Abstract: The mesoporous MoO3/γ-Al2O3 catalyst was prepared
by incipient wetness impregnation method aiming to investigate the
effect of drying method and molybdenum content on the catalyst
property and performance towards the oxidation of benzothiophene
(BT), dibenzothiophene (DBT) and 4,6-dimethyle dibenzothiophene
(4,6-DMDBT) with H2O2 for deep oxidative desulfurization of diesel
fuel. The catalyst was characterized by XRD, BET, BJH and SEM
method. The catalyst with 10wt.% and 15wt.% Mo content represent
same optimum performance for DBT and 4,6-DMDBT removal, but
a catalyst with 10wt.% Mo has higher efficiency than 15wt.% Mo for
BT conversion. The SEM images show that use of rotary evaporator
in drying step reaches a more homogenous impregnation. The
oxidation reactivity of different sulfur compounds was studied which
followed the order of DBT>4,6-DMDBT>>BT.