Abstract: Fluidized bed reactors are known as highly exothermic and endothermic according to uniformity in temperature as a safe and effective mean for catalytic reactors. In these reactors, a wide range of catalyst particles can be used and by using a continuous operation proceed to produce in succession. Providing optimal conditions for the operation of these types of reactors will prevent the exorbitant costs necessary to carry out laboratory work. In this regard, a hydrodynamic analysis was carried out with heat transfer in the solid-gas fluidized bed reactor for solar thermal applications. The results showed that in the fluid flow the input of the reactor has a lower temperature than the outlet, and when the fluid is passing from the reactor, the heat transfer happens between cylinder and solar panel and fluid. It increases the fluid temperature in the outlet pump and also the kinetic energy of the fluid has been raised in the outlet areas.
Abstract: Combustion of biomass is a promising alternative to reduce the high pollutant emission levels associated to the combustion of fossil flues due to the net null emission of CO2 attributed to biomass. However, the biomass selected should also have low contents of nitrogen and sulfur to limit the NOx and SOx emissions derived from its combustion. In this sense, olive stone is an excellent fuel to power combustion reactors with reduced levels of pollutant emissions. In this work, the combustion of olive stone particles is analyzed experimentally in a thermogravimetric analyzer (TGA) and in a bubbling fluidized bed reactor (BFB). The bubbling fluidized bed reactor was installed over a scale, conforming a macro-TGA. In both equipment, the evolution of the mass of the samples was registered as the combustion process progressed. The results show a much faster combustion process in the bubbling fluidized bed reactor compared to the thermogravimetric analyzer measurements, due to the higher heat transfer coefficient and the abrasion of the fuel particles by the bed material in the BFB reactor.
Abstract: In this experimental study, effects of addition of rice husk on coal gasification in a bubbling fluidized bed gasifier, operating at atmospheric pressure with air as gasifying agent, are reported. Rice husks comprising of 6.5% and 13% by mass are added to coal. Results show that, when rice husk is added the methane yield increases from volumetric percentage of 0.56% (with no rice husk) to 2.77% (with 13% rice husk). CO and H2 remain almost unchanged and CO2 decreases with addition of rice husk. The calorific value of the synthetic gas is around 2.73 MJ/Nm3. All performance indices, such as cold gas efficiency and carbon conversion, increase with addition of rice husk.
Abstract: Computational fluid dynamics analysis of the burning
of syngas fuels derived from biomass and plastic solid waste mixture
through gasification process is presented in this paper. The syngas
fuel is burned in gas turbine can combustor. Gas turbine can
combustor with swirl is designed to burn the fuel efficiently and
reduce the emissions. The main objective is to test the impact of the
alternative syngas fuel compositions and lower heating value on the
combustion performance and emissions. The syngas fuel is produced
by blending palm kernel shell (PKS) with polyethylene (PE) waste
via catalytic steam gasification (fluidized bed reactor). High
hydrogen content syngas fuel was obtained by mixing 30% PE waste
with PKS. The syngas composition obtained through the gasification
process is 76.2% H2, 8.53% CO, 4.39% CO2 and 10.90% CH4. The
lower heating value of the syngas fuel is LHV = 15.98 MJ/m3. Three
fuels were tested in this study natural gas (100%CH4), syngas fuel
and pure hydrogen (100% H2). The power from the combustor was
kept constant for all the fuels tested in this study. The effect of syngas
fuel composition and lower heating value on the flame shape, gas
temperature, mass of carbon dioxide (CO2) and nitrogen oxides
(NOX) per unit of energy generation is presented in this paper. The
results show an increase of the peak flame temperature and NO mass
fractions for the syngas and hydrogen fuels compared to natural gas
fuel combustion. Lower average CO2 emissions at the exit of the
combustor are obtained for the syngas compared to the natural gas
fuel.
Abstract: In this research a mathematical model for direct
oxidization of hydrogen sulfide into elemental sulfur in a fluidized
bed reactor with external circulation was developed. As the catalyst
is deactivated in the fluidized bed, it might be placed in a reduction
tank in order to remove sulfur through heating above its dew point.
The reactor model demonstrated via MATLAB software. It was
shown that variations of H2S conversion as well as; products formed
were reasonable in comparison with corresponding results of a fixed
bed reactor. Through analyzing results of this model, it became
possible to propose the main optimized operating conditions for the
process considered. These conditions included; the temperature range
of 100-130ºC and utilizing the catalyst as much as possible providing
the highest bed density respect to dimensions of bed, economical
aspects that the bed ever remained in fluidized mode. A high active
and stable catalyst under the optimum conditions exhibited 100%
conversion in a fluidized bed reactor.
Abstract: In a pilot plant scale of a fluidized bed reactor, a
reduction reaction of sodium sulfate by natural gas has been
investigated. Natural gas is applied in this study as a reductant. Feed
density, feed mass flow rate, natural gas and air flow rate
(independent parameters)and temperature of bed and CO
concentration in inlet and outlet of reactor (dependent parameters)
were monitored and recorded at steady state. The residence time was
adjusted close to value of traditional reaction [1]. An artificial neural
network (ANN) was established to study dependency of yield and
carbon gradient on operating parameters. Resultant 97% accuracy of
applied ANN is a good prove that natural gas can be used as a
reducing agent. Predicted ANN model for relation between other
sources carbon gradient (accuracy 74%) indicates there is not a
meaningful relation between other sources carbon variation and
reduction process which means carbon in granule does not have
significant effect on the reaction yield.
Abstract: In this research, heat transfer of a poly Ethylene
fluidized bed reactor without reaction were studied experimentally
and computationally at different superficial gas velocities. A multifluid
Eulerian computational model incorporating the kinetic theory
for solid particles was developed and used to simulate the heat
conducting gas–solid flows in a fluidized bed configuration.
Momentum exchange coefficients were evaluated using the Syamlal–
O-Brien drag functions. Temperature distributions of different phases
in the reactor were also computed. Good agreement was found
between the model predictions and the experimentally obtained data
for the bed expansion ratio as well as the qualitative gas–solid flow
patterns. The simulation and experimental results showed that the gas
temperature decreases as it moves upward in the reactor, while the
solid particle temperature increases. Pressure drop and temperature
distribution predicted by the simulations were in good agreement
with the experimental measurements at superficial gas velocities
higher than the minimum fluidization velocity. Also, the predicted
time-average local voidage profiles were in reasonable agreement
with the experimental results. The study showed that the
computational model was capable of predicting the heat transfer and
the hydrodynamic behavior of gas-solid fluidized bed flows with
reasonable accuracy.
Abstract: New design of a grid for preparation of high density
granules with enhanced mechanical strength by granulation of
dispersed materials is suggested.
A method for hydrodynamic dimensioning of the grid depending
on granulation conditions, hydrodynamic regime of the operation,
dispersity and physicochemical characteristics of the materials to be
granulated was suggested.
The aim of the grid design is to solve the problems arising by the
granulation of disperse materials.
Abstract: Methanol-to-olefins (MTO) coupled with
transformation of coal or natural gas to methanol gives an interesting
and promising way to produce ethylene and propylene. To investigate
solid concentration in gas-solid fluidized bed for methanol-to-olefins
process catalyzed by SAPO-34, a cold model experiment system is
established in this paper. The system comprises a gas distributor in a
300mm internal diameter and 5000mm height acrylic column, the
fiber optic probe system and series of cyclones. The experiments are
carried out at ambient conditions and under different superficial gas
velocity ranging from 0.3930m/s to 0.7860m/s and different initial bed
height ranging from 600mm to 1200mm. The effects of radial
distance, axial distance, superficial gas velocity, initial bed height on
solid concentration in the bed are discussed. The effects of distributor
shape and porosity on solid concentration are also discussed. The
time-averaged solid concentration profiles under different conditions
are obtained.
Abstract: The production of glass, ceramic materials and many non-ferrous metals (Zn, Cu, Pb, etc.), ferrous metals (pig iron) and others is connected with the use of a considerable number of initial solid raw materials. Before carrying out the basic technological processes (oxidized roasting, melting, agglomeration, baking) it is necessary to mix and homogenize the raw materials that have different chemical and phase content, granulometry and humidity. For this purpose zinc sulfide concentrates differing in origin are studied for their more complete characteristics using chemical, X-ray diffraction analyses, DTA and TGA as well as Mössbauer spectroscopy. The phases established in most concentrates are: β-ZnS, mZnS.nFeS, FeS2, CuFeS2, PbS, SiO2 (α-quartz). With the help of the developed by us a Web-based information system for a continued period of time different mix proportions from zinc concentrates are calculated and used in practice (roasting in fluidized bed reactor), which have to conform to the technological requirements of the zinc hydrometallurgical technological scheme.