Effect of Temperature on Specific Retention Volumes of Selected Volatile Organic Compounds Using the Gas - Liquid Chromatographic Technique Revisited
This paper is a continuation of our interest in the influence of temperature on specific retention volumes and the resulting infinite dilution activity coefficients. This has a direct effect in the design of absorption and stripping columns for the abatement of volatile organic compounds. The interaction of 13 volatile organic compounds (VOCs) with polydimethylsiloxane (PDMS) at varying temperatures was studied by gas liquid chromatography (GLC). Infinite dilution activity coefficients and specific retention volumes obtained in this study were found to be in agreement with those obtained from static headspace and group contribution methods by the authors as well as literature values for similar systems. Temperature variation also allows for transport calculations for different seasons. The results of this work confirm that PDMS is well suited for the scrubbing of VOCs from waste gas streams. Plots of specific retention volumes against temperature gave linear van-t Hoff plots.
[1] E. Muzenda, A. Arrowsmith, M. Belaid and F. Ntuli, "Temperature
dependence of specific retention volumes of environmentally important
VOCs using GLC", in Proc. ISEEE 09, Rayong, 2009
[2] E. Muzenda, M. Belaid and F. Ntuli, "Influence of temperature on
specific retention volumes of environmentally important VOCs,
EnvironmentAsia, Accepted for Publication, February 2010.
[3] E. Muzenda, A. Arrowsmith, and N. Ashton, "Study of the Effects of
Experimental Variables in Solute Retention Volumes by Gas Liquid
Chromatogrphy (glc) in Polymer Solution Thermodynamics," in Proc.
CHEMCON, Chandigarh, December 2008.
[4] E. Muzenda, M. Belaid, F. Ntuli, and A. Arrowsmith, "Absorption of
Volatile Organic Compounds in Silicon: Determination of Infinite
Dilution Activity Coefficients by Dynamic Gas Liquid
Chromatographic Technique," in Proc. The 8th WCCE 2009, Montreal,
August 2009.
[5] A. B. Littlewood, C. S. G. Phillips, and D. T. Price, "The
Chromatography of gases and vapours Part V: Partition analysis with
columns of Silicone 702 and Tritolylphosphate," J. Chemical Soc., pp.
1480, 1955.
[6] R. N. Lichtenthaler, R.D. Newman, and J. M. Prausnitz, "Specific
retention volumes from Gas - Liquid Chromatography for
Polydimethylsiloxane Hydrocarbon Systems," Macromolecules, vol. 4,
no. 4, pp 650-651, 1973.
[7] W. R. Summers, Y. B. Tewari, and H. P. Schreiber, "Thermodynamic
Interaction in Polydimethysiloxane - hydrocarbon Systems from Gas -
Liquid Chromatography," Macromolecules, vol. 5, no. 1, pp. 11 - 16,
1972.
[8] A. J. Ashworth, C. F. Chien, D. L. Furio, D. M. Hooker, M. M. Kopecni,
R.J. Laub, and G. J. Price, "Comparison of static with gaschromatographic
solute infinite-dilution activity coefficients with
polydimethylsiloxane solvent," Macromolecules, vol. 17, no. 5, pp.
1090 - 1094, 1984.
[9] K. Heberger, M. Gorgenyi, and T. Kowalska, "Temperature dependence
of Kovats indices in gas chromatography revisited," J. Chromatography
A, vol. 973, pp. 135-142.
[10] K. B. Sentell, N. I. Ryan, and A. N. Henderson, "Temperature and
salvation effects on homologous series selectivity in reversed phase
liquid chromatography," Analytical Chimica Acta, vol. 203- 215, 1995.
[11] E. Muzenda, A. Arrowsmith, and N. Ashton, "Ashton N, "Infinite
dilution activity coefficients for VOCs in polydimethylsiloxane," in
Proc. IChemE 2000, Bath, January 2000.
[12] E. Muzenda, A. Arrowsmith, and N. Ashton, "Ashton N, "GLC as an
optimization technique," in Proc. 5th International Conference on
Manufacturing Process Systems and Operations Management in Less
Industrialised Regions, Bulawayo, 2002.
[13] E. Muzenda, A. Arrowsmith, and N. Ashton, "Measurement of Infinite
Dilution Activity Coefficients for Volatile Organic Compounds in
Polydimethylsiloxane by Gas Liquid Chromatography," in Proc.
CHEMCON, Chandigarh, December 2008.
[14] H. Purnell, Gas Chromatography, John Willey and sons, 1962.
[15] D. D. Deshpande, D. Patterson, H. P. Schreiber, and C. S. Su,
"Thermodynamic Interactions in Polymer Systems by Gas - Liquid
Chromatography. IV. Interactions between Components in a Mixed
Stationary Phase," Macromolecules, vol. 7, no. 4, pp. 530-535, 1974.
[16] O. Smidsrod, J. E. Guillet, "Study of polymer interactions by gas
chromatography," Macromolecules, vol. 2, pp. 272, 1969.
[17] B. Sellergren, and J. H. Shea, "Origin of peak asymmetry and the effect
of temperature on the solute retention in enantiomer separations on
imprinted chiral stationary phases," J. Chromatography A, vol. 690, pp.
29-39, 1995.
[18] K. Bay, H. Wanko, and J. Ulrich, "Absorption of Volatile Organic
Compounds in Biodisel: Determination of Infinite Dilution Activity
Coefficients by Headspace Gas Chromatography," Inst. Chem. Eng.
Trans IChemE, vol. 84, no. A1, pp. 22-28, 2006.
[19] U. Domanska, and A. Marciniak, "Measurements of activity coefficients
at infinite dilution of aromatic and aliphatic hydrocarbons, alcohols,
and water in the new ionic liquid (EMIM)(SCN) using GLC," J.
Chemical Thermo., vol. 40, pp. 860-866, 2008.
[20] E. Tudor, "Temperature dependence of the retention index for perfumery
compounds on a SE - 30 glass capillary column I. Linear Equations," J.
Chromatography A, vol. 779, 287-297, 1997.
[21] E.Tudor, and D. Moldovan, "Temperature dependence of the retention
index for perfumery compounds on a SE - 30 glass capillary column
II. The hyperbolic equation," J. Chromatography A, vol. 848, pp. 215-
227, 1999.
[22] C. S. Lee, and W. J. Cheong, "Thermodynamic properties for the solute
transfer from the mobile to the stationary phase in reversed phase
liquid chromatography obtained by squalane - impregnated C18 bonded
phase," J. Chromatography A, vol. 848, pp. 9-20. 1999; 848.
[23] M. Makela, and L. Pyy, "Effect of temperature on the retention time
reproducibility and on the use of programmable fluorescence detection
of fifteen polycyclic aromatic hydrocarbons," J. Chromatography A,
vol. 699, pp. 49-57, 1995.
[24] E. Muzenda, M. Belaid and F. Ntuli, "Measurement of infinite dilution
activity coefficients of selected environmentally important volatile
organic compounds in polydimethylsiloxane using gas - liquid
chromatography," Korean Journal of Chemical Engineering, Received
14 August 2009, Accepted 6 February 2010, First online 4 August 2010.
pp 1.4.4
[1] E. Muzenda, A. Arrowsmith, M. Belaid and F. Ntuli, "Temperature
dependence of specific retention volumes of environmentally important
VOCs using GLC", in Proc. ISEEE 09, Rayong, 2009
[2] E. Muzenda, M. Belaid and F. Ntuli, "Influence of temperature on
specific retention volumes of environmentally important VOCs,
EnvironmentAsia, Accepted for Publication, February 2010.
[3] E. Muzenda, A. Arrowsmith, and N. Ashton, "Study of the Effects of
Experimental Variables in Solute Retention Volumes by Gas Liquid
Chromatogrphy (glc) in Polymer Solution Thermodynamics," in Proc.
CHEMCON, Chandigarh, December 2008.
[4] E. Muzenda, M. Belaid, F. Ntuli, and A. Arrowsmith, "Absorption of
Volatile Organic Compounds in Silicon: Determination of Infinite
Dilution Activity Coefficients by Dynamic Gas Liquid
Chromatographic Technique," in Proc. The 8th WCCE 2009, Montreal,
August 2009.
[5] A. B. Littlewood, C. S. G. Phillips, and D. T. Price, "The
Chromatography of gases and vapours Part V: Partition analysis with
columns of Silicone 702 and Tritolylphosphate," J. Chemical Soc., pp.
1480, 1955.
[6] R. N. Lichtenthaler, R.D. Newman, and J. M. Prausnitz, "Specific
retention volumes from Gas - Liquid Chromatography for
Polydimethylsiloxane Hydrocarbon Systems," Macromolecules, vol. 4,
no. 4, pp 650-651, 1973.
[7] W. R. Summers, Y. B. Tewari, and H. P. Schreiber, "Thermodynamic
Interaction in Polydimethysiloxane - hydrocarbon Systems from Gas -
Liquid Chromatography," Macromolecules, vol. 5, no. 1, pp. 11 - 16,
1972.
[8] A. J. Ashworth, C. F. Chien, D. L. Furio, D. M. Hooker, M. M. Kopecni,
R.J. Laub, and G. J. Price, "Comparison of static with gaschromatographic
solute infinite-dilution activity coefficients with
polydimethylsiloxane solvent," Macromolecules, vol. 17, no. 5, pp.
1090 - 1094, 1984.
[9] K. Heberger, M. Gorgenyi, and T. Kowalska, "Temperature dependence
of Kovats indices in gas chromatography revisited," J. Chromatography
A, vol. 973, pp. 135-142.
[10] K. B. Sentell, N. I. Ryan, and A. N. Henderson, "Temperature and
salvation effects on homologous series selectivity in reversed phase
liquid chromatography," Analytical Chimica Acta, vol. 203- 215, 1995.
[11] E. Muzenda, A. Arrowsmith, and N. Ashton, "Ashton N, "Infinite
dilution activity coefficients for VOCs in polydimethylsiloxane," in
Proc. IChemE 2000, Bath, January 2000.
[12] E. Muzenda, A. Arrowsmith, and N. Ashton, "Ashton N, "GLC as an
optimization technique," in Proc. 5th International Conference on
Manufacturing Process Systems and Operations Management in Less
Industrialised Regions, Bulawayo, 2002.
[13] E. Muzenda, A. Arrowsmith, and N. Ashton, "Measurement of Infinite
Dilution Activity Coefficients for Volatile Organic Compounds in
Polydimethylsiloxane by Gas Liquid Chromatography," in Proc.
CHEMCON, Chandigarh, December 2008.
[14] H. Purnell, Gas Chromatography, John Willey and sons, 1962.
[15] D. D. Deshpande, D. Patterson, H. P. Schreiber, and C. S. Su,
"Thermodynamic Interactions in Polymer Systems by Gas - Liquid
Chromatography. IV. Interactions between Components in a Mixed
Stationary Phase," Macromolecules, vol. 7, no. 4, pp. 530-535, 1974.
[16] O. Smidsrod, J. E. Guillet, "Study of polymer interactions by gas
chromatography," Macromolecules, vol. 2, pp. 272, 1969.
[17] B. Sellergren, and J. H. Shea, "Origin of peak asymmetry and the effect
of temperature on the solute retention in enantiomer separations on
imprinted chiral stationary phases," J. Chromatography A, vol. 690, pp.
29-39, 1995.
[18] K. Bay, H. Wanko, and J. Ulrich, "Absorption of Volatile Organic
Compounds in Biodisel: Determination of Infinite Dilution Activity
Coefficients by Headspace Gas Chromatography," Inst. Chem. Eng.
Trans IChemE, vol. 84, no. A1, pp. 22-28, 2006.
[19] U. Domanska, and A. Marciniak, "Measurements of activity coefficients
at infinite dilution of aromatic and aliphatic hydrocarbons, alcohols,
and water in the new ionic liquid (EMIM)(SCN) using GLC," J.
Chemical Thermo., vol. 40, pp. 860-866, 2008.
[20] E. Tudor, "Temperature dependence of the retention index for perfumery
compounds on a SE - 30 glass capillary column I. Linear Equations," J.
Chromatography A, vol. 779, 287-297, 1997.
[21] E.Tudor, and D. Moldovan, "Temperature dependence of the retention
index for perfumery compounds on a SE - 30 glass capillary column
II. The hyperbolic equation," J. Chromatography A, vol. 848, pp. 215-
227, 1999.
[22] C. S. Lee, and W. J. Cheong, "Thermodynamic properties for the solute
transfer from the mobile to the stationary phase in reversed phase
liquid chromatography obtained by squalane - impregnated C18 bonded
phase," J. Chromatography A, vol. 848, pp. 9-20. 1999; 848.
[23] M. Makela, and L. Pyy, "Effect of temperature on the retention time
reproducibility and on the use of programmable fluorescence detection
of fifteen polycyclic aromatic hydrocarbons," J. Chromatography A,
vol. 699, pp. 49-57, 1995.
[24] E. Muzenda, M. Belaid and F. Ntuli, "Measurement of infinite dilution
activity coefficients of selected environmentally important volatile
organic compounds in polydimethylsiloxane using gas - liquid
chromatography," Korean Journal of Chemical Engineering, Received
14 August 2009, Accepted 6 February 2010, First online 4 August 2010.
pp 1.4.4
@article{"International Journal of Chemical, Materials and Biomolecular Sciences:51201", author = "Edison Muzenda and Ayo S. Afolabi", title = "Effect of Temperature on Specific Retention Volumes of Selected Volatile Organic Compounds Using the Gas - Liquid Chromatographic Technique Revisited", abstract = "This paper is a continuation of our interest in the influence of temperature on specific retention volumes and the resulting infinite dilution activity coefficients. This has a direct effect in the design of absorption and stripping columns for the abatement of volatile organic compounds. The interaction of 13 volatile organic compounds (VOCs) with polydimethylsiloxane (PDMS) at varying temperatures was studied by gas liquid chromatography (GLC). Infinite dilution activity coefficients and specific retention volumes obtained in this study were found to be in agreement with those obtained from static headspace and group contribution methods by the authors as well as literature values for similar systems. Temperature variation also allows for transport calculations for different seasons. The results of this work confirm that PDMS is well suited for the scrubbing of VOCs from waste gas streams. Plots of specific retention volumes against temperature gave linear van-t Hoff plots.
", keywords = "Specific retention volume, Waste gas streams,specific retention, infinite dilution, abatement, transport.", volume = "4", number = "9", pages = "549-5", }
