Abstract: The present study examines the adsorption of phenol, 3-nitrophenol and dyes (methylene blue, alizarine yellow), from aqueous solutions onto a commercial activated carbon. Two different operations, semi-batch and continuous with reflux, were applied. The commercial activated carbon exhibits high adsorption abilities for phenol, 3-nitrophenol and dyes (methylene blue and alizarin yellow) from their aqueous solutions. The adsorption of all adsorbates after 1 h is higher by the continuous operation with reflux than by the semibatch operation. The adsorption of phenol is higher than that of 3-nitrophenol for both operations. Similarly, the adsorption of alizarin yellow is higher than that of methylene blue for both operations. The regenerated commercial activated carbon regains its adsorption ability due to the removal of the adsorbate from its pores during the regeneration.
Abstract: The quantified residence time distribution (RTD)
provides a numerical characterization of mixing in a reactor, thus
allowing the process engineer to better understand mixing
performance of the reactor.This paper discusses computational
studies to investigate flow patterns in a two impinging streams
cyclone reactor(TISCR) . Flow in the reactor was modeled with
computational fluid dynamics (CFD). Utilizing the Eulerian-
Lagrangian approach, implemented in FLUENT (V6.3.22), particle
trajectories were obtained by solving the particle force balance
equations. From simulation results obtained at different Δts, the mean
residence time (tm) and the mean square deviation (σ2) were
calculated. a good agreement can be observed between predicted and
experimental data. Simulation results indicate that the behavior of
complex reactor systems can be predicted using the CFD technique
with minimum data requirement for validation.
Abstract: The Ni/α-Al2O3 catalysts with different amounts of La
as promoter from 0 to 4 wt % were prepared, characterized and their
catalytic activity was investigated in syngas methanation reaction.
Effects of reaction temperature and lanthanum loading on carbon
oxides conversion and methane selectivity were also studied. Adding
certain amount of lanthanum to 10Ni /α-Al2O3 catalysts can decrease
the average NiO crystallite diameter which leads to higher activity and
stability while excessive addition would cause deactivation quickly.
Stability on stream towards deactivation was observed up to 800 min
at 500 °C, 0.1MPa and 600000 mL·g-1·h-1.
Abstract: Carbon dioxide capture process has been simulated
and studied under different process conditions. It has been shown
that several process parameters such as lean amine temperature,
number of adsorber stages, number of stripper stages and stripper
pressure affect different process conditions and outputs such as
carbon dioxide removal and reboiler duty. It may be concluded that
the simulation of carbon dioxide capture process can help to estimate
the best process conditions.
Abstract: In this work, statistical experimental design was
applied for the optimization of medium constituents for Gentamicin
production by Micromsonospora echinospora subs pallida (MTCC
708) in a batch reactor and the results are compared with the ANN
predicted values. By central composite design, 50 experiments are
carried out for five test variables: Starch, Soya bean meal, K2HPO4,
CaCO3 and FeSO4. The optimum condition was found to be: Starch
(8.9,g/L), Soya bean meal (3.3 g/L), K2HPO4 (0.8 g/L), CaCO3 (4
g/L) and FeSO4 (0.03 g/L). At these optimized conditions, the yield
of gentamicin was found to be 1020 mg/L. The R2 values were found
to be 1 for ANN training set, 0.9953 for ANN test set, and 0.9286 for
RSM.
Abstract: Design of Converter transformer insulation is a major
challenge. The insulation of these transformers is stressed by both
AC and DC voltages. Particle contamination is one of the major
problems in insulation structures, as they generate partial discharges
leading it to major failure of insulation. Similarly corona discharges
occur in transformer insulation. This partial discharge due to particle
movement / corona formation in insulation structure under different
voltage wave shapes, are different. In the present study, UHF
technique is adopted to understand the discharge activity and could
be realized that the characteristics of UHF signal generated under
low and high fields are different. In the case of corona generated
signal, the frequency content of the UHF sensor output lies in the
range 0.3-1.2 GHz and is not much varied except for its increase in
magnitude of discharge with the increase in applied voltage. It is
realized that the current signal injected due to partial
discharges/corona is about 4ns duration measured for first one half
cycle. Wavelet technique is adopted in the present study. It allows
one to identify the frequency content present in the signal at different
instant of time. The STD-MRA analysis helps one to identify the
frequency band in which the energy content of the UHF signal is
maximum.
Abstract: Electrochemical-oxidation of Reactive Black-5 (RB- 5) was conducted for degradation using DSA type Ti/RuO2-SnO2- Sb2O5 electrode. In the study, for electro-oxidation, electrode was indigenously fabricated in laboratory using titanium as substrate. This substrate was coated using different metal oxides RuO2, Sb2O5 and SnO2 by thermal decomposition method. Laboratory scale batch reactor was used for degradation and decolorization studies at pH 2, 7 and 11. Current density (50mA/cm2) and distance between electrodes (8mm) were kept constant for all experiments. Under identical conditions, removal of color, COD and TOC at initial pH 2 was 99.40%, 55% and 37% respectively for initial concentration of 100 mg/L RB-5. Surface morphology and composition of the fabricated electrode coatings were characterized using scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDX) respectively. Coating microstructure was analyzed by X-ray diffraction (XRD). Results of this study further revealed that almost 90% of oxidation occurred within 5-10 minutes.
Abstract: Determination of wellbore problems during a
production/injection process might be evaluated thorough
temperature log analysis. Other applications of this kind of log
analysis may also include evaluation of fluid distribution analysis
along the wellbore and identification of anomalies encountered
during production/injection process. While the accuracy of such
prediction is paramount, the common method of determination of a
wellbore temperature log includes use of steady-state energy balance
equations, which hardly describe the real conditions as observed in
typical oil and gas flowing wells during production operation; and
thus increase level of uncertainties. In this study, a practical method
has been proposed through development of a simplified semianalytical
model to apply for predicting temperature profile along the
wellbore. The developed model includes an overall heat transfer
coefficient accounting all modes of heat transferring mechanism,
which has been focused on the prediction of a temperature profile as
a function of depth for the injection/production wells. The model has
been validated with the results obtained from numerical simulation.
Abstract: Two novel hydrodesulfurization (HDS) catalysts:
FeN4/C and FeN2/C, were prepared using an impregnation-pyrolysis
method. The two materials were investigated as catalysts for
hydrodesulfurization (HDS) and hydrodearomitization (HDA) of
model compounds. The turnover frequency of the two FeN catalysts
is comparable to (FeN4/C) or even higher (FeN2/C) than that of
MoNi/Al2O3. The FeN4/C catalyst also exhibited catalytic activity
toward HDA.
Abstract: Direct fermentation of 226 white rose tapioca stem to
ethanol by Fusarium oxysporum was studied in a batch reactor.
Fermentation of ethanol can be achieved by sequential pretreatment
using dilute acid and dilute alkali solutions using 100 mesh tapioca
stem particles. The quantitative effects of substrate concentration, pH
and temperature on ethanol concentration were optimized using a full
factorial central composite design experiment. The optimum process
conditions were then obtained using response surface methodology.
The quadratic model indicated that substrate concentration of 33g/l,
pH 5.52 and a temperature of 30.13oC were found to be optimum for
maximum ethanol concentration of 8.64g/l. The predicted optimum
process conditions obtained using response surface methodology was
verified through confirmatory experiments. Leudeking-piret model
was used to study the product formation kinetics for the production
of ethanol and the model parameters were evaluated using
experimental data.
Abstract: The mesoporous MoO3/γ-Al2O3 catalyst was prepared
by incipient wetness impregnation method aiming to investigate the
effect of drying method and molybdenum content on the catalyst
property and performance towards the oxidation of benzothiophene
(BT), dibenzothiophene (DBT) and 4,6-dimethyle dibenzothiophene
(4,6-DMDBT) with H2O2 for deep oxidative desulfurization of diesel
fuel. The catalyst was characterized by XRD, BET, BJH and SEM
method. The catalyst with 10wt.% and 15wt.% Mo content represent
same optimum performance for DBT and 4,6-DMDBT removal, but
a catalyst with 10wt.% Mo has higher efficiency than 15wt.% Mo for
BT conversion. The SEM images show that use of rotary evaporator
in drying step reaches a more homogenous impregnation. The
oxidation reactivity of different sulfur compounds was studied which
followed the order of DBT>4,6-DMDBT>>BT.
Abstract: Solutions are proposed for the central problem of estimating the reaction rate coefficients in homogeneous kinetics. The first is based upon the fact that the right hand side of a kinetic differential equation is linear in the rate constants, whereas the second one uses the technique of neural networks. This second one is discussed deeply and its advantages, disadvantages and conditions of applicability are analyzed in the mirror of the first one. Numerical analysis carried out on practical models using simulated data, and our programs written in Mathematica.
Abstract: This paper reports the influence of sucrose on the
preservation of CO2 hydrate crystal samples. The particle diameter of
hydrate samples were 1.0 and 5.6-8.0 mm. Mass fraction of sucrose in
the sample was 0.16. The samples were stored at the aerated condition
under atmospheric pressure and at the temperature of 253 or 258 K.
The results indicated that the mass fractions of CO2 hydrate in the
samples with sucrose were 0.10 ± 0.03 at the end of 3-week
preservation, regardless of temperature and particle diameter. Mass
fraction of CO2 hydrate in the samples with sucrose was higher than
that of pure CO2 hydrate for 1.0 mm particle diameter, while was
lower than that of pure CO2 hydrate for 5.6-8.0 mm particle diameter.
Discussion is made on the influence of sucrose on the dissociation of
CO2 hydrate and the resulting formation of ice.
Abstract: In this paper we present discretization and decomposition methods for a multi-component transport model of a chemical vapor deposition (CVD) process. CVD processes are used to manufacture deposition layers or bulk materials. In our transport model we simulate the deposition of thin layers. The microscopic model is based on the heavy particles, which are derived by approximately solving a linearized multicomponent Boltzmann equation. For the drift-process of the particles we propose diffusionreaction equations as well as for the effects of heat conduction. We concentrate on solving the diffusion-reaction equation with analytical and numerical methods. For the chemical processes, modelled with reaction equations, we propose decomposition methods and decouple the multi-component models to simpler systems of differential equations. In the numerical experiments we present the computational results of our proposed models.
Abstract: Excilamps are new UV sources with great potential
for application in wastewater treatment. In the present work, a XeBr
excilamp emitting radiation at 283 nm has been used for the
photodegradation of 4-chlorophenol within a range of concentrations
from 50 to 500 mg L-1. Total removal of 4-chlorophenol was
achieved for all concentrations assayed. The two main photoproduct
intermediates formed along the photodegradation process,
benzoquinone and hydroquinone, although not being completely
removed, remain at very low residual concentrations. Such
concentrations are insignificant compared to the 4-chlorophenol
initial ones and non-toxic. In order to simulate the process and scaleup,
a kinetic model has been developed and validated from the
experimental data.
Abstract: There is growing interest in biodiesel (fatty acid
methyl ester or FAME) because of the similarity in its properties
when compared to those of diesel fuels. Diesel engines operated on
biodiesel have lower emissions of carbon monoxide, unburned
hydrocarbons, particulate matter, and air toxics than when operated
on petroleum-based diesel fuel. Production of fatty acid methyl ester
(FAME) from rapeseed (nonedible oil) fatty acid distillate having
high free fatty acids (FFA) was investigated in this work. Conditions
for esterification process of rapeseed oil were 1.8 % H2SO4 as
catalyst, MeOH/oil of molar ratio 2 : 0.1 and reaction temperature
65 °C, for a period of 3h. The yield of methyl ester was > 90 % in 1
h.
The amount of FFA was reduced from 93 wt % to less than 2 wt %
at the end of the esterification process. The FAME was pureed by
neutralization with 1 M sodium hydroxide in water solution at a
reaction temperature of 62 °C. The final FAME product met with the
biodiesel quality standard, and ASTM D 6751.
Abstract: The objective of this research is to examine the shear thinning behaviour of mixing flow of non-Newtonian fluid like toothpaste in the dissolution container with rotating stirrer. The problem under investigation is related to the chemical industry. Mixing of fluid is performed in a cylindrical container with rotating stirrer, where stirrer is eccentrically placed on the lid of the container. For the simulation purpose the associated motion of the fluid is considered as revolving of the container, with stick stirrer. For numerical prediction, a time-stepping finite element algorithm in a cylindrical polar coordinate system is adopted based on semi-implicit Taylor-Galerkin/pressure-correction scheme. Numerical solutions are obtained for non-Newtonian fluids employing power law model. Variations with power law index have been analysed, with respect to the flow structure and pressure drop.
Abstract: Nowadays, butyl acetate, a pineapple flavor has been applied widely in food, beverage, cosmetic and pharmaceutical industries. In this study, Butyl acetate, a flavor ester was successfully synthesized via green synthesis of enzymatic reaction route. Commercial immobilized lipase from Rhizomucor miehei (Lipozyme RMIM) was used as biocatalyst in the esterification reaction between acetic acid and butanol. Various reaction parameters such as reaction time (RT), temperature (T) and amount of enzyme (E) were chosen to optimize the reaction synthesis in solvent-free system. The optimum condition to produce butyl acetate was at reaction time (RT), 18 hours; temperature (T), 37°C and amount of enzyme, 25 % (w/w of total substrate). Analysis of yield showed that at optimum condition, >78 % of butyl acetate was produced. The product was confirmed as butyl acetate from FTIR analysis whereby the presence of an ester group was observed at wavenumber of 1742 cm-1.
Abstract: Simultaneous effects of temperature, immersion time, salt concentration, sucrose concentration, pressure and convective dryer temperature on the combined osmotic dehydration - convective drying of edible button mushrooms were investigated. Experiments were designed according to Central Composite Design with six factors each at five different levels. Response Surface Methodology (RSM) was used to determine the optimum processing conditions that yield maximum water loss and rehydration ratio and minimum solid gain and shrinkage in osmotic-convective drying of edible button mushrooms. Applying surfaces profiler and contour plots optimum operation conditions were found to be temperature of 39 °C, immersion time of 164 min, salt concentration of 14%, sucrose concentration of 53%, pressure of 600 mbar and drying temperature of 40 °C. At these optimum conditions, water loss, solid gain, rehydration ratio and shrinkage were found to be 63.38 (g/100 g initial sample), 3.17 (g/100 g initial sample), 2.26 and 7.15%, respectively.
Abstract: In this research, CaO-ZnO catalysts (with various
Ca:Zn atomic ratios of 1:5, 1:3, 1:1, and 3:1) prepared by incipientwetness
impregnation (IWI) and co-precipitation (CP) methods were
used as a catalyst in the transesterification of palm oil with methanol
for biodiesel production. The catalysts were characterized by several
techniques, including BET method, CO2-TPD, and Hemmett
Indicator. The effects of precursor concentration, and calcination
temperature on the catalytic performance were studied under reaction
conditions of a 15:1 methanol to oil molar ratio, 6 wt% catalyst,
reaction temperature of 60°C, and reaction time of 8 h. At Ca:Zn
atomic ratio of 1:3 gave the highest FAME value owing to a basic
properties and surface area of the prepared catalyst.