Abstract: Simultaneous determination of multicomponents of phenol, resorcinol and catechol with a chemometric technique a PCranking artificial neural network (PCranking-ANN) algorithm is reported in this study. Based on the data correlation coefficient method, 3 representative PCs are selected from the scores of original UV spectral data (35 PCs) as the original input patterns for ANN to build a neural network model. The results obtained by iterating 8000 .The RMSEP for phenol, resorcinol and catechol with PCranking- ANN were 0.6680, 0.0766 and 0.1033, respectively. Calibration matrices were 0.50-21.0, 0.50-15.1 and 0.50-20.0 μg ml-1 for phenol, resorcinol and catechol, respectively. The proposed method was successfully applied for the determination of phenol, resorcinol and catechol in synthetic and water samples.
Abstract: The quantified residence time distribution (RTD)
provides a numerical characterization of mixing in a reactor, thus
allowing the process engineer to better understand mixing
performance of the reactor.This paper discusses computational
studies to investigate flow patterns in a two impinging streams
cyclone reactor(TISCR) . Flow in the reactor was modeled with
computational fluid dynamics (CFD). Utilizing the Eulerian-
Lagrangian approach, implemented in FLUENT (V6.3.22), particle
trajectories were obtained by solving the particle force balance
equations. From simulation results obtained at different Δts, the mean
residence time (tm) and the mean square deviation (σ2) were
calculated. a good agreement can be observed between predicted and
experimental data. Simulation results indicate that the behavior of
complex reactor systems can be predicted using the CFD technique
with minimum data requirement for validation.