surfactant to Fe ion weight ratio was also studied during this
project by using two different amount of Dextran. Results showed the
presence of a biocompatible superparamagnetic ferrofluid including
magnetite nanoparticles with particle size ranging under 20 nm. The
increase in the surfactant content results in the narrowing of the size
distribution and reduction of the particle size and more solution
stability.
Abstract: Simulations of magnetic microstructure in elliptical
Permalloy elements used for controlled motion of magnetic particles
are discussed. The saturating field of the elliptical elements was
studied with respect to lateral dimensions for one-vortex, cross-tie,
diamond and double-diamond states as initial zero-field domain
configurations. With aspect ratio of 1:3 the short axis was varied
from 125 nm to 1000 nm, whereas the thickness was kept constant at
50 nm.
Abstract: A computational study at the level density functional theory (DFT) was carried out to investigate the influences of Si and C-doping on the 14N and 27Al quadrupole coupling constant in the (10, 0) zigzag single ? walled Aluminum-Nitride nanotube (AlNNT). To this aim, a 1.16nm, length of AlNNT consisting of 40 Al atoms and 40 N atoms were selected where the end atoms are capped by hydrogen atom. To follow the purpose, three Si atoms and three C atoms were doped instead of three Al atoms and three N atoms as a central ring in the surface of the Si and C-doped AlNNT. At first both of systems optimized at the level of BLYP method and 6-31G (d) basis set and after that, the NQR parameters were calculated at the level BLYP method and 6-311+G** basis set in two optimized forms. The calculate CQ values for both optimized AlNNT systems, raw and Si and C-doped, reveal different electronic environments in the mentioned systems. It was also demonstrated that the end nuclei have the largest CQ values in both considered AlNNT systems. All the calculations were carried out using Gaussian 98 package of program.
Abstract: Extraction of lactic acid by emulsion liquid membrane technology (ELM) using n-trioctyl amine (TOA) in n-heptane as carrier within the organic membrane along with sodium carbonate as acceptor phase was optimized by using response surface methodology (RSM). A three level Box-Behnken design was employed for experimental design, analysis of the results and to depict the combined effect of five independent variables, vizlactic acid concentration in aqueous phase (cl), sodium carbonate concentration in stripping phase (cs), carrier concentration in membrane phase (ψ), treat ratio, and batch extraction time (τ)
with equal volume of organic and external aqueous phase on lactic acid extraction efficiency. The maximum lactic acid extraction efficiency (ηext) of 98.21%from aqueous phase in a batch reactor using ELM was found at the optimized values for test variables, cl, cs, ψ, and τ as 0.06 [M], 0.18 [M], 4.72 (%,v/v), 1.98 (v/v) and 13.36 min respectively.
Abstract: Mature landfill leachates contain some macromolecular organic substances that are resistant to biological degradation. Recently, Fenton-s oxidation has been investigated for chemical treatment or pre-treatment of mature landfill leachates. The aim of this study was to reduce the recalcitrant organic load still remaining after the complete treatment of a mature landfill leachate by Fenton-s oxidation post-treatment. The effect of various parameters such as H2O2 to Fe2+ molar ratio, dosage of Fe2+ reagent, initial pH, reaction time and initial chemical oxygen demand (COD) strength, that have an important role on the oxidation, was analysed. A molar ratio H2O2/Fe2+ = 3, a Fe2+ dosage of 4 mmol·L-1, pH 3, and a reaction time of 40 min were found to achieve better oxidation performances. At these favorable conditions, COD removal efficiency was 60.9% and 31.1% for initial COD of 93 and 743 mg·L-1 respectively (diluted and non diluted leachate). Fenton-s oxidation also presented good results for color removal. In spite of being extremely difficult to treat this leachate, the above results seem rather encouraging on the application of Fenton-s oxidation.
Abstract: Using plug flow model in conjunction with
experimental solute concentration profiles, overall volumetric mass
transfer coefficient based on continuous phase (Koca), in a packed
liquid-liquid extraction column has been optimized. Number of 12
experiments has been done using standard system of water/acid
acetic/toluene in a 6 cm diameter, 120 cm height column. Thorough
consideration of influencing parameters we intended to correlate
dimensionless parameters in term of overall Sherwood number which
has an acceptable average error of about 15.8%.
Abstract: Thermochemcial characteristics of powder fabricated
using oxidation treatment of spent PWR fuel and SIMFUEL were
evaluated for recycling of spent fuel such as DUPIC process.
Especially, the influence of spent fuel burn-ups on the powder
fabrication characteristics was experimentally evaluated, ranging from
27,300 to 65,000 MWd/tU. Densities of powder manufactured from an
oxidation, OREOX and the milling processes at the same process
conditions were compared as a function of the fuel burn-ups
respectively. Also, based on chemical analysis results, homogeneity of
fissile elements in oxidized powder was confirmed.
Abstract: This work deals with modeling and simulation of SO2 removal in a ceramic membrane by means of FEM. A mass transfer model was developed to predict the performance of SO2 absorption in a chemical solvent. The model was based on solving conservation equations for gas component in the membrane. Computational fluid dynamics (CFD) of mass and momentum were used to solve the model equations. The simulations aimed to obtain the distribution of gas concentration in the absorption process. The effect of the operating parameters on the efficiency of the ceramic membrane was evaluated. The modeling findings showed that the gas phase velocity has significant effect on the removal of gas whereas the liquid phase does not affect the SO2 removal significantly. It is also indicated that the main mass transfer resistance is placed in the membrane and gas phase because of high tortuosity of the ceramic membrane.
Abstract: This paper is a continuation of our interest in the influence of temperature on specific retention volumes and the resulting infinite dilution activity coefficients. This has a direct effect in the design of absorption and stripping columns for the abatement of volatile organic compounds. The interaction of 13 volatile organic compounds (VOCs) with polydimethylsiloxane (PDMS) at varying temperatures was studied by gas liquid chromatography (GLC). Infinite dilution activity coefficients and specific retention volumes obtained in this study were found to be in agreement with those obtained from static headspace and group contribution methods by the authors as well as literature values for similar systems. Temperature variation also allows for transport calculations for different seasons. The results of this work confirm that PDMS is well suited for the scrubbing of VOCs from waste gas streams. Plots of specific retention volumes against temperature gave linear van-t Hoff plots.
Abstract: Carboneous catalytical methane decomposition is an
attractive process because it produces two valuable products:
hydrogen and carbon. Furthermore, this reaction does not emit any
green house or hazardous gases. In the present study, experiments
were conducted in a thermo gravimetric analyzer using Fluka 05120
as carboneous catalyst to analyze its effectiveness in methane
decomposition. Various temperatures and methane partial pressures
were chosen and carbon mass gain was observed as a function of
time. Results are presented in terms of carbon formation rate,
hydrogen production and catalytical activity. It is observed that there
is linearity in carbon deposition amount by time at lower reaction
temperature (780 °C). On the other hand, it is observed that carbon
and hydrogen formation rates are increased with increasing
temperature. Finally, we observed that the carbon formation rate is
highest at 950 °C within the range of temperatures studied.
Abstract: The purpose of this research is to establish the experimental conditions for removal of Cibacron Brilliant Yellow 3G-P dye (CBY) from aqueous solutions by sorption onto coffee husks as a low-cost sorbent. The effects of various experimental parameters (e.g. initial CBY dye concentration, sorbent mass, pH, temperature) were examined and the optimal experimental conditions were determined. The results indicated that the removal of the dye was pH dependent and at initial pH of 2, the dye was removed effectively. The CBY dye sorption data were fitted to Langmuir, Freundlich, Temkin and Dubinin-Radushkevich equilibrium models. The maximum sorption capacity of CBY dye ions onto coffee husks increased from 24.04 to 35.04 mg g-1 when the temperature was increased from 293 to 313 K. The calculated sorption thermodynamic parameters including ΔG°, ΔH°, and ΔS° indicated that the CBY dye sorption onto coffee husks is a spontaneous, endothermic and mainly physical in nature.
Abstract: Sulphur dioxide is a harmful gaseous product that
needs to be minimized in the atmosphere. This research work
investigates the use of zeolite as a possible additive that can improve
the sulphur dioxide capture in wet flue gas desulphurisation
dissolution process. This work determines the effect of temperature,
solid to liquid ratio, acid concentration and stirring speed on the
leaching of zeolite using a pH stat apparatus. The atomic absorption
spectrometer was used to measure the calcium ions from the solution.
It was found that the dissolution rate of zeolite decreased with
increase in solid to liquid ratio and increases with increase in
temperature, stirring speed and acid concentration. The activation
energy for the dissolution rate of zeolite in hydrochloric acid was
found to be 9.29kJ/mol. and therefore the product layer diffusion was
the rate limiting step.
Abstract: The production of glass, ceramic materials and many non-ferrous metals (Zn, Cu, Pb, etc.), ferrous metals (pig iron) and others is connected with the use of a considerable number of initial solid raw materials. Before carrying out the basic technological processes (oxidized roasting, melting, agglomeration, baking) it is necessary to mix and homogenize the raw materials that have different chemical and phase content, granulometry and humidity. For this purpose zinc sulfide concentrates differing in origin are studied for their more complete characteristics using chemical, X-ray diffraction analyses, DTA and TGA as well as Mössbauer spectroscopy. The phases established in most concentrates are: β-ZnS, mZnS.nFeS, FeS2, CuFeS2, PbS, SiO2 (α-quartz). With the help of the developed by us a Web-based information system for a continued period of time different mix proportions from zinc concentrates are calculated and used in practice (roasting in fluidized bed reactor), which have to conform to the technological requirements of the zinc hydrometallurgical technological scheme.
Abstract: Effect of viscosity of media on kinetic parameters of the coupled enzyme system NADH:FMN-oxidoreductase–luciferase was investigated with addition of organic solvents (glycerol and sucrose), because bioluminescent enzyme systems based on bacterial luciferases offer a unique and general tool for analysis of the many analytes and enzymes in the environment, research and clinical laboratories and other fields. The possibility of stabilization and increase of activity of the coupled enzyme system NADH:FMN-oxidoreductase–luciferase activity in vicious aqueous-organic mixtures have been shown.
Abstract: The composition, vapour pressure, and heat capacity
of nine biodiesel fuels from different sources were measured. The
vapour pressure of the biodiesel fuels is modeled assuming an ideal
liquid phase of the fatty acid methyl esters constituting the fuel. New
methodologies to calculate the vapour pressure and ideal gas and
liquid heat capacities of the biodiesel fuel constituents are proposed.
Two alternative optimization scenarios are evaluated: 1) vapour
pressure only; 2) vapour pressure constrained with liquid heat
capacity. Without physical constraints, significant errors in liquid
heat capacity predictions were found whereas the constrained
correlation accurately fit both vapour pressure and liquid heat
capacity.
Abstract: The direct discharge of palm oil mill effluent (POME) wastewater causes serious environmental pollution due to its high chemical oxygen demand (COD) and biochemical oxygen demand (BOD). Traditional ways for POME treatment have both economical and environmental disadvantages. In this study, a membrane anaerobic system (MAS) was used as an alternative, cost effective method for treating POME. Six steady states were attained as a part of a kinetic study that considered concentration ranges of 8,220 to 15,400 mg/l for mixed liquor suspended solids (MLSS) and 6,329 to 13,244 mg/l for mixed liquor volatile suspended solids (MLVSS). Kinetic equations from Monod, Contois and Chen & Hashimoto were employed to describe the kinetics of POME treatment at organic loading rates ranging from 2 to 13 kg COD/m3/d. throughout the experiment, the removal efficiency of COD was from 94.8 to 96.5% with hydraulic retention time, HRT from 400.6 to 5.7 days. The growth yield coefficient, Y was found to be 0.62gVSS/g COD the specific microorganism decay rate was 0.21 d-1 and the methane gas yield production rate was between 0.25 l/g COD/d and 0.58 l/g COD/d. Steady state influent COD concentrations increased from 18,302 mg/l in the first steady state to 43,500 mg/l in the sixth steady state. The minimum solids retention time, which was obtained from the three kinetic models ranged from 5 to 12.3 days. The k values were in the range of 0.35 – 0.519 g COD/ g VSS • d and values were between 0.26 and 0.379 d-1. The solids retention time (SRT) decreased from 800 days to 11.6 days. The complete treatment reduced the COD content to 2279 mg/l equivalent to a reduction of 94.8% reduction from the original.
Abstract: Copper sulfide nanoparticles (CuS) were successfully synthesized by the pulsed plasma in liquid method, using two copper rod electrodes submerged in molten sulfur. Low electrical energy and no high temperature were applied for synthesis. Obtained CuS nanoparticles were then analyzed by means of X-ray diffraction, Low and High Resolution Transmission Electron Microscopy, Electron Diffraction, X-ray Photoelectron, Raman Spectroscopies and Field Emission Scanning Electron Microscopy. XRD analysis revealed peaks for CuS with hexagonal phase composition. TEM and HRTEM studies showed that sizes of CuS nanoparticles ranged between 10-60 nm, with the average size of about 20 nm. Copper sulfide nanoparticles have short nanorod-like structure. Raman spectroscopy found peak for CuS at 474.2cm-1of Raman region.
Abstract: Stirred tanks have applications in many chemical
processes where mixing is important for the overall performance of
the system. In present work 5%v of the tank is filled by solid particles
with diameter of 700 m that Rushton Turbine and Propeller impeller
is used for stirring. An Eulerian-Eulerian Multi Fluid Model coupled
and for modeling rotating of impeller, moving reference frame
(MRF) technique was used and standard-k- model was selected for
turbulency. Flow field, radial velocity and axial distribution of solid
for both of impellers was investigation and comparison. Comparisons
of simulation results between Rushton Turbine and propeller impeller
shows that final quality of solid-liquid slurry in different rotating
speed for propeller impeller is better than the Rushton Turbine.
Abstract: The bromination of five selected pharmaceuticals
(metoprolol, naproxen, amoxicillin, hydrochlorotiazide and
phenacetin) in ultrapure water and in three water matrices (a
groundwater, a surface water from a public reservoir and a secondary
effluent from a WWTP) was investigated. The apparent rate
constants for the bromination reaction were determined as a function
of the pH, and the sequence obtained for the reaction rate was
amoxicillin > naproxen >> hydrochlorotiazide ≈ phenacetin ≈
metoprolol. The proposal of a kinetic mechanism, which specifies the
dissociation of bromine and each pharmaceutical according to their
pKa values and the pH allowed the determination of the intrinsic rate
constants for every elementary reaction. The influence of the main
operating conditions (pH, initial bromine dose, and the water matrix)
on the degradation of pharmaceuticals was established. In addition,
the presence of bromide in chlorination experiments was
investigated. The presence of bromide in wastewaters and drinking
waters in the range of 10 to several hundred μg L-1 accelerated
slightly the oxidation of the selected pharmaceuticals during chorine
disinfection.
Abstract: In this study, the ability of Aspergillus niger and
Penicillium simplicissimum to extract heavy metals from a spent
refinery catalyst was investigated. For the first step, a spent
processing catalyst from one of the oil refineries in Iran was
physically and chemically characterized. Aspergillus niger and
Penicillium simplicissimum were used to mobilize Al/Co/Mo/Ni from
hazardous spent catalysts. The fungi were adapted to the mixture of
metals at 100-800 mg L-1 with increments in concentration of 100 mg
L-1. Bioleaching experiments were carried out in batch cultures. To
investigate the production of organic acids in sucrose medium,
analyses of the culture medium by HPLC were performed at specific
time intervals after inoculation. The results obtained from Inductive
coupled plasma-optical emission spectrometry (ICP-OES) showed
that after the one-step bioleaching process using Aspergillus niger,
maximum removal efficiencies of 27%, 66%, 62% and 38% were
achieved for Al, Co, Mo and Ni, respectively. However, the highest
removal efficiencies using Penicillium simplicissimum were of 32%,
67%, 65% and 38% for Al, Co, Mo and Ni, respectively